CN107266936A - A kind of dyestuff, dye material composition and dye material composition and application - Google Patents

A kind of dyestuff, dye material composition and dye material composition and application Download PDF

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Publication number
CN107266936A
CN107266936A CN201710530494.8A CN201710530494A CN107266936A CN 107266936 A CN107266936 A CN 107266936A CN 201710530494 A CN201710530494 A CN 201710530494A CN 107266936 A CN107266936 A CN 107266936A
Authority
CN
China
Prior art keywords
dye
material composition
component
dye material
oso
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710530494.8A
Other languages
Chinese (zh)
Inventor
韩伟鹏
夏先广
朱镇
燕美芳
杨建�
韩莹莹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd
Shanghai Anoky Digital Technology Co Ltd
Yantai Anoky Fine Chemical Co Ltd
Shanghai Anoky Group Co Ltd
Jiangsu Anoky Chemicals Co Ltd
Original Assignee
DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd
Shanghai Anoky Digital Technology Co Ltd
Yantai Anoky Fine Chemical Co Ltd
Shanghai Anoky Group Co Ltd
Jiangsu Anoky Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd, Shanghai Anoky Digital Technology Co Ltd, Yantai Anoky Fine Chemical Co Ltd, Shanghai Anoky Group Co Ltd, Jiangsu Anoky Chemicals Co Ltd filed Critical DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd
Priority to CN201710530494.8A priority Critical patent/CN107266936A/en
Publication of CN107266936A publication Critical patent/CN107266936A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0079—Azoic dyestuff preparations
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0034—Mixtures of two or more pigments or dyes of the same type
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/004—Mixtures of two or more reactive dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0047—Mixtures of two or more reactive azo dyes
    • C09B67/005—Mixtures of two or more reactive azo dyes all the reactive groups being not directly attached to a heterocyclic system
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0072—Preparations with anionic dyes or reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of dyestuff, dye material composition and dye material composition and application.The dye material composition, it includes following being calculated as 1.1 with parts by weight:1~8.7:1 component A and B component, described component A is the dye monomer A compounds shown in one or more following formula (1), and described B component is the dye monomer B compounds shown in one or more following formula (2).This kind of dyestuff, with higher deep concentration, excellent color fastness, easily high levelling property, washing property.

Description

A kind of dyestuff, dye material composition and dye material composition and application
Technical field
The present invention relates to a kind of dyestuff, dye material composition and dye material composition and application.
Background technology
With the increasingly raising of living standard, requirement of the people to textile product also more and more higher, thereby using in weaving Requirement of the reactive dye of product dyeing on properties is increasingly harsh.Reactive dye not only will have excellent dyefastness and Dyeability, and to meet environmental requirement.
Active orange dye product in the market, otherwise depth is not enough, it is normal in dark color can also use reluctantly, but Product does not have advantage when doing some special dark colors, or depth is splendid, but bright-colored degree and every fastness have been short of.
The content of the invention
The present invention is in order to overcome the defects such as orange dyefastness and dyeability be not good in the prior art, so as to provide A kind of dyestuff, dye material composition and dye material composition and application.The invention provides a kind of combination of reactive dye Thing, using compounded technology, the advantage of two components of summary component A and component B, the active orange production of compounding out Product, there is excellent enhancing in dyeability, and each side fastness is excellent, with more apparent advantage.
The invention provides a kind of dye material composition, it includes following being calculated as 1.1 with parts by weight:1~8.7:1 Component A and B component；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1For-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na, and R1For contraposition or meta substitution；
R2For-NHCONH2Or-NHCOCH3；
R3、R4、R5And R6It is each independently H ,-SO3H or-SO3Na；
R7And R8It is each independently-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na；
Preferred R in described component A structure1For-SO2C2H4OSO3Na；
Preferred R in described component A structure3For-SO3Na；
Preferred R in described component A structure4For H.
Preferred R in described B component structure5For-SO3Na；
Preferred R in described B component structure6For H；
Preferred R in described B component structure7And R8It is each independently-SO2C2H4OSO3Na。
After the substituent combination, the compound of formation is commercial dyes chemicals.
Formula (1) is preferably as follows structure：
Or
Formula (2) is preferably as follows structure：
Or
Described dye material composition can be made up of described dye monomer A with described dye monomer B.
The dye monomer A and dye monomer B can be independently of one another preferably with powdery, synthetic solvent or its is water-soluble Liquid form is present.
Described dye monomer A and described dye monomer B, is preferably calculated as 1.4 with parts by weight:1~5:1.
As needed, the component form that dye material composition of the present invention can mix for all the components, also may be used Independently or by each composition it is divided into some groups of many component nested forms for each composition.
Present invention also offers a kind of dye composite, it includes, dye material composition and auxiliary agent as described above.
Described dye composite can by described dye monomer A, described dye monomer B is constituted and auxiliary agent is constituted.
The auxiliary agent can be the conventional auxiliary agent of this area, such as Dispersant MF and/or dispersing agent NNO.
The auxiliary agent exists preferably in the form of powder and/or solution.The auxiliary agent can use commercially available prod.
In described dye composite, it may include following components by percentage to the quality：For example, described chromatid A is 87%, 80%, 75%, 70%, 65%, 60%, 55% or 50%；Described chromatid B be 10%, 16%, 20%, 25%th, 32%, 36%, 40% or 45%.
Described dye composite is preferably comprised following components by percentage to the quality：Dye described in 50%~87% Chromophoric monomer A, the chromatid B described in 10%~45%, the auxiliary agent described in 3~5%；More preferably, described dye composite bag Include following components by percentage to the quality：Chromatid A described in 65%~80%, the chromatid described in 16%~32% B, the auxiliary agent described in 3~5%.
As needed, the component form that dye composite of the present invention can mix for all the components, or respectively Composition is independent or each composition is divided into some groups of many component nested forms.
The present invention's additionally provides a kind of dyestuff, and it is mixed with by the dye composite and obtained.Described mixing can This area conventional mixing method is used, ratio mechanically mixed dye monomer A, dye monomer B and auxiliary agent, or with ability such as needed for Mode known to domain carries out blending；More preferably, described dye composite is spray-dried again using liquid slurry blending, or The mode of monomer powders blending is prepared；The liquid slurry blending time is 3 hours；At present mouth material is returned the powder blending Material suitable for reading 3 times, total incorporation time 3 hours.
Present invention also offers the dyestuff cellulosic material dyeing in application, the preferred cotton of cellulosic material, Fiber crops or viscose fiber, more preferably viscose fiber.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, and produce the present invention each preferably Example.
Dye monomer A and dye monomer B can use commercially available prod, it would however also be possible to employ method system well known in the art It is standby.
The positive effect of the present invention is：The invention provides a kind of dye material composition and containing the dye material The dye composite of composition, the dyestuff that the dye material composition is prepared has excellent dyefastness and dyeability Can, and it is highly suitable for the dyeing of cellulosic material, with excellent enhancing, excellent every color fastness, thick in color.
Embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality Apply among a scope.The experimental method of unreceipted actual conditions in the following example, conventionally and condition, or according to business Product specification is selected.
Dye monomer A, dye monomer B can be prepared using method well known in the art, the change being known in the art Compound.
Embodiment 1~9：
Dye monomer A is compound (I), and dye monomer B is compound (III)；
Embodiment 10~12：
Dye monomer A is compound (II), and dye monomer B is compound (IV)；
Comparative example 1 is compound (I), and comparative example 2 is compound (IV)；
According to data in table 1, by dye monomer A, dye monomer B and auxiliary agent, using liquid slurry blending, mixing is equal After even, then it is spray-dried.The liquid slurry blending time is 2 hours.
Table 1 (the dye material composition of embodiment 1~12 proportioning)
Reactive dye made from above-described embodiment are subjected to dyeing survey using the reactive dye of standard on pure cotton knitting cloth Try (chemically-reactive dyes dyeing colo r light and the bioassay standard GB/T 2387-2006 of intensity), obtain its corresponding performance data, be shown in Table 2。
Table 2 (is contaminated, bath raio 1:10,60 degree of dyeing, O.W.F：3%)
Wherein Integ values are a numerical value for representing to dye cloth specimen Apparent Depth, and numerical value is bigger, and the color that represents is deeper, is logical Colour photometer is crossed directly to measure.
Reactive dye effect detection made from above-described embodiment uses standard for wear resistance：ISO 105X12；Perspiration resistance Fastness：ISO 105 E04；Soaping fastness：ISO 105 C03.
Data analysis is detected by table 2, the compound orange that the present invention is obtained completely can be according to coloured differently form and aspect and depth To adjust proportioning, every fastness can reach standard requirement.

Claims (10)

1. a kind of dye material composition, it is characterised in that it includes following being calculated as 1.1 with parts by weight:1~8.7:1 A groups Divide and B component；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1For-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na, and R1For contraposition or meta substitution；
R2For-NHCONH2Or-NHCOCH3；
R3、R4、R5And R6It is each independently H ,-SO3H or-SO3Na；
R7And R8It is each independently-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na。
2. dye material composition as claimed in claim 1, it is characterised in that in described component A, R1For- SO2C2H4OSO3Na；
And/or, R3For-SO3Na；
And/or, R4For-H.
3. dye material composition as claimed in claim 1, it is characterised in that described component A is
4. dye material composition as claimed in claim 1, it is characterised in that in described B component, R5For-SO3Na；
And/or, R6For H；
And/or, R7And R8It is each independently-SO2C2H4OSO3Na。
5. dye material composition as claimed in claim 1, it is characterised in that described B component is
6. dye material composition as claimed in claim 1, it is characterised in that the dye monomer A and described dyestuff list Body B is present in powder, synthetic solvent or the aqueous solution independently of one another；
And/or, described dye monomer A and described dye monomer B is calculated as 1.4 with parts by weight:1~5:1.
7. a kind of dye composite, it is characterised in that it includes the dye material combination as described in any one of claim 1~6 Thing and auxiliary agent.
8. dye composite as claimed in claim 7, it is characterised in that the auxiliary agent is deposited in the form of powder and/or solution ；
And/or, described auxiliary agent is Dispersant MF and/or dispersing agent NNO；
And/or, described dye composite includes following components by percentage to the quality：Dyeing list described in 50%~87% Body A, the chromatid B described in 10%~45%, the auxiliary agent described in 3~5%；It is preferred that the chromatid A described in 65%~80%, Chromatid B described in 16%~32%, the auxiliary agent described in 3~5%.
9. a kind of dyestuff, it is characterised in that will be prepared as the dye combinations mixture described in claim 7 or 8.
10. a kind of application of dyestuff as claimed in claim 9 in the dyeing of cellulosic material.
CN201710530494.8A 2017-07-03 2017-07-03 A kind of dyestuff, dye material composition and dye material composition and application Pending CN107266936A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710530494.8A CN107266936A (en) 2017-07-03 2017-07-03 A kind of dyestuff, dye material composition and dye material composition and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710530494.8A CN107266936A (en) 2017-07-03 2017-07-03 A kind of dyestuff, dye material composition and dye material composition and application

Publications (1)

Publication Number Publication Date
CN107266936A true CN107266936A (en) 2017-10-20

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1590469A (en) * 2003-08-16 2005-03-09 德意志戴斯达纺织品及染料两合公司 Dye mixtures of fiber-reactive azo dyes, their preparation and their use
CN101775235A (en) * 2009-12-21 2010-07-14 浙江龙盛集团股份有限公司 Reactive black dye
CN103965653A (en) * 2014-05-12 2014-08-06 浙江亿得化工有限公司 Post-mercerized composite activated dye as well as dyeing method and use thereof
CN105315720A (en) * 2014-07-21 2016-02-10 上海安诺其集团股份有限公司 Preparation method for dye
CN105315709A (en) * 2014-07-21 2016-02-10 上海安诺其集团股份有限公司 Dye

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1590469A (en) * 2003-08-16 2005-03-09 德意志戴斯达纺织品及染料两合公司 Dye mixtures of fiber-reactive azo dyes, their preparation and their use
CN101775235A (en) * 2009-12-21 2010-07-14 浙江龙盛集团股份有限公司 Reactive black dye
CN103965653A (en) * 2014-05-12 2014-08-06 浙江亿得化工有限公司 Post-mercerized composite activated dye as well as dyeing method and use thereof
CN105315720A (en) * 2014-07-21 2016-02-10 上海安诺其集团股份有限公司 Preparation method for dye
CN105315709A (en) * 2014-07-21 2016-02-10 上海安诺其集团股份有限公司 Dye

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Application publication date: 20171020