CN107285633A - A kind of surface resistant porcelain and its preparation technology - Google Patents

A kind of surface resistant porcelain and its preparation technology Download PDF

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Publication number
CN107285633A
CN107285633A CN201710509094.9A CN201710509094A CN107285633A CN 107285633 A CN107285633 A CN 107285633A CN 201710509094 A CN201710509094 A CN 201710509094A CN 107285633 A CN107285633 A CN 107285633A
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CN
China
Prior art keywords
parts
resistant
glaze
porcelain
titanium oxide
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710509094.9A
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Chinese (zh)
Inventor
闵海龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Porcelain Gas Epoch Cleaning Equipment Co Ltd
Original Assignee
Suzhou Porcelain Gas Epoch Cleaning Equipment Co Ltd
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Publication date
Application filed by Suzhou Porcelain Gas Epoch Cleaning Equipment Co Ltd filed Critical Suzhou Porcelain Gas Epoch Cleaning Equipment Co Ltd
Priority to CN201710509094.9A priority Critical patent/CN107285633A/en
Publication of CN107285633A publication Critical patent/CN107285633A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/02Antibacterial glass, glaze or enamel

Abstract

A kind of surface resistant porcelain of the present invention, it is characterised in that including ceramic idiosome, the ceramic idiosome surface is provided with resistant glaze layer, and the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25 38 parts;Nano titanium oxide:35 parts;Nano silicon:14 parts;Aluminium borate:5 12 parts;Aluminium metaphosphate:3 10 parts;Tungsten oxide:14 parts;Zirconium silicate:15 parts;Manganese dioxide:5 14 parts;Ceruse:0.5 2.5 parts;Quartz sand:25 parts.A kind of surface resistant porcelain that the present invention is provided, nano titanium oxide, nano silicon are added to resistant glaze layer, while the porcelain burnt out has attractive in appearance in itself, the adhesion of dust spot can also effectively be prevented, add the wholesomeness during use, and preparation method is simple, is conducive to industrialized production.

Description

A kind of surface resistant porcelain and its preparation technology
Technical field
The present invention relates to a kind of surface resistant porcelain and its preparation technology.
Background technology
Porcelain is unique creation of Chinese people, and the long civilization of China is represent with its unique national cultural feature, Nowadays, porcelain has goed deep into the life of people as the higher technique of artistic value and commodity.But traditional porcelain is The need for it can not meet people, it is therefore desirable to which a kind of new porcelain replaces.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of surface resistant porcelain.The surface is resistance to Dirty porcelain, resistant glaze layer is added to by nano titanium oxide, nano silicon, and the porcelain burnt out has attractive in appearance in itself Simultaneously, moreover it is possible to effectively prevent the adhesion of dust spot, the wholesomeness during use is added, and preparation method is simple, Be conducive to industrialized production.
To reach above-mentioned purpose, the technical scheme is that:
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer Include the raw material of following parts by weight:Calcined kaolin:25-38 parts;Nano titanium oxide:3-5 parts;Nano silicon:1-4 Part;Aluminium borate:5-12 parts;Aluminium metaphosphate:3-10 parts;Tungsten oxide:1-4 parts;Zirconium silicate:1-5 parts;Manganese dioxide:5-14 parts;Carbon Lead plumbate:0.5-2.5 parts;Quartz sand:2-5 parts.
Further, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25-30 parts;Nanometer two Titanium oxide:4-5 parts;Nano silicon:2-4 parts;Aluminium borate:8-12 parts;Aluminium metaphosphate:3-8 parts;Tungsten oxide:2-4 parts;Silicon Sour zirconium:1-3 parts;Manganese dioxide:5-10 parts;Ceruse:1.5-2.5 part;Quartz sand:2-4 parts.
Further, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:27 parts;Nano-silica Change titanium:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Aluminium metaphosphate:6 parts;Tungsten oxide:3 parts;Zirconium silicate:2.5 part; Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
Further, the particle diameter of the nano titanium oxide is 80-120nm.
Further, the particle diameter of the nano silicon is 60-100nm.
A kind of surface resistant porcelain, comprises the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, is made antibacterial porcelain.
Further, the step(3)The temperature of middle glaze firing is 1050 ~ 1120 DEG C, and the glaze firing time is 17 ~ 19h.
The beneficial effects of the present invention are:
A kind of surface resistant porcelain that the present invention is provided, resistant glaze layer, institute are added to by nano titanium oxide, nano silicon While the porcelain burnt out has attractive in appearance in itself, moreover it is possible to effectively prevent the adhesion of dust spot, during adding use Wholesomeness, and preparation method is simple, is conducive to industrialized production.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is further detailed with reference to embodiments Describe in detail bright.
Embodiment 1
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer Include the raw material of following parts by weight:Calcined kaolin:28 parts;Nano titanium oxide:5 parts;Nano silicon:2 parts;Boric acid Aluminium:9 parts;Aluminium metaphosphate:7 parts;Tungsten oxide:4 parts;Zirconium silicate:5 parts;Manganese dioxide:10 parts;Ceruse:0.5 part;Quartz sand: 2.5 part.
Embodiment 2
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer Include the raw material of following parts by weight:Calcined kaolin:25 parts;Nano titanium oxide:3 parts;Nano silicon:1 part;Boric acid Aluminium:12 parts;Aluminium metaphosphate:3 parts;Tungsten oxide:2 parts;Zirconium silicate:1 part;Manganese dioxide:14 parts;Ceruse:2.5 part;Quartz sand: 3 parts.
Embodiment 3
A kind of surface resistant porcelain, including ceramic idiosome, the resistant glaze layer include the raw material of following parts by weight:Calcine kaolinite Soil:27 parts;Nano titanium oxide:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Aluminium metaphosphate:6 parts;Tungsten oxide:3 Part;Zirconium silicate:2.5 part;Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
Embodiment 4
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer Include the raw material of following parts by weight:Calcined kaolin:31 parts;Nano titanium oxide:4 parts;Nano silicon:4 parts;Boric acid Aluminium:5 parts;Aluminium metaphosphate:10 parts;Tungsten oxide:1 part;Zirconium silicate:4 parts;Manganese dioxide:5 parts;Ceruse:1.5 part;Quartz sand:5 Part.
Embodiment 5
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer Include the raw material of following parts by weight:Calcined kaolin:38 parts;Nano titanium oxide:3 parts;Nano silicon:2 parts;Boric acid Aluminium:7 parts;Aluminium metaphosphate:7.5 part;Tungsten oxide:2 parts;Zirconium silicate:4 parts;Manganese dioxide:7 parts;Ceruse:1 part;Quartz sand:3 Part.
A kind of surface resistant porcelain, comprises the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, the temperature of glaze firing is 1050 ~ 1120 DEG C, and the glaze firing time is 17 ~ 19h, and antibacterial porcelain is made.
A kind of surface resistant porcelain that the present invention is provided, resistant glaze is added to by nano titanium oxide, nano silicon Layer, while the porcelain burnt out has attractive in appearance in itself, moreover it is possible to effectively prevent the adhesion of dust spot, add and use process In wholesomeness, and preparation method is simple, is conducive to industrialized production.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention In sharp claimed range.

Claims (7)

1. a kind of surface resistant porcelain, it is characterised in that including ceramic idiosome, the ceramic idiosome surface is provided with resistant glaze Layer, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25-38 parts;Nano titanium oxide:3-5 parts; Nano silicon:1-4 parts;Aluminium borate:5-12 parts;Aluminium metaphosphate:3-10 parts;Tungsten oxide:1-4 parts;Zirconium silicate:1-5 parts;Two Manganese oxide:5-14 parts;Ceruse:0.5-2.5 parts;Quartz sand:2-5 parts.
2. a kind of surface resistant porcelain according to claim 1, it is characterised in that the resistant glaze layer includes following weight The raw material of number:Calcined kaolin:25-30 parts;Nano titanium oxide:4-5 parts;Nano silicon:2-4 parts;Aluminium borate:8- 12 parts;Aluminium metaphosphate:3-8 parts;Tungsten oxide:2-4 parts;Zirconium silicate:1-3 parts;Manganese dioxide:5-10 parts;Ceruse:1.5-2.5 Part;Quartz sand:2-4 parts.
3. a kind of surface resistant porcelain according to claim 1, it is characterised in that the resistant glaze layer includes following weight The raw material of number:Calcined kaolin:27 parts;Nano titanium oxide:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Partially Aluminum phosphate:6 parts;Tungsten oxide:3 parts;Zirconium silicate:2.5 part;Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
4. a kind of surface resistant porcelain according to claim 1, it is characterised in that the particle diameter of the nano titanium oxide is 80-120nm。
5. a kind of surface resistant porcelain according to claim 1, it is characterised in that the particle diameter of the nano silicon is 60-100nm。
6. a kind of surface resistant porcelain as claimed in claim 1, it is characterised in that comprise the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, is made antibacterial porcelain.
7. a kind of surface resistant porcelain according to claim 6, it is characterised in that the step(3)The temperature of middle glaze firing For 1050 ~ 1120 DEG C, the glaze firing time is 17 ~ 19h.
CN201710509094.9A 2017-06-28 2017-06-28 A kind of surface resistant porcelain and its preparation technology Pending CN107285633A (en)

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Application Number Priority Date Filing Date Title
CN201710509094.9A CN107285633A (en) 2017-06-28 2017-06-28 A kind of surface resistant porcelain and its preparation technology

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116082030A (en) * 2022-12-26 2023-05-09 广西产研院新型功能材料研究所有限公司 Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof

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CN102276293A (en) * 2011-06-20 2011-12-14 华北水利水电学院 Kieselguhr-based environmentally-friendly glaze material for inner wall brick and inner wall brick prepared by utilizing same
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116082030A (en) * 2022-12-26 2023-05-09 广西产研院新型功能材料研究所有限公司 Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof

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