CN107337936A - A kind of dyestuff, dye material composition and dye material composition and application - Google Patents
A kind of dyestuff, dye material composition and dye material composition and application Download PDFInfo
- Publication number
- CN107337936A CN107337936A CN201710530565.4A CN201710530565A CN107337936A CN 107337936 A CN107337936 A CN 107337936A CN 201710530565 A CN201710530565 A CN 201710530565A CN 107337936 A CN107337936 A CN 107337936A
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- China
- Prior art keywords
- dye
- material composition
- component
- monomer
- dye material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 0 CC1C2=C*C=CC(*)C2C=C[C@@]1N=NC(C(C*)=*C=C1C=C(*)C=C(C)C11)=C1O Chemical compound CC1C2=C*C=CC(*)C2C=C[C@@]1N=NC(C(C*)=*C=C1C=C(*)C=C(C)C11)=C1O 0.000 description 5
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
- C09B67/0052—Mixtures of two or more reactive monoazo dyes
- C09B67/0054—Mixtures of two or more reactive monoazo dyes all the reactive groups not being directly attached to a heterocyclic system
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
Abstract
The invention discloses a kind of dyestuff, dye material composition and dye material composition and application.The dye material composition, it includes following being calculated as 1.1 with parts by weight:1~8.7:1 component A and B component, described component A are the dye monomer A compounds shown in one or more following formula (1), and described B component is the dye monomer B compounds shown in one or more following formula (2).This kind of dyestuff, there is higher deep concentration, excellent color fastness, easily high levelling property, washing property.
Description
Technical field
The present invention relates to a kind of dyestuff, dye material composition and dye material composition and application.
Background technology
With the increasingly raising of living standard, requirement of the people to textile product also more and more higher, thereby using in weaving
Requirement of the reactive dye of product dyeing on properties is increasingly harsh.Reactive dye not only will have excellent dyefastness and
Dyeability, and to meet environmental requirement.
Active orange dye product in the market, or depth is inadequate, normal middle dark color can also use reluctantly, but
Product do some it is special dark when there is no advantage, or depth is splendid, but bright-colored degree and every fastness have been short of.
The content of the invention
The defects of present invention is in order to overcome orange dyefastness in the prior art and bad dyeability, so as to provide
A kind of dyestuff, dye material composition and dye material composition and application.The invention provides a kind of dye composite, adopt
With compounded technology, the advantages of two components of summary component A and component B, the active orange dye product that compounds out is contaminating
Color performance has excellent enhancing, and each side fastness is excellent, has more apparent advantage.
The invention provides a kind of dye material composition, it includes following being calculated as 1.1 with parts by weight:1~8.7:1
Component A and B component；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1、R5And R6It is each independently H ,-SO3H or-SO3Na；
R2、R3And R4It is each independently-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na；
The described preferred R of component A structure1For H or-SO3Na。
The described preferred R of component A structure2For-SO2C2H4OSO3Na。
The described preferred R of B component structure3And R4It is each independently-SO2C2H4OSO3Na。
The described preferred R of B component structure5For H.
The described preferred R of B component structure6For H or-SO3Na。
After the substituent combination, the compound of formation is commercial dyes chemicals.
Formula (1) is preferably as follows structure formula：
Formula (2) is preferably as follows structure：
Described dye material composition can be made up of described dye monomer A and described dye monomer B.
The dye monomer A and dye monomer B can be each independent preferably with powdery, synthetic solvent or its is water-soluble
Liquid form is present.
Described dye monomer A and described dye monomer B, is preferably calculated as 1.4 with parts by weight:1~5:1.
As needed, dye material composition of the present invention can be a component form of all the components mixing, also may be used
Independently or by each composition it is divided into some groups of more component nested forms for each composition.
Present invention also offers a kind of dye composite, and it includes, dye material composition and auxiliary agent as described above.
Described dye composite can be made up of described dye monomer A, described dye monomer B and auxiliary agent.
The auxiliary agent can be the conventional auxiliary agent of this area, such as Dispersant MF and/or dispersing agent NNO.
The auxiliary agent exists preferably in the form of powder and/or solution.The auxiliary agent can use commercially available prod.
In described dye composite, it may include following components by percentage to the quality：For example, described chromatid
A is 87%, 80%, 75%, 70%, 65%, 60%, 55% or 50%；Described chromatid B be 10%, 16%, 20%,
25%th, 32%, 36%, 40% or 45%.
Described dye composite is preferably comprised following components by percentage to the quality：Dye described in 50%~87%
Chromophoric monomer A, the auxiliary agent described in chromatid B and 3~5% described in 10%~45%；More preferably, described dye composite bag
Include following components by percentage to the quality：Chromatid A described in 65%~80%, the chromatid described in 16%~32%
Auxiliary agent described in B and 3~5%.
As needed, dye composite of the present invention can be a component form of all the components mixing, or respectively
Composition is independent or each composition is divided into some groups of more component nested forms.
The present invention's additionally provides a kind of dyestuff, and it is mixed with to obtain by the dye composite.Described mixing can
With this area conventional mixing method, ratio mechanically mixed dye monomer A, dye monomer B and auxiliary agent, or with ability such as needed for
Mode known to domain carries out blending；More preferably, described dye composite is spray-dried again using liquid slurry blending, or
The mode of monomer powders blending is prepared；The liquid slurry blending time is 3 hours；At present mouth material returns the powder blending
Material suitable for reading 3 times, total incorporation time 3 hours.
Present invention also offers application of the dyestuff in cellulosic material dyeing, the preferred cotton of the cellulosic material,
Fiber crops or viscose fiber, more preferably viscose fiber.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, and it is each preferably to produce the present invention
Example.
Dye monomer A and dye monomer B can use commercially available prod, can also use method system well known in the art
It is standby.
The positive effect of the present invention is：The invention provides a kind of dye material composition and containing the dye material
The dye composite of composition, the dyestuff that the dye material composition is prepared have excellent dyefastness and dyeability
Can, and it is highly suitable for the dyeing of cellulosic material, there is excellent enhancing, excellent every color fastness, thick in color.
Embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality
Apply among a scope.The experimental method of unreceipted actual conditions in the following example, conventionally and condition, or according to business
Product specification selects.
Dye monomer A, dye monomer B can be prepared using method well known in the art, the change being known in the art
Compound.
Embodiment 1~8：
Dye monomer A is compound (I), and dye monomer B is compound (IV)；
Embodiment 9~12：
Dye monomer A is compound (II), and dye monomer B is compound (III)；
Comparative example 1 is compound (I), and comparative example 2 is compound (IV)；
It is equal using liquid slurry blending, mixing by dye monomer A, dye monomer B and auxiliary agent according to data in table 1
After even, then it is spray-dried.The liquid slurry blending time is 2 hours.
Table 1 (the dye material composition of embodiment 1~12 proportioning)
Reactive dye made from above-described embodiment are subjected to dyeing survey using the reactive dye of standard on pure cotton knitting cloth
Try (chemically-reactive dyes dyeing colo r light and the bioassay standard GB/T 2387-2006 of intensity), obtain its corresponding performance data, be shown in Table
2。
Table 2 (is contaminated, bath raio 1:10,60 degree of dyeing, O.W.F：3%)
Wherein Integ values are a numerical value for representing to dye cloth specimen Apparent Depth, and numerical value is bigger, and the color that represents is deeper, is logical
Colour photometer is crossed directly to measure.
Reactive dye effect detection made from above-described embodiment uses standard as wear resistance：ISO 105X12；Perspiration resistance
Fastness：ISO 105E04；Soaping fastness：ISO 105C03.
Data analysis is detected by table 2, the compound orange that the present invention obtains completely can be according to coloured differently form and aspect and depth
To adjust proportioning, every fastness can reach standard requirement.
Claims (10)
1. a kind of dye material composition, it is characterised in that it includes following being calculated as 1.1 with parts by weight:1~8.7:1 A groups
Point and B component；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1、R5And R6It is each independently H ,-SO3H or-SO3Na；
R2、R3And R4It is each independently-SO2CH=CH2、-SO2C2H4OSO3H or-SO2C2H4OSO3Na。
A kind of 2. dye material composition as claimed in claim 1, it is characterised in that in described component A structure, R1For H or-
SO3Na；
And/or R2For-SO2C2H4OSO3Na。
3. dye material composition as claimed in claim 1, it is characterised in that described component A is
4. dye material composition as claimed in claim 1, it is characterised in that in described B component, R3And R4It is each independent
Ground is-SO2C2H4OSO3Na；
And/or R5For H；
And/or R6For H or-SO3Na。
5. dye material composition as claimed in claim 1, it is characterised in that described B component is
6. dye material composition as claimed in claim 1, it is characterised in that described dye monomer A and described dyestuff
Monomer B is present in powder, synthetic solvent or the aqueous solution independently of one another；
And/or described dye monomer A and described dye monomer B, it is calculated as 1.4 with parts by weight:1~5:1.
7. a kind of dye composite, it is characterised in that it includes the dye material combination as described in any one of claim 1~6
Thing and auxiliary agent.
8. dye composite as claimed in claim 7, it is characterised in that the auxiliary agent is deposited in the form of powder and/or solution
；
And/or described auxiliary agent is Dispersant MF and/or dispersing agent NNO；
And/or described dye composite includes following components by percentage to the quality：Dyeing list described in 50%~87%
Body A, the auxiliary agent described in chromatid B and 3~5% described in 10%~45%；It is preferred that the chromatid described in 65%~80%
A, the auxiliary agent described in chromatid B and 3~5% described in 16%~32%.
9. a kind of dyestuff, it is characterised in that will be prepared as the dye combinations mixture described in claim 7 or 8.
A kind of 10. application of the dyestuff in the dyeing of cellulosic material as claimed in claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710530565.4A CN107337936A (en) | 2017-07-03 | 2017-07-03 | A kind of dyestuff, dye material composition and dye material composition and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710530565.4A CN107337936A (en) | 2017-07-03 | 2017-07-03 | A kind of dyestuff, dye material composition and dye material composition and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107337936A true CN107337936A (en) | 2017-11-10 |
Family
ID=60218318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710530565.4A Pending CN107337936A (en) | 2017-07-03 | 2017-07-03 | A kind of dyestuff, dye material composition and dye material composition and application |
Country Status (1)
| Country | Link |
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| CN (1) | CN107337936A (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5554731A (en) * | 1991-06-22 | 1996-09-10 | Bayer Aktiengesellschaft | Process for the preparation of aminoazo dyes |
| US20030019055A1 (en) * | 1999-06-24 | 2003-01-30 | Zamponi Andrea Maria | Reactive dye mixture |
| JP2006045448A (en) * | 2004-08-09 | 2006-02-16 | Sumitomo Chemical Co Ltd | Reactive dye composition, and method for dyeing or printing with the composition |
| JP2006063202A (en) * | 2004-08-27 | 2006-03-09 | Sumitomo Chemical Co Ltd | Reactive dye composition and method for dyeing or textile printing using the same |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
| CN101775235A (en) * | 2009-12-21 | 2010-07-14 | 浙江龙盛集团股份有限公司 | Active black dye |
| KR20120049577A (en) * | 2010-11-09 | 2012-05-17 | 이화산업 주식회사 | Redish-yellow reactive dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
| CN105062140A (en) * | 2015-09-02 | 2015-11-18 | 湖北华丽染料工业有限公司 | Composite reactive deep yellow dye as well as preparation method and application thereof |
| CN106700651A (en) * | 2016-12-30 | 2017-05-24 | 江苏安诺其化工有限公司 | Preparation method of yellow dye |
-
2017
- 2017-07-03 CN CN201710530565.4A patent/CN107337936A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5554731A (en) * | 1991-06-22 | 1996-09-10 | Bayer Aktiengesellschaft | Process for the preparation of aminoazo dyes |
| US20030019055A1 (en) * | 1999-06-24 | 2003-01-30 | Zamponi Andrea Maria | Reactive dye mixture |
| JP2006045448A (en) * | 2004-08-09 | 2006-02-16 | Sumitomo Chemical Co Ltd | Reactive dye composition, and method for dyeing or printing with the composition |
| JP2006063202A (en) * | 2004-08-27 | 2006-03-09 | Sumitomo Chemical Co Ltd | Reactive dye composition and method for dyeing or textile printing using the same |
| CN101775235A (en) * | 2009-12-21 | 2010-07-14 | 浙江龙盛集团股份有限公司 | Active black dye |
| CN101735649A (en) * | 2009-12-23 | 2010-06-16 | 浙江龙盛集团股份有限公司 | Yellow to red composite reactive dye |
| KR20120049577A (en) * | 2010-11-09 | 2012-05-17 | 이화산업 주식회사 | Redish-yellow reactive dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
| CN105062140A (en) * | 2015-09-02 | 2015-11-18 | 湖北华丽染料工业有限公司 | Composite reactive deep yellow dye as well as preparation method and application thereof |
| CN106700651A (en) * | 2016-12-30 | 2017-05-24 | 江苏安诺其化工有限公司 | Preparation method of yellow dye |
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Application publication date: 20171110 |
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