CN107372590A - A kind of aquaculture insecticide and preparation method thereof - Google Patents

A kind of aquaculture insecticide and preparation method thereof Download PDF

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Publication number
CN107372590A
CN107372590A CN201710494665.6A CN201710494665A CN107372590A CN 107372590 A CN107372590 A CN 107372590A CN 201710494665 A CN201710494665 A CN 201710494665A CN 107372590 A CN107372590 A CN 107372590A
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China
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parts
insecticide
added
aquaculture
powder
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CN201710494665.6A
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Chinese (zh)
Inventor
朱伟
朱蓓
张琛
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ANHUI HUANGHUAI VETERINARY MEDICINE CO LTD
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ANHUI HUANGHUAI VETERINARY MEDICINE CO LTD
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Priority to CN201710494665.6A priority Critical patent/CN107372590A/en
Publication of CN107372590A publication Critical patent/CN107372590A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to the preparation of insecticide, and in particular to a kind of aquaculture insecticide and preparation method thereof, the insecticide is made up of following raw material：10 20 parts of Chlorhexidine powder, 7 12 parts of sodium hypochlorite, 37 parts of hydrogen peroxide, 25 parts of glutaraldehyde, 36 parts of benzalkonium bromide, 58 parts of hexa powder, 36 parts of benzoyl peroxide, 14 parts of azone；Technical scheme provided by the present invention can make up the insecticide that prior art is provided to a certain extent and the defects of bactericidal range is small, and insecticidal effect is not strong be present.

Description

A kind of aquaculture insecticide and preparation method thereof
Technical field
The present invention relates to the preparation of insecticide, and in particular to a kind of aquaculture insecticide and preparation method thereof.
Background technology
The insecticide species of modern fish medicine in the market is a lot, common are mebendazole solution, chrysanthemum esters insecticide, AVM hereinafter Rhzomorph solution, copper sulphate etc..Because the physilogical characteristics of various fish are different with drug resistance, exist to the adaptability of different insecticides Difference, once improper use is easy to cause fish dead, therefore, how proper use of insecticide becomes raiser's headache Problem.
For obtaining a kind of water solubility containing active AVM in patent application CN103734153A disclosed in China Biological insecticides and preparation method thereof, belong to agricultural chemicals technical field, be related to insecticide, solve existing AVM and kill The problem of environmental pollution existing for worm agent is big, insecticidal action gradually weakens, the water-soluble biological insecticide, including following quality hundred Divide each component of ratio：Benzalkonium bromide 5~60%, AVM 0.1~5%, organic acid 0.5~5%, complexing agent 1~10%, increase Agent 0.5~5% is imitated, alcohol 1~10%, surplus is water.Product Activity of the present invention is higher, and effect doubles, and toxic side effect is small, water-soluble Property using more convenient, and can be widely applied to crops and aquaculture fish, the desinsection of shrimps, suppression worm.Disclosed in China specially For obtaining a kind of aquiculture animal insecticide in profit application CN106563059A, using betel nut, kuh-seng, chinaberry, rheum officinale, Chinese cassia tree, stone-like omphalia, flea stop, ice cube, camphor etc. be raw material, and obtained insecticide has efficient, spectrum, without the resistance to the action of a drug, low-residual, peace Entirely, it is environmentally friendly.
Although the insecticide that currently available technology is provided increases culture benefit with the aging for preventing breeding water body water quality The advantages that, but insecticide be present and the defects of bactericidal range is small, and insecticidal effect is not strong be present.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of aquaculture insecticide and preparation method thereof.The present invention The technical scheme provided can make up the insecticide that prior art is provided small, the desinsection that bactericidal range be present to a certain extent The defects of effect is not strong.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：Chlorhexidine powder 10-20 parts, sodium hypochlorite 7-12 parts, hydrogen peroxide 3-7 parts, glutaraldehyde 2-5 parts, benzalkonium bromide 3-6 parts, hexa powder 5-8 parts, benzoyl peroxide Formyl 3-6 parts, azone 1-4 parts.
Preferably, the insecticide, it is made up of following parts by weight raw material：Chlorhexidine powder 12-18 parts, sodium hypochlorite 8-11 Part, hydrogen peroxide 4-6 parts, glutaraldehyde 3-4 parts, benzalkonium bromide 2-5 parts, hexa powder 6-7 parts, benzoyl peroxide 4-5 parts, azone 2-3 parts.
Preferably, the insecticide, preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to certain temperature, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, it is vibration mixing a period of time, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in thermostat water bath, heating water bath 5-10min is standby；
(4) above-mentioned steps products therefrom and leftover materials stir as appropriate water in agitator, is added, obtain water Production cultivation insecticide.
Preferably, temperature is 55-60 DEG C after being heated up in the step (1).
Preferably, vibration incorporation time is 10-20min in the step (2).
Preferably, water bath with thermostatic control kettle temperature is 20 DEG C in the step (3).
Using above-mentioned technical scheme, the beneficial effects of the invention are as follows：Sodium hypochlorite has certain water quality bleaching and killed The effect of bacterium sterilization, Chlorhexidine is surfactant, has bactericidal action, and both are used cooperatively, the complex of formation it is positive from Son can make the phospholipid molecule of bacterial cell membrane interact and be attached together as target, cause bacterial cell membrane to break Split, damage, cellular content is overflowed so as to kill bacterium, enhance the action effect of aquaculture insecticide；Hydrogen peroxide It is a kind of strong oxidizer, oxygen can be provided for aquaculture, also belong to high-effective disinfecting with certain sterilizing ability, glutaraldehyde Agent, but with it is less toxic the defects of, glutaraldehyde and hydrogen peroxide compounding form aldehyde peroxide, have synergic remove, can be with Microorganism insects cell wall molecule or atom are ionized, causes the fat chain on cell membrane to be broken, so as to destroy microorganism Cell membrane, amino acid and protein etc., improve insecticidal effect, improve the stability of insecticide, meanwhile, the aldehyde mistake after compounding The toxicity of oxide substantially reduces, and reduces potential safety hazard；Hexa and benzalkonium bromide compounding, can make bacterial cell Film ruptures, and destroys the protein of microbial bacterial, has to microbial bacterials such as Escherichia coli, Candida albicans and kills well Effect, improve killing effect of the insecticide to microorganism.
Embodiment is handed over flat
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
Embodiment 1：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：10 parts of Chlorhexidine powder, 7 parts of sodium hypochlorite, 3 parts of hydrogen peroxide, 2 parts of glutaraldehyde, 3 parts of benzalkonium bromide, 5 parts of hexa powder, 3 parts of benzoyl peroxide, azone 1 Part.
A kind of aquaculture insecticide, its preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to 55 DEG C, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, vibration mixes 10min, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in 20 DEG C of thermostat water baths, heating water bath 5min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred, obtained as appropriate water in agitator, is added Aquaculture insecticide.
Embodiment 2：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：20 parts of Chlorhexidine powder, sodium hypochlorite 12 Part, 7 parts of hydrogen peroxide, 5 parts of glutaraldehyde, 6 parts of benzalkonium bromide, 8 parts of hexa powder, 6 parts of benzoyl peroxide, azone 4 parts.
A kind of aquaculture insecticide, its preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to 60 DEG C, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, vibration mixes 20min, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in 20 DEG C of thermostat water baths, heating water bath 10min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred, obtained as appropriate water in agitator, is added Aquaculture insecticide.
Embodiment 3：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：12 parts of Chlorhexidine powder, 8 parts of sodium hypochlorite, 4 parts of hydrogen peroxide, 3 parts of glutaraldehyde, 2 parts of benzalkonium bromide, 6 parts of hexa powder, 4 parts of benzoyl peroxide, azone 2 Part.
A kind of aquaculture insecticide, its preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to 56 DEG C, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, vibration mixes 12min, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in 20 DEG C of thermostat water baths, heating water bath 6min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred, obtained as appropriate water in agitator, is added Aquaculture insecticide.
Embodiment 4：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：18 parts of Chlorhexidine powder, sodium hypochlorite 11 Part, 6 parts of hydrogen peroxide, 4 parts of glutaraldehyde, 5 parts of benzalkonium bromide, 7 parts of hexa powder, 5 parts of benzoyl peroxide, azone 3 parts.
A kind of aquaculture insecticide, its preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to 58 DEG C, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, vibration mixes 15min, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in 20 DEG C of thermostat water baths, heating water bath 7min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred, obtained as appropriate water in agitator, is added Aquaculture insecticide.
Embodiment 5：
A kind of aquaculture insecticide, it is made up of following parts by weight raw material：15 parts of Chlorhexidine powder, sodium hypochlorite 10 Part, 5 parts of hydrogen peroxide, 3 parts of glutaraldehyde, 4 parts of benzalkonium bromide, 6 parts of hexa powder, 4 parts of benzoyl peroxide, azone 2 parts.
A kind of aquaculture insecticide, its preparation method include the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, it is closed to keep away After light preserves 20min, Chlorhexidine powder is added, is warming up to 58 DEG C, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fat equal with the two quality as in low-frequency oscillator Fat alcohol ether, vibration mixes 18min, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then add and the two quality sum Equal water, after being uniformly mixed, as in 20 DEG C of thermostat water baths, heating water bath 9min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred, obtained as appropriate water in agitator, is added Aquaculture insecticide.
Product in product and market in the present invention is made to kill the performance test of Escherichia coli and gold-coloured staphylococci, Test result is as follows：
Gold-coloured staphylococci/% Escherichia coli/%
Embodiment 1 98 95
Embodiment 2 99 98
Embodiment 3 96 97
Embodiment 4 97 96
Embodiment 5 96 97
Reference examples 1 68 68
Reference examples 2 67 71
The insecticide in the present invention has good killing compared to insecticide common in market as can be seen from the above table Escherichia coli and the effect of gold-coloured staphylococci, there is stronger killing microbial bacterial.
Above example is only to illustrate the technical scheme of type of the present invention, rather than its limitations；Although with reference to foregoing implementation Type of the present invention is described in detail example, it will be understood by those within the art that：It still can be to foregoing each Technical scheme described in embodiment is modified, or carries out equivalent substitution to which part technical characteristic；And these are changed Or replace, the essence of appropriate technical solution is departed from the spirit and scope of each embodiment technical scheme of type of the present invention.

Claims (6)

1. a kind of aquaculture insecticide, it is characterised in that be made up of following parts by weight raw material：Chlorhexidine powder 10-20 parts, Sodium hypochlorite 7-12 parts, hydrogen peroxide 3-7 parts, glutaraldehyde 2-5 parts, benzalkonium bromide 3-6 parts, hexa powder 5-8 parts, Benzoyl peroxide 3-6 parts, azone 1-4 parts.
2. aquaculture insecticide according to claim 1, it is characterised in that be made up of following parts by weight raw material：Chlorine Oneself determines powder 12-18 parts, sodium hypochlorite 8-11 parts, hydrogen peroxide 4-6 parts, glutaraldehyde 3-4 parts, benzalkonium bromide 2-5 parts, six methylenes Urotropine powder 6-7 parts, benzoyl peroxide 4-5 parts, azone 2-3 parts.
3. aquaculture insecticide according to claim 1, it is characterised in that preparation method includes the following steps：
(1) sodium hypochlorite is added in container, adds the water for decupling sodium hypochlorite quality, be well mixed, closed lucifuge is protected After depositing 20min, Chlorhexidine powder is added, is warming up to certain temperature, is mixed standby；
(2) glutaraldehyde and hydrogen peroxide are added into the polyoxyethylene fatty alcohol equal with the two quality as in low-frequency oscillator Ether, it is vibration mixing a period of time, standby；
(3) hexa powder is added in container, adds benzalkonium bromide, then added equal with the two quality sum Water, after being uniformly mixed, as in thermostat water bath, heating water bath 5-10min is standby；
(4) above-mentioned steps products therefrom and leftover materials are stirred as appropriate water in agitator, is added, obtains aquatic products Cultivate insecticide.
4. aquaculture method for producing insecticide according to claim 3, it is characterised in that risen in the step (1) Temperature is 55-60 DEG C after temperature.
5. aquaculture method for producing insecticide according to claim 3, it is characterised in that shaken in the step (2) It is 10-20min to swing incorporation time.
6. aquaculture method for producing insecticide according to claim 3, it is characterised in that permanent in the step (3) Tepidarium kettle temperature is 20 DEG C.
CN201710494665.6A 2017-06-26 2017-06-26 A kind of aquaculture insecticide and preparation method thereof Pending CN107372590A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114145311A (en) * 2021-12-01 2022-03-08 武汉回盛生物科技股份有限公司 Diflubenzuron particles and preparation method and application thereof

Citations (1)

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CN102626403A (en) * 2012-03-14 2012-08-08 北京万海康医科技有限公司 Disinfectant for animals and its preparation method and use

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Publication number Priority date Publication date Assignee Title
CN114145311A (en) * 2021-12-01 2022-03-08 武汉回盛生物科技股份有限公司 Diflubenzuron particles and preparation method and application thereof
CN114145311B (en) * 2021-12-01 2024-05-03 武汉回盛生物科技股份有限公司 Diflubenzuron particles, and preparation method and application thereof

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