CN107287031A - The aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent - Google Patents
The aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent Download PDFInfo
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- CN107287031A CN107287031A CN201710418463.3A CN201710418463A CN107287031A CN 107287031 A CN107287031 A CN 107287031A CN 201710418463 A CN201710418463 A CN 201710418463A CN 107287031 A CN107287031 A CN 107287031A
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- maillard reaction
- aobvious
- turkish tobaccos
- reaction thing
- additive agent
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
Abstract
The present invention provides method and the application that the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares tobacco additive agent.The preparation method of the tobacco additive agent is after Turkish tobaccos are shredded, oriental tobacco leaf concrete is obtained after adding ethanol extraction, filtering and concentrating, then reduced sugar and amino acid is added to be stirred continuously carry out Maillard reaction, reactant is added in molecular distillation instrument and carries out I grades of distillations, retain the I level distillates flowed out along chamber walls, proceed ii level distillation and obtain aobvious Studies of The Aromatic Substances, as tobacco additive agent.This aobvious Studies of The Aromatic Substances spray is added in cigarette shreds, flue gas mass can be improved, increase cigarette flavor, make abundant, sweet cigarette smoke, saturating hair alcohol and, suppression thorn subtracts miscellaneous, and plays the features such as abundant cigarette perfume, profit sweet tea sense of enhancing flue gas.
Description
Technical field
The present invention relates to Field of Tobacco, relate in particular to the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing and prepare tobacco
The method of additive and application obtain a kind of field of new essence spice for cigarette.
Background technology
Cigarette market is required to attribute of the cigarette commodity with " high fragrance, high concentration, low tar " both at home and abroad at present.With
Smoking is increasingly paid close attention to health by the whole society, improves safety cigarette, and development low-coke tar cigarette turns into tobacco business
Main direction and development trend, but while coke tar in cigarette is reduced, often also result in the loss of smoke perfume and dense
The decrease of degree, this just must make up the fragrance of cigarette by perfuming means, so that meet consumer sucks demand.
Turkish tobaccos are a kind of tobacco types rich in a variety of aobvious Studies of The Aromatic Substances, are that the various famous-brand and high-quality cigarette of production are especially high-grade mixed
The necessary raw material of mould assembly cigarette.Many researchs are all pointed out both at home and abroad, ladanum class compound, Beta-methyl valeric acid in Turkish tobaccos,
The content of the special flavor matter such as isovaleric acid, dorinone, solanone is above other types of tobacco several times even decades of times, these
Composition is considered as to constitute Turkish tobaccos peculiar fragrance and jealous important component.
Maillard reaction is condensation, dehydration, degraded and the redox that amino acid occurs with reduced sugar or carbonyls
Etc. series reaction.Species can be produced by Maillard reaction to enrich and the big chemical substance of molecular weight, make whole reactant
Full aroma, in addition, contain substantial amounts of fragrance matter in maillard reaction thing, and also most of and cigarette perfume is coordinated, thus turn into
Good tobacco aromaticss.
Flavoring and casing technology is the flue gas concentration and an effective way of fragrance of enhancement and raising cigarette.By studying profit
With the isolated tobacco flavor matter of molecular distillation, it can assign cigarette natural note, make the fragrant body material of cigarette richer
Richness, improves the overall quality of cigarette, while opening new approach for the utilization of the natural resources of China's abundant.Current molecule steams
Evaporate processing Turkish tobaccos Maillard reaction medicinal extract and prepare the research that tobacco additive agent applied in tobacco and be rarely reported.
Although the oriental tobacco leaf concrete maillard reaction thing obtained by Maillard reaction can relatively well make up cigarette perfume, by
In not carrying out Selective Separation to aroma component, wherein being unfavorable for the material of cigarette odor-absorbing containing some, in the same of increase cigarette perfume
Uncomfortable, the side effect such as harsh feeling and dry sensation increase that when also brings suction taste.Therefore, it is necessary to be separated by molecular distillation equipment
Remove the material for being unfavorable for cigarette odor-absorbing in oriental tobacco leaf concrete maillard reaction thing.
The content of the invention
In order to solve above-mentioned technical problem, the present invention provides the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing and obtains one
Plant the method for new essence spice for cigarette and the application of the tobacco additive agent.The spray of this oriental tobacco leaf concrete light component is added to cigarette cigarette
In silk, flue gas mass can be improved, increase cigarette flavor, make abundant, sweet cigarette smoke, saturating hair alcohol and, suppression thorn subtracts miscellaneous, and
To the features such as abundant cigarette perfume, the profit sweet tea sense of enhancing flue gas, heavy constituent can be used for thin slice charging and Low-end Cigarettes charging.Party's legal system
Making improves jealous and lifting cigarette flavor amount the effective approach of cigarette, while the wasting of resources and environmental pollution are reduced,
Improve cigarette added value.
The technical scheme is that：The aobvious fragrant composition separation of the Turkish tobaccos maillard reaction thing prepares tobacco additive agent
Method and application, this method comprise the following steps：
A. after Turkish tobaccos are shredded, the addition for adding 8~12mL ethanol by every gram of Turkish tobaccos adds dense into Turkish tobaccos
The ethanol for 50% is spent, 1~3h is extracted under 50~70 DEG C of environment, filtering and concentrating is oriental tobacco leaf concrete；
B. by the oriental tobacco leaf concrete: reduced sugar of gained in step a: amino acid is using quality parts ratio as 1: 0.2~0.4: 0.1
After~0.3 ratio mixing, under conditions of 85 DEG C~105 DEG C, it is stirred continuously progress Maillard reaction 4~6 hours, perfume is made
Expect smoke-dipping paste maillard reaction thing；Wherein described reduced sugar is glucose or fructose, and described amino acid is proline, glutamic acid
Or alanine；
C. the oriental tobacco leaf concrete maillard reaction thing of gained in step b is added in molecular distillation instrument and carries out I grades of distillations,
Molecular distillation equipment vapo(u)rizing temperature is set as 50 DEG C~70 DEG C, material flow is 1~2ml/min, knifing rotating speed is 40~60r/
Min, vacuum is 20~30Pa, retains the I level distillates flowed out along chamber walls；
D. the I level distillates of gained in step c are proceeded into ii level distillation in molecular distillation instrument and obtains light group
Divide and heavy constituent, as tobacco additive agent；Wherein secondary distillation sets vapo(u)rizing temperature as 65 DEG C~80 DEG C, and material flow 1~
3ml/min, knifing rotating speed is 100~150r/min, and vacuum is 15~20Pa.
The present invention preferably technical scheme：Every gram of Turkish tobaccos add the ethanol that 10mL concentration is 50% in the step a, carry
It is 65 DEG C to take temperature, and oriental tobacco leaf concrete is 1.150~1.200 with respect to the density of water after filtering and concentrating.
The present invention preferably technical scheme：Oriental tobacco leaf concrete in the step b: reduced sugar: the mass parts ratio of amino acid is 1
: 0.3: 0.2, the reduced sugar is glucose, and described amino acid is proline, and Maillard reaction temperature control is at 100 DEG C.
The present invention preferably technical scheme：The vapo(u)rizing temperature of I grades of molecular distillations is 60 DEG C, material flow in the step c
For 2ml/min, knifing rotating speed is 60r/min, and vacuum is 25Pa；The vapo(u)rizing temperature of II grades of molecular distillations is 75 DEG C, material stream
Speed is 1ml/min, and knifing rotating speed is 120r/min, and vacuum is 15Pa.
The Turkish tobaccos quality is with adding the volume ratio of the ethanol of concentration 50% for solid-liquid ratio, and solid-liquid ratio is using every in the present invention
Gram Turkish tobaccos correspondence adds 50% ethanol milliliter number.It is spices that every gram of Turkish tobaccos, which add 8~12mL concentration for 50% ethanol,
Cigarette and 50% ethanol solid-liquid ratio are 8~12.
Another technical scheme that the present invention is provided is that the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares tobacco and added
Plus method and the application of agent, it is characterised in that：It will obtain high during II grades of distillation light component sprays are added to for preparing in the above method
In the pipe tobacco of shelves cigarette, medium-to-high grade cigarette is made according to the preparation method of existing cigarette, its addition is pipe tobacco gross weight
0.05~0.1%.
Oriental tobacco leaf concrete generates species by Maillard reaction and enriched and the big chemical substance of molecular weight in the present invention, leads to
Cigarette flavor matter can be improved by crossing the Turkish tobaccos maillard reaction thing that molecular distillation equipment is collected into and showing Studies of The Aromatic Substances application in cigarette
Amount and class sense, increase tobacco this perfume, make flue gas it is abundant, sweet, it is saturating send out alcohol and, press down thorn and subtract miscellaneous.
The aobvious Studies of The Aromatic Substances prepared by separating is pure natural spice, with great market potential, and its application is easy, existing
Realization is readily obtained in some Cigarette processing technique, the sucking quality of cigarette can be lifted.This patent provides skill for flavouring essence for tobacco
Art and theoretical direction.
Beneficial effects of the present invention：
(1) the obtained aobvious Studies of The Aromatic Substances odor characteristic of the present invention has pleasant caramel sample fragrant, and Turkish tobaccos feature is fragrant, stays
It is fragrant lasting.
(2) the obtained aobvious Studies of The Aromatic Substances of the present invention is used in tobacco charging, can improve cigarette flavor quality and class sense, increase
This perfume of tobacco, make flue gas it is abundant, sweet, it is saturating hair alcohol and, suppression thorn subtract miscellaneous.
(3) reaction condition of the present invention is gentle, and cost is relatively low, it is easy to industrialized production；And the method provided in the present invention
It is not required to other additional chemical reagent, it is to avoid because additional ingredients introduce other potential safety hazards and bad breath.
Embodiment
Technical scheme is illustrated with reference to specific embodiment, but protection scope of the present invention is not limited to
This：
Embodiment 1, the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent, including
Following steps：
A, 10kg Turkish tobaccos are crushed, add 100L concentration and extract 2h for 50% ethanol stirring, Extracting temperature is 65 DEG C；
After extract solution is filtered, take out filtrate and acquisition oriental tobacco leaf concrete is concentrated in vacuo under the conditions of 50 DEG C, oriental tobacco leaf concrete is with respect to water
Density is 1.150~1.200；
B, the oriental tobacco leaf concrete progress Maillard reaction by gained：Weigh the oriental tobacco leaf concrete 100g prepared in step a, Portugal
Grape sugar 30g, proline 20g, are then mixed uniformly, are put into Conventional compact reactor, temperature control is at 100 DEG C, not
Maillard reaction is carried out in disconnected stirring 6 hours, that is, oriental tobacco leaf concrete maillard reaction thing is made；
C, by step b gained oriental tobacco leaf concrete maillard reaction thing be added in molecular distillation instrument carry out I grade distill：
The optimum condition that molecular clock Turkish tobaccos maillard reaction thing is determined by Preliminary Experiment is：Vapo(u)rizing temperature is 60 DEG C,
Material flow is 2ml/min, and knifing rotating speed is 60r/min, and vacuum is 25Pa；Retain and distilled along the I levels that chamber walls flow out
Light component, it is 1.075 with respect to the density of water to detect I grades of distillation light components；
D, the I levels distillation light component progress ii level distillation by gained in step c, determine molecule by Preliminary Experiment and steam
Evaporate and prepare the optimum condition of Turkish tobaccos maillard reaction thing and be：Vapo(u)rizing temperature is 75 DEG C, material flow 1ml/min, knifing rotating speed
For 120r/min, vacuum is 15Pa；The aobvious Studies of The Aromatic Substances of II grades of distillations is collected into, detects that the aobvious Studies of The Aromatic Substances of II grades of distillations is close with respect to water
Spend for 1.038.
Embodiment 2, the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent, including
Following steps：
A, 10kg Turkish tobaccos are crushed, add 80L concentration and extract 3h for 50% ethanol stirring, Extracting temperature is 50 DEG C,
After extract solution is filtered, take out filtrate and acquisition oriental tobacco leaf concrete is concentrated in vacuo under the conditions of 50 DEG C, oriental tobacco leaf concrete is with respect to water
Density is 1.150~1.200；
B, the oriental tobacco leaf concrete progress Maillard reaction by gained：Weigh the oriental tobacco leaf concrete 100g prepared in step a, Portugal
Grape sugar 20g, tryptophan 30g, are then mixed uniformly, are put into Conventional compact reactor, temperature control is at 90 DEG C, continuous
Maillard reaction is carried out in stirring 5 hours, that is, oriental tobacco leaf concrete maillard reaction thing is made；
C, by step b gained oriental tobacco leaf concrete maillard reaction thing be added in molecular distillation instrument carry out I grade distill：
The optimum condition that molecular clock Turkish tobaccos maillard reaction thing is determined by Preliminary Experiment is：Vapo(u)rizing temperature is 50 DEG C,
Material flow is 2ml/min, and knifing rotating speed is 50r/min, and vacuum is 20Pa；Retain and distilled along the I levels that chamber walls flow out
Light component, it is 1.073 with respect to the density of water to detect I grades of distillation light components；
D, I grades of gained distillation light components are subjected to iis level distilled, it is fragrant that molecular clock is determined by Preliminary Experiment
Material cigarette maillard reaction thing optimum condition be：Vapo(u)rizing temperature is 75 DEG C, and material flow 1ml/min, knifing rotating speed is 120r/
Min, vacuum is 15Pa；The aobvious Studies of The Aromatic Substances of II grades of distillations is collected into, detects that the aobvious Studies of The Aromatic Substances of II grades of distillations is with respect to the density of water
1.037。
Embodiment 3, the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent, including
Following steps：
A, 10kg Turkish tobaccos are crushed, add 120L concentration and extract 2h for 50% ethanol stirring, Extracting temperature is 70 DEG C,
After extract solution is filtered, take out filtrate and acquisition oriental tobacco leaf concrete is concentrated in vacuo under the conditions of 50 DEG C, oriental tobacco leaf concrete is with respect to water
Density is oriental tobacco leaf concrete for 1.150~1.200；
B, the oriental tobacco leaf concrete progress Maillard reaction by gained：Weigh oriental tobacco leaf concrete 100g, fructose 30g, alanine
30g, is then mixed uniformly, is put into Conventional compact reactor, and temperature control is carried out beautiful at 100 DEG C in being stirred continuously
Maillard reaction 5 hours, that is, be made oriental tobacco leaf concrete maillard reaction thing；
C, by gained oriental tobacco leaf concrete maillard reaction thing be added in molecular distillation instrument carry out I grade distill：Pass through experiment
The optimum condition for having primarily determined that molecular clock Turkish tobaccos maillard reaction thing is：Vapo(u)rizing temperature is 55 DEG C, material flow
For 2ml/min, knifing rotating speed is 50r/min, and vacuum is 30Pa；Retain along the I levels that chamber walls flow out and distill light component, inspection
It is 1.076 that I grades of distillation light components, which are surveyed, with respect to the density of water；
D, I grades of gained distillation light components are subjected to iis level distilled, it is fragrant that molecular clock is determined by Preliminary Experiment
Material cigarette maillard reaction thing optimum condition be：Vapo(u)rizing temperature is 70 DEG C, and material flow 1ml/min, knifing rotating speed is 130r/
Min, vacuum is 18Pa；The aobvious Studies of The Aromatic Substances of II grades of distillations is collected into, detects that the aobvious Studies of The Aromatic Substances of II grades of distillations is with respect to the density of water
1.039。
Embodiment 4:The aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent, including
Following steps：
A, 10kg Turkish tobaccos are crushed, it is that 2h is extracted in the stirring of 50% ethanol to add 100L concentration, and Extracting temperature is 65 DEG C, will
After extract solution filtering, take out filtrate and acquisition oriental tobacco leaf concrete is concentrated in vacuo under the conditions of 50 DEG C, oriental tobacco leaf concrete is close with respect to water
Spend for 1.150~1.200；
B, the oriental tobacco leaf concrete progress Maillard reaction by gained：Weigh and oriental tobacco leaf concrete 100g, fructose are prepared in step a
20g, tryptophan 10g, are then mixed uniformly, are put into Conventional compact reactor, temperature control is constantly being stirred at 100 DEG C
Mix middle progress Maillard reaction 4 hours, that is, oriental tobacco leaf concrete maillard reaction thing is made；
C, by gained oriental tobacco leaf concrete maillard reaction thing be added in molecular distillation instrument carry out I grade distill：Pass through experiment
The optimum condition for having primarily determined that molecular clock Turkish tobaccos maillard reaction thing is：Vapo(u)rizing temperature is 60 DEG C, material flow
For 2ml/min, knifing rotating speed is 60r/min, and vacuum is 26Pa；Retain along the I levels that chamber walls flow out and distill light component, inspection
It is 1.074 that I grades of distillation light components, which are surveyed, with respect to the density of water；
D, I grades of gained distillation light components are subjected to iis level distilled, it is fragrant that molecular clock is determined by Preliminary Experiment
Material cigarette maillard reaction thing optimum condition be：Vapo(u)rizing temperature is 80 DEG C, and material flow 1ml/min, knifing rotating speed is 150r/
Min, vacuum is 20Pa；The aobvious Studies of The Aromatic Substances of II grades of distillations is collected into, detects that the aobvious Studies of The Aromatic Substances of II grades of distillations is with respect to the density of water
1.041。
The oriental tobacco leaf concrete obtained in above-described embodiment 1, oriental tobacco leaf concrete maillard reaction thing and II grades are distilled light group
Point and heavy constituent enter to pass through GC-MS analysis, by WILEY and MAINLIB library searchings, 26,35,40 and 24 kind are identified respectively
Volatile ingredient.
The oriental tobacco leaf concrete of table 1, oriental tobacco leaf concrete maillard reaction thing and II grades of distillation light components and heavy constituent mainly show perfume
Material chemical composition is contrasted
The western cypress alkanes of class has solanone, western cypress amylene, the enediol of western cypress three in table one, and ladanum class has ambrox, oxygen
Change sclareol, imperial saliva aldehyde, 8,12- epoxy-14s-ladanum -13- alcohol, drop ambreinolide, carotenoidses have damascenone, six
Hydrogen method Buddhist nun ketone, Megastigmatrienone, dihydroactinidiolide, 3- oxos-а-ionol, other fragrance matters have furfural, furans
Ketone, acetyl pyrrole, neophytadiene, ethyl linolenate, methyl hexadecanoate, phenmethylol, benzyl carbinol.
It can show that aobvious Studies of The Aromatic Substances odor characteristic has pleasant caramel sample fragrant by table one, Turkish tobaccos feature is fragrant,
Lasting is lasting.
Application Example, by the oriental tobacco leaf concrete prepared in above-described embodiment 1, oriental tobacco leaf concrete maillard reaction thing and II
Apply ratio under level distillation light component progress charging perfuming, identical conditions identical, and sense organ contrast carried out to application sample and smoke panel test,
9 members of sensory evaluating smoking group, the standard of smokeing panel test uses GB5606.4-2005, and smoking result is averaged, its results detailed in Table 2,
3、4.Described application ratio is the percentage by weight for accounting for pipe tobacco.
Table 2：Application ratio is 0.05% sensory evaluating smoking's result
| Sample | Gloss | Fragrance | Coordinate | Miscellaneous gas | Stimulate | Pleasant impression | It is total |
| Reference cigarette | 5 | 24.1 | 4.0 | 7.9 | 15.0 | 20.0 | 76.0 |
| Oriental tobacco leaf concrete | 5 | 24.5 | 4.7 | 8.1 | 16.2 | 20.2 | 78.7 |
| Oriental tobacco leaf concrete maillard reaction thing | 5 | 24.6 | 4.7 | 8.2 | 16.3 | 20.6 | 79.4 |
| The aobvious Studies of The Aromatic Substances of II grades of distillations | 5 | 25.2 | 4.9 | 8.5 | 16.7 | 20.9 | 81.2 |
Table 3：Application ratio is 0.10% sensory evaluating smoking's result
| Sample | Gloss | Fragrance | Coordinate | Miscellaneous gas | Stimulate | Pleasant impression | It is total |
| Reference cigarette | 5 | 24.1 | 4.0 | 7.9 | 15.0 | 20.0 | 76.0 |
| Oriental tobacco leaf concrete | 5 | 24.6 | 4.7 | 8.2 | 16.4 | 20.2 | 79.1 |
| Oriental tobacco leaf concrete maillard reaction thing | 5 | 24.8 | 4.7 | 8.2 | 16.3 | 20.6 | 79.6 |
| The aobvious Studies of The Aromatic Substances of II grades of distillations | 5 | 25.3 | 4.9 | 8.5 | 16.7 | 20.9 | 81.3 |
Table 4 applies sensory evaluating smoking's result that ratio is 0.15%
| Sample | Gloss | Fragrance | Coordinate | Miscellaneous gas | Stimulate | Pleasant impression | It is total |
| Reference cigarette | 5 | 24.1 | 4.0 | 7.9 | 15.0 | 20.0 | 76.0 |
| Oriental tobacco leaf concrete | 5 | 24.6 | 4.7 | 7.9 | 15.4 | 20.2 | 77.8 |
| Oriental tobacco leaf concrete maillard reaction thing | 5 | 24.8 | 4.7 | 8.0 | 15.3 | 20.3 | 78.1 |
| The aobvious Studies of The Aromatic Substances of II grades of distillations | 5 | 24.9 | 4.7 | 8.0 | 15.7 | 20.2 | 78.5 |
The aobvious Studies of The Aromatic Substances of II grades of distillations and tobacco aromaticss smoke-dipping paste Mei Lade are can be seen that from sensory evaluating smoking's result of table 2~4
Reactant is compared with tobacco aromaticss smoke-dipping paste, when the application ratio of the aobvious Studies of The Aromatic Substances of II grades of distillations is 0.05~0.1%, can improve volume
Cigarette aroma quality and class sense, increase tobacco this perfume, make abundant, sweet flue gas, saturating hair alcohol and, suppression thorn subtracts miscellaneous effect, low
Used on tar cigarette, strengthen the fragrance of cigarette and return sweet tea sense.The aobvious Studies of The Aromatic Substances of II grades of distillations solves oriental tobacco leaf concrete and spices
Smoke-dipping paste maillard reaction thing is used for minimal irritation, the astringent sense brought in tobacco flavoring, slightly miscellaneous gas, flue gas particle shape residue
Heavier, flue gas diverging.
Above-described embodiment is the preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes made without departing from the present invention should be equivalent substitute mode, be included in the guarantor of the present invention
Within the scope of shield.
Claims (5)
1. the method that a kind of aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares tobacco additive agent, it is characterised in that specific step
It is rapid as follows：
A. after Turkish tobaccos are shredded, the addition for adding 8~12mL ethanol by every gram of Turkish tobaccos adds concentration into Turkish tobaccos and is
50% ethanol, extracts 1~3h, filtering and concentrating is oriental tobacco leaf concrete under 50~70 DEG C of environment；
B. by the oriental tobacco leaf concrete: reduced sugar: amino acid of gained in step a using mass parts ratio as 1: 0.2~0.4: 0.1~0.3
Ratio mixing after, under conditions of 85 DEG C~105 DEG C, be stirred continuously progress Maillard reaction 4~6 hours, Turkish tobaccos be made
Medicinal extract maillard reaction thing；Wherein described reduced sugar is glucose or fructose, and described amino acid is proline, glutamic acid or third
Propylhomoserin；
C. the oriental tobacco leaf concrete maillard reaction thing of gained in step b is added in molecular distillation instrument and carries out I grades of distillations, setting
Molecular distillation equipment vapo(u)rizing temperature is 50 DEG C~70 DEG C, and material flow is 1~2ml/min, and knifing rotating speed is 40~60r/min,
Vacuum is 20~30Pa, retains the I level distillates flowed out along chamber walls；
D. by step c gained I level distillates proceed in molecular distillation instrument ii level distillation obtain light component with
Heavy constituent, as tobacco additive agent；Wherein secondary distillation sets vapo(u)rizing temperature as 65 DEG C~80 DEG C, 1~3ml/ of material flow
Min, knifing rotating speed is 100~150r/min, and vacuum is 15~20Pa.
2. the method that the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing according to claim 1 prepares tobacco additive agent,
It is characterized in that：Every gram of Turkish tobaccos add the ethanol that 10mL concentration is 50% in the step a, and Extracting temperature is 65 DEG C, filtering
Oriental tobacco leaf concrete is 1.150~1.200 with respect to the density of water after concentration.
3. the method that the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing according to claim 1 prepares tobacco additive agent,
It is characterized in that：Oriental tobacco leaf concrete in the step b: reduced sugar: the mass parts ratio of amino acid is 1: 0.3: 0.2, the reduction
Sugar is glucose, and described amino acid is proline, and Maillard reaction temperature control is at 100 DEG C.
4. the method that the aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing according to claim 1 prepares tobacco additive agent,
It is characterized in that：The vapo(u)rizing temperature of I grades of molecular distillations is 60 DEG C in the step c, and material flow is 2ml/min, knifing rotating speed
For 60r/min, vacuum is 25Pa；The vapo(u)rizing temperature of II grades of molecular distillations is 75 DEG C, and material flow is 1ml/min, and knifing turns
Speed is 120r/min, and vacuum is 15Pa.
5. a kind of application of claim 1 tobacco additive agent that into claim 4 prepared by any one in tobacco, its feature
It is：The aobvious Studies of The Aromatic Substances spray of II grades of distillations will be obtained in the above method to be added in cigarette shreds, prepares medium-to-high grade cigarette, its addition
For the 0.05~0.1% of pipe tobacco gross weight.
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| CN108384637A (en) * | 2018-03-13 | 2018-08-10 | 江西中烟工业有限责任公司 | A kind of preparation method of aroma type maillard flavour and its application in cigarette |
| CN108504454A (en) * | 2018-03-13 | 2018-09-07 | 江西中烟工业有限责任公司 | A kind of modified form cigarette preparation method of liquor tailing fragrance and its application in cigarette |
| CN113142643A (en) * | 2021-02-08 | 2021-07-23 | 广东中烟工业有限责任公司 | Cigarette essence for heating non-combustible cigarettes and preparation method and application thereof |
| CN114703021A (en) * | 2022-03-21 | 2022-07-05 | 云南巴菰生物科技股份有限公司 | Emblic leafflower fruit extract and its preparing method and use |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101194752A (en) * | 2006-12-29 | 2008-06-11 | 河南农业大学 | Oriental tobacco leaf concrete extracting method and use method thereof |
| CN102041173A (en) * | 2010-12-22 | 2011-05-04 | 华芳烟用香料有限公司 | Extraction and separation method of aromatic part in aromatic tobacco extract and application thereof to cigarettes |
| CN102396773A (en) * | 2011-07-19 | 2012-04-04 | 黄鹤楼香精香料有限公司 | Preparation method of plum hydrolysate for cigarettes and application of plum hydrolysate to cigarettes |
| CN103013665A (en) * | 2012-12-13 | 2013-04-03 | 湖北中烟工业有限责任公司 | Preparation method of fenugreek extract Maillard reaction product and application of reaction product in cigarette |
| CN103320230A (en) * | 2013-06-28 | 2013-09-25 | 湖北中烟工业有限责任公司 | Preparation method of tobacco extractum glycyrrhizae maillard reactant, and application thereof |
| CN103484247A (en) * | 2013-09-27 | 2014-01-01 | 福建中烟工业有限责任公司 | Segmented camellia sinensis flower exaction and preparation method thereof, and application of exaction in cigarettes |
| CN104017647A (en) * | 2014-06-13 | 2014-09-03 | 广西科技大学 | Method for preparing maillard reaction product of mango extract and application of product to cigarettes |
| CN104351944A (en) * | 2014-10-22 | 2015-02-18 | 浙江中烟工业有限责任公司 | Tobacco perfuming agent prepared through molecular distillation treatment of extractum obtained through Maillard reaction from inferior tobacco leaves, preparation method and application of tobacco perfuming agent |
| CN104789364A (en) * | 2015-04-27 | 2015-07-22 | 湖北中烟工业有限责任公司 | Preparation method and application of purple laver extract Maillard reaction product |
| CN105238564A (en) * | 2015-06-18 | 2016-01-13 | 湖北中烟工业有限责任公司 | Preparation method and application of Maillard reaction product of Rhodiola rosea extract |
| CN106047481A (en) * | 2016-06-03 | 2016-10-26 | 湖北中烟工业有限责任公司 | Preparation method and application of discarded tobacco leaf fermentation extract |
| CN106333384A (en) * | 2016-11-01 | 2017-01-18 | 湖北中烟工业有限责任公司 | Mixed type tobacco molecular distillation light component electronic tobacco liquid and preparation method thereof |
| CN106418663A (en) * | 2016-10-31 | 2017-02-22 | 湖北中烟工业有限责任公司 | Biochemical joint preparation method and application of absolute rose oil |
| CN106509981A (en) * | 2016-11-22 | 2017-03-22 | 中国烟草总公司郑州烟草研究院 | Preparation method of high-nicotine tobacco extract |
-
2017
- 2017-06-06 CN CN201710418463.3A patent/CN107287031B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101194752A (en) * | 2006-12-29 | 2008-06-11 | 河南农业大学 | Oriental tobacco leaf concrete extracting method and use method thereof |
| CN102041173A (en) * | 2010-12-22 | 2011-05-04 | 华芳烟用香料有限公司 | Extraction and separation method of aromatic part in aromatic tobacco extract and application thereof to cigarettes |
| CN102396773A (en) * | 2011-07-19 | 2012-04-04 | 黄鹤楼香精香料有限公司 | Preparation method of plum hydrolysate for cigarettes and application of plum hydrolysate to cigarettes |
| CN103013665A (en) * | 2012-12-13 | 2013-04-03 | 湖北中烟工业有限责任公司 | Preparation method of fenugreek extract Maillard reaction product and application of reaction product in cigarette |
| CN103320230A (en) * | 2013-06-28 | 2013-09-25 | 湖北中烟工业有限责任公司 | Preparation method of tobacco extractum glycyrrhizae maillard reactant, and application thereof |
| CN103484247A (en) * | 2013-09-27 | 2014-01-01 | 福建中烟工业有限责任公司 | Segmented camellia sinensis flower exaction and preparation method thereof, and application of exaction in cigarettes |
| CN104017647A (en) * | 2014-06-13 | 2014-09-03 | 广西科技大学 | Method for preparing maillard reaction product of mango extract and application of product to cigarettes |
| CN104351944A (en) * | 2014-10-22 | 2015-02-18 | 浙江中烟工业有限责任公司 | Tobacco perfuming agent prepared through molecular distillation treatment of extractum obtained through Maillard reaction from inferior tobacco leaves, preparation method and application of tobacco perfuming agent |
| CN104789364A (en) * | 2015-04-27 | 2015-07-22 | 湖北中烟工业有限责任公司 | Preparation method and application of purple laver extract Maillard reaction product |
| CN105238564A (en) * | 2015-06-18 | 2016-01-13 | 湖北中烟工业有限责任公司 | Preparation method and application of Maillard reaction product of Rhodiola rosea extract |
| CN106047481A (en) * | 2016-06-03 | 2016-10-26 | 湖北中烟工业有限责任公司 | Preparation method and application of discarded tobacco leaf fermentation extract |
| CN106418663A (en) * | 2016-10-31 | 2017-02-22 | 湖北中烟工业有限责任公司 | Biochemical joint preparation method and application of absolute rose oil |
| CN106333384A (en) * | 2016-11-01 | 2017-01-18 | 湖北中烟工业有限责任公司 | Mixed type tobacco molecular distillation light component electronic tobacco liquid and preparation method thereof |
| CN106509981A (en) * | 2016-11-22 | 2017-03-22 | 中国烟草总公司郑州烟草研究院 | Preparation method of high-nicotine tobacco extract |
Non-Patent Citations (2)
| Title |
|---|
| 王萍，等: ""分子蒸馏处理香料烟浸膏制备烟用香料"", 《香料香精化妆品》 * |
| 赵铭钦等: "香料烟浸膏香气物质成分研究 ", 《西北农林科技大学学报(自然科学版)》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384637A (en) * | 2018-03-13 | 2018-08-10 | 江西中烟工业有限责任公司 | A kind of preparation method of aroma type maillard flavour and its application in cigarette |
| CN108504454A (en) * | 2018-03-13 | 2018-09-07 | 江西中烟工业有限责任公司 | A kind of modified form cigarette preparation method of liquor tailing fragrance and its application in cigarette |
| CN108384637B (en) * | 2018-03-13 | 2021-07-27 | 江西中烟工业有限责任公司 | Preparation method of bouquet type Maillard spice and application of bouquet type Maillard spice in cigarettes |
| CN113142643A (en) * | 2021-02-08 | 2021-07-23 | 广东中烟工业有限责任公司 | Cigarette essence for heating non-combustible cigarettes and preparation method and application thereof |
| CN114703021A (en) * | 2022-03-21 | 2022-07-05 | 云南巴菰生物科技股份有限公司 | Emblic leafflower fruit extract and its preparing method and use |
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