CN106854384A - A kind of weld, dye material composition and application - Google Patents
A kind of weld, dye material composition and application Download PDFInfo
- Publication number
- CN106854384A CN106854384A CN201611261820.1A CN201611261820A CN106854384A CN 106854384 A CN106854384 A CN 106854384A CN 201611261820 A CN201611261820 A CN 201611261820A CN 106854384 A CN106854384 A CN 106854384A
- Authority
- CN
- China
- Prior art keywords
- dye
- component
- monomer
- yellow dye
- material composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 239000000975 dye Substances 0.000 claims description 32
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 claims description 20
- 239000001043 yellow dye Substances 0.000 claims description 20
- 238000004043 dyeing Methods 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 229910004727 OSO3H Inorganic materials 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 229910006069 SO3H Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000985 reactive dye Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
- C09B67/0042—Mixtures containing two reactive dyes one of them being an azo dye
- C09B67/0045—Mixtures containing two reactive dyes one of them being an azo dye both having the reactive group not directly attached to a heterocyclic system
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0072—Preparations with anionic dyes or reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of weld, dye material composition and its application.The dye material composition, it includes following components by weight percentage：50~90% component A and 10~50% B component are mixed to prepare, described component A is the dye monomer A compounds shown in one or more following formula (1), and described B component is the dye monomer B compounds shown in one or more following formula (2).This kind of weld, with deep concentration higher, excellent color fastness, easily high levelling property, washing property.
Description
Technical Field
The invention relates to a yellow dye, a dye raw material composition and application.
Background
With the increasing living standard, people have higher and higher requirements on textile products, so that the requirements on various properties of the reactive dyes for dyeing textiles are more and more strict. The reactive dye not only has excellent dyeing fastness and dyeing performance, but also meets the requirement of environmental protection.
The yellow variety of the dye monomer A in the current market belongs to one of three primary colors, normal medium and deep colors can be used reluctantly, but the product has no advantages and insufficient deep dyeing property when being used in some extra deep colors, while the dye monomer B is mainly used for normally splicing black colors, has excellent depth, but has defects of color brightness and various fastnesses.
Disclosure of Invention
The invention provides a dye, a dye raw material composition and application thereof, aiming at overcoming the defects of poor color fastness and dyeing performance of yellow dye in the prior art. The invention provides an active yellow dye composition, which adopts a compounding technology, integrates the advantages of the component A and the component B, and the compounded active yellow dye product has excellent promotion on dyeing property, excellent fastness in all aspects and obvious advantages.
The invention provides a yellow dye raw material composition, which comprises the following components in percentage by weight: 50-90% of the component A and 10-50% of the component B;
the component A is one or more dye monomer A compounds shown as the following formula (1):
the component B is one or more dye monomer B compounds shown as the following formula (2):
the total amount of the raw materials is 100 percent;
wherein,
R1is-SO2CH＝CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3One of Na, R1Can be substituted at any position, preferably at para and meta positions;
R2is-NH2CONH2and/or-CH2CONH2；
R3、R4、R7And R8Each independently is H, -SO3H and-SO3One of Na;
R5and R6Each independently is-SO2CH＝CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One of Na;
in the A component structure, preferably, R1is-SO2C2H4OSO3Na；
And/or, R2is-CH2CONH2；
And/or, R3Is H and/or-SO3Na；
And/or, R4is-SO3Na。
In the structure of the component B, R is preferred5And R6Each independently is-SO2C2H4OSO3Na；
And/or, R7Is H;
and/or, R8Is H and/or-SO3Na。
The compounds formed after the combination of the R groups are all commercially available dye chemicals.
Formula (1) is preferably of the structure:
or
Formula (2) is preferably of the structure:
or
Wherein the dye monomer A and the dye monomer B can be respectively and independently present, preferably in the form of powder, synthetic solution or aqueous solution thereof.
In the yellow dye raw material composition, the raw materials can also be added with the auxiliary agents commonly used in the field, such as a dispersant MF and/or a diffusant NNO.
The auxiliaries are preferably present in the form of a powder and/or a solution.
The addition amount of the auxiliary agent is preferably 3-5% of the total weight of the product;
and/or, the content of the dyeing monomer A is preferably 50-87%;
and/or, the content of the dyeing monomer B is preferably 10-45%.
The auxiliary agent can be a commercial product.
The invention also provides a yellow dye which is prepared by mixing the dye raw material composition. The mixing can be carried out by methods conventional in the art. Preferably, the dye composition is prepared by mixing liquid slurry and then spray drying or mixing monomer powder, wherein the mixing time of the liquid slurry is at least 2 hours; when the powder is mixed, the lower material is returned to the upper material for at least 2 times, and the total mixing time is at least 2 hours.
The invention also provides the application of the dye in dyeing of cellulose materials, wherein the cellulose materials are preferably cellulose fibers such as cotton, hemp and the like, and more preferably viscose fibers.
The above preferred conditions can be arbitrarily combined to obtain preferred embodiments of the present invention without departing from the common general knowledge in the art.
Dye monomer A and dye monomer B may be prepared from commercially available products or by methods well known in the art.
The positive progress effects of the invention are as follows: the invention provides a yellow dye raw material composition, and the dye prepared from the dye raw material composition has excellent color fastness and dyeing performance, is very suitable for dyeing of cellulose materials, and has excellent promotion, excellent various color fastnesses and dark colors.
Detailed Description
The invention is further illustrated by the following examples, which are not intended to limit the scope of the invention. The experimental methods without specifying specific conditions in the following examples were selected according to the conventional methods and conditions, or according to the commercial instructions.
Dye monomer A and dye monomer B can be prepared by methods well known in the art and are compounds known in the art.
Examples 1 to 9:
the dye monomer A is a compound (I), and the dye monomer B is a compound (III);
examples 10 to 12:
the dye monomer A is a compound (II), and the dye monomer B is a compound (IV);
comparative example 1 is compound (I) and comparative example 2 is compound (III);
according to data shown in table 1, dye monomer a, dye monomer B, cosolvent and water are mixed by using liquid slurry, and after being uniformly mixed, spray drying is carried out. The blending time of the liquid slurry is 2 hours.
TABLE 1 (example 1 ~ 12 dye raw material composition ratio)
The reactive dye prepared in the above embodiment is subjected to a dyeing test (the determination standard of the dyeing color light and intensity of the reactive dye GB/T2387-.
TABLE 2 (Dip dyeing, bath ratio 1:10,60 degree dyeing, O.W.F: 3%)
Wherein the integer value is a numerical value representing the apparent depth of the dyed cloth sample, and the larger the numerical value is, the darker the color is, the larger the color is, the color is directly measured by a color measuring instrument.
The reactive dye prepared in the embodiment has the following effect detection standards of wear resistance: ISO105X 12; fastness to perspiration: ISO 105E 04; soaping fastness: ISO 105C 03.
Through the analysis of the detection data in the table 2, the compound yellow obtained by the invention can be completely adjusted in proportion according to different dyeing hues and depths, and all fastnesses can reach the standard requirements.
Claims (10)
1. A yellow dye raw material composition is characterized by comprising the following components in percentage by mass: 50-90% of the component A and 10-50% of the component B;
the component A is one or more dye monomer A compounds shown as the following formula (1):
the component B is one or more dye monomer B compounds shown as the following formula (2):
wherein,
R1is-SO2CH＝CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One of Na, and R1Is para or meta substitution;
R2is-NH2CONH2and/or-CH2CONH2；
R3、R4、R7And R8Each independently is H, -SO3H and-SO3One of Na;
R5and R6Each independently is-SO2CH＝CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One of Na.
2. The yellow dye starting composition of claim 1 wherein in component A, R is1is-SO2C2H4OSO3Na；
And/or, R2is-CH2CONH2；
And/or, R3is-SO3Na；
And/or, R4is-H.
3. The yellow dye starting composition of claim 1 wherein the a component is selected from the group consisting of
4. As in claimA yellow dye raw material composition as defined in claim 1, wherein in the component B, R is5And R6Each independently is-SO2C2H4OSO3Na；
And/or, R7Is H;
and/or, R8Is H and/or-SO3Na。
5. The yellow dye starting composition of claim 1 wherein the component B is selected from the group consisting of
6. The yellow dye starting composition of claim 1 wherein the dye monomer a and the dye monomer B are each independently present in a powder, a synthetic solution, or an aqueous solution.
7. The yellow dye raw material composition as claimed in any one of claims 1 to 6, further comprising an auxiliary agent.
8. The yellow dye starting composition of claim 7, wherein the auxiliary agent is present in the form of a powder and/or a solution;
and/or the auxiliary agent is dispersant MF and/or diffusant NNO;
and/or the mass of the auxiliary agent accounts for 3-5% of the mass of the dye composition;
and/or, the content of the dyeing monomer A is 50-87%;
and/or, the content of the dyeing monomer B is 10-45%.
9. A yellow dye, which is prepared by mixing the yellow dye raw material composition as defined in any one of claims 1 to 8.
10. Use of the yellow dye according to claim 9 for dyeing cellulosic material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611261820.1A CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611261820.1A CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106854384A true CN106854384A (en) | 2017-06-16 |
Family
ID=59126627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611261820.1A Pending CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106854384A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101469137A (en) * | 2007-12-28 | 2009-07-01 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
-
2016
- 2016-12-30 CN CN201611261820.1A patent/CN106854384A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101469137A (en) * | 2007-12-28 | 2009-07-01 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170616 |
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| WD01 | Invention patent application deemed withdrawn after publication |