CN207376192U - A kind of anti-electron radiation wool product - Google Patents

A kind of anti-electron radiation wool product Download PDF

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Publication number
CN207376192U
CN207376192U CN201720942695.4U CN201720942695U CN207376192U CN 207376192 U CN207376192 U CN 207376192U CN 201720942695 U CN201720942695 U CN 201720942695U CN 207376192 U CN207376192 U CN 207376192U
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Prior art keywords
wool
fiber
silver
wool fiber
electron radiation
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CN201720942695.4U
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Chinese (zh)
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张�杰
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Jiaxing Zhulang Clothing Co Ltd
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Jiaxing Zhulang Clothing Co Ltd
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Abstract

The utility model provides a kind of anti-electron radiation wool product, it includes 10 ~ 20% wool fibers, 30 ~ 40% modified polyester fibers, 25 ~ 35% silver-plated long filaments and 15 ~ 35% bamboo pulp fibers, wherein, modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp fibre blending are into having the function of the fabric of anti-electron radiation, coordinate production technology provided by the utility model, it can obtain with high effectiveness, comfortable feel simultaneously, suitable for the anti-electron radiation wool product of dress.

Description

A kind of anti-electron radiation wool product
Technical field
The utility model is related to functional wool fields, and in particular to a kind of anti-electron radiation wool product.
Background technology
Wool fiber is the deformations of the skin of sheep, and warmth retention property is splendid, is chiefly used in the clothes of autumn and winter, wool fiber tool Flexible good, the advantages that hygroscopicity is strong, warmth retention property is good is that earliest exploitation ice cup extensively sends out one of practical natural textile raw material, tool There is excellent textile process performance, wool product has soft gloss, abundant and flexible feel, good pendency The advantages that property, heat and moisture preserving and resistance to soiling.
In recent years, advancing by leaps and bounds with science and technology, various electric appliances, electronic equipment are greatly popularized, and electromagnetic radiation becomes The pollution sources after air pollution, water pollution and noise pollution.It can not only generate the communication apparatus such as radio and television Interference, can also influence health, human body is chronically exposed in electromagnetic radiation environment, nervous system, cardiovascular system, endocrine System, reproductive system, immune system etc. can all be subject to different degrees of injury.
As consuming public is to healthy convenient worry so that various clothings start with radiation proof function, and shielding is knitted The appearance and development of object, away from it is modern oneself experienced a stage from formulation standard to centurial year before generation, loomage from scratch, by Step development, the use of loomage are only limitted to the one's of military project scientific research, health care and industrial enterprise's century, and loomage starts Into Common People, quickly grow, kind increases, after quantity increase generation in centurial year, continuation fast development, quality optimization, quantity It increases sharply, new product continues to bring out.It is one that now oneself, which forms one to be related to electronics industry, textile industry, biomedicine and detection supervision, The new industry of body.
In the utility model patent of patent No. CN103238957B, a kind of Anti-electromagneticantistatic antistatic wool is disclosed Shirt mainly by wire and wool fiber weaving is blended according to a certain percentage forms, has the function of Radiation-proof antistatic, but this Utility model is bad in the presence of dress experience, and too hard for human body, comfort level is too poor, it is difficult into market.
Utility model content
(One)Technical problems to be solved
Problem to be solved in the utility model is that existing anti-electron radiation wool product is excessively heavy hard, is not easy to wear It.
(Two)Technical solution
In order to solve the above technical problems, the utility model provides a kind of anti-electron radiation wool product, whole soft, pro-skin Comfortably, to the good absorption effect of electromagnetic wave and ultraviolet light, service life is long.
The anti-electron radiation wool product includes the raw material of following mass percent:
Wool fiber 10 ~ 20%
Modified polyester fiber 30 ~ 40%
Silver-plated long filament 25 ~ 35%
Bamboo pulp fiber 15 ~ 35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp Fiber blend is into having the function of the fabric of anti-electron radiation.
It further limits, includes the raw material of following mass percent:
Wool fiber 10%
Modified polyester fiber 30%
Silver-plated long filament 25%
Bamboo pulp fiber 35%.
Alternatively, include the raw material of following mass percent:
Wool fiber 15%
Modified polyester fiber 35%
Silver-plated long filament 30%
Bamboo pulp fiber 20%.
It is corresponding, the following production stage of anti-electron radiation wool product in the utility model:
S1 configures chloroform/methanol solvent, wool fiber is immersed in the solvent, and fine to wool using soxhlet's extractor Dimension carries out reflux extraction, and extraction time control is washed wool fiber using deionized water after completing in 2 ~ 2.5h, extraction It washs, dries afterwards;
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, 20 ~ 25min is stirred to react, reaction is washed after completing first with ethyl alcohol, and profit is washed with deionized afterwards, so repeatedly twice It is washed, is dried afterwards;
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen In enzymatic treatment liquid, 30 ~ 40min is stirred to react, temperature after completing is appreciated 100 DEG C, keeps 10 ~ 15min, utilize afterwards by reaction Deionized water is washed, and is dried afterwards;
S4 will be immersed by the wool fiber of S2 processing in reduction treatment agent, the PH of reduction treatment agent control 8 ~ 8.4 it Between, bath raio is arranged to 1:45, wool fiber is stirred at normal temperatures, it is made fully to be reacted with reduction treatment agent, during reaction Between control in 30 ~ 45min, reaction rinses wool fiber using deionized water after completing, and rinses 2 times altogether, every time 10min, rinsing carry out drying operation after completing to wool fiber;
S5 configures modified polyester fiber, by ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester Polycondensation reaction is carried out, obtains modified polyamide ester, by the argentiferous that the modified polyamide ester and grain size of synthesis are 0.1 ~ 0.5 micron Inorganic ultrafine antimicrobial powder is using mass ratio as 8:1 is mixed, and is carried out spinning afterwards and is handled to obtain modified polyester fiber;
S6 configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is passed through Siro Core-spun Yarn technique Radiation protection covering yarn is prepared, using silver-plated long filament as cored wire, wool fiber and modified polyester fiber are as covering thread, wherein plating The fineness of silver-colored long filament is controlled in 35D, and the density domination of covering thread is in 15 ~ 18tex;
S7, the radiation protection covering yarn in S6 and bamboo pulp fiber progress is blended, and weaved using rib construction structure, Obtain anti-electron radiation wool product.
It is further defined, in S1, the volume ratio of chloroform and methanol is 85:15.
Further be defined, in S6, blending process be followed successively by silver mixing, a pin, two pins, three pins, four pins, rove, spun yarn, Winder, doubling and double twisting.
(Three)Advantageous effect
(1)Anti-electron radiation wool product provided by the utility model has good electron-irradiation resisting effect, to various The assimilation effect of electromagnetic wave and ultraviolet light is preferable, and effectively the health of wearer can be protected, and fabric simultaneously Flexible, breathable, comfortable feel, appearance looks elegant are not easy pilling.
(2)The production technology of radiation-proof wool product provided by the utility model, first pre-processes wool surfaces, profit The surface nature of wool fiber can be changed with ion processing liquid, the scale layer of corrosion wool surface reduces surface lipoid Substance interrupts disulfide bond, promotes the effect of following protein enzyme, while accelerates the hydrolysis rate of proteases on wool fiber, Reach good wool surface scale modified effect so that wool fiber more soft comfortable, avoid the occurrence of contraction and The phenomenon that pilling;Modified polyester fiber, ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphorous acid are utilized afterwards Ester carries out polycondensation reaction, obtains modified polyamide ester, obtained modified polyamide ester feel is very comfortable, is aided with the ultra-fine of addition Silver-containing inorganic ultrafine anti-bacterial powder so that the modified polyester fiber has radiation proof function simultaneously, further promotes the anti-of entirety Electron radiation effect;Particularly, wherein using Siro Core-spun Yarn technique by modified polyester fiber, wool and silver-plated long filament Cored operation is carried out, the anti-electromagnetic-radiation performance of cored fabric is better than and twisted weave object under identical silver-plated long filament content, and twisted weave Object is better than intertexture, substitutes simultaneously twisted weave object and intertexture using cored fabric, not only avoids appearance of fabrics by silver ion Limitation, and cost has been saved, while higher radioresistance effect is can reach, while utilize wool and modified polyester fiber pair Silver-plated long filament is coated, and obtained covering yarn becomes sufficiently flexible, and Surface feel is soft comfortable, while avoids silver-plated long filament naked It exposes outside so that it can which with more different colors, appearance is more beautiful;It is eventually adding bamboo fibre so that quality of item is more The more comfortable color simultaneously with fashion of excellent, dress.
Description of the drawings
Fig. 1 is the structure diagram of covering yarn in the utility model.
Specific embodiment
With reference to embodiment, specific embodiment of the present utility model is described in further detail.Following embodiment For illustrating the utility model, but it is not intended to limit the scope of the present invention.
With reference to figure 1, the utility model provides a kind of anti-electron radiation wool product, includes the original of following mass percent Material:
Wool fiber 10 ~ 20%
Modified polyester fiber 30 ~ 40%
Silver-plated long filament 25 ~ 35%
Bamboo pulp fiber 20 ~ 35%
The modified polyester fiber coats silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp Fiber blend is into having the function of the fabric of anti-electron radiation.
The utility model additionally provides a kind of production technology of anti-electron radiation wool product, comprises the following steps:
S1 configures chloroform/methanol solvent, wool fiber is immersed in the solvent, and fine to wool using soxhlet's extractor Dimension carries out reflux extraction, and extraction time control is washed wool fiber using deionized water after completing in 2 ~ 2.5h, extraction It washs, dries afterwards;
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, 20 ~ 25min is stirred to react, reaction is washed after completing first with ethyl alcohol, and profit is washed with deionized afterwards, so repeatedly twice It is washed, is dried afterwards;
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen In enzymatic treatment liquid, 30 ~ 40min is stirred to react, temperature after completing is appreciated 100 DEG C, keeps 10 ~ 15min, utilize afterwards by reaction Deionized water is washed, and is dried afterwards;
S4 will be immersed by the wool fiber of S2 processing in reduction treatment agent, the PH of reduction treatment agent control 8 ~ 8.4 it Between, bath raio is arranged to 1:45, wool fiber is stirred at normal temperatures, it is made fully to be reacted with reduction treatment agent, during reaction Between control in 30 ~ 45min, reaction rinses wool fiber using deionized water after completing, and rinses 2 times altogether, every time 10min, rinsing carry out drying operation after completing to wool fiber;
S5 configures modified polyester fiber, by ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester Polycondensation reaction is carried out, obtains modified polyamide ester, by the argentiferous that the modified polyamide ester and grain size of synthesis are 0.1 ~ 0.5 micron Inorganic ultrafine antimicrobial powder is using mass ratio as 8:1 is mixed, and is carried out spinning afterwards and is handled to obtain modified polyester fiber;
S6 configures covering yarn, silver-plated long filament, modified polyester fiber and wool fiber is passed through Siro Core-spun Yarn technique Radiation protection covering yarn is prepared, using silver-plated long filament as cored wire, wool fiber and modified polyester fiber are as covering thread, wherein plating The fineness of silver-colored long filament is controlled in 35D, and the density domination of covering thread is in 15 ~ 18tex;
S7, the radiation protection covering yarn in S6 and bamboo pulp fiber progress is blended, and weaved using rib construction structure, Obtain anti-electron radiation wool product.
Wherein, in S1, the volume ratio of chloroform and methanol is 85:15.
Wherein, in S6, blending process is followed successively by silver mixing, a pin, two pins, three pins, four pins, rove, spun yarn, winder, simultaneously Line and double twisting.
The utility model is further elaborated with reference to embodiment:
Embodiment 1
S1 configures chloroform/methanol solvent, the wool fiber of quality accounting 10% is immersed in the solvent, and is extracted using Soxhlet Device is taken to carry out reflux extraction to wool fiber, wool fiber is utilized deionization by extraction time control after 2h, extraction are completed Water is washed, and washing three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, Be stirred to react 20min, reaction is washed after completing first with ethyl alcohol, and profit is washed with deionized afterwards, so repeatedly twice into Row washing, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen In enzymatic treatment liquid, 30min is stirred to react, temperature after completing is appreciated 100 DEG C, keeps 15min, utilize deionization afterwards by reaction Water washing is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S4 will be immersed by the wool fiber of S2 processing in reduction treatment agent, the PH of reduction treatment agent control 8 ~ 8.4 it Between, bath raio is arranged to 1:45, wool fiber is stirred at normal temperatures, it is made fully to be reacted with reduction treatment agent, during reaction Between control in 30min, reaction rinses wool fiber using deionized water after completing, and rinses 2 times, each 10min altogether, Rinsing carries out drying operation after completing to wool fiber;
S5 configures modified polyester fiber, by ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester Carry out polycondensation reaction, obtain the modified polyamide ester of quality accounting 30%, by the modified polyamide ester and grain size of synthesis for 0.1 ~ 0.5 micron of silver-containing inorganic ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and is carried out spinning afterwards and is handled to obtain modified gather Ester fiber;
S6 configures covering yarn, 25% silver-plated long filament of quality accounting, 30% modified polyester fiber and 10% wool fiber is led to It crosses Siro Core-spun Yarn technique and prepares radiation protection covering yarn, using silver-plated long filament as cored wire, wool fiber and modified poly ester are fine Dimension is controlled as covering thread, the wherein fineness of silver-plated long filament in 35D, and the density domination of covering thread is 18tex;
S7, the radiation protection covering yarn in S6 and the progress of 35% bamboo pulp fiber of quality accounting is blended, and use rib construction knot Structure is weaved, and obtains anti-electron radiation wool product.
Embodiment 2
S1 configures chloroform/methanol solvent, the wool fiber of quality accounting 15% is immersed in the solvent, and is extracted using Soxhlet Device is taken to carry out reflux extraction to wool fiber, wool fiber is utilized deionization by extraction time control after 2h, extraction are completed Water is washed, and washing three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, Be stirred to react 20min, reaction is washed after completing first with ethyl alcohol, and profit is washed with deionized afterwards, so repeatedly twice into Row washing, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen In enzymatic treatment liquid, 30min is stirred to react, temperature after completing is appreciated 100 DEG C, keeps 15min, utilize deionization afterwards by reaction Water washing is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S4 will be immersed by the wool fiber of S2 processing in reduction treatment agent, the PH of reduction treatment agent control 8 ~ 8.4 it Between, bath raio is arranged to 1:45, wool fiber is stirred at normal temperatures, it is made fully to be reacted with reduction treatment agent, during reaction Between control in 30min, reaction rinses wool fiber using deionized water after completing, and rinses 2 times, each 10min altogether, Rinsing carries out drying operation after completing to wool fiber;
S5 configures modified polyester fiber, by ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester Carry out polycondensation reaction, obtain the modified polyamide ester of quality accounting 35%, by the modified polyamide ester and grain size of synthesis for 0.1 ~ 0.5 micron of silver-containing inorganic ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and is carried out spinning afterwards and is handled to obtain modified gather Ester fiber;
S6 configures covering yarn, 30% silver-plated long filament of quality accounting, 35% modified polyester fiber and 15% wool fiber is led to It crosses Siro Core-spun Yarn technique and prepares radiation protection covering yarn, using silver-plated long filament as cored wire, wool fiber and modified poly ester are fine Dimension is controlled as covering thread, the wherein fineness of silver-plated long filament in 35D, and the density domination of covering thread is 18tex;
S7, the radiation protection covering yarn in S6 and the progress of 20% bamboo pulp fiber of quality accounting is blended, and use rib construction knot Structure is weaved, and obtains anti-electron radiation wool product.
Embodiment 3
S1 configures chloroform/methanol solvent, the wool fiber of quality accounting 20% is immersed in the solvent, and is extracted using Soxhlet Device is taken to carry out reflux extraction to wool fiber, wool fiber is utilized deionization by extraction time control after 2h, extraction are completed Water is washed, and washing three times, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S2 configures ionic liquid, ionic liquid is heated up to 50 DEG C, and the wool fiber in S1 is immersed in ionic liquid, Be stirred to react 20min, reaction is washed after completing first with ethyl alcohol, and profit is washed with deionized afterwards, so repeatedly twice into Row washing, is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S3 configures Protease Treatment liquid, Protease Treatment liquid is heated up to 40 DEG C, and the wool fiber in S2 is immersed albumen In enzymatic treatment liquid, 30min is stirred to react, temperature after completing is appreciated 100 DEG C, keeps 15min, utilize deionization afterwards by reaction Water washing is put into baking oven and is dried in the environment of 50 degrees Celsius afterwards;
S4 will be immersed by the wool fiber of S2 processing in reduction treatment agent, the PH of reduction treatment agent control 8 ~ 8.4 it Between, bath raio is arranged to 1:45, wool fiber is stirred at normal temperatures, it is made fully to be reacted with reduction treatment agent, during reaction Between control in 30min, reaction rinses wool fiber using deionized water after completing, and rinses 2 times, each 10min altogether, Rinsing carries out drying operation after completing to wool fiber;
S5 configures modified polyester fiber, by ethylene glycol terephthalate and phosphate, sodium tripolyphosphate, phosphite ester Carry out polycondensation reaction, obtain the modified polyamide ester of quality accounting 40%, by the modified polyamide ester and grain size of synthesis for 0.1 ~ 0.5 micron of silver-containing inorganic ultrafine anti-bacterial powder is using mass ratio as 8:1 is mixed, and is carried out spinning afterwards and is handled to obtain modified gather Ester fiber;
S6 configures covering yarn, 25% silver-plated long filament of quality accounting, 40% modified polyester fiber and 20% wool fiber is led to It crosses Siro Core-spun Yarn technique and prepares radiation protection covering yarn, using silver-plated long filament as cored wire, wool fiber and modified poly ester are fine Dimension is controlled as covering thread, the wherein fineness of silver-plated long filament in 35D, and the density domination of covering thread is 18tex;
S7, the radiation protection covering yarn in S6 and the progress of 15% bamboo pulp fiber of quality accounting is blended, and use rib construction knot Structure is weaved, and obtains anti-electron radiation wool product.
In embodiment 1 ~ 3, the shielding properties of this anti-electron radiation wool product can reach more than 48db, have good Electromagnet shield effect, wherein the wool product shielding properties in embodiment 2 is up to 55db, while comfortable feel, fabric are breathed freely, It is very soft.
In conclusion the restricted embodiment that it is the utility model that the above embodiment, which is not, the technology of all this fields The modification or equivalent deformation that personnel are carried out on the basis of the substantive content of the utility model, the skill in the utility model Art scope.

Claims (1)

1. a kind of anti-electron radiation wool product, including the following raw material:Wool fiber, modified polyester fiber, silver-plated long filament, bamboo Pulp fibres, the modified polyester fiber coat silver-plated long filament to form covering yarn, the covering yarn and wool fiber and bamboo pulp Fiber blend is into having the function of the fabric of anti-electron radiation.
CN201720942695.4U 2017-07-31 2017-07-31 A kind of anti-electron radiation wool product Expired - Fee Related CN207376192U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097879A (en) * 2018-08-06 2018-12-28 梧州市兴能农业科技有限公司 A kind of anti-electron radiation wool product
CN110284251A (en) * 2019-07-01 2019-09-27 福建长源纺织有限公司 A kind of environmental protection knitting fabric and its storing unit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097879A (en) * 2018-08-06 2018-12-28 梧州市兴能农业科技有限公司 A kind of anti-electron radiation wool product
CN110284251A (en) * 2019-07-01 2019-09-27 福建长源纺织有限公司 A kind of environmental protection knitting fabric and its storing unit

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Granted publication date: 20180518

Termination date: 20190731