CN106752083A - A kind of orchil, dye material composition and application - Google Patents

A kind of orchil, dye material composition and application Download PDF

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Publication number
CN106752083A
CN106752083A CN201611261777.9A CN201611261777A CN106752083A CN 106752083 A CN106752083 A CN 106752083A CN 201611261777 A CN201611261777 A CN 201611261777A CN 106752083 A CN106752083 A CN 106752083A
Authority
CN
China
Prior art keywords
orchil
component
feedstock composition
dye
dye monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611261777.9A
Other languages
Chinese (zh)
Inventor
蔡连杰
冯全明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Anoky Digital Technology Co Ltd
Shanghai Anoky Group Co Ltd
Jiangsu Anoky Chemicals Co Ltd
Original Assignee
Shanghai Anoky Digital Technology Co Ltd
Shanghai Anoky Group Co Ltd
Jiangsu Anoky Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Anoky Digital Technology Co Ltd, Shanghai Anoky Group Co Ltd, Jiangsu Anoky Chemicals Co Ltd filed Critical Shanghai Anoky Digital Technology Co Ltd
Priority to CN201611261777.9A priority Critical patent/CN106752083A/en
Publication of CN106752083A publication Critical patent/CN106752083A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0047—Mixtures of two or more reactive azo dyes
    • C09B67/005—Mixtures of two or more reactive azo dyes all the reactive groups being not directly attached to a heterocyclic system
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group

Abstract

The invention discloses a kind of orchil, dye material composition and its application.The orchil feedstock composition, it includes 50 90%A components and 10 50%B components by weight percentage, described component A is the dye monomer A compounds shown in one or more following formula (1), and described B component is the dye monomer B compounds shown in one or more following formula (2).This kind of orchil, with deep concentration higher, excellent color fastness, easily high levelling property, washing property.

Description

A kind of orchil, dye material composition and application
Technical field
The present invention relates to a kind of orchil, dye material composition and application.
Background technology
With the increasingly raising of living standard, requirement of the people to textile product also more and more higher, so that for weaving Requirement of the reactive dye of product dyeing on properties is increasingly harsh.Reactive dye not only will have excellent dyefastness and Dyeability, and to meet environmental requirement.
The red cultivar of dye monomer A, belongs to one of three primary colors in the market, and normal middle dark color can also make reluctantly With, but product does not have advantage when some special dark colors are done, and depth is inadequate, and dye monomer B is mainly normal black of spelling and uses, Depth is splendid, but bright-colored degree level items fastness has been short of.
The content of the invention
The present invention for the defect such as overcome orchil dyefastness and dyeability in the prior art not good, so as to provide A kind of dyestuff, dye material composition and application thereof.The invention provides a kind of active red dye composition, using compounding Technology, two advantages of component of summary component A and component B, compounding activity red dye product out, in dyeability There is excellent enhancing, each side fastness is excellent, with more apparent advantage.
The invention provides a kind of orchil feedstock composition, it includes following components by weight percentage：A groups Divide 50~90% and B component 10~50%；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
The raw material total amount is 100%；
Wherein,
R1、R3And R4It is independently each H ,-SO3H and-SO3One kind in Na；
R2、R5And R6It is independently each-SO2CH=CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One kind in Na；
Described component A structure is preferred, R1It is H and/or-SO3Na；
And/or, R2For-SO2C2H4OSO3Na。
Described B component structure is preferred, R3It is H and/or-SO3Na；
And/or, R4It is H；
And/or, R5And R6It is independently each-SO2C2H4OSO3Na。
After R group combination, the compound of formation is commercial dyes chemicals.
Formula (1) is preferably as follows structure formula：
Or
Formula (2) is preferably as follows structure：
Or
Wherein, the dye monomer A and dye monomer B can each it is independent preferably with powdery, synthetic solvent or Its aqueous solution form is present.
In the orchil feedstock composition of the invention, the conventional auxiliary agent of this area can be also added, preferably disperseed Agent MF and/or dispersing agent NNO.
The auxiliary agent exists preferably in the form of powder and/or solution.
The addition of described auxiliary agent is preferably the 3-5% of product gross weight；
And/or, the content preferably 50%~87% of described chromatid A；
And/or, the content preferably 10%~45% of described chromatid B.
Auxiliary agent can use commercially available prod.
Of the invention to additionally provide a kind of orchil, it is mixed with by the dye material composition and obtained.It is described Mixing can use this area conventional mixing method.It is preferred that described dye composite is sprayed again using liquid slurry blending Dry or the mode of monomer powders blending is prepared, the liquid slurry blending time is at least 2 hours；The powder is spelled Mixed mouth material at present returns material suitable for reading at least 2 times, total incorporation time at least 2 hours.
Present invention also offers the dyestuff cellulosic material dyeing in application, the preferred cotton of cellulosic material, The cellulose fibres such as fiber crops, more preferably viscose fiber.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, and obtain final product the present invention each preferably Example.
Dye monomer A and dye monomer B can use commercially available prod, it would however also be possible to employ method system well known in the art It is standby.
Positive effect of the invention is：The invention provides a kind of orchil feedstock composition, the dyestuff is former The dyestuff that feed composition is prepared has excellent dyefastness and dyeability, and is highly suitable for the dye of cellulosic material Color, with excellent enhancing, excellent every color fastness, thick in color.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality Apply among a scope.The experimental technique of unreceipted actual conditions in the following example, conventionally and condition, or according to business Product specification is selected.
Dye monomer A, dye monomer B can be prepared using method well known in the art, the change being known in the art Compound.
Embodiment 1~9：
Dye monomer A is compound (I), and dye monomer B is compound (IV)；
Embodiment 10~12：
Dye monomer A is compound (II), and dye monomer B is compound (III)；
Comparative example 1 is compound (I), and comparative example 2 is compound (IV)；
According to data in table 1, by dye monomer A, dye monomer B and cosolvent and water, using liquid slurry blending, After well mixed, then it is spray-dried.The liquid slurry blending time is 2 hours.
Table 1 (the dye material composition of embodiment 1~12 proportioning)
Reactive dye obtained in above-described embodiment are carried out into dyeing survey using the reactive dye of standard on pure cotton knitting cloth Examination (the bioassay standard GB/T 2387-2006 of chemically-reactive dyes dyeing colo r light and intensity), obtains its corresponding performance data, is shown in Table 2。
Table 2 (is contaminated, bath raio 1:10,60 degree of dyeing, O.W.F：3%)
Wherein Integ values are a numerical value for representing dyeing cloth specimen Apparent Depth, and numerical value is bigger, and the color that represents is deeper, is logical Colour photometer is crossed directly to measure.
Reactive dye effect detection obtained in above-described embodiment uses standard for wear resistance：ISO105X12；Perspiration resistance Fastness：ISO 105 E04；Soaping fastness：ISO 105 C03.
By the detection data of table 2 analyze, the present invention obtain it is compound red completely can be according to coloured differently form and aspect and depth To adjust proportioning, every fastness can reach standard requirement.

Claims (10)

1. a kind of orchil feedstock composition, it is characterised in that it includes following components by percentage to the quality：Component A 50-90% and B component 10-50%；
Described component A is the dye monomer A compounds shown in one or more following formula (1)：
Described B component is the dye monomer B compounds shown in one or more following formula (2)：
Wherein,
R1、R3And R4It is independently each H ,-SO3H and-SO3One kind in Na；
R2、R5And R6It is independently each-SO2CH=CH2、-SO2C2H4OSO3H and-SO2C2H4OSO3One kind in Na.
2. orchil feedstock composition as claimed in claim 1, it is characterised in that in described component A structure, R1For H and/ Or-SO3Na；
And/or, R2For-SO2C2H4OSO3Na。
3. orchil feedstock composition as claimed in claim 1, it is characterised in that described component A is selected from
Or
4. orchil feedstock composition as claimed in claim 1, it is characterised in that in described B component, R3For-SO3Na；
And/or, R4It is H；
And/or, R5And R6It is independently each-SO2C2H4OSO3Na。
5. orchil feedstock composition as claimed in claim 1, it is characterised in that described B component is selected from
Or
6. orchil feedstock composition as claimed in claim 1, it is characterised in that described dye monomer A and described Dye monomer B is each independent to be present in powder, synthetic solvent or the aqueous solution.
7. the orchil feedstock composition as described in any one of claim 1~6, it is characterised in that also including auxiliary agent.
8. orchil feedstock composition as claimed in claim 7, it is characterised in that the auxiliary agent is with powder and/or solution Form exist；
And/or, described auxiliary agent is Dispersant MF and/or dispersing agent NNO；
And/or, the quality of the auxiliary agent accounts for the 3%~5% of the dye combinations amount of substance；
And/or, the content of described chromatid A is 50%~87%；
And/or, the content of described chromatid B is 10%~45%.
9. a kind of orchil, it is characterised in that mix the orchil material combination as described in any one of claim 1~8 Compound is prepared.
10. application of a kind of orchil as claimed in claim 9 in the dyeing of cellulosic material.
CN201611261777.9A 2016-12-30 2016-12-30 A kind of orchil, dye material composition and application Pending CN106752083A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611261777.9A CN106752083A (en) 2016-12-30 2016-12-30 A kind of orchil, dye material composition and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611261777.9A CN106752083A (en) 2016-12-30 2016-12-30 A kind of orchil, dye material composition and application

Publications (1)

Publication Number Publication Date
CN106752083A true CN106752083A (en) 2017-05-31

Family

ID=58954852

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611261777.9A Pending CN106752083A (en) 2016-12-30 2016-12-30 A kind of orchil, dye material composition and application

Country Status (1)

Country Link
CN (1) CN106752083A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101323709A (en) * 2007-06-11 2008-12-17 上海雅运纺织化工有限公司 Red reactive dye composition and dyeing application thereof to fibre material
CN101323710A (en) * 2007-06-11 2008-12-17 上海雅运纺织化工有限公司 Red reactive dye composition and dyeing application thereof
CN101497747A (en) * 2008-02-02 2009-08-05 上海雅运纺织化工有限公司 Red reactive dye composition and application thereof
CN104710841A (en) * 2015-02-15 2015-06-17 江苏德美科化工有限公司 Red reactive dye composition
CN105778560A (en) * 2016-03-17 2016-07-20 浙江瑞华化工有限公司 Red active dye composition and preparation method and use thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101323709A (en) * 2007-06-11 2008-12-17 上海雅运纺织化工有限公司 Red reactive dye composition and dyeing application thereof to fibre material
CN101323710A (en) * 2007-06-11 2008-12-17 上海雅运纺织化工有限公司 Red reactive dye composition and dyeing application thereof
CN101497747A (en) * 2008-02-02 2009-08-05 上海雅运纺织化工有限公司 Red reactive dye composition and application thereof
CN104710841A (en) * 2015-02-15 2015-06-17 江苏德美科化工有限公司 Red reactive dye composition
CN105778560A (en) * 2016-03-17 2016-07-20 浙江瑞华化工有限公司 Red active dye composition and preparation method and use thereof

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