CN107266935B - A kind of dyestuff, dye composite and dye material composition - Google Patents
A kind of dyestuff, dye composite and dye material composition Download PDFInfo
- Publication number
- CN107266935B CN107266935B CN201710509422.5A CN201710509422A CN107266935B CN 107266935 B CN107266935 B CN 107266935B CN 201710509422 A CN201710509422 A CN 201710509422A CN 107266935 B CN107266935 B CN 107266935B
- Authority
- CN
- China
- Prior art keywords
- dye
- monomer
- composite
- dyestuff
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000975 dye Substances 0.000 title claims abstract description 92
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 13
- 108091060290 Chromatid Proteins 0.000 claims description 9
- 210000004756 chromatid Anatomy 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000002708 enhancing effect Effects 0.000 abstract description 8
- 241000288027 Chrysolophus pictus Species 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000985 reactive dye Substances 0.000 description 4
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 3
- 241000083869 Polyommatus dorylas Species 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009725 powder blending Methods 0.000 description 2
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 2
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0034—Mixtures of two or more pigments or dyes of the same type
- C09B67/0035—Mixtures of phthalocyanines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/004—Mixtures of two or more reactive dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0092—Dyes in solid form
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of dyestuff, dye composite and dye material compositions.The present invention provides a kind of dye material compositions comprising, the dye monomer A as shown in formula (1), the dye monomer B as shown in formula (2), wherein a+b=3.5；X+Y+Z=3.5~4.0；The dye monomer A and dye monomer B, is based on parts by weight 1.1:1~8.7:1.The invention also discloses a kind of dye composite containing the dye material composition, the dyestuff which is prepared, enhancing with higher, excellent color fastness, high performance-price ratio.
Description
Technical field
The present invention relates to a kind of dyestuff, dye composite and dye material compositions.
Background technique
With the increasingly raising of living standard, requirement of the people to textile product is also higher and higher, to be used in weaving
Requirement of the reactive dye of product dyeing on properties is increasingly harsh.Reactive dye not only to have excellent dyefastness and
Dyeability, and to meet environmental requirement.
The dye monomer of bright blue kind currently on the market, commonly used in the stamp of cellulose fibre, enhancing is inadequate, often
More than 30g/kg dosage, with the increase of dye strength, stamp cloth cover depth cannot but increase therewith, reach saturation depth,
Therefore some deeper turquoise blues can not accomplish；Or predominantly normal dyeing uses, depth is splendid when for stamp, but coloured light
Greener dark, every fastness is lacking.
Summary of the invention
The defects of present invention is in order to overcome bright blue dye printing enhancing in the prior art and bad fastness ability, to mention
A kind of dyestuff, dye composite and dye material composition are supplied.Dye composite of the invention, using compounded technology, compounding
Reactive turquoise blue dye product out, uses on stamp, there is excellent enhancing, and various aspects fastness is excellent, has more apparent
Advantage.
The present invention provides a kind of dye material compositions comprising, as dye monomer A shown in formula (1) is (bright blue
14#):
The dye monomer B as shown in formula (2) (bright blue 21#):
Wherein, a+b=3.5；X+Y+Z=3.5~4.0；
The dye monomer A and dye monomer B, is based on parts by weight 1.1:1~8.7:1.
The dye material composition can be made of the dye monomer A and the dye monomer B.
The dye monomer A and dye monomer B is preferably 1.4:1~5:1 based on parts by weight.
Wherein, the dye monomer A and dye monomer B can each independently preferably with powdery, synthetic solvent or
Its aqueous solution form exists.
(the bright blue K-GL of golden pheasant (Jiangsu golden pheasant industry) or the bright blue K- of good enlightening may be selected in bright blue 14) to the dye monomer A
GL (praises Dihua work in Shaoxing), the preferably bright blue K-GL of golden pheasant.
(the bright blue KN-G of golden pheasant (Jiangsu golden pheasant industry) or the bright blue G of good enlightening may be selected in bright blue 21) to the dye monomer B
266% (praising Dihua work in Shaoxing), the preferably bright blue KN-G of golden pheasant.
As needed, dye material composition of the present invention can be a component form of all the components mixing, can also
Independently or by each ingredient it is divided into multiple groups part nested form of several groups for each ingredient.
The present invention also provides a kind of dye composites comprising, dye material composition and auxiliary agent as described above.
The dye composite can by the dye monomer A, the dye monomer B is formed and auxiliary agent forms.
The auxiliary agent can be the common auxiliary agent of this field, such as Dispersant MF and/or dispersing agent NNO.
The auxiliary agent exists preferably in the form of powder and/or solution.Commercial product can be used in the auxiliary agent.
In the dye composite, it may include following components by percentage to the quality: for example, the chromatid
A is 87%, 80%, 75%, 70%, 65%, 60%, 55% or 50%；The chromatid B be 10%, 16%, 20%,
25%, 32%, 36%, 40% or 45%.
The dye composite is preferably comprised following components by percentage to the quality: dye described in 50%~87%
Chromophoric monomer A, chromatid B described in 10%~45%, auxiliary agent described in 3~5%；More preferably, the dye composite packet
Include following components by percentage to the quality: chromatid A described in 65%~80%, chromatid described in 16%~32%
B, auxiliary agent described in 3~5%.
As needed, dye composite of the present invention can be a component form of all the components mixing, can also be each
Ingredient is independent or each ingredient is divided into multiple groups part nested form of several groups.
Of the invention additionally provides a kind of dyestuff, is mixed with to obtain by the dye composite.The mixing can
With this field conventional mixing method, such as in required ratio mechanically mixed dye monomer A, dye monomer B and auxiliary agent, or with ability
Mode known to domain carries out blending；More preferably, the dye composite is spray-dried again using liquid slurry blending, or
The mode of monomer powders blending is prepared；The liquid slurry blending time is 3 hours；At present mouth material returns the powder blending
Material 3 times suitable for reading, total incorporation time 3 hours.
The present invention also provides application of the dyestuff in cellulosic material dyeing, the preferred cotton of the cellulosic material,
Fiber crops or viscose fiber, more preferable viscose fiber.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can any combination to get the present invention it is each preferably
Example.
Commercial product can be used in dye monomer A and dye monomer B, can also use method system well known in the art
It is standby.
The positive effect of the present invention is that: the present invention provides a kind of dye material composition and contain the dye material
The dye composite of composition, the dyestuff which is prepared have excellent dyefastness and dyeability, and
It is highly suitable for the dyeing of cellulosic material, there is excellent enhancing, excellent every color fastness, thick in color.
Detailed description of the invention
Fig. 1 is enhancing curve comparison.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.In the following examples, the experimental methods for specific conditions are not specified, according to conventional methods and conditions, or according to quotient
The selection of product specification.
Examples 1 to 8 and comparative example 1~9
(bright blue 14) are the bright blue K-GL of golden pheasant to dye monomer A；(bright blue 21) are the bright blue KN-G of golden pheasant to dye monomer B.
Dye monomer A, dye monomer B can be used method well known in the art and prepared, the compound being known in the art.
Embodiment 1-8 and comparative example 1~9 are all made of monomer dry powder blending, using the taper blending device that dye industry is common,
Blending 3 hours, feed back was primary per hour, and totally 3 times, abundant blending is uniform, with upper and lower Sampling Intensity difference be no more than 2% for up to
Mark.
Table 1
Turquoise reactive dyestuffs made from above-described embodiment are subjected to stamp test using the printing with reactive dye method of standard
(measurement of GB/T2388-2003 chemically-reactive dyes stamp coloured light and intensity), obtains its corresponding performance data, is shown in Table 2.
Table 2 (stamp depth 30g/kg, pure cotton plain cloth)
Reactive turquoise blue dyestuff effect detection made from above-described embodiment uses standard for wear resistance: ISO 105X12；It is resistance to
Perspiration fastness: 105 E04 of ISO；Soaping fastness: 105 C03 of ISO.
It is analyzed by 2 embodiment 1-8 detection data of table, the compound bright blue dyestuff that the present invention obtains can be according to market need
It asks, proportion is adjusted according to different form and aspect and depth, every fastness can reach standard requirements.
It is analyzed by 2 comparative example 1-9 detection data of table, when component B ratio is higher than component A, fastness can be declined；When
When being compounded using the combination of bright blue 72# and bright blue 25#, fastness is not so good as the effect of component A and component B compounding.
The comparison of stamp enhancing is carried out by embodiment 3 and comparative example 1 and comparative example 2, prints 10/20/30/40/50/ respectively
60/70/80g/kg cloth specimen, with embodiment 3, the cloth specimen of stamp depth 80g/kg is surveyed using colour photometer respectively as reference depth
Other cloth specimen depth are tried, and draw following enhancing curve comparison Fig. 1.It will be seen from figure 1 that embodiment 3 is mentioned compared to comparative example 2
The rate of liter is obviously high.
Claims (9)
1. a kind of dye material composition, which is characterized in that including the dye monomer as shown in formula (1)
A:
The dye monomer B as shown in formula (2):
Wherein, a+b=3.5；X+Y+Z=3.5~4.0；
The dye monomer A and dye monomer B, is based on parts by weight 1.1:1~8.7:1.
2. dye material composition as described in claim 1, which is characterized in that the dye monomer A and the dyestuff list
Body B is independent to be existed in the form of powdery, synthetic solvent or its aqueous solution；
And/or the dye monomer A and dye monomer B, it is based on parts by weight 1.4:1~5:1.
3. a kind of dye composite, which is characterized in that including dye material composition as claimed in claim 1 or 2 and auxiliary agent.
4. dye composite as claimed in claim 3, which is characterized in that the auxiliary agent is Dispersant MF and/or diffusant
NNO。
5. dye composite as claimed in claim 3, which is characterized in that the auxiliary agent is deposited in the form of powder and/or solution
?.
6. dye composite as claimed in claim 3, which is characterized in that the dye composite includes following with quality hundred
Divide the component than meter: chromatid A described in 50%~87%, chromatid B described in 10%~45%, described in 3~5%
Auxiliary agent.
7. dye composite as claimed in claim 6, which is characterized in that the dye composite includes following with quality hundred
Divide the component than meter: chromatid A described in 65%~80%, chromatid B described in 16%~32%, described in 3~5%
Auxiliary agent.
8. a kind of dyestuff, which is characterized in that will be mixed with to obtain by any one of claim 3~7 dye composite.
9. dyestuff as claimed in claim 8, which is characterized in that described is mixed into the dye monomer A, the dye
Material list body B and the auxiliary agent are spray-dried again using liquid slurry blending or monomer powders blending.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710509422.5A CN107266935B (en) | 2017-06-28 | 2017-06-28 | A kind of dyestuff, dye composite and dye material composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710509422.5A CN107266935B (en) | 2017-06-28 | 2017-06-28 | A kind of dyestuff, dye composite and dye material composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107266935A CN107266935A (en) | 2017-10-20 |
| CN107266935B true CN107266935B (en) | 2019-04-12 |
Family
ID=60071047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710509422.5A Expired - Fee Related CN107266935B (en) | 2017-06-28 | 2017-06-28 | A kind of dyestuff, dye composite and dye material composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107266935B (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI290946B (en) * | 2000-07-26 | 2007-12-11 | Nippon Kayaku Kk | Cyan dye mixture, aqueous cyanic ink composition and ink-jet printing method |
| JP2002097393A (en) * | 2000-09-26 | 2002-04-02 | Mitsubishi Chemicals Corp | Ink set for ink jet recording and method for ink jet recording |
| CN1445297A (en) * | 2003-04-10 | 2003-10-01 | 孙德锁 | Complex reactive turquoise blue dye |
| KR20060085780A (en) * | 2005-01-25 | 2006-07-28 | (주)경인양행 | Mixture of reactive dye compounds and dyeing method of the same |
| CN104478887A (en) * | 2014-12-11 | 2015-04-01 | 吴江桃源染料有限公司 | Reactive turquoise blue dye semifinished product, and preparation method and application thereof |
| CN106049105B (en) * | 2016-06-08 | 2018-08-17 | 山东黄河三角洲纺织科技研究院有限公司 | A method of improving the emerald green blue stamp level-dyeing property of activity |
-
2017
- 2017-06-28 CN CN201710509422.5A patent/CN107266935B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN107266935A (en) | 2017-10-20 |
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Effective date of registration: 20190809 Address after: 201703 Shanghai city Qingpu District Songhua Road No. 881 Co-patentee after: YANTAI ANOKY FINE CHEMICALS Co.,Ltd. Patentee after: SHANGHAI ANOKY GROUP Co.,Ltd. Co-patentee after: SHANGHAI ANOKY DIGITAL TECHNOLOGY Co.,Ltd. Co-patentee after: DONGYING ANOKY TEXTILE MATERIALS Co.,Ltd. Co-patentee after: SHANGHAI SHANGHU DIGITAL TECHNOLOGY Co.,Ltd. Co-patentee after: Yantai Shangyu Digital Technology Co.,Ltd. Address before: 224631 North of Weiliu Road, Chenjiagang Town, Xiangshui County, Yancheng City, Jiangsu Province Co-patentee before: SHANGHAI ANOKY GROUP Co.,Ltd. Patentee before: JIANGSU ANOKY CHEMICALS Co.,Ltd. Co-patentee before: SHANGHAI ANOKY DIGITAL TECHNOLOGY Co.,Ltd. Co-patentee before: YANTAI ANOKY FINE CHEMICALS Co.,Ltd. Co-patentee before: DONGYING ANOKY TEXTILE MATERIALS Co.,Ltd. |
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Effective date of registration: 20201228 Address after: 265601 Hairun Road, BEIGOU Town, Penglai District, Yantai City, Shandong Province Patentee after: YANTAI ANOKY FINE CHEMICALS Co.,Ltd. Patentee after: SHANGHAI ANOKY GROUP Co.,Ltd. Patentee after: SHANGHAI ANOKY DIGITAL TECHNOLOGY Co.,Ltd. Patentee after: DONGYING ANOKY TEXTILE MATERIALS Co.,Ltd. Patentee after: SHANGHAI SHANGHU DIGITAL TECHNOLOGY Co.,Ltd. Patentee after: Yantai Shangyu Digital Technology Co.,Ltd. Patentee after: Shandong annuoqi Fine Chemical Co.,Ltd. Address before: No. 881, Songhua Road, Qingpu District, Shanghai City, Shanghai Patentee before: SHANGHAI ANOKY GROUP Co.,Ltd. Patentee before: YANTAI ANOKY FINE CHEMICALS Co.,Ltd. Patentee before: SHANGHAI ANOKY DIGITAL TECHNOLOGY Co.,Ltd. Patentee before: DONGYING ANOKY TEXTILE MATERIALS Co.,Ltd. Patentee before: SHANGHAI SHANGHU DIGITAL TECHNOLOGY Co.,Ltd. Patentee before: Yantai Shangyu Digital Technology Co.,Ltd. |
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