CN107337496A - A kind of method that organic fertilizer is produced using tylosin dreg - Google Patents
A kind of method that organic fertilizer is produced using tylosin dreg Download PDFInfo
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- CN107337496A CN107337496A CN201710676503.4A CN201710676503A CN107337496A CN 107337496 A CN107337496 A CN 107337496A CN 201710676503 A CN201710676503 A CN 201710676503A CN 107337496 A CN107337496 A CN 107337496A
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- Prior art keywords
- tylosin
- dreg
- bacteria residue
- organic fertilizer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
- C05D1/02—Manufacture from potassium chloride or sulfate or double or mixed salts thereof
Abstract
A kind of method that organic fertilizer is produced using tylosin dreg, it is related to harmless treatment and the resource utilization method of tylosin dreg.It is high the invention solves existing tylosin dreg processing cost, the problems such as remaining environmental risk after processing.The present invention adds persulfate and copper sulphate to tylosin dreg, heating water bath oxidation processes, is then centrifuged for, and collects bacteria residue, prepares organic fertilizer.The present invention is up to 99.9% using persulfate to tylosin removal efficiency, and sterilizing ability is strong, and process cycle is short, can complete within 0.5 1.0 hours.
Description
Technical field
The present invention relates to the harmless treatment of tylosin dreg and resource utilization method.
Background technology
China is the production, use, big export country of antibiotic, and its bacteria residue is every in process of production for China's ferment antibiotics
About 2,000,000 tons of the discharge capacity in year, is rich in a large number of nutrients, but be anti-because wherein containing a small amount of antibiotic residue in bacteria residue
Only antibiotic residue triggers the risk of bacterial resistance in environment, and antibiotic bacterium dregs must first pass around processing and remove wherein antibiotic
Residual, then can just be used.But up to the present, China's antibiotic bacterium dregs still lack safely and effectively innoxious and resource
Change processing method, the overwhelming majority can only burning disposal, not only cause ample resources to waste, and burning disposal cost is high, exists
The risk of secondary pollution.Meanwhile the high cost of bacteria residue processing is severely impacted the sound development of pharmaceutical industry.
The special anti-infective and somatotrophic antibiotic of tylosin category macrolides livestock and poultry, obtain in many countries wide
The history of general application existing nearly 40, is greatly promoted the development of animal husbandry, is widely used for animals anti-in the world at present
One of raw element, and the most widely used pig feed additive.Counted according to Minister Agriculture of China, international market is to safe happy bacterium at present
For plain annual requirement at 1500 tons or so, domestic annual requirement is 200 tons or so.
Early in 2002, antibiotic bacterium dregs were just put into The Ministry of Agriculture of the People's Republic of China, MOA and announce No. 176 file《Forbid
The types of drugs catalogue used in feed and animal drinking water》In.2008,《National Hazard waste register》In, it will change
Learn the mother liquor in pharmaceutical raw material medicine production process and reaction solution or culture medium waste is also included in wherein.
For the realistic problem such as antibiotic bacterium dregs yield is big, intractability is big,《Pharmaceuticals industry pollution prevention technique political affairs
Plan》" reutilization technology of encouraging exploitation fermentation bacteria residue in production technology, harmless treatment skill are proposed in (exposure draft)
Art, comprehensive utilization technique " policy and suggestion.
China there is no tylosin dreg safely and effectively processing method at present.
In the method that the relevant tylosin dreg processing delivered both at home and abroad at present utilizes with Fertilizer Transformed, it is primarily upon
Whether bacteria residue and made fertilizer contain after the processing of the removal of middle antibiotic residue and the fertilizer efficiency as organic fertilizer, not yet concern
Tylosin drug-fast bacteria, whether there is security as Fertilizer application.
A kind of biological organic fertilizer and preparation method thereof is disclosed in application number CN201310575477 domestic patent, the life
The raw material composition of organic fertilizer is erythromycin bacterium slag 40~45%, tylosin dreg 20~25%, stalk 10~15%, beer
Yeast dry matter 5~10%, people store excrement 5~25%.This method prepares biological organic fertilizer by microbial fermentation, but bacteria residue is through hair
Not only still contain after ferment compared with high tylosin residual, fermentation vat floor space is big, foul gas yield is big, and fermented
A large amount of tylosin drug-fast bacteria breedings occur in journey, increase the application risk of fertilizer.
The content of the invention
It is high the invention solves existing tylosin dreg processing cost, the problems such as remaining environmental risk after processing, carry
For a kind of method that organic fertilizer is produced using tylosin dreg.
A kind of method that organic fertilizer is produced using tylosin dreg of the present invention, it is followed the steps below：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 85~90%, obtain pending bacteria residue；
2nd, persulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Safe happy bacterium in bacteria residue
Element is 1 with the mol ratio of over cure acid group and copper ion：40~60：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, 0.5~1.0h of oxidation processes；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1200~1500mg/kg, and the pH value of bacteria residue is
8.0-8.5.Described persulfate is potassium peroxydisulfate or ammonium persulfate.
The present invention principle be：Sulfuric acid is produced by transition metal copper ion effective activation persulfate in a heated condition
Root free radical, potentiometric titrations have very strong oxidisability, can effectively destroy the molecular structure of tylosin in bacteria residue, kill simultaneously
Antibiotic resistant bacteria in sterilizing slag, makes bacteria residue organic fertilizer without antibiotic resistant bacteria and does not trigger bacterium resistance in soil
Medicine, safety in utilization improves, so as to realize the harmless treatment of bacteria residue and recycling.
The removal that tylosin remains in the high solid phase bacteria residue slurry of the present invention is different from organic matter removal in waste water, waste water
The target of processing is the organic matter of all kinds in water removal, and the target of bacteria residue processing is to remove antibiotic residue and retain egg
The organic nutrient substance beneficial to plant growth such as white matter, amino acid, i.e., organic matter is selective removal in bacteria residue, and copper ion
Activation is advantageous to the removal of tylosin residual, while has the function that to kill drug-fast bacteria in bacteria residue.Moreover, the present invention passes through tune
The addition of whole copper ion and persulfate, completes the removal of tylosin in bacteria residue well.
Moreover, the moisture content of tylosin dreg and be by strict with persulfate and copper ion mol ratio in the present invention
Condition limitation, above-mentioned condition of the invention is set based on the situation of tylosin high concentration in bacteria residue, not random
Change, it is entirely different operation technique with Antibiotics of Low Concentration in processing water；The persulfate and copper of the application are excessive
Add, the removal efficiency of antibiotic will not significantly improve, but cause the reduction of nutrition organic matter in bacteria residue, be unfavorable for having
Machine fertilizer is produced；Cross and do not have obvious removal effect at least；Therefore, bacteria residue processing ability is only carried out in the conditions of the invention
Reach 99.9% removal effect.
Compared with antibiotic bacterium Slag treatment, activated by copper ions persulfate is used for organic matter removal in waste water, may
If water reuse is difficult to the problems such as up to standard after bringing the secondary pollution problem of copper ion and sulfate and handling；And it is used for antibiosis
Plain bacteria residue processing is then different, and potassium peroxydisulfate or ammonium persulfate can be transformed into potassium sulfate or ammonium sulfate, potassium and nitrogen in use
It is soil needed nutrient matter, sulfate radical is in the fully acceptable scope of soil, and trace copper is then needed for plant growth
Trace element.
The present invention includes following beneficial effect：
1. fertilizer reparation technology is simple in the present invention, easily operated, processing cost is low.
2. tylosin degradation efficiency is high in the present invention, tylosin drug-fast bacteria can be killed effectively in bacteria residue, fertilizer
It is safe to use.
3. the oxidant used in the present invention is potassium peroxydisulfate or ammonium persulfate, they change during bacteria residue is handled
Into potassium sulfate or ammonium sulfate, be advantageous to improve the content for producing the nutritional ingredient of potassium and nitrogen in fertilizer.
4. the tylosin residual quantity that the present invention is handled is 1200~1500mg/kg, content is very high, and in bacteria residue also
There are other complicated ingredients, the removal difficulty of tylosin is larger in bacteria residue, how to handle the tylosin dreg of such high concentration,
It is currently that no correlation technique can be used for reference.The present invention is up to 99.9% using potassium peroxydisulfate to tylosin removal efficiency,
Sterilizing ability is strong, and process cycle is short, and 0.5-1.0 hours can complete.
5. activator copper ion used is finally transformed into the micro- of plant growth needs in use in the present invention
Secondary element, copper participate in a variety of metabolic responses in plant growth and development process, are polyphenol oxidase, ascorbic acid oxidase, thin
The constituent of born of the same parents' chromo-oxidase etc., the oxidation-reduction process in plant is participated in, exist in the plastocyanin of chloroplaset
In, participate in photosynthetic electron transmission.
The addition of copper sulphate makes the content of trace copper in fertilizer improve about 0.025% in the present invention, and organic fertilizer is by small
In 1% dose be manured into soil after, in per kilogram soil copper content at most increase by 2.5 milligrams, do not interfere with country completely
Primary standard copper content is less than 35mg/kg requirement in standard of soil environment quality, and plays the effect of its trace nutrient.
6. treatment process condition is relatively mild in the present invention, low for the organic matter nutritional ingredient destructiveness in bacteria residue,
It is advantageously implemented the recycling of nutriment.
7. the present invention can provide a kind of method of bacteria residue safe disposal and recycling for pharmacy corporation, at reduction
Cost is managed, certain economic benefit is brought for enterprise.
Embodiment
Embodiment one：A kind of method that organic fertilizer is produced using tylosin dreg of present embodiment, it is
Follow the steps below：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 85~90%, obtain pending bacteria residue；
2nd, persulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Safe happy bacterium in bacteria residue
Element is 1 with the mol ratio of over cure acid group and copper ion：40~60：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, 0.5~1.0h of oxidation processes；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1200~1500mg/kg, and the pH value of bacteria residue is
8.0-8.5。
Embodiment two：Present embodiment is unlike embodiment one：Tylosin and over cure acid group
And the mol ratio of copper ion is 1：45~60：0.4.It is other identical with embodiment one.
Embodiment three：Present embodiment is unlike embodiment one：Tylosin and over cure acid group
And the mol ratio of copper ion is 1：45~55：0.4.It is other identical with embodiment one.
Embodiment four：Present embodiment is unlike embodiment one：Tylosin and over cure acid group
And the mol ratio of copper ion is 1：50~55：0.4.It is other identical with embodiment one.
Embodiment five：Present embodiment is unlike embodiment one：Tylosin and over cure acid group
And the mol ratio of copper ion is 1：52：0.4.It is other identical with embodiment one.
Embodiment six：Present embodiment is unlike embodiment one：Described tylosin dreg
In tylosin residual quantity be 1300~1500mg/kg, the pH value of bacteria residue is 8.0-8.5.Other and embodiment one
It is identical.
Embodiment seven：Present embodiment is unlike embodiment one：Described tylosin dreg
In tylosin residual quantity be 1400~1500mg/kg, the pH value of bacteria residue is 8.0-8.5.Other and embodiment one
It is identical.
Embodiment eight：Present embodiment is unlike embodiment one：Gather fresh tylosin bacterium
Slag, add water and adjust moisture content to 87~90%, obtain pending bacteria residue.It is other identical with embodiment one.
Embodiment nine：Present embodiment is unlike embodiment one：Gather fresh tylosin bacterium
Slag, add water and adjust moisture content to 85~88%, obtain pending bacteria residue.It is other identical with embodiment one.
Embodiment ten：Present embodiment is unlike embodiment one：The bacterium that will be handled through step 2
Slag is placed in 60~90 DEG C of water-baths, 0.5~0.8h of oxidation processes.It is other identical with embodiment one.
Present invention is not limited only to the content of the respective embodiments described above, the group of one of them or several embodiments
Contract sample can also realize the purpose of invention.
Beneficial effects of the present invention are verified by following examples：
Embodiment 1
A kind of method that organic fertilizer is produced using tylosin dreg of the present embodiment, it is to follow the steps below
's：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 85%, obtain pending bacteria residue；
2nd, potassium peroxydisulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Tylosin and over cure
The mol ratio of acid group and copper ion is 1：60：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, oxidation processes 1h；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1500mg/kg, and the pH value of bacteria residue is 8.0.
The present embodiment is up to 99.9% using potassium peroxydisulfate to tylosin removal efficiency, and sterilizing ability is strong, process cycle
Short, 0.5-1.0 hours can complete.Bacteria residue organic fertilizer and application fertilizer (dose 1%) safe happy bacterium in the soil after 1~30 day
The testing result of plain drug-fast bacteria drug resistant gene is negative.
Embodiment 2
A kind of method that organic fertilizer is produced using tylosin dreg of the present embodiment, it is to follow the steps below
's：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 85%, obtain pending bacteria residue；
2nd, potassium peroxydisulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Tylosin and over cure
The mol ratio of acid group and copper ion is 1：50：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, oxidation processes 1h；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1350mg/kg, and the pH value of bacteria residue is 8.2.
The present embodiment is up to 99.9% using potassium peroxydisulfate to tylosin removal efficiency, and sterilizing ability is strong, process cycle
It is short, it can complete within 1 hour.Tylosin resistance in the soil of bacteria residue organic fertilizer and application fertilizer (dose 1%) after 1~30 day
The testing result of bacterium drug resistant gene is negative.
Embodiment 3
A kind of method that organic fertilizer is produced using tylosin dreg of the present embodiment, it is to follow the steps below
's：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 90%, obtain pending bacteria residue；
2nd, potassium peroxydisulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Tylosin and over cure
The mol ratio of acid group and copper ion is 1：45：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, oxidation processes 0.8h；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1250mg/kg, and the pH value of bacteria residue is 8.2.
The present embodiment is up to 99.9% using potassium peroxydisulfate to tylosin removal efficiency, and sterilizing ability is strong, process cycle
It is short, it can complete within 0.8 hour.Tylosin is resistance in the soil of bacteria residue organic fertilizer and application fertilizer (dose 1%) after 1~30 day
The testing result of medicine bacterium drug resistant gene is negative.
Embodiment 4
A kind of method that organic fertilizer is produced using tylosin dreg of the present embodiment, it is to follow the steps below
's：
First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 90%, obtain pending bacteria residue；
2nd, ammonium persulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Tylosin and over cure
The mol ratio of acid group and copper ion is 1：45：0.4；
3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, oxidation processes 0.8h；
4th, the tylosin dreg after oxidation processes is cooled to room temperature, in the condition that rotating speed is 4000~8000r/min
Under, 20min is centrifuged, obtained bacteria residue is precipitated and is granulated with auxiliary material humic acid or bentonite mixing drying, i.e., described in completion
Utilization tylosin dreg produce organic fertilizer；
Tylosin residual quantity in described tylosin dreg is 1250mg/kg, and the pH value of bacteria residue is 8.2.
The present embodiment is up to 99.9% using ammonium persulfate to tylosin removal efficiency, and sterilizing ability is strong, process cycle
It is short, it can complete within 0.8 hour.Tylosin is resistance in the soil of bacteria residue organic fertilizer and application fertilizer (dose 1%) after 1~30 day
The testing result of medicine bacterium drug resistant gene is negative.
Claims (10)
- A kind of 1. method that organic fertilizer is produced using tylosin dreg, it is characterised in that it is followed the steps below：First, fresh tylosin dreg is gathered, water is added and adjusts moisture content to 85~90%, obtain pending bacteria residue；2nd, persulfate and copper sulphate is separately added into the bacteria residue handled through step 1, mixed；Tylosin in bacteria residue with The mol ratio of over cure acid group and copper ion is 1：40~60：0.4；3rd, the bacteria residue handled through step 2 is placed in 60~90 DEG C of water-baths, 0.5~1.0h of oxidation processes；4th, the tylosin dreg after oxidation processes is cooled to room temperature, under conditions of rotating speed is 4000~8000r/min, 20min is centrifuged, obtained bacteria residue precipitation is mixed into drying with auxiliary material humic acid or bentonite is granulated, that is, completes described profit Organic fertilizer is produced with tylosin dreg；Tylosin residual quantity in described tylosin dreg is 1200~1500mg/kg, and the pH value of bacteria residue is 8.0- 8.5。
- A kind of 2. method that organic fertilizer is produced using tylosin dreg according to claim 1, it is characterised in that bacteria residue In tylosin and over cure acid group and the mol ratio of copper ion be 1：45~60：0.4.
- A kind of 3. method that organic fertilizer is produced using tylosin dreg according to claim 2, it is characterised in that bacteria residue In tylosin and over cure acid group and the mol ratio of copper ion be 1：45~55：0.4.
- A kind of 4. method that organic fertilizer is produced using tylosin dreg according to claim 3, it is characterised in that bacteria residue In tylosin and over cure acid group and the mol ratio of copper ion be 1：50~55：0.4.
- 5. a kind of method that organic fertilizer is produced using tylosin dreg according to claim 4, it is characterised in that described Persulfate be potassium peroxydisulfate or ammonium persulfate.
- 6. a kind of method that organic fertilizer is produced using tylosin dreg according to claim 1, it is characterised in that described Tylosin dreg in tylosin residual quantity be 1300~1500mg/kg, the pH value of bacteria residue is 8.0-8.5.
- 7. a kind of method that organic fertilizer is produced using tylosin dreg according to claim 6, it is characterised in that described Tylosin dreg in tylosin residual quantity be 1400~1500mg/kg, the pH value of bacteria residue is 8.0-8.5.
- A kind of 8. method that organic fertilizer is produced using tylosin dreg according to claim 1, it is characterised in that collection Fresh tylosin dreg, add water and adjust moisture content to 87~90%, obtain pending bacteria residue.
- A kind of 9. method that organic fertilizer is produced using tylosin dreg according to claim 1, it is characterised in that collection Fresh tylosin dreg, add water and adjust moisture content to 85~88%, obtain pending bacteria residue.
- 10. a kind of method that organic fertilizer is produced using tylosin dreg according to claim 1, it is characterised in that will be through The bacteria residue of step 2 processing is placed in 60~90 DEG C of water-baths, 0.5~0.8h of oxidation processes.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824391A (en) * | 2019-03-26 | 2019-05-31 | 北京科技大学 | A kind of tylosin dreg compost method of resource |
| CN112934932A (en) * | 2021-04-14 | 2021-06-11 | 同济大学 | Harmless treatment method for antibiotic mushroom dregs |
| CN113087552A (en) * | 2021-04-14 | 2021-07-09 | 同济大学 | Method for preparing organic fertilizer from antibiotic bacterium residues and product thereof |
| CN114455988A (en) * | 2022-02-11 | 2022-05-10 | 山东鲁抗中和环保科技有限公司 | Tylosin fungus dreg compost fermentation process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
| CN105502776A (en) * | 2016-01-21 | 2016-04-20 | 中华人民共和国济南出入境检验检疫局 | Method for removing antibiotics in water by using UV/H2O2 combination |
| CN106110562A (en) * | 2016-06-29 | 2016-11-16 | 上海化工研究院 | A kind of for removing the method for griseofulvin in biological medicine waste residue |
| CN106422152A (en) * | 2016-09-22 | 2017-02-22 | 上海化工研究院 | Method for removing oxytetracycline in biological medicine waste residues |
| CN106588386A (en) * | 2016-12-29 | 2017-04-26 | 华北制药河北华民药业有限责任公司 | Harmless treatment method of antibiotic fermented mushroom residues for manufacturing organic fertilizer |
-
2017
- 2017-08-09 CN CN201710676503.4A patent/CN107337496A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
| CN105502776A (en) * | 2016-01-21 | 2016-04-20 | 中华人民共和国济南出入境检验检疫局 | Method for removing antibiotics in water by using UV/H2O2 combination |
| CN106110562A (en) * | 2016-06-29 | 2016-11-16 | 上海化工研究院 | A kind of for removing the method for griseofulvin in biological medicine waste residue |
| CN106422152A (en) * | 2016-09-22 | 2017-02-22 | 上海化工研究院 | Method for removing oxytetracycline in biological medicine waste residues |
| CN106588386A (en) * | 2016-12-29 | 2017-04-26 | 华北制药河北华民药业有限责任公司 | Harmless treatment method of antibiotic fermented mushroom residues for manufacturing organic fertilizer |
Non-Patent Citations (6)
| Title |
|---|
| HANS F.STROO等: "《地下水氯化烃污染羽原位修复》", 31 March 2015, 地质出版社 * |
| 佟娟等: "污水处理厂削减耐药菌与抗性基因的研究进展", 《环境科学学报》 * |
| 张楠等: "金属离子对UV协同过硫酸盐降解结晶紫的影响", 《河南科技学院学报（自然科学版）》 * |
| 斯•阿•巴列金: "《物理化学和胶体化学实验》", 31 May 1960, 人民教育出版社 * |
| 段子恒: "青霉素菌渣肥对土壤环境和西红柿生长的影响研究", 《中国优秀硕士学位论文全文数据库农业科技辑》 * |
| 陈家斌等: "《几种PPCPs的毒性作用及降解反应研究》", 31 May 2017, 同济大学出版社 第1版 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824391A (en) * | 2019-03-26 | 2019-05-31 | 北京科技大学 | A kind of tylosin dreg compost method of resource |
| CN112934932A (en) * | 2021-04-14 | 2021-06-11 | 同济大学 | Harmless treatment method for antibiotic mushroom dregs |
| CN113087552A (en) * | 2021-04-14 | 2021-07-09 | 同济大学 | Method for preparing organic fertilizer from antibiotic bacterium residues and product thereof |
| CN114455988A (en) * | 2022-02-11 | 2022-05-10 | 山东鲁抗中和环保科技有限公司 | Tylosin fungus dreg compost fermentation process |
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Application publication date: 20171110 |