CN109497642A - Wool product with health-care effect - Google Patents
Wool product with health-care effect Download PDFInfo
- Publication number
- CN109497642A CN109497642A CN201811218817.0A CN201811218817A CN109497642A CN 109497642 A CN109497642 A CN 109497642A CN 201811218817 A CN201811218817 A CN 201811218817A CN 109497642 A CN109497642 A CN 109497642A
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- Prior art keywords
- wool
- fiber
- polyester fiber
- health
- care effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/26—UV light protection
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
This application involves a kind of wool products with health-care effect, and the wool product includes the following raw material: wool fiber, modified polyester fiber, silver-plated long filament, bamboo pulp fiber；The modified polyester fiber coats silver-plated long filament to form covering yarn, and the covering yarn and wool fiber and bamboo pulp fibre blending are at the fabric with anti-electron radiation function；The modified polyester fiber includes polyester fiber ontology, is equipped with Cu-Cu composite membrane in polyester fiber body surface.
Description
Technical field
This application involves functional wool technical field more particularly to a kind of wool products with health-care effect.
Background technique
Wool fiber is the deformations of the skin of sheep, and warmth retention property is splendid, is chiefly used in the clothes of autumn and winter, wool fiber tool
Flexible good, the advantages that hygroscopicity is strong, warmth retention property is good is one of the natural textile raw material that earliest exploitation ice cup is extensively sent out practical, tool
There is excellent textile process performance, wool product has soft gloss, abundant and flexible feel, good pendency
The advantages that property, heat and moisture preserving and resistance to soiling.
In recent years, advancing by leaps and bounds with science and technology, various electric appliances, electronic equipment are greatly universal, and electromagnetic radiation becomes
The pollution sources after air pollution, water pollution and noise pollution.It can not only generate the communication apparatus such as radio and television
Interference, also will affect human health, human body is chronically exposed in electromagnetic radiation environment, nervous system, cardiovascular system, endocrine
System, reproductive system, immune system etc. all can be by different degrees of injuries.
As consuming public is to healthy convenient worry, so that various clothings start with radiation proof function, shielding is knitted
The emergence and development of object, away from it is modern oneself experienced a stage from formulation standard to centurial year before generation, loomage from scratch, by
Step development, the use of loomage are only limitted to the one's of military project scientific research, health care and industrial enterprise's century, and loomage starts
Into Common People, quickly grow, kind increases, quantity increases centurial year for after, continuation fast development, quality optimization, quantity
It increases sharply, new product continues to bring out.It is one that now oneself, which forms one to be related to electronics industry, textile industry, biomedicine and detection supervision,
The new industry of body.
In the utility model patent of patent No. CN103238957B, a kind of Anti-electromagneticantistatic antistatic wool is disclosed
Shirt has the function of Radiation-proof antistatic mainly by wire and wool fiber weaving is blended according to a certain percentage forms, but this
Utility model is bad in the presence of dress experience, and too hard for human body, comfort level is too poor, it is difficult to enter market.
Summary of the invention
The present invention is intended to provide a kind of wool product with health-care effect, set forth above to solve the problems, such as.
A kind of wool product with health-care effect is provided in the embodiment of the present invention, the wool product includes as follows
Raw material: wool fiber, modified polyester fiber, silver-plated long filament, bamboo pulp fiber；Silver-plated long filament is coated shape by the modified polyester fiber
At covering yarn, the covering yarn and wool fiber and bamboo pulp fibre blending are at the fabric with anti-electron radiation function；It is described
Modified polyester fiber includes polyester fiber ontology, is equipped with Cu-Cu composite membrane in polyester fiber body surface.
The technical solution that the embodiment of the present invention provides can include the following benefits:
Anti-electron radiation wool product provided by the invention has good electron-irradiation resisting effect, to various electromagnetic waves
And the assimilation effect of ultraviolet light is preferable, can effectively protect to the health of wearer, and fabric is soft thoroughly simultaneously
Gas, comfortable feel, appearance looks elegant are not easy pilling.
The additional aspect of the application and advantage will be set forth in part in the description, and will partially become from the following description
It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only
Be it is exemplary and explanatory, the application can not be limited.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings, but the embodiment in attached drawing is not constituted to any limit of the invention
System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings
Other attached drawings.
Fig. 1 is the structural schematic diagram of covering yarn in the present invention.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to
When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistented with the present invention.On the contrary, they be only with it is such as appended
The example of device and method being described in detail in claims, some aspects of the invention are consistent.
Embodiments herein is related to a kind of wool product with health-care effect comprising the original of following mass percent
Material:
Wool fiber 10~20%
Modified polyester fiber 30~40%
Silver-plated long filament 25~35%
Bamboo pulp fiber 20~35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp
Fiber blend is at the fabric with anti-electron radiation function.
The modified polyester fiber includes polyester fiber ontology, is equipped with Cu-Cu composite membrane in polyester fiber body surface.
The polyester fiber ontology is by adding filler A, using melting blended be prepared；Wherein, polyester fiber sheet
Material content is respectively as follows: the filler A of 6-10% in body, and surplus is polyester.Above-mentioned filler A includes CNT, Cu nanoparticle and Ag
Nanoparticle.
Preferably, in polyester fiber ontology material content be respectively as follows: 9% filler A, surplus is polyester.
In this embodiment, Cu, Ag nanoparticle are added in polyester fiber ontology as filler, and on the one hand it can
It combines closely with the formation of subsequent Cu-Cu composite membrane, considerably increases the combination of polyester fiber ontology and metal composite film, solve
Metal composite film unstable problem in conjunction with substrate；On the other hand, which can also be with the metal
Composite membrane collectively forms electromagnetic shielding network, increases electromagnetic shielding efficiency.
The carbon nanotube is preferably single-walled carbon nanotube, and using single-walled carbon nanotube, structure can be regarded as by single layer sheet
Graphite crimps, surface with higher can, for and above-mentioned filler A in the combinations of other particles play and unexpected have
Beneficial effect.
In filler A, the mass fraction of each substance is respectively as follows: 4 parts of CNT, 7 parts of Cu nanoparticle, 8 parts of Ag nanoparticle；It fills out
Expect in A, the partial size of Cu nanoparticle and Ag nanoparticle is followed successively by 100nm, 200nm.It is understood that the polyester fiber ontology is logical
Cross addition filler A, wherein CNT, Cu nanoparticle and Ag nanoparticle can be cooperateed with and be played a role, and can guarantee polyester fiber
The effectiveness ageing resistance of ontology is good, while playing the role of washing-resistance.
The Cu-Cu composite membrane of the polyester fiber body surface is successively to be realized using magnetron sputtering copper film and chemical plating copper film
's.The magnetron sputtering copper film with a thickness of 1 μm；The chemical plating copper film with a thickness of 2 μm；
The scheme that the technical solution of the application is combined using magnetic control and chemical plating, is successively equipped in polyester fiber body surface
Magnetron sputtering copper film and chemical plating copper film, Cu-Cu composite membrane of the two in conjunction with described in being formed, on the one hand, it leads with excellent
The filler A being equipped in electrical property, wearability, washability and electromagnetic shielding performance also, polyester fiber ontology can be compound with Cu-Cu
Film is combined closely, and the binding force of polyester fiber ontology outer membrane is increased.
The present invention also provides the production technologies of wool product, comprising the following steps:
S1 configures chloroform/methanol solvent, wool fiber is immersed in the solvent, and using soxhlet's extractor to wool fibre
Dimension carries out reflux extraction, and extraction time control is washed wool fiber using deionized water after completing in 2~2.5h, extraction
It washs, dries later；
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid,
Be stirred to react 20~25min, reaction complete after first with ethanol washing, benefit is washed with deionized later, repeatedly two
It is secondary to be washed, it dries later；
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen
In enzymatic treatment liquid, it is stirred to react 30~40min, reaction appreciates temperature 100 DEG C after completing, and keeps 10~15min, Zhi Houli
It is washed with deionized, dries later；
S4 will immerse in reduction treatment agent by the wool fiber of S2 processing, and the PH of reduction treatment agent is controlled 8~8.4
Between, bath raio is set as 1:45, is stirred at normal temperature to wool fiber, reacts it sufficiently with reduction treatment agent, reacts
Time control rinses wool fiber using deionized water after completing in 30~45min, reaction, altogether rinsing 2 times, every time
10min, rinsing carry out drying operation to wool fiber after completing；
S5 configures modified polyester fiber；
S6 configures covering yarn, and silver-plated long filament, modified polyester fiber and wool fiber are passed through Siro Core-spun Yarn technique
Radiation protection covering yarn is prepared, using silver-plated long filament as core wire, wool fiber and modified polyester fiber are as covering thread, wherein plating
The fineness of silver-colored long filament is controlled in 35D, and the density domination of covering thread is in 15~18tex；
S7, by S6 radiation protection covering yarn and bamboo pulp fiber carry out blended, and weaved using rib construction structure,
Obtain anti-electron radiation wool product.
Wherein, in S1, the volume ratio of chloroform and methanol is 85:15.
Wherein, in S6, blending process is followed successively by silver mixing, a needle, two needles, three needles, four needles, rove, spun yarn, winder, simultaneously
Line and double twisting.
Wherein, in S5, modified polyester fiber is configured specifically:
A, polyester fiber is prepared using melting is blended；
B, to polyester fibre surface magnetron sputtering C u film；
C, again to polyester fibre surface Electroless Cu Plating film；
In a, specifically, described prepare polyester fiber using melting is blended specifically: firstly, according to mass ratio, it will
CNT, Cu nanoparticle and Ag nanoparticle are uniformly mixed, and after wet grinding, are put into Muffle furnace and are carried out 310 DEG C of calcinings
50min obtains the filler A after cooling down；Then, it weighs filler A and polyester slice carries out combination drying；Drying is in vacuum
It carries out in rotary drum dryer, extracts moisture with air by vacuum system, drying temperature is 130 DEG C；Original after drying
Melt of the material under screw extruder effect after melting is pumped to uniform removing in homogeneous removal of impurities blender through melt and live together
Reason, melt are 30min~90min in the residence time of homogeneous removal of impurities blender；Polyester fondant after homogeneous removal of impurities is through Melt Pump
It send to secondary filter, filtered melt enters spinning manifold, condition of spinning manifold temperature after being set the blend melt on pipeline
Control is at 250~280 DEG C；Fiber after spinning is carried out drawing-off to process to get polyester fiber；
Preferably, material content is respectively as follows: the filler A of 6-10% in the polyester fiber, and surplus is polyester；
In b, specifically, described to polyester fibre surface magnetron sputtering C u film specifically: polyester fiber is put into magnetic control and is splashed
It penetrates in instrument, is evacuated to 1.5 × 10-5Pa opens argon gas, gate valve is adjusted, so that pressure between 1.5~5.0Pa, is beaten
Sample autobiography program is opened, pre-sputtering 15min, then magnetron sputtering C u film, after sputtering, polyester fiber is taken out, using nitrogen
Air-blowing is swept；Wherein, the magnetron sputtering C u film with a thickness of 1 μm.The magnetron sputtering power is 300W.In magnetron sputtering process
In, the bombardment of metal ion will cause the raising of polyester fibre surface temperature, so that polyester fibre surface forms suitable metallic film
The active site of growth, and then the binding force of magnetron sputtering C u film and polyester fiber can be effectively increased.
In c, specifically, described again to polyester fibre surface Electroless Cu Plating film specifically: after above-mentioned magnetron sputtering C u film
Polyester fiber be placed in copper plating bath, the copper facing at 53 DEG C is rinsed with water after copper facing, and it is poly- that the modification is obtained after drying
Ester fiber；Wherein, the composition of the chemical bronze plating liquid are as follows: Salzburg vitriol 5g/L, sodium hypophosphite 35g/L, citric acid
28g/L, bitter salt 0.8g/L, boric acid 16g/L, sodium borohydride 12g/L；Specifically, the chemical bronze plating liquid hydrogen-oxygen
Changing sodium to adjust the pH of plating solution is 12.5；Specifically, the chemical plating copper film with a thickness of 2 μm.In view of magnetron sputtering time mistake
Long and excessively high temperature can have an adverse effect to fabric body, therefore, in technical scheme, by by magnetron sputtering C u
In conjunction with plating Cu, the two is tightly combined film, smaller in conjunction with resistance, so that the Cu-Cu composite membrane has good electromagnetism
Shield effectiveness, also, overcome magnetron sputtering overlong time and excessively high temperature and can have an adverse effect to fabric body.Using
The Cu-Cu composite membrane plays unexpected beneficial effect for the absorption of electromagnetic shielding.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention
Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of wool product with health-care effect, which is characterized in that the wool product includes the following raw material: wool is fine
Dimension, modified polyester fiber, silver-plated long filament, bamboo pulp fiber；The modified polyester fiber coats silver-plated long filament to form covering yarn, institute
Covering yarn and wool fiber and bamboo pulp fibre blending are stated into the fabric with anti-electron radiation function；The modified polyester fiber
Including polyester fiber ontology, Cu-Cu composite membrane is equipped in polyester fiber body surface.
2. a kind of wool product with health-care effect according to claim 1, which is characterized in that it includes following quality
The raw material of percentage:
Wool fiber 10~20%
Modified polyester fiber 30~40%
Silver-plated long filament 25~35%
Bamboo pulp fiber 20~35%.
3. a kind of wool product with health-care effect according to claim 2, which is characterized in that the polyester fiber sheet
Body is by adding filler A, using melting blended be prepared；Wherein, material content is respectively as follows: 6- in polyester fiber ontology
10% filler A, surplus are polyester；Above-mentioned filler A includes CNT, Cu nanoparticle and Ag nanoparticle.
4. a kind of wool product with health-care effect according to claim 3, which is characterized in that the carbon nanotube is excellent
It is selected as single-walled carbon nanotube.
5. a kind of wool product with health-care effect according to claim 3, which is characterized in that described each in filler A
The mass fraction of substance is respectively as follows: 4 parts of CNT, 7 parts of Cu nanoparticle, 8 parts of Ag nanoparticle；In filler A, Cu nanoparticle and
The partial size of Ag nanoparticle is followed successively by 100nm, 200nm.
6. a kind of wool product with health-care effect according to claim 3, which is characterized in that the polyester fiber sheet
The Cu-Cu composite membrane in body surface face is successively to be realized using magnetron sputtering copper film and chemical plating copper film.
7. a kind of wool product with health-care effect according to claim 3, which is characterized in that
The production technology of the wool product, comprising the following steps:
S1, configure chloroform/methanol solvent, wool fiber is immersed in the solvent, and using soxhlet's extractor to wool fiber into
Row reflux extraction, extraction time control are washed wool fiber using deionized water after completing in 2~2.5h, extraction,
It dries later；
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, stirring
React 20~25min, reaction complete after first with ethanol washing, benefit is washed with deionized later, repeatedly twice into
Row washing, is dried later；
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed at protease
It manages in liquid, is stirred to react 30~40min, reaction appreciates temperature 100 DEG C after completing, and 10~15min is kept, later using going
Ion water washing, is dried later；
S4 will immerse in reduction treatment agent by the wool fiber of S2 processing, and the PH of reduction treatment agent is controlled between 8~8.4,
Bath raio is set as 1:45, is stirred at normal temperature to wool fiber, reacts it sufficiently with reduction treatment agent, reaction time control
System rinses wool fiber using deionized water after completing in 30~45min, reaction, rinses 2 times, each 10min altogether,
Rinsing carries out drying operation to wool fiber after completing；
S5 configures modified polyester fiber；
S6 configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is prepared by Siro Core-spun Yarn technique
Radiation protection covering yarn, using silver-plated long filament as core wire, wool fiber and modified polyester fiber are as covering thread, wherein silver-plated length
The fineness of silk is controlled in 35D, and the density domination of covering thread is in 15~18tex；
S7, by S6 radiation protection covering yarn and bamboo pulp fiber carry out blended, and weaved using rib construction structure, obtained
Anti-electron radiation wool product.
8. a kind of wool product with health-care effect according to claim 7, which is characterized in that in S1, chloroform with
The volume ratio of methanol is 85:15.
9. a kind of wool product with health-care effect according to claim 7, which is characterized in that in S6, blended work
Sequence is followed successively by silver mixing, a needle, two needles, three needles, four needles, rove, spun yarn, winder, doubling and double twisting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811218817.0A CN109497642A (en) | 2018-10-19 | 2018-10-19 | Wool product with health-care effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811218817.0A CN109497642A (en) | 2018-10-19 | 2018-10-19 | Wool product with health-care effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109497642A true CN109497642A (en) | 2019-03-22 |
Family
ID=65746798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811218817.0A Pending CN109497642A (en) | 2018-10-19 | 2018-10-19 | Wool product with health-care effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109497642A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687507A (en) * | 2005-04-12 | 2005-10-26 | 夏芝林 | Method for preparing silver metallized organic fiber and textile |
| CN106149162A (en) * | 2016-08-24 | 2016-11-23 | 中央军委后勤保障部军需装备研究所 | A kind of Electromagnetically shielding fabrics with electric conductivity periodic structure and preparation method |
| CN107237038A (en) * | 2017-07-31 | 2017-10-10 | 嘉兴珠朗服饰有限公司 | A kind of its production technology of anti-electron radiation wool product |
| CN107263944A (en) * | 2017-07-28 | 2017-10-20 | 杭州爱睿生物技术有限公司 | The silver-colored fabric of Anti-radiation nano and its technique prepared by a kind of utilization space technology |
-
2018
- 2018-10-19 CN CN201811218817.0A patent/CN109497642A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687507A (en) * | 2005-04-12 | 2005-10-26 | 夏芝林 | Method for preparing silver metallized organic fiber and textile |
| CN106149162A (en) * | 2016-08-24 | 2016-11-23 | 中央军委后勤保障部军需装备研究所 | A kind of Electromagnetically shielding fabrics with electric conductivity periodic structure and preparation method |
| CN107263944A (en) * | 2017-07-28 | 2017-10-20 | 杭州爱睿生物技术有限公司 | The silver-colored fabric of Anti-radiation nano and its technique prepared by a kind of utilization space technology |
| CN107237038A (en) * | 2017-07-31 | 2017-10-10 | 嘉兴珠朗服饰有限公司 | A kind of its production technology of anti-electron radiation wool product |
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Application publication date: 20190322 |