CN107057403B - A kind of golden yellow disperse dye composition, disperse dyes product and its application - Google Patents
A kind of golden yellow disperse dye composition, disperse dyes product and its application Download PDFInfo
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- CN107057403B CN107057403B CN201710324686.3A CN201710324686A CN107057403B CN 107057403 B CN107057403 B CN 107057403B CN 201710324686 A CN201710324686 A CN 201710324686A CN 107057403 B CN107057403 B CN 107057403B
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- dye
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- 239000000986 disperse dye Substances 0.000 title claims abstract description 36
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000000975 dye Substances 0.000 claims abstract description 115
- 239000000126 substance Substances 0.000 claims abstract description 20
- 239000004744 fabric Substances 0.000 claims abstract description 6
- 229920004933 Terylene® Polymers 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims abstract description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 5
- 238000007639 printing Methods 0.000 claims abstract description 5
- 238000004043 dyeing Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 18
- 239000012752 auxiliary agent Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 4
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical class [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZLCUIOWQYBYEBG-UHFFFAOYSA-N 1-Amino-2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=C(N)C(C)=CC=C3C(=O)C2=C1 ZLCUIOWQYBYEBG-UHFFFAOYSA-N 0.000 description 1
- ZXXVVTBKBDDTSE-UHFFFAOYSA-N 3-[4-[(2-chloro-4-nitrophenyl)diazenyl]-n-(2-cyanoethyl)anilino]propanenitrile Chemical compound ClC1=CC([N+](=O)[O-])=CC=C1N=NC1=CC=C(N(CCC#N)CCC#N)C=C1 ZXXVVTBKBDDTSE-UHFFFAOYSA-N 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/36—Material containing ester groups using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of golden yellow disperse dye composition, disperse dyes product and its applications, and the dye moiety of the dye composite includes two or more following dye component：One is the dye component A of chemical formula (I), content is the 65~97%% of dye moiety total weight, secondly for the dye component B of chemical formula (II), content is the 1~15% of dye moiety total weight, thirdly for the dye component C of chemical formula (III), content is the 1~15% of dye moiety total weight, and four be the dye component D of chemical formula (IV), and content is the 1~5% of dye moiety total weight.For dyestuff made from disperse dye composition with the present invention in fabric printings such as terylene, fibers, dyeability is superior, and pH is applied widely, temperature dependence is low, and every fastness is high, is especially compounded with other low temperature type dyes, with compatibility, the characteristic of compatibility, and upper dye plateau.
Description
Technical field
The invention belongs to dye fields, and in particular to it is a kind of golden yellow disperse dye composition, disperse dyes product and its
Using more particularly to a kind of terylene and its blended fabric printing and dyeing golden yellow disperse dyes and its application.
Background technology
With the raising that the fast development of acetate fiber and people require weaving in recent years, there is dyeability to dyestuff itself
Energy, higher requirements are also raised for environmental-protecting performance.There should be dyeing firmness, also to there is fine low temperature dye-uptake and compatibility.
Disperse Yellow RGFL is also referred to as C.I. disperse yellows 23, is a kind of a kind of bigger dyestuff of dosage, and chemical formula is
Azo dyes can be cleaved under the conditions of certain specific, generate aromatic amine carcinogen, therefore violated by being classified as from European Union
Dyestuff.And the substitute of Disperse Yellow RGFL is found, the not achievement of making a breakthrough property, develops the replacement of Disperse Yellow RGFL at home
Product are still a great project.
The 23 preferable product of effect of replacement C.I. disperse yellows occurred currently on the market is mainly that Wenzhou Katyuan leather is limited
The SE-3R of company is golden yellow, and a kind of low-temperature environment-friendly type disperse dyes of Zhejiang Province Longsheng Group Co., Ltd (are specifically shown in patent
CN1257235C), but the use through application producer finds that said two products dyeability has shortcoming, and light fastness only has 4
Grade, washing and sublimation reliability also only have 4 grades, cannot be satisfied following market demand.
Invention content
In order to solve the above-mentioned problems in the prior art, the present invention provides a kind of alternative C.I. disperse yellows 23, with
And the haveing excellent performance of main product, a kind of golden yellow disperse dyes combination that upper dye curve is steady, coloured light is gorgeous currently on the market
Object, disperse dyes product and its application.
In order to achieve the above objectives, the present invention uses following technical scheme：
A kind of golden yellow disperse dye composition, the dye moiety of the dye composite include following two kinds or two kinds with
On dye component：
One is the dye component A of chemical formula (I), and content is the 65~97% of dye moiety total weight,
Secondly for the dye component B of chemical formula (II), content is the 1~15% of dye moiety total weight,
Thirdly for the dye component C of chemical formula (III), content is the 1~15% of dye moiety total weight,
Its four for chemical formula (IV) dye component D, content is the 1~5% of dye moiety total weight,
Preferably, a kind of golden yellow disperse dye composition is made of following dye component：Dye component A weight
Score is 65~97%, and dye component B weight fractions are 1~15%, and dye component C weight fractions are 1~15%, dye component
D weight fractions are 1~5%.
Preferably, a kind of golden yellow disperse dye composition is made of following dye component：Dye component A weight
Score is 80~97%, and dye component B weight fractions are 1~15%, and dye component D weight fractions are 1~5%.
Preferably, a kind of golden yellow disperse dye composition is made of following dye component：Dye component A weight
Score is 80~97%, and dye component C weight fractions are 1~15%, and dye component D weight fractions are 1~5%.
Preferably, a kind of golden yellow disperse dye composition is made of following dye component：Dye component A weight
Score is 80~97%, and dye component B weight fractions are 1~15%.
Preferably, a kind of golden yellow disperse dye composition is made of following dye component：Dye component A weight
Score is 80~97%, and dye component C weight fractions are 1~15%.
Preferably, the dye composite further includes auxiliary agent.
Preferably, the auxiliary agent includes diffusant and dispersant, wherein diffusant is selected from MF or/and NNO, dispersant choosing
From sodium lignin sulfonate class.
A kind of golden yellow disperse dye composition of the present invention, is prepared by the following method：By above-mentioned metering compare by
After each dye component, auxiliary agent, water or the mixing of other wetting agents, it is ground dispersion with grinder, then spray drying obtains.
The present invention also protects a kind of golden yellow disperse dyes product, including above-mentioned golden yellow disperse dye composition.
The present invention also protects application of the golden yellow disperse dyes product in terylene, fabric printing and dyeing.
Above-mentioned dye component A is obtained by my company's independent research, and dye component B, dye component C, dye component D can be used
Commercial product, such as the C.I disperse orange 25s that Wenzhou District of Zhejiang Province Yan Leng limited liability companies produce, the C.I of jiangsu wuxi dyestuff factory production
Disperse orange 44 etc..
In said program, auxiliary agent does not include water and other wetting agents.
In said program, " dye moiety " refer to the present invention dye mixture in pure dye substance, do not include
Aid Portions.It is well known that during the former dyestuff of synthetic disperse dyes is processed into commodity disperse dyes, need to add
Enter a large amount of auxiliary agent, such as dispersant sodium lignin sulfonate B or sodium lignin sulfonate 85A, dispersing agent MF or NNO and a small amount of anti-
Dust agent JH2112).Obviously, between each dye component of the dye mixture of aforementioned present invention on the basis of weight ratio, addition
The product that auxiliary agent dilutes is still within the protection of this patent.Even if auxiliary agent kind used is in patent specification
It does not refer to, is still within the protection domain of this patent as long as its dye moiety proportioning is within the scope of the present invention.
In said program, the percentage composition of " dye moiety " refers to the percentage for removing auxiliary agent and outer pure dye dry product
Content.And general industry formula is using former dyestuff dry product content, due to containing a small amount of impurity, original dye in former dyestuff dry product
The number of material dry product content is approximate instead of pure dye dry product content.The former dyestuff wet cake being synthesized can be converted to former dye
Dry product is expected to measure.Some commercial formulations also (such as are dyed with the sample of certain trade mark commodity disperse dyes containing a large amount of auxiliary agents
The sample of intensity 100% or 200%) weight calculate content, which can be scaled pure dye dry product content.
In the present invention, the C.I. labels on dyestuff title head are that English Color Index abridge, i.e. Colour Index, in
Between partly indicate color type, tail portion is dyestuff number.This name format is general at home and abroad.The Colour Index is contaminated by Britain
Se Jia associations (Society of Dyers and Colorists；) and American Association of Textile Chemists and Colourists SDC
(American Association of Textile Chemists and Colorists；AATCC it) compiles in collaboration with.As for those heads
The dyestuff title that portion does not have C.I. to mark is that the dye species title of structure is not yet announced by Colour Index.
For dyestuff made from disperse dye composition with the present invention in fabric printings such as terylene, fibers, dyeability is excellent
More, pH is applied widely, is especially compounded with other low temperature type dyes, has compatibility, the characteristic of compatibility, and upper dye curve
It is flat.The light for the dye composite that the present invention is prepared is greatly improved, by ISO-105/B02-
1994 method carries out light shine color fastness test, is graded with blue wool, and variation as former state is 5-6 grades；By G/BT 3921-
2008 fastness to soaping are tested, and fastness is 5 grades；By GB/T 2394-2013 disperse dyes coloured light strength tests, coloured light is gorgeous
Beautiful, upper dye curve is steady.
Description of the drawings
Fig. 1 is the upper dye curve of the present invention.
Wherein abscissa is sample point.
Specific implementation mode
With reference to embodiment, the present invention will be further described, but protection scope of the present invention is not limited to this.
It needs to illustrate：The content of each component refers to being combined with mixed crystal type Yellow disperse dye in following embodiment formula
Weight percentage on the basis of object total weight, wherein mixed crystal type yellow disperse dye composition total weight is all dyestuffs
The sum of weight and all auxiliary agent weight.And the percentage composition described in technical solution of the front in invention content is to remove auxiliary agent
And the weight percentage on the basis of outer dye moiety total weight.There is conversion relation between the two.
Examples 1 to 10：
According to data shown in table 1, dye component A, dye component B, dye component C, dye component D, auxiliary agent plus water are spelled
After mixed, with grinder grinding distribution, spray drying, finished product.
Table 1
Embodiment 11：
Disperse dyes made from 0.5 gram of Examples 1 to 10 are respectively taken to be dispersed in 500 milliliters of water, with 60 after drawing 20 milliliters
The water mixing of milliliter, is 5 with acetic acid tune dye bath pH, is warming up to 70 DEG C while being put into 2 grams of polyester fibers and dyed, in 30 minutes
It is interior to be warming up to 130 DEG C by 70 DEG C, 30 minutes are kept the temperature, starts to sample when being cooled to 90 degree.Sample cloth coloured light is observed, using national standard GB/T
3921-2008, GB/T 3920-2008, GB/T 3922-2013 and GB/T 8427-2008 test respectively its washable, rub resistance,
Perspiration resistance, the color fastness of resistance to artificial light the results are shown in Table 2.
Table 2
Embodiment 12：
Dyestuff obtained in Examples 1 to 10 is dyed according to the step in embodiment 11, and is existed according to raffinate method
Respective dye-uptake is measured on spectrophotometer.The result shows that：The dyestuff dye-uptake of Examples 1 to 10 is almost the same, and upper dye is bent
Line is relatively more steady (see Fig. 1).
It will be recognized by those skilled in the art, can be to above-mentioned under the premise of without departing from protection scope of the present invention
Embodiment is carry out various modifications, changes and is combined, and thinks that this modification, variation and combination are the models in originality thought
Within enclosing.
Claims (5)
1. a kind of golden yellow disperse dye composition, which is characterized in that be made of following dye component：Dye component A weight point
Number is 65~97%, and dye component B weight fractions are 1~15%, and dye component C weight fractions are 1~15%, dye component D
Weight fraction is 1~5%, wherein
The chemical formula (I) of dye component A is：
The chemical formula (II) of dye component B is：
The chemical formula (III) of dye component C is：
The chemical formula (IV) of dye component D is：
2. a kind of golden yellow disperse dye composition, which is characterized in that be made of following dye component：Dye component A weight point
Number is 80~97%, and dye component B weight fractions are 1~15%, and dye component D weight fractions are 1~5%
The chemical formula (I) of dye component A is：
The chemical formula (II) of dye component B is：
The chemical formula (IV) of dye component D is：
3. a kind of golden yellow disperse dye composition, which is characterized in that be made of following dye component：Dye component A weight point
Number is 80~97%, and dye component C weight fractions are 1~15%, and dye component D weight fractions are 1~5%,
The chemical formula (I) of dye component A is：
The chemical formula (III) of dye component C is：
The chemical formula (IV) of dye component D is：
4. a kind of golden yellow disperse dyes product, which is characterized in that including the golden yellow described in any one of claim 1-3 point
Dissipate dye composite.
5. application of the golden yellow disperse dyes product in terylene, fabric printing and dyeing described in claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710324686.3A CN107057403B (en) | 2017-05-10 | 2017-05-10 | A kind of golden yellow disperse dye composition, disperse dyes product and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710324686.3A CN107057403B (en) | 2017-05-10 | 2017-05-10 | A kind of golden yellow disperse dye composition, disperse dyes product and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107057403A CN107057403A (en) | 2017-08-18 |
| CN107057403B true CN107057403B (en) | 2018-08-17 |
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| CN201710324686.3A Active CN107057403B (en) | 2017-05-10 | 2017-05-10 | A kind of golden yellow disperse dye composition, disperse dyes product and its application |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108170001B (en) * | 2017-12-29 | 2020-07-10 | 深圳市华星光电技术有限公司 | Photoresist composition, color filter and display panel |
| CN110568722B (en) * | 2018-02-05 | 2021-06-25 | Tcl华星光电技术有限公司 | Blue light cut-off film and blue light display device |
| CN111454589B (en) * | 2020-05-12 | 2022-02-15 | 浙江山峪集团股份有限公司 | Disperse yellow dye composition and preparation method thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH10251534A (en) * | 1997-03-11 | 1998-09-22 | Daisutaa Japan Kk | Mixture of orange color-based disperse dye |
| CN100577743C (en) * | 2007-06-29 | 2010-01-06 | 浙江龙盛染料化工有限公司 | Composition of dispersed yellow dye |
| CN101307191B (en) * | 2008-06-28 | 2011-11-30 | 浙江龙盛集团股份有限公司 | Disperse dye composition and disperse dyes |
| CN102516811B (en) * | 2011-10-31 | 2014-07-09 | 浙江龙盛集团股份有限公司 | Disperse black dye composition |
| CN104087017B (en) * | 2013-05-16 | 2016-05-25 | 上海安诺其集团股份有限公司 | A kind of preparation method of orange disperse dye |
| CN105038314A (en) * | 2015-07-10 | 2015-11-11 | 浙江迪邦化工有限公司 | Environment-friendly type composite disperse green dye composition and dye |
| CN105860579A (en) * | 2016-04-29 | 2016-08-17 | 浙江龙盛集团股份有限公司 | High-fastness dispersion blue-to-black dye composition and dye product |
| CN106833021A (en) * | 2017-02-17 | 2017-06-13 | 朱友富 | A kind of fastness to perspiration disperse dyes high |
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Address after: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou Patentee after: Zhejiang Shanyu Group Co.,Ltd. Address before: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou Patentee before: ZHEJIANG SHANYU TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20231011 Address after: 333300 Tashan Industrial Zone, Leping Industrial Park, Jingdezhen City, Jiangxi Province Patentee after: LEPING SAFELY PHARMACEUTICAL Co.,Ltd. Address before: 318000 three mountain village, Jiaojiang District, Taizhou, Zhejiang Patentee before: Zhejiang Shanyu Group Co.,Ltd. |
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Denomination of invention: A golden dispersed dye composition, dispersed dye product and its application Effective date of registration: 20231117 Granted publication date: 20180817 Pledgee: Agricultural Bank of China Limited Leping sub branch Pledgor: LEPING SAFELY PHARMACEUTICAL Co.,Ltd. Registration number: Y2023980066395 |