CN107285633A - A kind of surface resistant porcelain and its preparation technology - Google Patents
A kind of surface resistant porcelain and its preparation technology Download PDFInfo
- Publication number
- CN107285633A CN107285633A CN201710509094.9A CN201710509094A CN107285633A CN 107285633 A CN107285633 A CN 107285633A CN 201710509094 A CN201710509094 A CN 201710509094A CN 107285633 A CN107285633 A CN 107285633A
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- CN
- China
- Prior art keywords
- parts
- resistant
- glaze
- porcelain
- titanium oxide
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
Abstract
A kind of surface resistant porcelain of the present invention, it is characterised in that including ceramic idiosome, the ceramic idiosome surface is provided with resistant glaze layer, and the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25 38 parts;Nano titanium oxide:35 parts;Nano silicon:14 parts;Aluminium borate:5 12 parts;Aluminium metaphosphate:3 10 parts;Tungsten oxide:14 parts;Zirconium silicate:15 parts;Manganese dioxide:5 14 parts;Ceruse:0.5 2.5 parts;Quartz sand:25 parts.A kind of surface resistant porcelain that the present invention is provided, nano titanium oxide, nano silicon are added to resistant glaze layer, while the porcelain burnt out has attractive in appearance in itself, the adhesion of dust spot can also effectively be prevented, add the wholesomeness during use, and preparation method is simple, is conducive to industrialized production.
Description
Technical field
The present invention relates to a kind of surface resistant porcelain and its preparation technology.
Background technology
Porcelain is unique creation of Chinese people, and the long civilization of China is represent with its unique national cultural feature,
Nowadays, porcelain has goed deep into the life of people as the higher technique of artistic value and commodity.But traditional porcelain is
The need for it can not meet people, it is therefore desirable to which a kind of new porcelain replaces.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of surface resistant porcelain.The surface is resistance to
Dirty porcelain, resistant glaze layer is added to by nano titanium oxide, nano silicon, and the porcelain burnt out has attractive in appearance in itself
Simultaneously, moreover it is possible to effectively prevent the adhesion of dust spot, the wholesomeness during use is added, and preparation method is simple,
Be conducive to industrialized production.
To reach above-mentioned purpose, the technical scheme is that:
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer
Include the raw material of following parts by weight:Calcined kaolin:25-38 parts;Nano titanium oxide:3-5 parts;Nano silicon:1-4
Part;Aluminium borate:5-12 parts;Aluminium metaphosphate:3-10 parts;Tungsten oxide:1-4 parts;Zirconium silicate:1-5 parts;Manganese dioxide:5-14 parts;Carbon
Lead plumbate:0.5-2.5 parts;Quartz sand:2-5 parts.
Further, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25-30 parts;Nanometer two
Titanium oxide:4-5 parts;Nano silicon:2-4 parts;Aluminium borate:8-12 parts;Aluminium metaphosphate:3-8 parts;Tungsten oxide:2-4 parts;Silicon
Sour zirconium:1-3 parts;Manganese dioxide:5-10 parts;Ceruse:1.5-2.5 part;Quartz sand:2-4 parts.
Further, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:27 parts;Nano-silica
Change titanium:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Aluminium metaphosphate:6 parts;Tungsten oxide:3 parts;Zirconium silicate:2.5 part;
Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
Further, the particle diameter of the nano titanium oxide is 80-120nm.
Further, the particle diameter of the nano silicon is 60-100nm.
A kind of surface resistant porcelain, comprises the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon
Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging
Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, is made antibacterial porcelain.
Further, the step(3)The temperature of middle glaze firing is 1050 ~ 1120 DEG C, and the glaze firing time is 17 ~ 19h.
The beneficial effects of the present invention are:
A kind of surface resistant porcelain that the present invention is provided, resistant glaze layer, institute are added to by nano titanium oxide, nano silicon
While the porcelain burnt out has attractive in appearance in itself, moreover it is possible to effectively prevent the adhesion of dust spot, during adding use
Wholesomeness, and preparation method is simple, is conducive to industrialized production.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is further detailed with reference to embodiments
Describe in detail bright.
Embodiment 1
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer
Include the raw material of following parts by weight:Calcined kaolin:28 parts;Nano titanium oxide:5 parts;Nano silicon:2 parts;Boric acid
Aluminium:9 parts;Aluminium metaphosphate:7 parts;Tungsten oxide:4 parts;Zirconium silicate:5 parts;Manganese dioxide:10 parts;Ceruse:0.5 part;Quartz sand:
2.5 part.
Embodiment 2
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer
Include the raw material of following parts by weight:Calcined kaolin:25 parts;Nano titanium oxide:3 parts;Nano silicon:1 part;Boric acid
Aluminium:12 parts;Aluminium metaphosphate:3 parts;Tungsten oxide:2 parts;Zirconium silicate:1 part;Manganese dioxide:14 parts;Ceruse:2.5 part;Quartz sand:
3 parts.
Embodiment 3
A kind of surface resistant porcelain, including ceramic idiosome, the resistant glaze layer include the raw material of following parts by weight:Calcine kaolinite
Soil:27 parts;Nano titanium oxide:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Aluminium metaphosphate:6 parts;Tungsten oxide:3
Part;Zirconium silicate:2.5 part;Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
Embodiment 4
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer
Include the raw material of following parts by weight:Calcined kaolin:31 parts;Nano titanium oxide:4 parts;Nano silicon:4 parts;Boric acid
Aluminium:5 parts;Aluminium metaphosphate:10 parts;Tungsten oxide:1 part;Zirconium silicate:4 parts;Manganese dioxide:5 parts;Ceruse:1.5 part;Quartz sand:5
Part.
Embodiment 5
A kind of surface resistant porcelain, including ceramic idiosome, the ceramic idiosome surface are provided with resistant glaze layer, the resistant glaze layer
Include the raw material of following parts by weight:Calcined kaolin:38 parts;Nano titanium oxide:3 parts;Nano silicon:2 parts;Boric acid
Aluminium:7 parts;Aluminium metaphosphate:7.5 part;Tungsten oxide:2 parts;Zirconium silicate:4 parts;Manganese dioxide:7 parts;Ceruse:1 part;Quartz sand:3
Part.
A kind of surface resistant porcelain, comprises the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon
Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging
Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, the temperature of glaze firing is 1050 ~ 1120 DEG C, and the glaze firing time is 17 ~ 19h, and antibacterial porcelain is made.
A kind of surface resistant porcelain that the present invention is provided, resistant glaze is added to by nano titanium oxide, nano silicon
Layer, while the porcelain burnt out has attractive in appearance in itself, moreover it is possible to effectively prevent the adhesion of dust spot, add and use process
In wholesomeness, and preparation method is simple, is conducive to industrialized production.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (7)
1. a kind of surface resistant porcelain, it is characterised in that including ceramic idiosome, the ceramic idiosome surface is provided with resistant glaze
Layer, the resistant glaze layer includes the raw material of following parts by weight:Calcined kaolin:25-38 parts;Nano titanium oxide:3-5 parts;
Nano silicon:1-4 parts;Aluminium borate:5-12 parts;Aluminium metaphosphate:3-10 parts;Tungsten oxide:1-4 parts;Zirconium silicate:1-5 parts;Two
Manganese oxide:5-14 parts;Ceruse:0.5-2.5 parts;Quartz sand:2-5 parts.
2. a kind of surface resistant porcelain according to claim 1, it is characterised in that the resistant glaze layer includes following weight
The raw material of number:Calcined kaolin:25-30 parts;Nano titanium oxide:4-5 parts;Nano silicon:2-4 parts;Aluminium borate:8-
12 parts;Aluminium metaphosphate:3-8 parts;Tungsten oxide:2-4 parts;Zirconium silicate:1-3 parts;Manganese dioxide:5-10 parts;Ceruse:1.5-2.5
Part;Quartz sand:2-4 parts.
3. a kind of surface resistant porcelain according to claim 1, it is characterised in that the resistant glaze layer includes following weight
The raw material of number:Calcined kaolin:27 parts;Nano titanium oxide:4.5 part;Nano silicon:3 parts;Aluminium borate:11 parts;Partially
Aluminum phosphate:6 parts;Tungsten oxide:3 parts;Zirconium silicate:2.5 part;Manganese dioxide:7 parts;Ceruse:2 parts;Quartz sand:3 parts.
4. a kind of surface resistant porcelain according to claim 1, it is characterised in that the particle diameter of the nano titanium oxide is
80-120nm。
5. a kind of surface resistant porcelain according to claim 1, it is characterised in that the particle diameter of the nano silicon is
60-100nm。
6. a kind of surface resistant porcelain as claimed in claim 1, it is characterised in that comprise the following steps:
(1)Training mud is prepared, by 8 ~ 10h of kiln-firing after training mud shaping and drying, ceramic idiosome is made;
(2)In proportion by calcined kaolin, nano titanium oxide, nano silicon, aluminium borate, aluminium metaphosphate, tungsten oxide, silicon
Sour zirconium, manganese dioxide, ceruse, quartz sand are well mixed, and are worn into the powder that fineness is 12-180 mesh, outer glaze are made, using swinging
Glaze method outer glaze on ceramic idiosome surface;
(3)Glaze firing, is made antibacterial porcelain.
7. a kind of surface resistant porcelain according to claim 6, it is characterised in that the step(3)The temperature of middle glaze firing
For 1050 ~ 1120 DEG C, the glaze firing time is 17 ~ 19h.
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CN201710509094.9A CN107285633A (en) | 2017-06-28 | 2017-06-28 | A kind of surface resistant porcelain and its preparation technology |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116082030A (en) * | 2022-12-26 | 2023-05-09 | 广西产研院新型功能材料研究所有限公司 | Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof |
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CN101857463A (en) * | 2010-06-04 | 2010-10-13 | 深圳市永丰源实业有限公司 | Ceramic glaze and preparation method thereof |
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CN101857463A (en) * | 2010-06-04 | 2010-10-13 | 深圳市永丰源实业有限公司 | Ceramic glaze and preparation method thereof |
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CN103755389A (en) * | 2013-12-23 | 2014-04-30 | 宾阳县明翔新材料科技有限公司 | Glaze material with heat-insulation and heat-preservation functions and preparation method of glaze material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116082030A (en) * | 2022-12-26 | 2023-05-09 | 广西产研院新型功能材料研究所有限公司 | Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof |
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