CN107189566A - A kind of polystyrene coating and preparation method thereof - Google Patents

A kind of polystyrene coating and preparation method thereof Download PDF

Info

Publication number
CN107189566A
CN107189566A CN201710457788.2A CN201710457788A CN107189566A CN 107189566 A CN107189566 A CN 107189566A CN 201710457788 A CN201710457788 A CN 201710457788A CN 107189566 A CN107189566 A CN 107189566A
Authority
CN
China
Prior art keywords
parts
polystyrene
component
polystyrene coating
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710457788.2A
Other languages
Chinese (zh)
Inventor
傅飞艳
胡建锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Saiwei Photoelectric Technology Co Ltd
Original Assignee
Foshan Saiwei Photoelectric Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Saiwei Photoelectric Technology Co Ltd filed Critical Foshan Saiwei Photoelectric Technology Co Ltd
Priority to CN201710457788.2A priority Critical patent/CN107189566A/en
Publication of CN107189566A publication Critical patent/CN107189566A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

It is 1 this application discloses the ratio of a kind of polystyrene coating and preparation method thereof, including component A and component B, component A and component B:2.5;Wherein component A includes by weight:200 600 parts of aliphatic alcohol polyoxyvinethene phosphate sylvite, 60 110 parts of triethanolamine, 8 25 parts of urea, 20 70 parts of acetic acid, 10 40 parts of rare-earth salts;Component B includes by weight:150 450 parts of castor oil, 20 70 parts of methyl acrylate, 10 40 parts of dodecyl acrylate, 5 25 parts of maleic rosin, 30 65 parts of p-methyl benzenesulfonic acid, 20 70 parts of polyoxyethylene alkyl amine, 30 75 parts of phenol sulfonic acid naphthalene sulfonic acid-formaldehyde condensation product sodium salt.Thus, after use, and of short duration stirring mixing is only needed to, it becomes possible to agricultural chemicals is quickly dissolved and be dispersed in water, and can be not in the phenomenon that is divided into or flocculates with long-time storage after agricultural chemicals dissolving.

Description

A kind of polystyrene coating and preparation method thereof
Technical field
The invention belongs to paint field, more particularly to a kind of polystyrene coating and preparation method thereof.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.
Coating is widely used in modern industry and construction industry, but coating surface has coarse particle, and future regards Attractive in appearance or architectural reason in feel, people need to clean the surface of coating, and the complexity of cleaning, high cost-effectivenes one It is directly great limitation effect, although some coating can reach surface smoothness, is susceptible to sunlight, rainwater influence, It can not keep for a long time.
The content of the invention
The purpose of the present invention is to be to provide a kind of polystyrene coating and preparation method thereof, solves above-mentioned prior art One or more in problem.
The polystyrene coating of the present invention, includes by weight:340-385 parts of polystyrene, 52-96 parts of titanium dioxide, 120-150 parts of lithopone, 85-104 parts of talcum powder, 46-76 parts of xylene solution, 163-184 parts of pentaerythrite, rosin solution 220-253 parts, 12-37 parts of acrylic acid, 82-104 parts of acetone, 150-175 parts of plasticizer, 93-110 parts of emulsifying agent, fire retardant 45- 85 parts, 22-43 parts of colouring agent.
In one embodiment:The concentration of the xylene solution is 20%.
In one embodiment:The pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 10-20um fineness, input material-compound tank and adds titanium white In powder, lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 60-80 DEG C, stirred while adding pentaerythrite and pine Fragrant solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to 120 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Substantially identical with polyvinyl acetate emulsion on the polystyrene coating property of the present invention, temperature in use is widened, tool There is frost resistance, overcoming polyvinyl acetate emulsion, performance changes at low temperature, reduce the cushion of cohesion, widened timber Constructed during processing storage condition.Its preparation technology is simple, using discarded polystyrene plastics as raw material, meets environmental protection and energy saving, follows The theory that ring is utilized.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1
Polystyrene coating, includes by weight:365 parts of polystyrene, 96 parts of titanium dioxide, 124 parts of lithopone, talcum 97 parts of powder, 55 parts of xylene solution, 174 parts of pentaerythrite, 241 parts of rosin solution, 27 parts of acrylic acid, 93 parts of acetone, plasticizer 167 parts, 104 parts of emulsifying agent, 80 parts of fire retardant, 28 parts of colouring agent.
Wherein, the concentration of the xylene solution is 20%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 15um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 74 DEG C, stirred while adding pentaerythrite and rosin Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to 120 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 2
Polystyrene coating, includes by weight:344 parts of polystyrene, 67 parts of titanium dioxide, 134 parts of lithopone, talcum 93 parts of powder, 54 parts of xylene solution, 175 parts of pentaerythrite, 247 parts of rosin solution, 34 parts of acrylic acid, 96 parts of acetone, plasticizer 167 parts, 100 parts of emulsifying agent, 73 parts of fire retardant, 34 parts of colouring agent.
Wherein, the concentration of the xylene solution is 17.5%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 20um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 75 DEG C, stirred while adding pentaerythrite and rosin Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 2h, is warming up to 125 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 3
Polystyrene coating, includes by weight:348 parts of polystyrene, 94 parts of titanium dioxide, 122 parts of lithopone, talcum 93 parts of powder, 57 parts of xylene solution, 172 parts of pentaerythrite, 245 parts of rosin solution, 15 parts of acrylic acid, 83 parts of acetone, plasticizer 162 parts, 97 parts of emulsifying agent, 80 parts of fire retardant, 27 parts of colouring agent.
Wherein, the concentration of the xylene solution is 21%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 18um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 77 DEG C, stirred while adding pentaerythrite and rosin Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1h, is warming up to 115 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 4
Polystyrene coating, includes by weight:363 parts of polystyrene, 93 parts of titanium dioxide, 134 parts of lithopone, talcum 97 parts of powder, 57 parts of xylene solution, 170 parts of pentaerythrite, 240 parts of rosin solution, 30 parts of acrylic acid, 90 parts of acetone, plasticizer 163 parts, 107 parts of emulsifying agent, 75 parts of fire retardant, 35 parts of colouring agent.
Wherein, the concentration of the xylene solution is 19%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 20um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 72 DEG C, stirred while adding pentaerythrite and rosin Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1h, is warming up to 140 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 5
Polystyrene coating, includes by weight:380 parts of polystyrene, 85 parts of titanium dioxide, 124 parts of lithopone, talcum 94 parts of powder, 55 parts of xylene solution, 173 parts of pentaerythrite, 248 parts of rosin solution, 23 parts of acrylic acid, 95 parts of acetone, plasticizer 163 parts, 104 parts of emulsifying agent, 47 parts of fire retardant, 40 parts of colouring agent.
Wherein, the concentration of the xylene solution is 22.5%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps:
Step one:Polystyrene is dispersed to using sand mill in 10um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 66 DEG C, stirred while adding pentaerythrite and rosin Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 2h, is warming up to 110 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
The product of above-described embodiment is as follows for the effect test of coating:
Wherein, inventor is drawn by substantial amounts of experiment, on polystyrene coating property of the invention substantially and poly-vinegar Sour vac emulsion is identical, and temperature in use is widened, and with frost resistance, overcoming polyvinyl acetate emulsion, performance changes at low temperature Become, reduce the cushion of cohesion, storage condition of being constructed when having widened timber processing.Its preparation technology is simple, with discarded polyphenyl Vinyl plastics are raw material, the theory for meet environmental protection and energy saving, recycling.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art, Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this Within the protection domain of invention.

Claims (4)

1. a kind of polystyrene coating, it is characterised in that:Include by weight:340-385 parts of polystyrene, titanium dioxide 52- 96 parts, 120-150 parts of lithopone, 85-104 parts of talcum powder, 46-76 parts of xylene solution, 163-184 parts of pentaerythrite, rosin It is 220-253 parts of solution, 12-37 parts of acrylic acid, 82-104 parts of acetone, 150-175 parts of plasticizer, 93-110 parts of emulsifying agent, fire-retardant 45-85 parts of agent, 22-43 parts of colouring agent.
2. a kind of polystyrene coating according to claim 1, it is characterised in that:The concentration of the xylene solution is 20%.
3. a kind of polystyrene coating according to claim 1, it is characterised in that:The pigment is iron oxide red, zinc Barium white, lead chromate yellow or barba hispanica.
4. the preparation method of the polystyrene coating according to claim any one of 1-3, it is characterised in that:Including following Step:
Step one:Polystyrene is dispersed to using sand mill in 10-20um fineness, input material-compound tank and adds titanium dioxide, In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby;
Step 2:Intermediate product made from upper step is heated to 60-80 DEG C, stirred while adding pentaerythrite and rosin is molten Liquid, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to 120 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
CN201710457788.2A 2017-06-16 2017-06-16 A kind of polystyrene coating and preparation method thereof Withdrawn CN107189566A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710457788.2A CN107189566A (en) 2017-06-16 2017-06-16 A kind of polystyrene coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710457788.2A CN107189566A (en) 2017-06-16 2017-06-16 A kind of polystyrene coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107189566A true CN107189566A (en) 2017-09-22

Family

ID=59879752

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710457788.2A Withdrawn CN107189566A (en) 2017-06-16 2017-06-16 A kind of polystyrene coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107189566A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050394A (en) * 1990-10-10 1991-04-03 邹晶明 Polystyrene varnish and manufacture method thereof
CN1233636A (en) * 1998-04-27 1999-11-03 陈民英 Multi-purpose color water-proof coating made of poly styrene wastes
CN103146267A (en) * 2013-03-15 2013-06-12 成钢 Waste polystyrene-prepared multifunctional dope capable of releasing microelement anions
CN103305067A (en) * 2013-06-26 2013-09-18 关锦池 Multifunctional coating capable of releasing trace element anions
CN103305069A (en) * 2013-07-03 2013-09-18 内蒙古大学 Method for preparing coating from waste polystyrene foam
CN105713515A (en) * 2015-11-09 2016-06-29 南通蛇类治疗研究所 Process for producing functional paint from waste rubber and plastics

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050394A (en) * 1990-10-10 1991-04-03 邹晶明 Polystyrene varnish and manufacture method thereof
CN1233636A (en) * 1998-04-27 1999-11-03 陈民英 Multi-purpose color water-proof coating made of poly styrene wastes
CN103146267A (en) * 2013-03-15 2013-06-12 成钢 Waste polystyrene-prepared multifunctional dope capable of releasing microelement anions
CN103305067A (en) * 2013-06-26 2013-09-18 关锦池 Multifunctional coating capable of releasing trace element anions
CN103305069A (en) * 2013-07-03 2013-09-18 内蒙古大学 Method for preparing coating from waste polystyrene foam
CN105713515A (en) * 2015-11-09 2016-06-29 南通蛇类治疗研究所 Process for producing functional paint from waste rubber and plastics

Similar Documents

Publication Publication Date Title
US7851545B2 (en) Paint composition
CN103627272B (en) Liquid rock particles of artificial granite sand textured coating
CN104609772A (en) Really stone paint and preparation method thereof
CN103881516A (en) One coat paint prepared by organic and inorganic compound emulsion and preparation method thereof
CN104592797A (en) Formula of quick-drying water-proof art painting paint
CN103881504A (en) Colored self-repairing heat reflecting coating and coating process thereof
CN105670454A (en) Ultra-low-temperature curing epoxy coating formula and preparation method
CN107162486A (en) A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof
CN103482905B (en) Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings
CN106867406A (en) The preparation method of the new environment-friendly type coating based on nano material
CN104530868A (en) Environment-friendly water-based glass paint and preparation method thereof
CN106433353A (en) Water-based half-open clear primer
CN107189566A (en) A kind of polystyrene coating and preparation method thereof
CN104530834A (en) High-brightness water-based color paste
CN102391753A (en) Water emulsion polymer camouflage color decorative coating and preparation method and use thereof
CN103305121A (en) Outer wall coating
CN106752440B (en) Architectural concrete protective agent and preparation method thereof
CN105670383B (en) A kind of production method of environment-friendly type aqueous high temperature resistant ink
CN106433355B (en) high temperature resistant damping paint
CN108085997A (en) A kind of weather-proof antifouling wallpaper and preparation method thereof
CN106752544A (en) A kind of environmental protection wall surface coating for preventing light pollution
CN102796452A (en) Antifouling self-cleaning nano functional paint and preparation method thereof
CN106147464A (en) A kind of water soluble green environmental wood door paint
CN107987651A (en) A kind of anticorrosive water paint synthetic method
CN107057499A (en) A kind of environmental-friendly aqueous coating

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20170922