CN107237038A - A kind of its production technology of anti-electron radiation wool product - Google Patents
A kind of its production technology of anti-electron radiation wool product Download PDFInfo
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- CN107237038A CN107237038A CN201710639609.7A CN201710639609A CN107237038A CN 107237038 A CN107237038 A CN 107237038A CN 201710639609 A CN201710639609 A CN 201710639609A CN 107237038 A CN107237038 A CN 107237038A
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- fiber
- wool
- silver
- wool fiber
- modified polyester
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- 210000002268 wool Anatomy 0.000 title claims abstract description 118
- 230000005855 radiation Effects 0.000 title claims abstract description 39
- 238000005516 engineering process Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 143
- 229920000728 polyester Polymers 0.000 claims abstract description 40
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 19
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 19
- 241001330002 Bambuseae Species 0.000 claims abstract description 19
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 19
- 239000011425 bamboo Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000004744 fabric Substances 0.000 claims abstract description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 108091005804 Peptidases Proteins 0.000 claims description 19
- 239000004365 Protease Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 18
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 238000000605 extraction Methods 0.000 claims description 18
- 239000002608 ionic liquid Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 230000009467 reduction Effects 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000004952 Polyamide Substances 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- 229920002647 polyamide Polymers 0.000 claims description 14
- 230000000844 anti-bacterial effect Effects 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- 150000008301 phosphite esters Chemical class 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000010276 construction Methods 0.000 claims description 6
- 238000010981 drying operation Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000006068 polycondensation reaction Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 241000168254 Siro Species 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 description 8
- 238000009941 weaving Methods 0.000 description 4
- 230000036541 health Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000748 cardiovascular system Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 210000000750 endocrine system Anatomy 0.000 description 1
- 239000010946 fine silver Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 210000004994 reproductive system Anatomy 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides a kind of anti-electron radiation wool product, it includes 10 ~ 20% wool fibers, 30 ~ 40% modified polyester fibers, 25 ~ 35% silver-plated long filaments and 15 ~ 35% bamboo pulp fibers, wherein, modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp fibre blending are into the fabric with anti-electron radiation function, the production technology for coordinating the present invention to provide, it can obtain with high effectiveness, while comfortable feel, the anti-electron radiation wool product suitable for dress.
Description
Technical field
The present invention relates to feature wool field, and in particular to a kind of anti-electron radiation wool product and its production work
Skill.
Background technology
Wool fiber is the deformations of the skin of sheep, and warmth retention property is splendid, is used for the clothes of autumn and winter, wool fiber tool
Flexible good, the advantages of hygroscopicity is strong, warmth retention property is good is one of practical natural textile raw material of the earliest wide hair of exploitation ice cup, tool
There is excellent textile process performance, wool product has soft gloss, enriched and the feel of high resilience, good pendency
The advantages of property, heat and moisture preserving and resistance to soiling.
In recent years, advancing by leaps and bounds with science and technology, various electrical equipment, electronic equipment are greatly popularized, and electromagnetic radiation turns into
After the pollution sources after air pollution, water pollution and noise pollution.It can not only be produced to communication apparatus such as radio and television
Interference, can also influence health, human body is chronically exposed in electromagnetic radiation environment, nervous system, cardiovascular system, endocrine
System, reproductive system, immune system etc. all can be by different degrees of injuries.
As consuming public is to the convenient worry of health so that various clothings start with radiation proof function, and shielding is knitted
The appearance and development of thing, away from it is modern oneself experienced a stage from formulation standard to centurial year before generation, loomage from scratch, by
Step development, the use of loomage is only limitted to military project scientific research, the one's of health care and industrial enterprise's century, and loomage starts
Into Common People, quickly grow, kind increases, after quantity increase generation in centurial year, continues fast-developing, quality optimization, quantity
Increase sharply, new product is continued to bring out.It is one that now oneself, which forms one to be related to electronics industry, textile industry, biomedicine and detection supervision,
The new industry of body.
In patent No. CN103238957B patent of invention, a kind of Anti-electromagneticantistatic antistatic woolen sweater is disclosed, it is main
To be formed by wire and wool fiber weaving blending according to a certain percentage, with Radiation-proof antistatic function, but the invention
Bad in the presence of dress experience, too hard for human body, comfort level is too poor, it is difficult to enter market.
The content of the invention
（One）The technical problem to be solved
The problem to be solved in the present invention is that existing anti-electron radiation wool product is excessively heavy hard, is difficult dress.
（Two）Technical scheme
In order to solve the above technical problems, the present invention provides a kind of anti-electron radiation wool product, overall soft, pro-skin is comfortable, right
The good absorbing effect of electromagnetic wave and ultraviolet, service life is long.
The anti-electron radiation wool product includes the raw material of following mass percent：
Wool fiber 10 ~ 20%
Modified polyester fiber 30 ~ 40%
Silver-plated long filament 25 ~ 35%
Bamboo pulp fiber 15 ~ 35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp fiber
Blending is into the fabric with anti-electron radiation function.
Further limit, include the raw material of following mass percent：
Wool fiber 10%
Modified polyester fiber 30%
Silver-plated long filament 25%
Bamboo pulp fiber 35%.
Or, include the raw material of following mass percent：
Wool fiber 15%
Modified polyester fiber 35%
Silver-plated long filament 30%
Bamboo pulp fiber 20%.
Corresponding, present invention also offers a kind of production technology of anti-electron radiation wool product, comprise the following steps：
S1, is configured chloroform/methanol solvent, wool fiber is immersed in the solvent, and wool fiber is entered using soxhlet's extractor
Row reflux extraction, extraction time control is washed wool fiber using deionized water after completing in 2 ~ 2.5h, extraction, it
After dry；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20 ~ 25min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, so carries out twice repeatedly
Washing, is dried afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage liquid in, 30 ~ 40min of stirring reaction, reaction complete after by temperature appreciate 100 DEG C, keep 10 ~ 15min, afterwards using go from
Sub- water washing, is dried afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30 ~ 45min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min,
Rinsing carries out drying operation after completing to wool fiber；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains modified polyamide ester, by the silver-containing inorganic that the modified polyamide ester and particle diameter of synthesis are 0.1 ~ 0.5 micron
Ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified polyester fiber；
S6, configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is prepared by Siro Core-spun Yarn technique
Radiation proof covering yarn, using silver-plated long filament as cored wire, wool fiber and modified polyester fiber are as covering thread, wherein silver-plated length
The fineness of silk is controlled in 35D, and the density domination of covering thread is in 15 ~ 18tex；
S7, blending is carried out by the radiation proof covering yarn in S6 and bamboo pulp fiber, and is weaved using rib construction structure, is obtained
Anti-electron radiation wool product.
Further it is defined, in S1, the volume ratio of chloroform and methanol is 85:15.
Further be defined, in S6, blending process be followed successively by silver mixing, a pin, two pins, three pins, four pins, rove, spun yarn,
Winder, doubling and double twisting.
（Three）Beneficial effect
（1）The antibacterial wool product that the present invention is provided, with good electron-irradiation resisting effect, to various electromagnetic waves and ultraviolet
The assimilation effect of line preferably, can be protected effectively to the healthy of wearer, and fabric flexible, breathable simultaneously, and feel is relaxed
Suitable, appearance looks elegant is difficult balling-up.
（2）Wool surfaces are first pre-processed, utilize ion by the production technology for the antibacterial wool product that the present invention is provided
Treatment fluid can change the surface nature of wool fiber, and the scale layer of corrosion wool surface reduces surface lipid material, beaten
Disconnected disulfide bond, promotes the action effect of following protein enzyme, while accelerating the hydrolysis rate of proteases on wool fiber, reaches good
Wool surface scale modified effect so that wool fiber more soft comfortable, it is to avoid occur shrinking and balling-up shows
As；Modified polyester fiber is utilized afterwards, and ethylene glycol terephthalate is contracted with phosphate, sodium tripolyphosphate, phosphite ester
Poly- reaction, obtains modified polyamide ester, obtained modified polyamide ester feel is very comfortable, is aided with the ultra-fine silver-containing inorganic of addition
The anti-electron radiation of ultrafine anti-bacterial powder so that the modified polyester fiber has radiation proof function simultaneously, further lifting entirety
Effect；Particularly, modified polyester fiber, wool and silver-plated long filament are subjected to cored using Siro Core-spun Yarn technique wherein
The anti-electromagnetic-radiation performance of cored fabric is better than and twisted weave thing under operation, identical silver-plated long filament content, and twisted weave thing is better than
Intertexture, is substituted and twisted weave thing and intertexture using cored fabric, not only avoid appearance of fabrics and limited by silver ion, and
Cost is saved, while higher radioresistance effect is can reach, while using wool and modified polyester fiber to silver-plated long filament
Coated, obtained covering yarn becomes sufficiently flexible, Surface feel is soft comfortable, while avoid silver-plated long filament exposed outside,
Allow it that there are more different colors, outward appearance is more beautiful；It is eventually adding bamboo fibre so that quality of item is more excellent, dress
It is more comfortable that there is the color of fashion simultaneously.
Embodiment
With reference to embodiment, the embodiment to the present invention is described in further detail.Following examples are used for
Illustrate the present invention, but be not limited to the scope of the present invention.
The present invention provides a kind of anti-electron radiation wool product, and it includes the raw material of following mass percent：
Wool fiber 10 ~ 20%
Modified polyester fiber 30 ~ 40%
Silver-plated long filament 25 ~ 35%
Bamboo pulp fiber 20 ~ 35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp fiber
Blending is into the fabric with anti-electron radiation function.
Present invention also offers a kind of production technology of anti-electron radiation wool product, comprise the following steps：
S1, is configured chloroform/methanol solvent, wool fiber is immersed in the solvent, and wool fiber is entered using soxhlet's extractor
Row reflux extraction, extraction time control is washed wool fiber using deionized water after completing in 2 ~ 2.5h, extraction, it
After dry；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20 ~ 25min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, so carries out twice repeatedly
Washing, is dried afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage liquid in, 30 ~ 40min of stirring reaction, reaction complete after by temperature appreciate 100 DEG C, keep 10 ~ 15min, afterwards using go from
Sub- water washing, is dried afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30 ~ 45min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min,
Rinsing carries out drying operation after completing to wool fiber；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains modified polyamide ester, by the silver-containing inorganic that the modified polyamide ester and particle diameter of synthesis are 0.1 ~ 0.5 micron
Ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified polyester fiber；
S6, configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is prepared by Siro Core-spun Yarn technique
Radiation proof covering yarn, using silver-plated long filament as cored wire, wool fiber and modified polyester fiber are as covering thread, wherein silver-plated length
The fineness of silk is controlled in 35D, and the density domination of covering thread is in 15 ~ 18tex；
S7, blending is carried out by the radiation proof covering yarn in S6 and bamboo pulp fiber, and is weaved using rib construction structure, is obtained
Anti-electron radiation wool product.
Wherein, in S1, the volume ratio of chloroform and methanol is 85:15.
Wherein, in S6, blending process is followed successively by silver mixing, a pin, two pins, three pins, four pins, rove, spun yarn, winder, simultaneously
Line and double twisting.
With reference to embodiment, the present invention will be further elaborated：
Embodiment 1
S1, configures chloroform/methanol solvent, the wool fiber of quality accounting 10% is immersed in the solvent, and utilize soxhlet's extractor
Reflux extraction is carried out to wool fiber, extraction time control is entered wool fiber using deionized water after completing in 2h, extraction
Row washing, is washed three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, is so washed twice repeatedly
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage in liquid, stirring reaction 30min, reaction appreciates temperature 100 DEG C after completing, and keeps 15min, and profit is washed with deionized water afterwards
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min, rinsing
Drying operation is carried out to wool fiber after completion；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains the modified polyamide ester of quality accounting 30%, is 0.1 ~ 0.5 by the modified polyamide ester and particle diameter of synthesis
The silver-containing inorganic ultrafine anti-bacterial powder of micron is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified poly ester
Fiber；
S6, configures covering yarn, and the silver-plated long filament of quality accounting 25%, 30% modified polyester fiber and 10% wool fiber are passed through into match
Network spun core-spun yarn technique prepares radiation proof covering yarn, using silver-plated long filament as cored wire, and wool fiber and modified polyester fiber are made
For covering thread, wherein the fineness control of silver-plated long filament is in 35D, and the density domination of covering thread is 18tex；
S7, carries out blending, and enter using rib construction structure by the radiation proof covering yarn in S6 and the bamboo pulp fiber of quality accounting 35%
Row weaving, obtains anti-electron radiation wool product.
Embodiment 2
S1, configures chloroform/methanol solvent, the wool fiber of quality accounting 15% is immersed in the solvent, and utilize soxhlet's extractor
Reflux extraction is carried out to wool fiber, extraction time control is entered wool fiber using deionized water after completing in 2h, extraction
Row washing, is washed three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, is so washed twice repeatedly
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage in liquid, stirring reaction 30min, reaction appreciates temperature 100 DEG C after completing, and keeps 15min, and profit is washed with deionized water afterwards
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min, rinsing
Drying operation is carried out to wool fiber after completion；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains the modified polyamide ester of quality accounting 35%, is 0.1 ~ 0.5 by the modified polyamide ester and particle diameter of synthesis
The silver-containing inorganic ultrafine anti-bacterial powder of micron is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified poly ester
Fiber；
S6, configures covering yarn, and the silver-plated long filament of quality accounting 30%, 35% modified polyester fiber and 15% wool fiber are passed through into match
Network spun core-spun yarn technique prepares radiation proof covering yarn, using silver-plated long filament as cored wire, and wool fiber and modified polyester fiber are made
For covering thread, wherein the fineness control of silver-plated long filament is in 35D, and the density domination of covering thread is 18tex；
S7, carries out blending, and enter using rib construction structure by the radiation proof covering yarn in S6 and the bamboo pulp fiber of quality accounting 20%
Row weaving, obtains anti-electron radiation wool product.
Embodiment 3
S1, configures chloroform/methanol solvent, the wool fiber of quality accounting 20% is immersed in the solvent, and utilize soxhlet's extractor
Reflux extraction is carried out to wool fiber, extraction time control is entered wool fiber using deionized water after completing in 2h, extraction
Row washing, is washed three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, is so washed twice repeatedly
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage in liquid, stirring reaction 30min, reaction appreciates temperature 100 DEG C after completing, and keeps 15min, and profit is washed with deionized water afterwards
Wash, be put into baking oven and dried in the environment of 50 degrees Celsius afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min, rinsing
Drying operation is carried out to wool fiber after completion；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains the modified polyamide ester of quality accounting 40%, is 0.1 ~ 0.5 by the modified polyamide ester and particle diameter of synthesis
The silver-containing inorganic ultrafine anti-bacterial powder of micron is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified poly ester
Fiber；
S6, configures covering yarn, and the silver-plated long filament of quality accounting 25%, 40% modified polyester fiber and 20% wool fiber are passed through into match
Network spun core-spun yarn technique prepares radiation proof covering yarn, using silver-plated long filament as cored wire, and wool fiber and modified polyester fiber are made
For covering thread, wherein the fineness control of silver-plated long filament is in 35D, and the density domination of covering thread is 18tex；
S7, carries out blending, and enter using rib construction structure by the radiation proof covering yarn in S6 and the bamboo pulp fiber of quality accounting 15%
Row weaving, obtains anti-electron radiation wool product.
In embodiment 1 ~ 3, the shielding properties of this anti-electron radiation wool product can reach more than 48db, with good
Electromagnet shield effect, the wherein wool product shielding properties in embodiment 2 is up to 55db, while comfortable feel, fabric is breathed freely,
It is very soft.
In summary, above-mentioned embodiment is not the restricted embodiment of the present invention, all those skilled in the art
The modification carried out on the basis of the substantive content of the present invention or equivalent deformation, the technology category in the present invention.
Claims (6)
1. a kind of anti-electron radiation wool product, it includes the raw material of following mass percent：
Wool fiber 10 ~ 20%
Modified polyester fiber 30 ~ 40%
Silver-plated long filament 25 ~ 35%
Bamboo pulp fiber 15 ~ 35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp fiber
Blending is into the fabric with anti-electron radiation function.
2. a kind of antibacterial wool product according to claim 1, it is characterised in that include the raw material of following mass percent：
Wool fiber 10%
Modified polyester fiber 30%
Silver-plated long filament 25%
Bamboo pulp fiber 35%.
3. a kind of antibacterial wool product according to claim 1, it is characterised in that include the raw material of following mass percent：
Wool fiber 15%
Modified polyester fiber 35%
Silver-plated long filament 30%
Bamboo pulp fiber 20%.
4. a kind of production technology of anti-electron radiation wool product, comprises the following steps：
S1, is configured chloroform/methanol solvent, wool fiber is immersed in the solvent, and wool fiber is entered using soxhlet's extractor
Row reflux extraction, extraction time control is washed wool fiber using deionized water after completing in 2 ~ 2.5h, extraction, it
After dry；
S2, configures ionic liquid, ionic liquid is heated up into 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
20 ~ 25min is reacted, reaction is washed after completing first with ethanol, and profit is washed with deionized afterwards, so carries out twice repeatedly
Washing, is dried afterwards；
S3, configures Protease Treatment liquid, Protease Treatment liquid is heated up into 40 DEG C, and the wool fiber in S2 is immersed at protease
Manage liquid in, 30 ~ 40min of stirring reaction, reaction complete after by temperature appreciate 100 DEG C, keep 10 ~ 15min, afterwards using go from
Sub- water washing, is dried afterwards；
S4, the wool fiber handled by S2 is immersed in reduction treatment agent, and the PH of reduction treatment agent is controlled between 8 ~ 8.4,
Bath raio is set to 1:45, wool fiber is stirred at normal temperatures, it is fully reacted with reduction treatment agent, reaction time control
System is rinsed after completing in 30 ~ 45min, reaction using deionized water to wool fiber, is rinsed 2 times altogether, each 10min,
Rinsing carries out drying operation after completing to wool fiber；
S5, configures modified polyester fiber, and ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester are carried out
Polycondensation reaction, obtains modified polyamide ester, by the silver-containing inorganic that the modified polyamide ester and particle diameter of synthesis are 0.1 ~ 0.5 micron
Ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and spinning processing is carried out afterwards and obtains modified polyester fiber；
S6, configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is prepared by Siro Core-spun Yarn technique
Radiation proof covering yarn, using silver-plated long filament as cored wire, wool fiber and modified polyester fiber are as covering thread, wherein silver-plated length
The fineness of silk is controlled in 35D, and the density domination of covering thread is in 15 ~ 18tex；
S7, blending is carried out by the radiation proof covering yarn in S6 and bamboo pulp fiber, and is weaved using rib construction structure, is obtained
Anti-electron radiation wool product.
5. a kind of production technology of antibacterial wool product according to claim 4, it is characterised in that in S1, chloroform and methanol
Volume ratio be 85:15.
6. a kind of production technology of antibacterial wool product according to claim 4, it is characterised in that in S6, blending process according to
Secondary is silver mixing, a pin, two pins, three pins, four pins, rove, spun yarn, winder, doubling and double twisting.
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| CN108866730A (en) * | 2018-07-09 | 2018-11-23 | 佛山市南海区佳妍内衣有限公司 | A kind of anti-electron radiation wool product |
| CN109023622A (en) * | 2018-08-09 | 2018-12-18 | 合肥五凡工程设计有限公司 | A kind of tear-resistant wool blended yarn of easy dyeing and its preparation process |
| CN109023620A (en) * | 2018-08-09 | 2018-12-18 | 合肥五凡工程设计有限公司 | A kind of flexible cored cashmere yarn of antistatic |
| CN109097879A (en) * | 2018-08-06 | 2018-12-28 | 梧州市兴能农业科技有限公司 | A kind of anti-electron radiation wool product |
| CN109137186A (en) * | 2018-09-21 | 2019-01-04 | 东莞绿邦智能科技有限公司 | A kind of wool product of anti-electromagnetic radiation |
| CN109137182A (en) * | 2018-08-22 | 2019-01-04 | 佛山市南海区佳妍内衣有限公司 | It can prevent the wool product of electromagnetic radiation |
| CN109497642A (en) * | 2018-10-19 | 2019-03-22 | 东莞幻鸟新材料有限公司 | Wool product with health-care effect |
| CN110241500A (en) * | 2019-05-17 | 2019-09-17 | 阜南华翔羊毛衫有限公司 | A kind of production technology of antimicrobial form wool textile |
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Application publication date: 20171010 |