CN106854384A - A kind of weld, dye material composition and application - Google Patents
A kind of weld, dye material composition and application Download PDFInfo
- Publication number
- CN106854384A CN106854384A CN201611261820.1A CN201611261820A CN106854384A CN 106854384 A CN106854384 A CN 106854384A CN 201611261820 A CN201611261820 A CN 201611261820A CN 106854384 A CN106854384 A CN 106854384A
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- CN
- China
- Prior art keywords
- weld
- component
- dye
- feedstock composition
- oso
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
- C09B67/0042—Mixtures containing two reactive dyes one of them being an azo dye
- C09B67/0045—Mixtures containing two reactive dyes one of them being an azo dye both having the reactive group not directly attached to a heterocyclic system
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0072—Preparations with anionic dyes or reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of weld, dye material composition and its application.The dye material composition, it includes following components by weight percentage：50~90% component A and 10~50% B component are mixed to prepare, described component A is the dye monomer A compounds shown in one or more following formula (1), and described B component is the dye monomer B compounds shown in one or more following formula (2).This kind of weld, with deep concentration higher, excellent color fastness, easily high levelling property, washing property.
Description
Technical field
The present invention relates to a kind of weld, dye material composition and application.
Background technology
With the increasingly raising of living standard, requirement of the people to textile product also more and more higher, so that for weaving
Requirement of the reactive dye of product dyeing on properties is increasingly harsh.Reactive dye not only will have excellent dyefastness and
Dyeability, and to meet environmental requirement.
The yellow cultivars of dye monomer A, belong to one of three primary colors in the market, and normal middle dark color can also make reluctantly
With, but product does not have advantage when some special dark colors are done, and depth is inadequate, and dye monomer B is mainly normal black of spelling and uses,
Depth is splendid, but bright-colored degree and every fastness have been short of.
The content of the invention
The present invention for the defect such as overcome weld dyefastness and dyeability in the prior art not good, so as to provide
A kind of dyestuff, dye material composition and application thereof.The invention provides a kind of active yellow dye composition, using compounding
Technology, two advantages of component of summary component A and component B, compounding active yellow dye product out, in dyeability
There is excellent enhancing, each side fastness is excellent, with more apparent advantage.
The invention provides a kind of weld feedstock composition, it includes following components by weight percentage：A groups
Divide 50~90% and B component 10~50%；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
The raw material total amount is 100%；
Wherein,
R1For-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3One kind in Na, R1Can replace for optional position,
It is preferred that contraposition and meta；
R2For-NH2CONH2And/or-CH2CONH2；
R3、R4、R7And R8It is independently each H ,-SO3H and-SO3One kind in Na；
R5And R6It is independently each-SO2CH=CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One kind in Na；
In described component A structure preferably, R1For-SO2C2H4OSO3Na；
And/or, R2For-CH2CONH2；
And/or, R3It is H and/or-SO3Na；
And/or, R4For-SO3Na。
In described B component structure preferably, R5And R6It is independently each-SO2C2H4OSO3Na；
And/or, R7It is H；
And/or, R8It is H and/or-SO3Na。
After R group combination, the compound of formation is commercial dyes chemicals.
Formula (1) is preferably as follows structure：
Or
Formula (2) is preferably as follows structure：
Or
Wherein, the dye monomer A and dye monomer B can each it is independent preferably with powdery, synthetic solvent or
Its aqueous solution form is present.
The conventional of this area can be also added to help in the weld feedstock composition of the invention, in the raw material
Agent, such as Dispersant MF and/or dispersing agent NNO.
The auxiliary agent exists preferably in the form of powder and/or solution.
The addition of described auxiliary agent is preferably the 3-5% of product gross weight；
And/or, the content preferably 50%~87% of described chromatid A；
And/or, the content preferably 10%~45% of described chromatid B.
Auxiliary agent can use commercially available prod.
Of the invention to additionally provide a kind of weld, it is mixed with by the dye material composition and obtained.It is described
Mixing can use this area conventional mixing method.It is preferred that described dye composite is sprayed again using liquid slurry blending
Dry or the mode of monomer powders blending is prepared, the liquid slurry blending time is at least 2 hours；The powder is spelled
Mixed mouth material at present returns material suitable for reading at least 2 times, total incorporation time at least 2 hours.
Present invention also offers the dyestuff cellulosic material dyeing in application, the preferred cotton of cellulosic material,
The cellulose fibres such as fiber crops, more preferably viscose fiber.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, and obtain final product the present invention each preferably
Example.
Dye monomer A and dye monomer B can use commercially available prod, it would however also be possible to employ method system well known in the art
It is standby.
Positive effect of the invention is：The invention provides a kind of weld feedstock composition, the dyestuff is former
The dyestuff that feed composition is prepared has excellent dyefastness and dyeability, and is highly suitable for the dye of cellulosic material
Color, with excellent enhancing, excellent every color fastness, thick in color.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality
Apply among a scope.The experimental technique of unreceipted actual conditions in the following example, conventionally and condition, or according to business
Product specification is selected.
Dye monomer A, dye monomer B can be prepared using method well known in the art, the change being known in the art
Compound.
Embodiment 1~9：
Dye monomer A is compound (I), and dye monomer B is compound (III)；
Embodiment 10~12：
Dye monomer A is compound (II), and dye monomer B is compound (IV)；
Comparative example 1 is compound (I), and comparative example 2 is compound (III)；
According to data in table 1, by dye monomer A, dye monomer B and cosolvent and water, using liquid slurry blending,
After well mixed, then it is spray-dried.The liquid slurry blending time is 2 hours.
Table 1 (the dye material composition of embodiment 1~12 proportioning)
Reactive dye obtained in above-described embodiment are carried out into dyeing survey using the reactive dye of standard on pure cotton knitting cloth
Examination (the bioassay standard GB/T 2387-2006 of chemically-reactive dyes dyeing colo r light and intensity), obtains its corresponding performance data, is shown in Table
2。
Table 2 (is contaminated, bath raio 1:10,60 degree of dyeing, O.W.F：3%)
Wherein Integ values are a numerical value for representing dyeing cloth specimen Apparent Depth, and numerical value is bigger, and the color that represents is deeper, is logical
Colour photometer is crossed directly to measure.
Reactive dye effect detection obtained in above-described embodiment uses standard for wear resistance：ISO105X12；Perspiration resistance
Fastness：ISO 105E04；Soaping fastness：ISO 105C03.
Analyzed by the detection data of table 2, the compound Huang that the present invention is obtained completely can be according to coloured differently form and aspect and depth
To adjust proportioning, every fastness can reach standard requirement.
Claims (10)
1. a kind of weld feedstock composition, it is characterised in that it includes following components by percentage to the quality：Component A
50~90% and B component 10~50%；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1For-SO2CH=CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One kind in Na, and R1It is contraposition or meta substitution；
R2For-NH2CONH2And/or-CH2CONH2；
R3、R4、R7And R8It is independently each H ,-SO3H and-SO3One kind in Na；
R5And R6It is independently each-SO2CH=CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One kind in Na.
2. weld feedstock composition as claimed in claim 1, it is characterised in that in described component A, R1For-
SO2C2H4OSO3Na；
And/or, R2For-CH2CONH2；
And/or, R3For-SO3Na；
And/or, R4For-H.
3. weld feedstock composition as claimed in claim 1, it is characterised in that described component A is selected from
4. weld feedstock composition as claimed in claim 1, it is characterised in that in described B component, R5And R6Each
It is independently-SO2C2H4OSO3Na；
And/or, R7It is H；
And/or, R8It is H and/or-SO3Na。
5. weld feedstock composition as claimed in claim 1, it is characterised in that described B component is selected from
6. weld feedstock composition as claimed in claim 1, it is characterised in that the dye monomer A and described dye
Material list body B is each independent to be present in powder, synthetic solvent or the aqueous solution.
7. the weld feedstock composition as described in any one of claim 1~6, it is characterised in that it also includes auxiliary agent.
8. weld feedstock composition as claimed in claim 7, it is characterised in that the auxiliary agent is with powder and/or solution
Form exist；
And/or, the auxiliary agent is Dispersant MF and/or dispersing agent NNO；
And/or, the quality of the auxiliary agent accounts for the 3%~5% of the dye combinations amount of substance；
And/or, the content 50%~87% of the chromatid A；
And/or, the content 10%~45% of the chromatid B.
9. a kind of weld, it is characterised in that will be mixed weld feedstock composition as described in any one of claim 1~8
Conjunction is prepared.
10. application of a kind of weld as claimed in claim 9 in cellulosic material dyeing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611261820.1A CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611261820.1A CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106854384A true CN106854384A (en) | 2017-06-16 |
Family
ID=59126627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611261820.1A Pending CN106854384A (en) | 2016-12-30 | 2016-12-30 | A kind of weld, dye material composition and application |
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| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101469137A (en) * | 2007-12-28 | 2009-07-01 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
-
2016
- 2016-12-30 CN CN201611261820.1A patent/CN106854384A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101469137A (en) * | 2007-12-28 | 2009-07-01 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170616 |
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