CN107233271A - A kind of true ginger shampoo of amino acid and preparation method thereof - Google Patents
A kind of true ginger shampoo of amino acid and preparation method thereof Download PDFInfo
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- CN107233271A CN107233271A CN201710515431.5A CN201710515431A CN107233271A CN 107233271 A CN107233271 A CN 107233271A CN 201710515431 A CN201710515431 A CN 201710515431A CN 107233271 A CN107233271 A CN 107233271A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Abstract
The invention belongs to cosmetic technical field, and in particular to a kind of true ginger shampoo of amino acid and preparation method thereof；The shampoo is main by race, sodium lauroyl sarcosine, Cocoamidopropyl betaine, LAA, sodium methyl cocoyl taurate, cocoamido sodium propionate, acrylate copolymer, coconut palm oleoyl monoethanolamine, ginger oil, Ginger P.E, polyquaternium 43, the Octyl Ethers of PPG 3, citric acid, piroctone olamine salt, polyquaternium 10, microcrystalline cellulose, the compositions such as curcumin are constituted, the shampoo foaming effect is good, foam stabilization, and excitant is small, Anti-hair loss, degreasing is strong, easily combed using rear hair, strengthen hair toughness.
Description
Technical field
The present invention relates to cosmetic technical field, and in particular to a kind of true ginger shampoo of amino acid and preparation method thereof.
Background technology
With the rapid development of economy, the continuous improvement of people's living standard, by environmental pollution, pressure fatigue and hair
The factor influence such as frequent moulding, the hair and scalp of people is more and more fragile.On the market to wash shield product category various, but allow people
It is dazzled, the effect that consumer cannot but be satisfied with after a variety of hair washing products were attempted, paid on the contrary hair it is serious by
The costs such as the sensitive fragility of damage, scalp.
Current most shampoo is all to use sulfate surfactant (SLS, SLES).It is on scalp and hair
Residue it is higher, to the excitant of scalp than larger because strong cleaning force, there is also certain injury work for correct scared scale
With.Compared with amino acid surfactant, SLS, SLES residue are the former nearly 7 times, and the excitant to scalp is for the former
Nearly 4 times, and with SLS clean scalp after, the percentage of water loss of skin is nearly 2 times of amino acid surfactant, therefore is generally made
With shampoos of the SLS as surfactant, will typically arrange in pairs or groups silicone oil, otherwise hair will do as withered grass, but with
Time passage, hair follicle obstruction, hair is easier to be damaged.
At present using the shampoo of amino acid surfactant, even if without using silicone oil, while scalp is very salubrious, hair
Water profit can still be compared.Therefore, big is stimulated to scalp and hair for shampoo in the market, hair care hair care effect is not to the utmost
Such as people's will, therefore, it is necessary to research and develop a kind of safety and Health, gentle cleaning, the shampoo for nourishing moisturizing healthy hair.Go out in the market
Existing substantial amounts of amino acid surfactant, but it is largely high using amino acid surfactant cost, and use amino acid table
Face activating agent foam is difficult rinsing, and soil release performance is poor.
Publication No. CN106109257A Chinese patent application discloses a kind of amino acid without silicone oil shampoo, includes ammonia
Base acid surfaces activating agent, NMF, conditioner, preservative and water, the invention are unique clear using amino acid surfactant
Clean composition, it is to avoid chemical detergent remains injury to human body, it is non-stimulated, without allergy, and it is fluffy to wash rear hair, elegant, peace
Loopful is protected；But the invention soil release performance is poor, especially with alanine type surfactant surface-active and poor permeability, go
Dirty ability is weak.
Publication No. CN106806270A Chinese patent application discloses a kind of stopping itching shampoo；Raw material is amino acid system
Surfactant 15-20%；Tea tree extract solution 1-5%；Ginger extract 1-3%；Radix Sophorae Flavescentis extractive liquid 1-3%；Frutus cnidii is extracted
Liquid 1-3%；Licorice root extract 1-3%；Borneol 0.1-0.3%；Menthol 0.1-0.3%；Citric acid 0-1%；Surplus is water；
The problem of invention preferably can solve scalp itch, but the shampoo soil release performance used is poor, and foam is unstable, and
Chinese medicine material component content is high, causes shampoo with high costs, is not suitable for industrialization production.
The content of the invention
In order to solve the presence of problem in the prior art, the invention discloses a kind of true ginger shampoo of amino acid and its preparation side
Method, shampoo foaming effect of the present invention is good, and dirt-removing power is strong, and easily rinses, and washes rear hair quality and improves.
Technical solution of the present invention is as follows：
A kind of true ginger shampoo of amino acid, is mainly made up of the composition of following mass fraction：
Race 22-28%, sodium lauroyl sarcosine 13-17%, Cocoamidopropyl betaine 10-14%, lauroyl two
Property guanidine-acetic acid sodium 4-6%, sodium methyl cocoyl taurate 2.5-3.5%, cocoamido sodium propionate 1.8-2.2%, propylene
Acid ester copolymer 1.8-2.2%, coconut palm oleoyl monoethanolamine 1.4-1.6%, ginger oil 0.4-0.6%, Ginger P.E 0.4-
0.6%th, polyquaternium -430.35-0.45%, PPG-3 Octyl Ethers 0.25-0.35%, citric acid 0.25-0.35%, pyrrole Roc
Ketone ethanolamine salt 0.18-0.22%, Polyquaternium-10 0.18-0.22%, microcrystalline cellulose 0.08-0.12%, curcumin
0.03-0.05%, Phenoxyethanol 0.4-0.6%, preservative 0.1-0.14%, essence 0.3-0.35% and water 20-50%.
It is preferred that, the true ginger shampoo of described amino acid is made up of the composition of following mass fraction：
Race 25%, sodium lauroyl sarcosine 15%, Cocoamidopropyl betaine 12%, LAA
5%th, sodium methyl cocoyl taurate 3%, cocoamido sodium propionate 2%, acrylate copolymer 2%, cocounut oil acyl list second
Hydramine 1.5%, ginger oil 0.5%, Ginger P.E 0.5%, polyquaternium -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid
0.3%th, piroctone olamine salt 0.2%, Polyquaternium-10 0.2%, microcrystalline cellulose 0.1%, curcumin 0.04%, benzene
Oxyethanol 0.5%, preservative 0.12%, essence 0.32% and water 31.02%.
Present invention also offers the preparation method of the true ginger shampoo of described amino acid, comprise the following steps：
S1, race removed the peel, is cleaned, it is 35-45 points of immersion in 0.3% antiseptic solution to be put into the mass fraction separately taken
Clock, is then washed with deionized water only, is put into dozen Jiang Jizhong and is crushed to pasty state, add water mixing, is warming up to 95-100 DEG C, constant temperature 80-
100 minutes, obtain race water solution A；
S2, add water in emulsification pot, open homogeneous, add microcrystalline cellulose, homogeneous 10-14 minutes waits to be completely dispersed
After add Polyquaternium-10, homogeneous 0.5-1.5 minutes then heats to 80-90 DEG C, adds coconut palm oleoyl monoethanolamine, methyl coconut palm
Oleoyl taurate, is incubated 25-35 minutes, obtains emulsion B；
S3, emulsion B is cooled to 50-60 DEG C, sequentially adds sodium lauroyl sarcosine, cocoamido sodium propionate, the moon
Osmanthus acyl both sexes guanidine-acetic acid sodium, piroctone olamine salt, stir to substantially uniformity, are then cooled to 43-48 DEG C, sequentially add
PPG-3 Octyl Ethers, polyquaternium -43, ginger oil, Ginger P.E, dispersing and filtering add acrylate copolymer and water, and stirring is extremely
Substantially uniformity, obtains mixed liquor C；
S4, citric acid is dissolved in water it is made pH adjusting agent, the pH value for the mixed liquor C that regulating step S3 is obtained, then successively
Cocoamidopropyl betaine, curcumin, essence, preservative, Phenoxyethanol, race water solution A are added, stirring is to completely
It is even, room temperature is down to, is produced.
It is preferred that, constant temperature 90 minutes in step S1.
Further, the pH value for the mixed liquor C that the regulating step S3 described in step S4 is obtained is 6.5-7.5.
Described preservative is the Preservative Technology for Personal Care being documented in GB/T29666-2013, methylchloroisothiazandnone
With methylisothiazolinone and magnesium chloride and the mixture of magnesium nitrate, wherein preservative is different by methylchloroisothiazandnone, methyl
Thiazolinone, magnesium chloride and magnesium nitrate are 11 by weight:4:8:230:747 compositions.
The present invention replaces traditional Sulfates surfactant using amino acid type surfactant, substantially reduces enemy
The stimulation and injury of skin, property are gentleer, and amino acid surfactant of the present invention is mainly sodium lauroyl sarcosine, methyl coconut palm
Oleoyl taurate and cocoamido sodium propionate (CAS:90170-45-9), and with the use of amino acid pattern deriving surface
Activating agent Cocoamidopropyl betaine, LAA, coconut palm oleoyl monoethanolamine, reduce nontraditional amino acid table
Face activating agent is poor due to the caused soil release performance of surface-active difference, and the unstable shortcoming of foam.
Amino acid surfactant major function in the present invention is cleaning action, because of amino acid and fatty alcohol or aliphatic acid
Produce after chemical reaction, with certain cleaning efficacy, and the characteristics of its alkalescent and faintly acid coexist can be kept, therefore amino acid
Shampoo it is safe.Amino acid surfactant is gentle, non-stimulated, close with acid-base scale of skin, so using hair washing
It during water, can not only play a part of dirt, apply also for nourishing hair and conserve hair.Amino acid surfactant also has
Have gentle pro-skin, without anaphylaxis and it is soluble in water the features such as, even if child, pregnant woman or sensitiveness skin can be applicable.
Acrylate copolymer (CAS:25133-97-5) it is a kind of good thickener, it can be surfactant body
System provides the stability and thickening properties of brilliance, and acrylate copolymer can preferably strengthen antistatic in shampoo
Performance, enhances the moisturizing compliance of shampoo.
Polyquaternium -43：Belong to cationic polymeric compound, used with amino acid surfactant compatibility, Ke Yizeng
Strong foamy body, strengthens the soil release performance of shampoo, and can strengthen the moisture retention of shampoo in scalp formation thin film
Can, improve hair quality.
Polyquaternium-10 is used for hair, and affinity is strong, maintenance hair jag, forms transparent, continuous thin on hair
Film improves damaged hair there is provided splendid performance of keeping humidity.
Piroctone olamine salt is a kind of efficient, nontoxic non-stimulated anti-dandruff agent, by sterilization and antioxidation from
The outside channel for fundamentally blocking dandruff to produce, so that effectively radical cure dandruff, stopping head itching.
Microcrystalline cellulose (CAS:It is 9004-34-6) a kind of purifying, the cellulose of part depolymerization, applies in shampoo
The mobility of shampoo can be strengthened, and increase the easy carding property for washing rear hair.
The true ginger shampoo of amino acid that the present invention is provided, the Sulfates surfactant of complete abandoning tradition, using more
The all amino acid formula of gentle safety, while adding ginger oil (CAS:8007-08-7), Ginger P.E (CAS:84696-15-
1), the various active ginger essence such as race, wherein ginger oil and Ginger P.E are separated using modern efficient, environmental protective type chemical
New technology --- supercritical carbon dioxide extracting isolation technics (SCFE-CO2).Ginger active component can be cleaned gently, be dispelled
Hair residual soil, adjusts scalp water and oil balance, mitigates scalp pressure；Root of hair is nourished, outer hair care silk, interior foster scalp supplements head
Nutrition needed for skin, firm root of hair allows the tough health of healthy hair, submissive glossy.
Ginger (scientific name：Zingiber officinale Rosc) contained by active ingredient be mainly gingerol and volatile oil,
Ginger and its extract have following physiology or pharmacologic action：Remove free radical, anti-oxidant, anti-aging；Antibacterial, anti-inflammatory；Promote
Blood circulation, strengthens cytotrophy；By Ginger P.E and ginger oil application in the present invention, scalp can be stimulated, capillary is expanded
Blood vessel, promotes the vascular circulation in skin, and more cytotrophies are conveyed to hair follicle, promotes scalp metabolism, activates hair follicle
Tissue, effectively anti-alopecia-stopping, white hair, stimulate kainogenesis long, and can suppress scalp pruritus, strengthen root of hair.In addition, it also has clearly
Clean scalp, dispel dandruff, the preventing and treating function such as alopecia.
The true ginger shampoo of amino acid that the present invention is provided adds a variety of ginger active components, can also remove hair heap contamination
Thing, dredges pore, prevents sebum from being deposited in hair follicle, ensures the smoothness of nutrition and moisture absorption and transport.Nourish scalp and hair
Core, tough root of hair, generating hair is moistened and nourished, and maintenance is damaged hair position, is reduced the fragile rapid wear of hair, is improved hair quality.
Compared with prior art, the present invention has advantages below：
(1) the true ginger shampoo of base acid of the present invention is using amino acid surfactant and amino acid derived surfactant compatibility
Use, strengthen the decontamination of shampoo, foam stability soaks and makes the more compliant function of hair quality, composition safety is realized without silicon
Oil, non-mineral oil, without nipagin esters, dye-free material, without animal raw materials, without petroleum-type surfactant.
(2) the true ginger shampoo of amino acid of the present invention plants extraction composition using natural, effectively removes aging cutin, accelerates scalp more
Newly, noresidue formula, deep layer cleaning washes chemical deposition off, the healthy scalp environment of reduction, fully nourishes scalp, cultivate it is flexible,
The healthy healthy hair of flexible.For the hair grown, epidermis can also be shunk, makes hair fluffy upwards from root, becomes
With appropriate elasticity, toughness and the hair quality of fluffy sense.
(3) preparation method of the true ginger shampoo of amino acid of the present invention is simple, and condition is controllable, process stabilizing, can be applicable.
Embodiment
Explanation by following examples to the present invention most further, makes those skilled in the art more understand skill of the present invention
Art scheme.
A kind of true ginger shampoo of the amino acid of embodiment 1
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：
Race 25%, sodium lauroyl sarcosine 15%, Cocoamidopropyl betaine 12%, LAA
5%th, sodium methyl cocoyl taurate 3%, cocoamido sodium propionate 2%, acrylate copolymer 2%, cocounut oil acyl list second
Hydramine 1.5%, ginger oil 0.5%, Ginger P.E 0.5%, polyquaternium -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid
0.3%th, piroctone olamine salt 0.2%, Polyquaternium-10 0.2%, microcrystalline cellulose 0.1%, curcumin 0.04%, benzene
Oxyethanol 0.5%, preservative 0.12%, essence 0.32% and water 31.02%.
The preparation method of the true ginger shampoo of described amino acid, comprise the following steps for：
S1, race removed the peel, is cleaned, being put into the mass fraction separately taken to be soaked 40 minutes in 0.3% antiseptic solution,
Then it is washed with deionized water only, is put into dozen Jiang Jizhong and is crushed to pasty state, add water mixing, is warming up to 98 DEG C, constant temperature 90 minutes is obtained
Race water solution A；
S2, add water to emulsification pot in, open homogeneous, add microcrystalline cellulose, homogeneous 12 minutes, after being completely dispersed plus
Enter Polyquaternium-10, homogeneous 1 minute then heats to 85 DEG C, adds coconut palm oleoyl monoethanolamine, methyl cocoyl taurine
Sodium, is incubated 30 minutes, obtains emulsion B；
S3, emulsion B is cooled to 55 DEG C, sequentially adds sodium lauroyl sarcosine, cocoamido sodium propionate, lauroyl
Both sexes guanidine-acetic acid sodium, piroctone olamine salt, stir to substantially uniformity, are then cooled to 45 DEG C, sequentially add PPG-3 octyl groups
Ether, polyquaternium -43, ginger oil, Ginger P.E, dispersing and filtering add acrylate copolymer and water, stir to substantially uniformity,
Obtain mixed liquor C；
S4, citric acid is dissolved in water pH adjusting agent is made, the pH value for the mixed liquor C that regulating step S3 is obtained is 7.0, then
Cocoamidopropyl betaine, curcumin, essence, preservative, Phenoxyethanol, race water solution A are sequentially added, is stirred to complete
Uniformly, room temperature is down to, is produced.
A kind of true ginger shampoo of the amino acid of embodiment 2
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：
Race 28%, sodium lauroyl sarcosine 13%, Cocoamidopropyl betaine 14%, LAA
4%th, sodium methyl cocoyl taurate 3.5%, cocoamido sodium propionate 1.8%, acrylate copolymer 2.2%, cocounut oil
Acyl MEA 1.4%, ginger oil 0.6%, Ginger P.E 0.4%, polyquaternium -430.45%, PPG-3 Octyl Ethers
0.25%th, citric acid 0.35%, piroctone olamine salt 0.18%, Polyquaternium-10 0.22%, microcrystalline cellulose
0.08%th, curcumin 0.05%, Phenoxyethanol 0.4%, preservative 0.14%, essence 0.3% and water 28.68%.
The preparation method of the true ginger shampoo of described amino acid, comprises the following steps：
S1, race removed the peel, is cleaned, being put into the mass fraction separately taken to be soaked 35 minutes in 0.3% antiseptic solution,
Then it is washed with deionized water only, is put into dozen Jiang Jizhong and is crushed to pasty state, add water mixing, is warming up to 100 DEG C, constant temperature 80 minutes is obtained
To race water solution A；
S2, add water to emulsification pot in, open homogeneous, add microcrystalline cellulose, homogeneous 10 minutes, after being completely dispersed plus
Enter Polyquaternium-10, homogeneous 1.5 minutes then heats to 80 DEG C, adds coconut palm oleoyl monoethanolamine, methyl cocoyl ox sulphur
Sour sodium, is incubated 35 minutes, obtains emulsion B；
S3, emulsion B is cooled to 50 DEG C, sequentially adds sodium lauroyl sarcosine, cocoamido sodium propionate, lauroyl
Both sexes guanidine-acetic acid sodium, piroctone olamine salt, stir to substantially uniformity, are then cooled to 43 DEG C, sequentially add PPG-3 octyl groups
Ether, polyquaternium -43, ginger oil, Ginger P.E, dispersing and filtering add acrylate copolymer and water, stir to substantially uniformity,
Obtain mixed liquor C；
S4, citric acid is dissolved in water pH adjusting agent is made, the pH value for the mixed liquor C that regulating step S3 is obtained is 6.5, then
Cocoamidopropyl betaine, curcumin, essence, preservative, Phenoxyethanol, race water solution A are sequentially added, is stirred to complete
Uniformly, room temperature is down to, is produced.
A kind of true ginger shampoo of the amino acid of embodiment 3
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：
Race 22%, sodium lauroyl sarcosine 17%, Cocoamidopropyl betaine 10%, LAA
6%th, sodium methyl cocoyl taurate 2.5%, cocoamido sodium propionate 2.2%, acrylate copolymer 1.8%, cocounut oil
Acyl MEA 1.6%, ginger oil 0.4%, Ginger P.E 0.6%, polyquaternium -430.35%, PPG-3 Octyl Ethers
0.35%th, citric acid 0.25%, piroctone olamine salt 0.22%, Polyquaternium-10 0.18%, microcrystalline cellulose
0.12%th, curcumin 0.03%, Phenoxyethanol 0.6%, preservative 0.1%, essence 0.35% and water 33.35%.
The preparation method of the true ginger shampoo of described amino acid, comprises the following steps：
S1, race removed the peel, is cleaned, being put into the mass fraction separately taken to be soaked 45 minutes in 0.3% antiseptic solution,
Then it is washed with deionized water only, is put into dozen Jiang Jizhong and is crushed to pasty state, add water mixing, is warming up to 95 DEG C, constant temperature 100 minutes is obtained
To race water solution A；
S2, add water to emulsification pot in, open homogeneous, add microcrystalline cellulose, homogeneous 14 minutes, after being completely dispersed plus
Enter Polyquaternium-10, homogeneous 0.5 minute then heats to 90 DEG C, adds coconut palm oleoyl monoethanolamine, methyl cocoyl ox sulphur
Sour sodium, is incubated 25 minutes, obtains emulsion B；
S3, emulsion B is cooled to 60 DEG C, sequentially adds sodium lauroyl sarcosine, cocoamido sodium propionate, lauroyl
Both sexes guanidine-acetic acid sodium, piroctone olamine salt, stir to substantially uniformity, are then cooled to 48 DEG C, sequentially add PPG-3 octyl groups
Ether, polyquaternium -43, ginger oil, Ginger P.E, dispersing and filtering add acrylate copolymer and water, stir to substantially uniformity,
Obtain mixed liquor C；
S4, citric acid is dissolved in water pH adjusting agent is made, the pH value for the mixed liquor C that regulating step S3 is obtained is 7.5, then
Cocoamidopropyl betaine, curcumin, essence, preservative, Phenoxyethanol, race water solution A are sequentially added, is stirred to complete
Uniformly, room temperature is down to, is produced.
A kind of true ginger shampoo of the amino acid of comparative example 1
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：Race 25%, lauroyl flesh ammonia
Sour sodium 15%, Cocoamidopropyl betaine 12%, LAA 5%, sodium methyl cocoyl taurate
4.5%th, cocoamido sodium propionate 2%, acrylate copolymer 2%, ginger oil 0.5%, Ginger P.E 0.5%, polyquaternary amine
Salt -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid 0.3%, piroctone olamine salt 0.2%, polyquaternium -
100.2%th, microcrystalline cellulose 0.1%, curcumin 0.04%, Phenoxyethanol 0.5%, preservative 0.12%, the and of essence 0.32%
Water 31.02%.
The preparation method of the true ginger shampoo of described amino acid is similar to Example 1.
Difference with embodiment 1 is, without coconut palm oleoyl monoethanolamine, to increase the content of sodium methyl cocoyl taurate.
A kind of true ginger shampoo of the amino acid of comparative example 2
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：Race 25%, lauroyl flesh ammonia
Sour sodium 15%, Cocoamidopropyl betaine 12%, LAA 5%, sodium methyl cocoyl taurate
3%th, cocoamido sodium propionate 2%, acrylate copolymer 2%, coconut palm oleoyl monoethanolamine 1.5%, ginger oil 0.5%, ginger
Extract 0.5%, PPG-3 Octyl Ethers 0.3%, citric acid 0.3%, piroctone olamine salt 0.2%, polyquaternium-
100.6%th, microcrystalline cellulose 0.1%, curcumin 0.04%, Phenoxyethanol 0.5%, preservative 0.12%, the and of essence 0.32%
Water 31.02%.
The preparation method of the true ginger shampoo of described amino acid is similar to Example 1.
Difference with embodiment 1 is, without polyquaternium -43, to increase the content of Polyquaternium-10.
A kind of true ginger shampoo of the amino acid of comparative example 3
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：Race 25%, lauroyl flesh ammonia
Sour sodium 15%, Cocoamidopropyl betaine 12%, LAA 5%, sodium methyl cocoyl taurate
3%th, cocoamido sodium propionate 2%, acrylate copolymer 2.1%, coconut palm oleoyl monoethanolamine 1.5%, ginger oil 0.5%, life
Ginger extract 0.5%, polyquaternium -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid 0.3%, piroctone olamine salt
0.2%th, Polyquaternium-10 0.2%, curcumin 0.04%, Phenoxyethanol 0.5%, preservative 0.12%, essence 0.32% and water
31.02%.
The preparation method of the true ginger shampoo of described amino acid is similar to Example 1.
Difference with embodiment 1 is, without microcrystalline cellulose, to increase the content of acrylate copolymer.
A kind of true ginger shampoo of the amino acid of comparative example 4
The true ginger shampoo of described amino acid is made up of the composition of following mass fraction：Race 25%, lauroyl flesh ammonia
Sour sodium 15%, Cocoamidopropyl betaine 12%, LAA 5%, sodium methyl cocoyl taurate
3%th, cocoamido sodium propionate 2%, acrylate copolymer 2%, coconut palm oleoyl monoethanolamine 1.5%, ginger oil 0.5%, ginger
Extract 0.54%, polyquaternium -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid 0.3%, piroctone olamine salt
0.2%th, Polyquaternium-10 0.2%, microcrystalline cellulose 0.1%, Phenoxyethanol 0.5%, preservative 0.12%, essence 0.32%
With water 31.02%.
The preparation method of the true ginger shampoo of described amino acid is similar to Example 1.
Difference with embodiment 1 is, without curcumin, to increase the content of Ginger P.E.
Test example 1, irritation test/toxicology test
Tested material：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 1-4 is prepared；
Animal model：Choose healthy rabbits 70,200 ± 20g of body weight, male and female half and half；
Test method：24h before experiment, cuts off a hair for rabbit back backbone both sides, does not damage epidermis, and it is 3cm to remove gross area
×3cm.Take each 0.5g of shampoo to be added on 2.5cm × 2.5cm 4 layers of gauze, be affixed on side skin, covered with one layer of oilpaper
Afterwards, with immobilization with adhesive tape, opposite side is blank control.Shampoo is removed after closing 4h, and residual tested material is washed away with clear water, is removed
After tested material 1,24,48h observation recipient site local skin reactions, press《Cosmetics health specification》(version in 2007) skin is pierced
Swash property/corrosion test and carry out dermoreaction scoring, the average value integrated with animal subject carries out overall merit, and observes except thorn
Swash other side effects effect beyond property.
Result of the test：Each observing time point top average ＜ 0.5 in experiment, belongs to nonirritant.That is, skin irritation
Result of the test is：It is nonirritant.Acute ocular irritation test result is：It is nonirritant.Therefore the true ginger of amino acid that the present invention is provided
Shampoo is gentleer to skin, nontoxic non-stimulated.
Test example 2, carding property test
Subjects：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 2-3 is prepared；
Test method：Using a shampoo (3ml), continuous to use 10 days, test last time uses back within every two days
The cardability of hair, including wet method state (being rinsed after being cleaned one minute using shampoo with clear water to non-foam) and dry hair state (hair washing
Dry naturally afterwards) carding property.Tester is：Dia-Stron combs instrument；Computational methods are：(unused combing resistance-
Resistance is combed after use)/combing resistance × 100% is not used.
Specific data are as shown in table 1：
The shampoo of table 1 combs drag reduction percentage
| Comb drag reduction percentage | Wet hair state | Dry hair state |
| Embodiment 1 | 82% | 69% |
| Embodiment 2 | 72% | 60% |
| Embodiment 3 | 70% | 58% |
| Comparative example 2 | 49% | 37% |
| Comparative example 3 | 45% | 39% |
From table 1 it follows that after using shampoo made from 1-3 of the embodiment of the present invention five times, Hair setting performance becomes
It is good, comb resistance and diminish, illustrate that hair is more compliant using after shampoo of the present invention.
Test example 3, foam height and stability
Subjects：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 1-3 is prepared；
Determined according to GB13173-2008, method is as follows：Example 1, embodiment 2, embodiment 3, comparative example 1 and contrast
Each 2.5g of shampoo prepared by example 2, is dissolved with 150ml hard water, is transferred in 1000mL volumetric flasks, and be diluted to quarter respectively
Degree, shake up, then by solution be placed in (40 ± 0.5) DEG C water bath with thermostatic control be aged, total time 30min since the molten sample that adds water, then
Foam height is determined with Roche foam meter, 2 are shown in Table.
The foam parameters of table 2
As shown in Table 2, the initial foam height of the true ginger shampoo of amino acid prepared by the present invention is 17.1-19.3cm, and
Comparative example 1-3 foaming characteristic is poorer than the effect of the amino acid shampoos prepared of embodiment of the present invention 1-3, illustrates that the present invention provides
The mutual compatibility enhancing foaming characteristic of amino acid surfactant, and the effect of embodiment 1 is preferably, and experiment also measured were foam after 5min
Height, it is found that 1-3 of embodiment of the present invention hair washing water bubble is more stablized.
Test example 4, Anti-hair loss effect
Subjects：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 1-4 are prepared；
Subject：Female, 25 ± 2 years old, 70 people were equally divided into 7 groups, hair lengths are 30 ± 3cm.
Application method：Using 3ml shampoos cleaning hair and massaging scalp 2min, (shampoo is applied to root of hair from hair tail, covers
Firmly hair), then clean to non-foam.
Computational methods：Before use, continuously the statistics hair loss amount of 5 days (counts alopecia amount during each wash my hair, washed within every 2 days
Hair), calculate daily average hair loss amount.After 60 days, the continuous counter alopecia amount of 5 days counts daily be averaged
Hair loss amount, is sub-health state more than 40.As a result it is as shown in table 3.
The Anti-hair loss effect of table 3
It can also be seen that being returned to normally using alopecia level after shampoo made from 1-3 of the embodiment of the present invention from table 3
Level, and the anti-alopecia-stopping effect of shampoo made from comparative example 1-4 is poor, shampoo effect is preferably, right wherein made from embodiment 1
The effect of ratio 4 is worst.
The hair toughness test of test example 5
Subjects：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 1-4 is prepared；
Subject：Female, 25 ± 2 years old, 70,7 groups are divided into, hair lengths are 30 ± 3cm.
Test method：The continuous shampoo prepared using embodiment 1-3 and comparative example 1-4 60 days, observation uses shape
Condition, and the strength (3 hair midpoints exert a force, and calculate power when breaking) carried using hair before and after 60 days is tested, every group takes
Average value, concrete outcome is as shown in table 4.
The shampoo behaviour in service of table 4 and carrying strength
As can be seen from Table 4, improved using hair toughness after shampoo made from 1-3 of the embodiment of the present invention, illustrate this
The shampoo of disclosure of the invention can improve hair quality.
Test example 6, detergency ability
Subjects：The true ginger shampoo of amino acid that embodiment 1-3 and comparative example 1-4 is prepared；
Test method：Greasy dirt is made in 50g lanolin and 1g charcoal powders (200 mesh) stirring；Then same human hair is used
Clean 10 minutes, rinsed well after taking-up using clear water, hair-dryer is blown to constant weight in 20% sodium lauryl sulfate solution vibrating machine
(W) 7 groups, are equally divided into, then greasy dirt is applied on topknot (per beam 0.1g greasy dirts), it is small that room temperature air-dries placement 48 by every group of 6 beams
When, then weigh (W1), is dissolved in using 0.5g shampoos in the water that 100ml hardness is 250mg/L, is put into topknot, vibrating machine is clear
Wash 30 minutes, take out, non-foam is washed till with clear water, hair-dryer is blown to constant weight, weighs (W2), calculates decontamination rate.Decontamination rate=
(W1-W2)/(W1-W) × 100%, it is specific as shown in table 5；
The shampoo decontamination rate of table 5
As can be seen from Table 5, it is strong using shampoo dirt-removing power made from 1-3 of the embodiment of the present invention, wherein to implement
The best results of example 1, decontamination rate has reached more than 90%.
Claims (5)
1. a kind of true ginger shampoo of amino acid, it is characterised in that be mainly made up of the composition of following mass fraction：
Race 22-28%, sodium lauroyl sarcosine 13-17%, Cocoamidopropyl betaine 10-14%, lauroyl both sexes base
Sodium acetate 4-6%, sodium methyl cocoyl taurate 2.5-3.5%, cocoamido sodium propionate 1.8-2.2%, acrylate
It is copolymer 1 .8-2.2%, coconut palm oleoyl monoethanolamine 1.4-1.6%, ginger oil 0.4-0.6%, Ginger P.E 0.4-0.6%, poly-
Quaternary ammonium salt -430.35-0.45%, PPG-3 Octyl Ethers 0.25-0.35%, citric acid 0.25-0.35%, piroctone olamine
Salt 0.18-0.22%, Polyquaternium-10 0.18-0.22%, microcrystalline cellulose 0.08-0.12%, curcumin 0.03-0.05%,
Phenoxyethanol 0.4-0.6%, preservative 0.1-0.14%, essence 0.3-0.35% and water 20-50%.
2. the true ginger shampoo of amino acid according to claim 1, it is characterised in that by following mass fraction into packet
Into：
Race 25%, sodium lauroyl sarcosine 15%, Cocoamidopropyl betaine 12%, LAA 5%,
Sodium methyl cocoyl taurate 3%, cocoamido sodium propionate 2%, acrylate copolymer 2%, coconut palm oleoyl monoethanolamine
1.5%th, ginger oil 0.5%, Ginger P.E 0.5%, polyquaternium -430.4%, PPG-3 Octyl Ethers 0.3%, citric acid
0.3%th, piroctone olamine salt 0.2%, Polyquaternium-10 0.2%, microcrystalline cellulose 0.1%, curcumin 0.04%, benzene
Oxyethanol 0.5%, preservative 0.12%, essence 0.32% and water 31.02%.
3. the preparation method of the true ginger shampoo of amino acid according to claim 1 or 2, it is characterised in that including following step
Suddenly：
S1, race removed the peel, is cleaned, being put into the mass fraction separately taken to be soaked 35-45 minutes in 0.3% antiseptic solution,
Then it is washed with deionized water only, is put into dozen Jiang Jizhong and is crushed to pasty state, add water mixing, is warming up to 95-100 DEG C, constant temperature 80-100
Minute, obtain race water solution A；
S2, add water to emulsification pot in, open homogeneous, add microcrystalline cellulose, homogeneous 10-14 minute, after being completely dispersed add
Enter Polyquaternium-10, homogeneous 0.5-1.5 minutes then heats to 80-90 DEG C, adds coconut palm oleoyl monoethanolamine, methyl cocoyl acyl
Base sodium taurocholate, is incubated 25-35 minutes, obtains emulsion B；
S3, emulsion B is cooled to 50-60 DEG C, sequentially adds sodium lauroyl sarcosine, cocoamido sodium propionate, lauroyl
Both sexes guanidine-acetic acid sodium, piroctone olamine salt, stir to substantially uniformity, are then cooled to 43-48 DEG C, sequentially add PPG-3
Octyl Ether, polyquaternium -43, ginger oil, Ginger P.E, dispersing and filtering add acrylate copolymer and water, stir to complete
Uniformly, mixed liquor C is obtained；
S4, citric acid is dissolved in water pH adjusting agent is made, then the pH value for the mixed liquor C that regulating step S3 is obtained sequentially adds
Cocoamidopropyl betaine, curcumin, essence, preservative, Phenoxyethanol, race water solution A, stirring to substantially uniformity, drop
To room temperature, produce.
4. the preparation method of the true ginger shampoo of amino acid according to claim 3, it is characterised in that constant temperature 90 in step S1
Minute.
5. the preparation method of the true ginger shampoo of amino acid according to claim 3, it is characterised in that described in step S4
The pH value for the mixed liquor C that regulating step S3 is obtained is 6.5-7.5.
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096173A (en) * | 2017-12-28 | 2018-06-01 | 广州蜜妆生物科技有限公司 | Mild amino acid shampoo of a kind of green and preparation method thereof |
| CN109998964A (en) * | 2019-05-24 | 2019-07-12 | 戴金花 | Man's anticreep shampoo and its production technology |
| CN110507555A (en) * | 2019-09-18 | 2019-11-29 | 贵州沐木皙颜生物科技有限公司 | A kind of anhydrous amino acid ginger tea shampoo and its processing method |
| CN111714429A (en) * | 2020-07-25 | 2020-09-29 | 广东雅丽洁精细化工有限公司 | Anti-hair loss shampoo |
| CN112006944A (en) * | 2020-09-21 | 2020-12-01 | 陆梦羽 | Formula and preparation method of active anti-hair loss and hair growth shampoo |
| CN112245316A (en) * | 2020-09-05 | 2021-01-22 | 广东领秀首美生物科技有限公司 | Amino acid shampoo composition, amino acid shampoo and preparation method thereof |
| CN112472630A (en) * | 2020-12-18 | 2021-03-12 | 上海家化联合股份有限公司 | Self-thickening composition of amino acid surfactants |
| CN112516065A (en) * | 2020-12-02 | 2021-03-19 | 孙世伟 | Preparation method of amino acid shampoo |
| CN112516047A (en) * | 2020-12-15 | 2021-03-19 | 彭氏(惠州)实业发展有限公司 | Oil-control hair washing gel and preparation method thereof |
| CN113599335A (en) * | 2021-07-21 | 2021-11-05 | 广州环亚化妆品科技有限公司 | Bubble mousse type shampoo and preparation method thereof |
| CN115518018A (en) * | 2022-11-11 | 2022-12-27 | 程莹 | Amino acid shampoo and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096173A (en) * | 2017-12-28 | 2018-06-01 | 广州蜜妆生物科技有限公司 | Mild amino acid shampoo of a kind of green and preparation method thereof |
| CN109998964A (en) * | 2019-05-24 | 2019-07-12 | 戴金花 | Man's anticreep shampoo and its production technology |
| CN110507555A (en) * | 2019-09-18 | 2019-11-29 | 贵州沐木皙颜生物科技有限公司 | A kind of anhydrous amino acid ginger tea shampoo and its processing method |
| CN111714429B (en) * | 2020-07-25 | 2022-05-20 | 广东雅丽洁精细化工有限公司 | Anti-hair loss shampoo |
| CN111714429A (en) * | 2020-07-25 | 2020-09-29 | 广东雅丽洁精细化工有限公司 | Anti-hair loss shampoo |
| CN112245316A (en) * | 2020-09-05 | 2021-01-22 | 广东领秀首美生物科技有限公司 | Amino acid shampoo composition, amino acid shampoo and preparation method thereof |
| CN112006944A (en) * | 2020-09-21 | 2020-12-01 | 陆梦羽 | Formula and preparation method of active anti-hair loss and hair growth shampoo |
| CN112516065A (en) * | 2020-12-02 | 2021-03-19 | 孙世伟 | Preparation method of amino acid shampoo |
| CN112516047A (en) * | 2020-12-15 | 2021-03-19 | 彭氏(惠州)实业发展有限公司 | Oil-control hair washing gel and preparation method thereof |
| CN112472630A (en) * | 2020-12-18 | 2021-03-12 | 上海家化联合股份有限公司 | Self-thickening composition of amino acid surfactants |
| CN112472630B (en) * | 2020-12-18 | 2023-10-17 | 上海家化联合股份有限公司 | Self-thickening compositions of amino acid surfactants |
| CN113599335A (en) * | 2021-07-21 | 2021-11-05 | 广州环亚化妆品科技有限公司 | Bubble mousse type shampoo and preparation method thereof |
| CN115518018A (en) * | 2022-11-11 | 2022-12-27 | 程莹 | Amino acid shampoo and preparation method thereof |
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Application publication date: 20171010 |