CN106437653B - A kind of hydrate exploitation and the carbon dioxide sequestration integrated processes of note quick lime and carbon dioxide process - Google Patents
A kind of hydrate exploitation and the carbon dioxide sequestration integrated processes of note quick lime and carbon dioxide process Download PDFInfo
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- CN106437653B CN106437653B CN201610859725.5A CN201610859725A CN106437653B CN 106437653 B CN106437653 B CN 106437653B CN 201610859725 A CN201610859725 A CN 201610859725A CN 106437653 B CN106437653 B CN 106437653B
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- carbon dioxide
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 110
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 55
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 55
- 239000000292 calcium oxide Substances 0.000 title claims abstract description 54
- 235000012255 calcium oxide Nutrition 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000009919 sequestration Effects 0.000 title claims abstract description 15
- 238000002347 injection Methods 0.000 claims abstract description 31
- 239000007924 injection Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical compound C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 claims abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005553 drilling Methods 0.000 claims abstract description 7
- 238000004321 preservation Methods 0.000 claims abstract description 4
- 238000000926 separation method Methods 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 150000004677 hydrates Chemical class 0.000 abstract description 4
- VTVVPPOHYJJIJR-UHFFFAOYSA-N carbon dioxide;hydrate Chemical compound O.O=C=O VTVVPPOHYJJIJR-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000243 solution Substances 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MVWDJLOUEUAWIE-UHFFFAOYSA-N O=C=O.O=C=O Chemical compound O=C=O.O=C=O MVWDJLOUEUAWIE-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B41/00—Equipment or details not covered by groups E21B15/00 - E21B40/00
- E21B41/0099—Equipment or details not covered by groups E21B15/00 - E21B40/00 specially adapted for drilling for or production of natural hydrate or clathrate gas reservoirs; Drilling through or monitoring of formations containing gas hydrates or clathrates
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/82—Solid phase processes with stationary reactants
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/164—Injecting CO2 or carbonated water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
The present invention provides the hydrate exploitation of a kind of note quick lime and carbon dioxide process and carbon dioxide sequestration integrated processes.It is target target area to choose hydrate preservation region, carries out quick lime and carbon dioxide injection well and gas-producing well drilling well;From quick lime and carbon dioxide injection well quick lime filling area is formed to hydrate layer injection quick lime;After quick lime reacts completely with the water in hydrate layer, carbon dioxide is injected from quick lime and carbon dioxide injection well;Gas-producing well outlet pressure is controlled, aerogenesis pressure is made to be more than the corresponding carbon dioxide hydrate vapor pressure of hydrate layer temperature, is less than the corresponding methane hydrate vapor pressure of hydrate layer temperature;Methane gas is collected in gas-producing well well head.The present invention realizes the safety and high efficiency of hydrate, and the environmental problems such as hydrate layer strength reduction, stratum unstability, have reached sequestration of carbon dioxide, mitigated the purpose of greenhouse effects during effective solution exploitation of gas hydrates.
Description
Technical field
The present invention relates to it is a kind of note quick lime and carbon dioxide process hydrate exploitation and carbon dioxide sequestration integrated processes,
Belong to new energy and field of new materials.
Background technology
With the development of the social economy, total energy consumption is continuously increased, traditional energy is increasingly reduced, and various countries provide the energy
The contention in source is increasingly fierce, and various countries gradually start to pay attention to the development and utilization of new energy.Wherein, gas hydrates have huge
Resource potential.In recent years, much the country of more early researching natural gas hydrate has further spread out to its production technique, exploitation
The researchs such as the environmental problem faced.Traditional gas hydrate mining methods have heat injection method, voltage drop method and note chemical reagent
Method, but defect, heat injection method energy consumption is big, efficiency of utilization is low, and voltage drop method has special want to gas hydrates property
It asks, note chemical-agent technique can bring some environmental problems etc..Three kinds of methods are all based on the principle for decomposing hydrate, can cause water
Nitride layer strength reduction is closed, the environmental problems such as stratum unstability are further caused.
Simultaneously as a large amount of uses of fossil fuel, cause huge carbon emission, the greenhouse effects of the earth are caused,
Cause Global Temperature to increase, a series of adverse effects are produced to mankind's activity and ball ecological environment.Therefore, carbon dioxide seals
It is considered as the effective way for mitigating greenhouse effects to deposit.Existing carbon dioxide sequestration method is mainly with chemical reaction method and geology
Based on sealing up for safekeeping.But chemical reaction method can consume a large amount of chemical raw materials, and the reaction product processing generated is a great problem, geology
The method of sealing up for safekeeping has carbon dioxide leakage, does not tackle the problem at its root.
Invention content
For the deficiency of prior art, the present invention provides the hydrate exploitation of a kind of note quick lime and carbon dioxide process and
Carbon dioxide sequestration integrated processes, its object is to realize hydrate safety and high efficiency, solve hydrate recovery process in
Layer destabilization problems and the excessively high problem of water yield, and sequestration of carbon dioxide mitigates greenhouse effects.
Technical scheme of the present invention:
A kind of hydrate exploitation and the carbon dioxide sequestration integrated processes of note quick lime and carbon dioxide process, steps are as follows:
(1) it is target target area to utilize high-resolution multichannel seismic exploration method to choose sea bottom hydrate preservation region, is carried out
Quick lime and carbon dioxide injection well and gas-producing well drilling well, quick lime and the bottom of carbon dioxide injection well and gas-producing well are non-
It permeates between top lithosphere and impermeable lower part lithosphere, quick lime and carbon dioxide injection bottom are filled for quick lime
Area;
(2) from quick lime and carbon dioxide injection well quick lime is injected to quick lime filling area;
(3) stop injection quick lime, after quick lime reacts completely with the water in hydrate layer, to quick lime and carbon dioxide
Carbon dioxide is injected in injection well, the injection pressure of carbon dioxide is 4-8MPa;
(4) control gas-producing well outlet pressure is 4-6MPa, and aerogenesis pressure is made to be more than the corresponding titanium dioxide of hydrate layer temperature
Kohlenhydrate vapor pressure is less than the corresponding methane hydrate vapor pressure of hydrate layer temperature;
(5) gas-water separation is carried out using whirlwind separator in gas-producing well well head, methane gas is collected using liquefaction storage tank,
And liquefaction storage tank is transported into gas station using marine transport ship;
(6) quick lime of quick lime filling area is emptied using drilling equipment;
(7) repeat the above steps (2)~(6), until gas-producing well outlet pressure close to carbon dioxide injection pressure, stops out
Adopt work.
Beneficial effects of the present invention:
1, the present invention makes itself and water exothermic heat of reaction, improves hydrate layer temperature first by the way of injecting quick lime,
Methane hydrate is broken to balance each other, provides heat for methane hydrate decomposition, realize the exploitation of methane hydrate.
2, quick lime decomposes the water reaction generation calcium hydroxide that the water generated reacts generation with methane hydrate, reduces water
The aquatic products closed in object recovery process goes out, and enhances the stability of hydrate reservoir;The carbon dioxide and calcium hydroxide reaction of injection
Calcium carbonate is generated, has achieved the purpose that carbon dioxide sequestration, while hydrate reservoir stability also can be improved.
3, remaining carbon dioxide can migrate flowing in hydrate layer, since aerogenesis pressure is controlled more than hydrate layer
The corresponding carbon dioxide hydrate vapor pressure of temperature, methane hydrate corresponding less than hydrate layer temperature balance each other pressure
Power, therefore carbon dioxide can generate carbon dioxide hydrate by metathesis, lead to the methane output in methane hydrate,
Achieve the purpose that sequestration of carbon dioxide, methane hydrate exploitation and improves reservoir stability.
The present invention realizes the safety and high efficiency of hydrate, water during effective solution exploitation of gas hydrates
The environmental problems such as nitride layer strength reduction, stratum unstability are closed, has reached sequestration of carbon dioxide, has mitigated the purpose of greenhouse effects.
Description of the drawings
Fig. 1 is that the hydrate exploitation of the note quick lime and carbon dioxide process of the present invention and carbon dioxide sequestration integrated processes show
It is intended to.
Specific implementation mode
Below in conjunction with attached drawing and technical solution, the specific implementation mode that further illustrates the present invention.
As shown in Figure 1, hydrate exploitation and the carbon dioxide sequestration integrated processes of a kind of note quick lime and carbon dioxide process,
Steps are as follows:
(1) it is target target area to utilize high-resolution multichannel seismic exploration method to choose sea bottom hydrate preservation region, is carried out
Quick lime and carbon dioxide injection well and gas-producing well drilling well, quick lime and the bottom of carbon dioxide injection well and gas-producing well are non-
It permeates between top lithosphere and impermeable lower part lithosphere, quick lime and carbon dioxide injection bottom are filled for quick lime
Area;
(2) from quick lime and carbon dioxide injection well quick lime is injected to quick lime filling area;
(3) stop injection quick lime, after quick lime reacts completely with the water in hydrate layer, to quick lime and carbon dioxide
Carbon dioxide is injected in injection well, the injection pressure of carbon dioxide is 5MPa;
(4) control gas-producing well outlet pressure is 5MPa, and aerogenesis pressure is made to be more than the corresponding carbon dioxide of hydrate layer temperature
Hydrate phase balance pressure is less than the corresponding methane hydrate vapor pressure of hydrate layer temperature;
(5) gas-water separation is carried out using whirlwind separator in gas-producing well well head, methane gas is collected using liquefaction storage tank,
And liquefaction storage tank is transported into gas station using marine transport ship;
(6) after quick lime is filled up in quick lime filling area, the quick lime of quick lime filling area is emptied using drilling equipment;
(7) repeat the above steps (2)~(6), until gas-producing well outlet pressure close to carbon dioxide injection pressure, stops out
Adopt work.
Claims (1)
1. hydrate exploitation and the carbon dioxide sequestration integrated processes of a kind of note quick lime and carbon dioxide process, which is characterized in that
Steps are as follows:
(1) it is target target area to utilize high-resolution multichannel seismic exploration method to choose sea bottom hydrate preservation region, carries out raw stone
Ash and carbon dioxide injection well and gas-producing well drilling well, quick lime and the bottom of carbon dioxide injection well and gas-producing well are impermeable
Between top lithosphere and impermeable lower part lithosphere, quick lime and carbon dioxide injection bottom are quick lime fill area;
(2) from quick lime and carbon dioxide injection well quick lime is injected to quick lime filling area;
(3) stop injection quick lime, after quick lime reacts completely with the water in hydrate layer, to quick lime and carbon dioxide injection
Carbon dioxide is injected in well, the injection pressure of carbon dioxide is 4-8MPa;
(4) control gas-producing well outlet pressure is 4-6MPa, and aerogenesis pressure is made to be more than the corresponding carbon dioxide water of hydrate layer temperature
Phase balance pressure is closed, the corresponding methane hydrate vapor pressure of hydrate layer temperature is less than;
(5) gas-water separation is carried out using whirlwind separator in gas-producing well well head, methane gas, and profit is collected using liquefaction storage tank
Liquefaction storage tank is transported into gas station with marine transport ship;
(6) quick lime of quick lime filling area is emptied using drilling equipment;
(7) repeat the above steps (2)~(6), until gas-producing well outlet pressure stops exploitation work close to carbon dioxide injection pressure
Make.
Priority Applications (1)
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CN201610859725.5A CN106437653B (en) | 2016-09-27 | 2016-09-27 | A kind of hydrate exploitation and the carbon dioxide sequestration integrated processes of note quick lime and carbon dioxide process |
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CN201610859725.5A CN106437653B (en) | 2016-09-27 | 2016-09-27 | A kind of hydrate exploitation and the carbon dioxide sequestration integrated processes of note quick lime and carbon dioxide process |
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CN106437653A CN106437653A (en) | 2017-02-22 |
CN106437653B true CN106437653B (en) | 2018-07-20 |
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CN107575190B (en) * | 2017-09-25 | 2018-08-24 | 中国石油大学(华东) | One kind being based on optimal flue gas CO2The CCUS systems and its working method of accumulation rate production of heavy oil reservoir |
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CN110652847B (en) * | 2019-11-14 | 2024-01-19 | 河南理工大学 | Device and method for disposing carbon dioxide in industrial waste gas based on coal mine goaf |
CN113323631B (en) * | 2020-02-28 | 2022-03-15 | 中国科学院地质与地球物理研究所 | Natural gas hydrate reservoir exploitation structure and natural gas hydrate exploitation method for injecting hydraulic calcium oxide through gas fracturing |
CN112761590B (en) * | 2021-01-21 | 2022-03-11 | 中国矿业大学 | Natural gas hydrate indirect displacement mining method based on gravity separation |
CN113431535B (en) * | 2021-08-11 | 2022-04-15 | 太原理工大学 | Method for carbon sequestration by using in-situ pyrolyzed organic ore bed |
CN114542021B (en) * | 2022-01-27 | 2023-05-23 | 华南理工大学 | Thermochemical method for strengthening CO 2 Replacement mining CH 4 Hydrate device and method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101052780A (en) * | 2004-09-23 | 2007-10-10 | 科诺科菲利浦公司 | Production of free gas by gas hydrate conversion |
CN102140907A (en) * | 2011-01-14 | 2011-08-03 | 何相龙 | Method for collecting methane from combustible ice |
CN103343678A (en) * | 2013-07-23 | 2013-10-09 | 中国石油大学(华东) | System and method for exploiting water-soluble gas by injecting carbon dioxide |
CN105422056A (en) * | 2016-01-26 | 2016-03-23 | 辽宁石油化工大学 | Method for mining natural gas hydrate in deep seafloor through carbon dioxide method |
CN105464634A (en) * | 2015-12-15 | 2016-04-06 | 中国科学院力学研究所 | Method for exploiting methane hydrate by using stored carbon dioxide |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009007453B4 (en) * | 2009-02-04 | 2011-02-17 | Leibniz-Institut für Meereswissenschaften | Process for natural gas production from hydrocarbon hydrates with simultaneous storage of carbon dioxide in geological formations |
US8869889B2 (en) * | 2010-09-21 | 2014-10-28 | Palmer Labs, Llc | Method of using carbon dioxide in recovery of formation deposits |
-
2016
- 2016-09-27 CN CN201610859725.5A patent/CN106437653B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101052780A (en) * | 2004-09-23 | 2007-10-10 | 科诺科菲利浦公司 | Production of free gas by gas hydrate conversion |
CN102140907A (en) * | 2011-01-14 | 2011-08-03 | 何相龙 | Method for collecting methane from combustible ice |
CN103343678A (en) * | 2013-07-23 | 2013-10-09 | 中国石油大学(华东) | System and method for exploiting water-soluble gas by injecting carbon dioxide |
CN105464634A (en) * | 2015-12-15 | 2016-04-06 | 中国科学院力学研究所 | Method for exploiting methane hydrate by using stored carbon dioxide |
CN105422056A (en) * | 2016-01-26 | 2016-03-23 | 辽宁石油化工大学 | Method for mining natural gas hydrate in deep seafloor through carbon dioxide method |
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