CN114703021A - Emblic leafflower fruit extract and its preparing method and use - Google Patents
Emblic leafflower fruit extract and its preparing method and use Download PDFInfo
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- CN114703021A CN114703021A CN202210278973.6A CN202210278973A CN114703021A CN 114703021 A CN114703021 A CN 114703021A CN 202210278973 A CN202210278973 A CN 202210278973A CN 114703021 A CN114703021 A CN 114703021A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/022—Refining
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/027—Recovery of volatiles by distillation or stripping
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Abstract
The invention relates to an emblic leafflower fruit extract, a preparation method and application thereof. The preparation method of the emblic extract comprises the steps of drying, crushing, heating, refluxing and extracting, filtering, removing an ethanol solvent by reduced pressure distillation and the like. The tobacco emblic extract Maillard reactant prepared from the emblic extract can be used in cigarettes to improve the aroma quality of the cigarettes and improve the sensory comfort of the cigarettes.
Description
[ technical field ] A method for producing a semiconductor device
The invention belongs to the technical field of flavors and fragrances. More particularly, the invention relates to an emblic leafflower fruit extract, a preparation method of the emblic leafflower fruit extract and application of the emblic leafflower fruit extract.
[ background ] A method for producing a semiconductor device
Emblic leafflower fruit is a plant of phyllanthus of euphorbiaceae, and fresh fruit is sour, sweet, crisp, slightly astringent and sweet in aftertaste, so the fruit is named as emblic leafflower fruit. The emblic leafflower fruit contains rich vitamins, various essential amino acids and essential fatty acids, and the research shows that the emblic leafflower fruit has the functions of resisting inflammation, resisting oxidation, resisting aging, protecting liver and the like. At present, the major application of emblic leafflower fruit is concentrated on the aspects of eating, medicine and a few cosmetic varieties.
The maillard reaction is non-enzymatic browning which is widely existed in nature, a series of chemical reactions occur between amino acid and reducing sugar or carbonyl compound to generate black macromolecular substance melanoidin or melanoid and fragrance substances such as reducing ketone, heterocyclic compound, aldehyde and the like, and the reaction is also called as a carbonyl ammonia reaction. The tobacco product has certain irritation which can affect the smoking experience, but the Maillard reaction can generate the fragrance which is coordinated with the tobacco in the tobacco, and also has the effects of improving the characteristic fragrance of the cigarette, covering up miscellaneous gas, reducing irritation, improving aftertaste, reducing tar and harm. Therefore, the application and research of the Maillard reaction in the fields of tobacco products, flavors and fragrances are widely concerned.
At present, no relevant tobacco emblic leafflower fruit Maillard reactant and relevant reports of the tobacco emblic leafflower fruit Maillard reactant for adding essence and spice are found, so that the tobacco emblic leafflower fruit Maillard reactant is prepared by using emblic leafflower fruit as a raw material to prepare an extract and using the extract as glycogen to perform a carbonyl ammonia reaction with edible amino acid, and the tobacco product quality is improved.
[ summary of the invention ]
[ problem to be solved ]
The invention aims to provide an extract of emblic leafflower fruit.
The invention also aims to provide a preparation method of the emblic leafflower fruit extract.
The invention also aims to provide the application of the emblic leafflower fruit extract.
[ solution ]
The invention is realized by the following technical scheme.
The invention relates to a preparation method of emblic leafflower fruit extract.
The preparation method comprises the following preparation steps:
putting the emblic leafflower fruit into drying equipment for drying and crushing, wherein the weight ratio of the emblic leafflower fruit to the ethanol solvent is 1: and 5-10 adding the obtained emblic leafflower powder into an ethanol solvent, uniformly mixing, heating and refluxing at the temperature of 60-80 ℃ for 1.0-5.0 h, filtering, removing the ethanol solvent from the obtained filtrate by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower extract.
According to a preferred embodiment of the present invention, the emblic leafflower fruit is dried in a drying apparatus until a water content of below 45% by weight is reached.
According to another preferred embodiment of the present invention, the crushed particle size of the dried emblic leafflower fruit is 40 to 80 mesh.
According to another preferred embodiment of the present invention, the concentration of the ethanol solvent is 65 to 95% by volume.
According to another preferred embodiment of the present invention, the ethanol solvent is distilled off from the filtrate obtained by filtration under a vacuum of-0.06 to-0.10 MPa and at a temperature of 55 to 80 ℃.
The invention also relates to the emblic leafflower fruit extract prepared by the preparation method.
The invention also relates to the application of the emblic leafflower fruit soaked in the tobacco emblic leafflower fruit extract Maillard reactant, wherein the tobacco emblic leafflower fruit extract Maillard reactant is prepared by the following preparation method:
according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1-3: 2-6: 15-35, adding the emblic leafflower fruit extract, glycogen and food-grade amino acid into a solvent, uniformly mixing, adjusting the pH value of a mixture solution to 8-12, heating to 80-180 ℃, carrying out Maillard reaction for 2-6 h at the temperature, carrying out reduced pressure concentration on the reaction solution at the pressure of-0.06-0.10 MPa and the temperature of 50-80 ℃ by using reduced pressure distillation equipment, and obtaining a concentrate, namely the tobacco emblic leafflower fruit extract.
According to another preferred embodiment of the present invention, said glycogen is one or more glycogen selected from the group consisting of monosaccharide, high fructose syrup, honey and maltose.
According to another preferred embodiment of the invention said food grade amino acid is one or more amino acids selected from glycine, alanine, proline, histidine, serine, leucine or isoleucine.
According to another preferred embodiment of the invention, the solvent is drinking water, ethanol or propylene glycol.
The present invention will be described in more detail below.
The invention relates to a preparation method of emblic leafflower fruit extract.
The preparation method comprises the following preparation steps:
putting the phyllanthus emblica into drying equipment, drying for 2-5 h at the temperature of 45-60 ℃, crushing, and mixing the phyllanthus emblica and an ethanol solvent according to the weight ratio of 1: and 5-10 adding the obtained emblic leafflower powder into an ethanol solvent, uniformly mixing, heating and refluxing at the temperature of 60-80 ℃ for 1.0-5.0 h, filtering, removing the ethanol solvent from the obtained filtrate by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower extract.
According to the invention, the emblic leafflower fruits are dried in a drying device for 2-5 hours at the temperature of 45-60 ℃ until the water content is below 45% by weight. When the drying time is 2-5 h, if the drying temperature is lower than 45 ℃, the water loss speed is slow, which is not beneficial to the crushing of the emblic leafflower fruits in the later period; if the drying temperature is higher than 60 ℃, the surface water of the emblic leafflower fruits is quickly lost to be not beneficial to internal dehydration; therefore, the drying temperature is reasonable to be 45-60 ℃;
when the drying temperature is 45-60 ℃, if the drying time is shorter than 2 hours, the water content of the emblic leafflower fruit is higher, which is not beneficial to the later-stage crushing; if the drying time is longer than 5 hours, the effective substances of the emblic leafflower fruit are volatilized more, so that waste is caused; therefore, the drying time is proper to be 2-5 h;
according to the standard analysis method of GB 5009.3-2010 national standard food moisture determination, the water content of dried emblic leafflower fruit is detected to be below 45% by weight, and if the water content of the dried emblic leafflower fruit exceeds the range, the drying is required to be continued until the water content is reached.
According to the invention, the crushed particle size of the dried emblic leafflower fruit is 40-80 meshes. If the particle size of the dried emblic leafflower fruit powder is smaller than 40 meshes, the emblic leafflower fruit components are not completely separated, and the utilization rate of the effective components is low; if the granularity of the dried emblic leafflower fruit powder is larger than 80 meshes, the difficulty is high during solvent separation, and impurities are more in the later-stage product; therefore, the particle size of the emblic leafflower fruit powder is suitable to be 40-80 meshes.
The weight ratio of the emblic leafflower fruit to the ethanol solvent is 1: 5-10, and heating and refluxing at 60-80 ℃ for extraction for 1.0-5.0 h. The concentration of the ethanol solvent used in the invention is 65-95% by volume.
When the emblic leafflower fruit is extracted by using an ethanol solvent, the weight ratio of the emblic leafflower fruit to the ethanol solvent is 1: 5 to 10. If the weight ratio of the emblic leafflower fruit to the ethanol solvent is more than 1: 5, the extraction rate of the emblic leafflower fruit components is low, so that the emblic leafflower fruit raw materials are wasted; if the weight ratio of the emblic leafflower fruit to the ethanol solvent is less than 1: 10, the ethanol solvent is wasted; thus, the weight ratio of emblic leafflower fruit to ethanol solvent is 1: 5 to 10 is appropriate;
when the heating reflux extraction time is 1.0-5.0 h, if the heating reflux extraction temperature is lower than 60 ℃, the extraction of the emblic leafflower fruit raw material is incomplete, and the raw material waste is caused; if the heating reflux extraction temperature is higher than 80 ℃, the aroma components of the emblic leafflower fruit raw material are volatilized to the environment, and the utilization rate of the raw material is reduced; therefore, the heating reflux extraction temperature is 60-80 ℃;
when the heating reflux extraction temperature is 60-80 ℃, if the heating reflux extraction time is shorter than 1.0h, the extraction rate of the phyllanthus emblica raw material is low, and the raw material waste is caused; if the heating reflux extraction time is longer than 5.0h, the extraction rate of the raw material phyllanthus emblica cannot be improved, and energy waste is caused; therefore, the heating reflux extraction time is 1.0-5.0 h;
the heating reflux extraction material is filtered by adopting a conventional vacuum filtration or centrifugal filtration method,
when the materials are heated, refluxed and extracted by adopting a conventional vacuum filter, the vacuum degree is 0.06-0.1 MPa, and if the vacuum degree of vacuum filtration is less than 0.05MPa, the materials are not thoroughly filtered, so that the material utilization rate is reduced; if the vacuum degree of vacuum filtration is higher than 0.1MPa, the utilization rate of the raw materials of the emblic leafflower fruits cannot be improved, so that the energy consumption is caused; therefore, the degree of vacuum in the vacuum filtration is preferably 0.06 to 0.1 MPa.
When the heating reflux extraction material is filtered by a conventional centrifuge, the rotation speed of the centrifuge is 1000-5000 rpm, and the centrifugal separation time is 20-50 min. When the centrifugal separation time is 20-50 min and the rotating speed of the centrifugal machine is lower than 1000rpm, the separation efficiency of the heating reflux extraction material is low; when the rotating speed of the centrifugal machine is higher than 5000rpm, the content of impurities in the materials obtained by centrifugal separation is higher; therefore, the rotating speed of the centrifuge is proper to be 1000-5000 rpm;
when the rotating speed of the centrifugal machine is 1000-5000 rpm, and the centrifugal separation time is less than 20min, the separation efficiency of the heating reflux extraction material is low, and the raw material cannot be fully utilized; if the centrifugal separation time is longer than 50min, the separation efficiency is not obviously increased, and energy waste is caused; therefore, the centrifugal separation time is 20-50 min;
and distilling the filtrate obtained by filtering to remove the ethanol solvent by using reduced pressure distillation equipment under the conditions of vacuum degree of-0.06 to-0.10 MPa and temperature of 55 to 80 ℃.
When the reduced pressure distillation temperature is in the range, if the vacuum degree of the reduced pressure distillation is higher than-0.06 MPa, the evaporation concentration efficiency is low, and the consumed time is long; if the vacuum degree of the reduced pressure distillation is lower than-0.10 MPa, the target product of the raw material can be decomposed, and the yield of the final product is reduced; therefore, a vacuum degree of-0.06 to-0.10 MPa is suitable for the vacuum distillation;
when the vacuum degree of the reduced pressure distillation is within the range, if the temperature of the reduced pressure distillation is lower than 55 ℃, the separation efficiency is low, and the time cost is increased; if the reduced pressure distillation temperature is higher than 80 ℃, the aroma components of the emblic leafflower fruits are volatilized, and the utilization rate of the materials is reduced; therefore, the reduced pressure distillation temperature is preferably 55-80 ℃;
according to the invention, the ethanol solvent of the filtrate obtained by filtering is removed by using the existing reduced pressure distillation equipment, and the filtrate is kept stand to obtain the emblic leafflower fruit extract.
The invention also relates to the emblic leafflower fruit extract prepared by the preparation method. The fructus Phyllanthi extract mainly contains gallic acid, punicalagin B, methyl gallate, geraniin, corilagin, chebulalin tannic acid, chebularianic acid and ellagic acid.
The invention also relates to the application of the emblic leafflower fruit soaked in the Maillard reactant for preparing the tobacco emblic leafflower fruit extract.
In the invention, the tobacco emblic extract Maillard reactant is understood to be a tobacco essence spice.
The tobacco emblic extract Maillard reactant is prepared by the following preparation method:
according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1-3: 2-6: 15-35, adding the emblic leafflower fruit extract, glycogen and food-grade amino acid into a solvent, uniformly mixing, adjusting the pH value of a mixture solution to 8-12, heating to 80-180 ℃, carrying out Maillard reaction for 2-6 h at the temperature, carrying out reduced pressure concentration on the reaction solution at the pressure of-0.06-0.10 MPa and the temperature of 50-80 ℃ by using reduced pressure distillation equipment, and obtaining a concentrate, namely the tobacco emblic leafflower fruit extract.
According to the invention, the main function of the emblic leafflower fruit extract in preparing the maillard reaction product of the tobacco emblic leafflower fruit extract is to provide characteristic fragrance reaction raw materials and partial glycogen;
the glycogen is mainly used as Maillard reaction glycogen in the preparation of Maillard reactants of tobacco emblic leafflower fruit extract; the glycogen used in the present invention is one or more glycogen selected from the group consisting of monosaccharide, glucose-fructose syrup, honey or maltose, which are all products currently marketed, for example, glucose-fructose syrup sold under the trade name F60 by santoprene biotechnology limited.
The food-grade amino acid mainly plays a role in preparing Maillard reactants of tobacco emblic leafflower fruit extract and providing a Maillard reaction nitrogen source; the food-grade amino acid used in the present invention is one or more amino acids selected from glycine, alanine, proline, histidine, serine, leucine, and isoleucine, which are currently commercially available products, such as glycine sold under the trade name food-grade glycine by Yunnan Yunxuan biological science and technology Co., Ltd, alanine sold under the trade name food-grade L-alanine by Jiangsu Changjingzhi bioengineering Co., Ltd, and proline sold under the trade name food-grade L-proline by Jiangxi Baiying biotechnologies Ltd.
The main function of the solvent in preparing the tobacco emblic leafflower fruit extract Maillard reactant is to dissolve reaction raw materials and provide a reaction system; the solvent used in the present invention is drinking water, ethanol or propylene glycol.
The weight ratio of the emblic extract, the glycogen, the food-grade amino acid and the solvent is 1: 1-3: 2-6: 15 to 35. When the using amounts of the emblic extract, the food-grade amino acid and the solvent are in the range, if the using amount of glycogen is lower than 1, the reaction is inhibited, and the utilization rate of raw materials is reduced; if the use amount of the glycogen is more than 3, the glycogen is excessive in the reaction, so that glycogen raw materials are wasted; therefore, the use amount of the glycogen is 1-3 reasonably;
when the using amounts of the emblic extract, the glycogen and the solvent are in the range, if the using amount of the food-grade amino acid is less than 2, the reaction is inhibited, and the utilization rate of raw materials is reduced; if the dosage of the food-grade amino acid is higher than 6, the nitrogen source is excessive in the reaction, so that the amino acid raw material is wasted; therefore, the dosage of the food-grade amino acid is proper to be 2-6;
when the using amounts of the emblic extract, the glycogen and the food-grade amino acid are in the range, if the using amount of the solvent is less than 15, the concentration in the reaction system is overlarge, and the reaction process is reduced; if the dosage of the solvent is higher than 35, the energy consumption is increased by the reaction concentration in the later period; therefore, the amount of the solvent is 15 to 35;
in the invention, inorganic alkali aqueous solution such as sodium hydroxide can be used for adjusting the pH value of the mixture solution of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent to 8-12, if the pH value is lower than 8, the reaction is not completely carried out, and the material utilization rate is low; if this pH is higher than 12, it causes corrosion of the apparatus by alkali;
and (3) carrying out Maillard reaction on the mixture solution with the adjusted pH value at the temperature of 80-180 ℃ for 2-6 h. When the Maillard reaction time is 2-6 h, if the reaction temperature is lower than 80 ℃, the reaction is not completely carried out, and the material utilization rate is low; if the reaction temperature is higher than 180 ℃, the reaction by-products are increased, and the mouthfeel of the reactants is reduced; therefore, the reaction temperature is suitably 80 to 180 ℃;
when the temperature of the Maillard reaction is 80-180 ℃, if the reaction time is shorter than 2 hours, the reaction is not completely carried out, and the material utilization rate is low; if the reaction time is longer than 6h, the reaction by-products are increased, and the fragrance of the reactants is reduced; therefore, the reaction time is between 2 and 6 hours;
the obtained Maillard reaction liquid is subjected to reduced pressure concentration by using reduced pressure distillation equipment under the conditions of pressure of-0.06 to-0.10 MPa and temperature of 50 to 80 ℃, and the obtained concentrate is the tobacco emblic leafflower fruit extract
When the reduced pressure distillation temperature is within the above range, if the reduced pressure distillation pressure is higher than-0.06, the evaporation concentration efficiency is low and the time consumption is long; if the reduced pressure distillation pressure is lower than-0.10 MPa, the target product of the raw material can be decomposed, and the yield of the final product is reduced; therefore, a reduced pressure distillation pressure of-0.06 to-0.10 MPa is suitable;
when the reduced pressure distillation pressure is in the range, if the reduced pressure distillation temperature is higher than 80 ℃, the aroma components of the emblic leafflower fruits are volatilized, and the material utilization rate is reduced; if the reduced pressure distillation temperature is lower than 50 ℃, the separation efficiency is low, and the time cost is increased; therefore, the reduced pressure distillation temperature is preferably 50-80 ℃;
according to the invention, the prepared tobacco emblic leafflower fruit Maillard reactant is added into tobacco shreds, cut stems or tobacco sheets in a spraying manner according to 0.005-0.5% of the weight of tobacco, and the tobacco shreds, the cut stems or the tobacco sheets are dried to obtain smokeable tobacco products. According to YC/T138-1998 tobacco and tobacco product sensory evaluation standards, a smoking group organization consisting of 15 smoking experts smokes cigarettes containing the tobacco emblic leafflower fruit Maillard reactant and the same cigarettes without the tobacco emblic leafflower fruit Maillard reactant, and the smoking result is shown in the detailed embodiment part.
The smoking result shows that the tobacco product has rich smoke, has the characteristic fragrance of nut flavor, baking fragrance and the like, improves the tobacco quality and improves the smoking experience.
[ advantageous effects ]
The invention has the beneficial effects that:
1. the invention provides a tobacco additive taking emblic leafflower fruits as raw materials, and the application of the tobacco additive taking the emblic leafflower fruits as Maillard reactants does not change the original cigarette processing technology, improves the aroma quality of cigarettes, and improves the sensory comfort of the cigarettes, so the tobacco additive has significance and value of actual production.
2. Through the Maillard reaction, the characteristic flavor of the emblic leafflower fruit is coordinated with the tobacco fragrance, and the smoking experience of cigarettes is improved.
3. Adding the types of tobacco additives and providing a new application way of the emblic leafflower fruit.
[ detailed description ] A
The invention will be better understood from the following examples.
Example 1: preparation of tobacco emblic extract
The implementation of this example is as follows:
putting the emblic leafflower fruits into a drying device, drying for 2.6 hours at the temperature of 57 ℃ until the water content is 45.0 percent by weight, and the crushing granularity is 40-80 meshes, wherein the weight ratio of the emblic leafflower fruits to an ethanol solvent is 1: 7 adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 77% by volume, uniformly mixing, heating and refluxing at the temperature of 68 ℃ for 3.4h, filtering by using a conventional vacuum filter under the vacuum degree of 0.06MPa, removing the ethanol solvent from the obtained filtrate under the conditions of the vacuum degree of-0.06 MPa and the temperature of 75 ℃ by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 2.6: 3.6: 23, adding the prepared emblic leafflower fruit extract, monosaccharide glycogen and glycine food-grade amino acid into a drinking water solvent, uniformly mixing, adjusting the pH value of the mixture solution to 10 by using a sodium hydroxide aqueous solution, heating to 140 ℃, carrying out Maillard reaction for 3.6 hours at the temperature, carrying out reduced pressure concentration on the reaction solution by using a reduced pressure distillation device under the conditions of pressure of 0.10MPa and temperature of 60 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reactant.
The tobacco emblic leaf maillard reactant prepared in the example is added into tobacco shreds in a spraying mode according to 0.1% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
A smokable tobacco product was prepared as a control sample according to the embodiment of this example without using a maillard reactant of tobacco emblic leafflower fruit, and smoking was performed according to the smoking method described in the specification of the present application, and the results of the smoking are also shown in table 1.
Example 2: preparation of tobacco emblic extract
The implementation of this example is as follows:
putting the emblic leafflower fruits into a drying device, drying for 2.0 hours at the temperature of 60 ℃ until the water content is 44.6 percent by weight, and the crushing granularity is 40-80 meshes, wherein the weight ratio of the emblic leafflower fruits to an ethanol solvent is 1: 10 adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 83% by volume, uniformly mixing, heating and refluxing at the temperature of 72 ℃ for 2.6h, filtering for 50min at the rotating speed of 1000rpm by using a conventional centrifugal machine, removing the ethanol solvent from the obtained filtrate by using reduced pressure distillation equipment under the conditions of the vacuum degree of-0.08 MPa and the temperature of 80 ℃, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 3.0: 4.4: 27, adding the prepared emblic leafflower fruit extract, the fructose glucose syrup glycogen and the alanine food grade amino acid into an ethanol solvent, uniformly mixing, adjusting the pH value of the mixture solution to 8 by using a sodium hydroxide aqueous solution, heating to the temperature of 160 ℃, carrying out Maillard reaction for 2.8 hours at the temperature, carrying out reduced pressure concentration on the reaction solution by using a reduced pressure distillation device under the conditions of pressure of 0.06MPa and temperature of 65 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reactant.
The tobacco emblic Maillard reactant prepared in the example is added into a tobacco sheet in a spraying mode according to 0.3% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
Example 3: preparation of tobacco emblic extract
The implementation of this example is as follows:
putting the emblic leafflower fruits into a drying device, drying for 5.0 hours at the temperature of 45 ℃ until the water content is 44.2 percent by weight, and the crushing granularity is 40-80 meshes, wherein the weight ratio of the emblic leafflower fruits to an ethanol solvent is 1: 8, adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 89% by volume, uniformly mixing, heating and refluxing at the temperature of 60 ℃ for 5.0h, filtering for 38min at the rotating speed of 3000rpm by using a conventional centrifugal machine, removing the ethanol solvent from the obtained filtrate by using reduced pressure distillation equipment under the conditions of the vacuum degree of-0.10 MPa and the temperature of 60 ℃, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1.0: 2.0: 31, adding the prepared emblic leafflower fruit extract, honey glycogen and serine food-grade amino acid into a propylene glycol solvent, uniformly mixing, adjusting the pH value of the mixture solution to 9 by using a sodium hydroxide aqueous solution, heating to 80 ℃, carrying out Maillard reaction for 6.0h at the temperature, carrying out reduced pressure concentration on the reaction solution by using reduced pressure distillation equipment under the conditions of pressure of 0.06MPa and temperature of 75 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reactant.
The tobacco emblic leaf maillard reactant prepared in the example is added into cut stems in a spraying mode according to 0.005% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
Example 4: preparation of tobacco emblic leafflower fruit extract
The implementation of this example is as follows:
putting the emblic leafflower fruits into a drying device, drying for 4.4 hours at the temperature of 48 ℃ until the water content is 43.8 percent by weight, and the crushing granularity is 40-80 meshes, wherein the weight ratio of the emblic leafflower fruits to an ethanol solvent is 1: adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 65 percent by volume, uniformly mixing, heating and refluxing at the temperature of 64 ℃ for extraction for 4.2 hours, filtering by adopting a conventional vacuum filter under the vacuum degree of 0.1MPa, removing the ethanol solvent from the obtained filtrate under the conditions of the vacuum degree of-0.06 MPa and the temperature of 65 ℃ by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1.4: 2.8: 35, adding the prepared emblic leafflower fruit extract, maltose glycogen and serine food-grade amino acid into an ethanol solvent, uniformly mixing, adjusting the pH value of the mixture solution to 10 by using a sodium hydroxide aqueous solution, heating to 100 ℃, carrying out Maillard reaction for 5.2h at the temperature, carrying out reduced pressure concentration on the reaction solution by using reduced pressure distillation equipment under the conditions of pressure of 0.08MPa and temperature of 80 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reaction product.
The tobacco emblic Maillard reactant prepared in the example is added into a tobacco sheet in a spraying mode according to 0.01% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
Example 5: preparation of tobacco emblic leafflower fruit extract
The implementation of this example is as follows:
putting the emblic leafflower fruits into a drying device, drying for 3.8 hours at the temperature of 51 ℃ until the water content is 42.9 percent by weight, and the crushing granularity is 40-80 meshes, wherein the weight ratio of the emblic leafflower fruits to the ethanol solvent is 1: 6, adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 71% by volume, uniformly mixing, heating and refluxing at the temperature of 76 ℃ for 1.8h, filtering for 26min at the rotation speed of 4000rpm by using a conventional centrifugal machine, removing the ethanol solvent from the obtained filtrate under the conditions of the vacuum degree of-0.08 MPa and the temperature of 55 ℃ by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1.8: 5.2: 15, adding the prepared emblic leafflower fruit extract, monosaccharide glycogen and histidine food grade amino acid into a propylene glycol solvent, uniformly mixing, adjusting the pH value of the mixture solution to 12 by using a sodium hydroxide aqueous solution, heating to 120 ℃, carrying out Maillard reaction for 4.4h at the temperature, carrying out reduced pressure concentration on the reaction solution by using reduced pressure distillation equipment under the conditions of pressure of 0.08MPa and temperature of 55 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reaction product.
The tobacco emblic leaf maillard reactant prepared in the embodiment is added into cut stems in a spraying mode according to 0.06% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
Example 6: preparation of tobacco emblic extract
The implementation of this example is as follows:
putting the phyllanthus emblica into a drying device, drying at 54 ℃ for 3.2 hours until the water content is 44.7% by weight and the crushing particle size is 40-80 meshes, and mixing the phyllanthus emblica and an ethanol solvent according to a weight ratio of 1: 9 adding the obtained emblic leafflower fruit powder into an ethanol solvent with the concentration of 95 percent by volume, uniformly mixing, heating and refluxing for extraction for 1.0h at the temperature of 80 ℃, filtering for 20min at the rotating speed of 5000rpm by adopting a conventional centrifugal machine, removing the ethanol solvent from the obtained filtrate under the conditions of the vacuum degree of-0.10 MPa and the temperature of 70 ℃ by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower fruit extract;
then, according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 2.2: 6.0: adding the prepared emblic leafflower fruit extract, honey glycogen and leucine food grade amino acid into a propylene glycol solvent, uniformly mixing, adjusting the pH value of the mixture solution to 11 by using a sodium hydroxide aqueous solution, heating to 180 ℃, carrying out Maillard reaction for 2.0h at the temperature, carrying out reduced pressure concentration on the reaction solution by using reduced pressure distillation equipment under the conditions of pressure of 0.10MPa and temperature of 70 ℃, and obtaining a concentrate which is the tobacco emblic leafflower fruit Maillard reaction product.
The tobacco emblic leaf maillard reactant prepared in the example is added into tobacco shreds in a spraying mode according to 0.5% of the weight of tobacco, and is dried to obtain a smokable tobacco product.
The results of the test smoking were shown in Table 1, according to the test method described in the present specification.
Table 1: EXAMPLES 1-6 evaluation results of cigarette samples prepared
As can be seen from the results of smoking evaluation listed in Table 1, the Maillard reaction product of emblic leafflower fruit can improve the aroma quality of cigarettes and improve the sensory comfort of the cigarettes when being used in the cigarettes.
Claims (10)
1. A preparation method of emblic extract is characterized in that the preparation method comprises the following preparation steps:
putting the emblic leafflower fruit into drying equipment for drying and crushing, wherein the weight ratio of the emblic leafflower fruit to the ethanol solvent is 1: and 5-10 adding the obtained emblic leafflower powder into an ethanol solvent, uniformly mixing, heating and refluxing at the temperature of 60-80 ℃ for 1.0-5.0 h, filtering, removing the ethanol solvent from the obtained filtrate by using reduced pressure distillation equipment, and standing to obtain the emblic leafflower extract.
2. The process according to claim 1, wherein the emblic leafflower fruit is dried in a drying apparatus until a water content of 45% by weight or less is reached.
3. The method according to claim 1, wherein the dried emblic leafflower fruit has a crushed particle size of 40 to 80 mesh.
4. The method according to claim 1, wherein the concentration of the ethanol solvent is 65 to 95% by volume.
5. The method according to claim 1, wherein the ethanol solvent is distilled off from the filtrate obtained by filtration under a vacuum of-0.06 to-0.10 MPa and at a temperature of 55 to 80 ℃.
6. The extract of Phyllanthus emblica prepared by the preparation method according to any one of claims 1 to 5.
7. The use of fructus Phyllanthi in preparing tobacco fructus Phyllanthi extract Maillard reactant according to claim 6, wherein the tobacco fructus Phyllanthi extract Maillard reactant is prepared by the following preparation method:
according to the weight ratio of the emblic leafflower fruit extract, the glycogen, the food-grade amino acid and the solvent of 1: 1-3: 2-6: 15-35, adding the emblic leafflower fruit extract, glycogen and food-grade amino acid into a solvent, uniformly mixing, adjusting the pH value of a mixture solution to 8-12, heating to 80-180 ℃, carrying out Maillard reaction for 2-6 h at the temperature, carrying out reduced pressure concentration on the reaction solution at the pressure of-0.06-0.10 MPa and the temperature of 50-80 ℃ by using reduced pressure distillation equipment, and obtaining a concentrate, namely the tobacco emblic leafflower fruit extract.
8. Use according to claim 7, characterized in that said glycogen is one or more glycogen(s) selected from the group consisting of monosaccharides, high fructose syrup, honey or maltose.
9. Use according to claim 7, characterized in that the food-grade amino acid is one or more amino acids selected from glycine, alanine, proline, histidine, serine, leucine or isoleucine.
10. Use according to claim 7, characterized in that the solvent is drinking water, ethanol or propylene glycol.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116622441A (en) * | 2023-05-11 | 2023-08-22 | 云南巴菰生物科技股份有限公司 | Semi-dry distillation natural spice and preparation method and application thereof |
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| CN104232309A (en) * | 2014-09-30 | 2014-12-24 | 云南中烟工业有限责任公司 | Tobacco flavor prepared from phyllanthus emblica, plum, broadleaf holly leaf and tobacco and application of tobacco flavor |
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| CN109090702A (en) * | 2018-06-29 | 2018-12-28 | 郑州轻工业学院 | The preparation method and applications of Luo Han Guo Paste In Foods maillard reaction product |
| CN111528519A (en) * | 2020-04-30 | 2020-08-14 | 广西中烟工业有限责任公司 | Preparation method and application of enzyme preparation treated tobacco emblic leafflower fruit enzymolysis extract |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104232309A (en) * | 2014-09-30 | 2014-12-24 | 云南中烟工业有限责任公司 | Tobacco flavor prepared from phyllanthus emblica, plum, broadleaf holly leaf and tobacco and application of tobacco flavor |
| CN107287031A (en) * | 2017-06-06 | 2017-10-24 | 武汉黄鹤楼香精香料有限公司 | The aobvious fragrant composition separation of Turkish tobaccos maillard reaction thing prepares method and the application of tobacco additive agent |
| CN109090702A (en) * | 2018-06-29 | 2018-12-28 | 郑州轻工业学院 | The preparation method and applications of Luo Han Guo Paste In Foods maillard reaction product |
| CN111528519A (en) * | 2020-04-30 | 2020-08-14 | 广西中烟工业有限责任公司 | Preparation method and application of enzyme preparation treated tobacco emblic leafflower fruit enzymolysis extract |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116622441A (en) * | 2023-05-11 | 2023-08-22 | 云南巴菰生物科技股份有限公司 | Semi-dry distillation natural spice and preparation method and application thereof |
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