CN107189566A - A kind of polystyrene coating and preparation method thereof - Google Patents
A kind of polystyrene coating and preparation method thereof Download PDFInfo
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- CN107189566A CN107189566A CN201710457788.2A CN201710457788A CN107189566A CN 107189566 A CN107189566 A CN 107189566A CN 201710457788 A CN201710457788 A CN 201710457788A CN 107189566 A CN107189566 A CN 107189566A
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- polystyrene
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- polystyrene coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
It is 1 this application discloses the ratio of a kind of polystyrene coating and preparation method thereof, including component A and component B, component A and component B:2.5；Wherein component A includes by weight:200 600 parts of aliphatic alcohol polyoxyvinethene phosphate sylvite, 60 110 parts of triethanolamine, 8 25 parts of urea, 20 70 parts of acetic acid, 10 40 parts of rare-earth salts；Component B includes by weight：150 450 parts of castor oil, 20 70 parts of methyl acrylate, 10 40 parts of dodecyl acrylate, 5 25 parts of maleic rosin, 30 65 parts of p-methyl benzenesulfonic acid, 20 70 parts of polyoxyethylene alkyl amine, 30 75 parts of phenol sulfonic acid naphthalene sulfonic acid-formaldehyde condensation product sodium salt.Thus, after use, and of short duration stirring mixing is only needed to, it becomes possible to agricultural chemicals is quickly dissolved and be dispersed in water, and can be not in the phenomenon that is divided into or flocculates with long-time storage after agricultural chemicals dissolving.
Description
Technical field
The invention belongs to paint field, more particularly to a kind of polystyrene coating and preparation method thereof.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and
The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face
Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.
Coating is widely used in modern industry and construction industry, but coating surface has coarse particle, and future regards
Attractive in appearance or architectural reason in feel, people need to clean the surface of coating, and the complexity of cleaning, high cost-effectivenes one
It is directly great limitation effect, although some coating can reach surface smoothness, is susceptible to sunlight, rainwater influence,
It can not keep for a long time.
The content of the invention
The purpose of the present invention is to be to provide a kind of polystyrene coating and preparation method thereof, solves above-mentioned prior art
One or more in problem.
The polystyrene coating of the present invention, includes by weight:340-385 parts of polystyrene, 52-96 parts of titanium dioxide,
120-150 parts of lithopone, 85-104 parts of talcum powder, 46-76 parts of xylene solution, 163-184 parts of pentaerythrite, rosin solution
220-253 parts, 12-37 parts of acrylic acid, 82-104 parts of acetone, 150-175 parts of plasticizer, 93-110 parts of emulsifying agent, fire retardant 45-
85 parts, 22-43 parts of colouring agent.
In one embodiment：The concentration of the xylene solution is 20%.
In one embodiment：The pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 10-20um fineness, input material-compound tank and adds titanium white
In powder, lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 60-80 DEG C, stirred while adding pentaerythrite and pine
Fragrant solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to
120 DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Substantially identical with polyvinyl acetate emulsion on the polystyrene coating property of the present invention, temperature in use is widened, tool
There is frost resistance, overcoming polyvinyl acetate emulsion, performance changes at low temperature, reduce the cushion of cohesion, widened timber
Constructed during processing storage condition.Its preparation technology is simple, using discarded polystyrene plastics as raw material, meets environmental protection and energy saving, follows
The theory that ring is utilized.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1
Polystyrene coating, includes by weight:365 parts of polystyrene, 96 parts of titanium dioxide, 124 parts of lithopone, talcum
97 parts of powder, 55 parts of xylene solution, 174 parts of pentaerythrite, 241 parts of rosin solution, 27 parts of acrylic acid, 93 parts of acetone, plasticizer
167 parts, 104 parts of emulsifying agent, 80 parts of fire retardant, 28 parts of colouring agent.
Wherein, the concentration of the xylene solution is 20%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 15um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 74 DEG C, stirred while adding pentaerythrite and rosin
Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to 120
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 2
Polystyrene coating, includes by weight:344 parts of polystyrene, 67 parts of titanium dioxide, 134 parts of lithopone, talcum
93 parts of powder, 54 parts of xylene solution, 175 parts of pentaerythrite, 247 parts of rosin solution, 34 parts of acrylic acid, 96 parts of acetone, plasticizer
167 parts, 100 parts of emulsifying agent, 73 parts of fire retardant, 34 parts of colouring agent.
Wherein, the concentration of the xylene solution is 17.5%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 20um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 75 DEG C, stirred while adding pentaerythrite and rosin
Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 2h, is warming up to 125
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 3
Polystyrene coating, includes by weight:348 parts of polystyrene, 94 parts of titanium dioxide, 122 parts of lithopone, talcum
93 parts of powder, 57 parts of xylene solution, 172 parts of pentaerythrite, 245 parts of rosin solution, 15 parts of acrylic acid, 83 parts of acetone, plasticizer
162 parts, 97 parts of emulsifying agent, 80 parts of fire retardant, 27 parts of colouring agent.
Wherein, the concentration of the xylene solution is 21%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 18um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 77 DEG C, stirred while adding pentaerythrite and rosin
Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1h, is warming up to 115
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 4
Polystyrene coating, includes by weight:363 parts of polystyrene, 93 parts of titanium dioxide, 134 parts of lithopone, talcum
97 parts of powder, 57 parts of xylene solution, 170 parts of pentaerythrite, 240 parts of rosin solution, 30 parts of acrylic acid, 90 parts of acetone, plasticizer
163 parts, 107 parts of emulsifying agent, 75 parts of fire retardant, 35 parts of colouring agent.
Wherein, the concentration of the xylene solution is 19%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 20um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 72 DEG C, stirred while adding pentaerythrite and rosin
Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1h, is warming up to 140
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Embodiment 5
Polystyrene coating, includes by weight:380 parts of polystyrene, 85 parts of titanium dioxide, 124 parts of lithopone, talcum
94 parts of powder, 55 parts of xylene solution, 173 parts of pentaerythrite, 248 parts of rosin solution, 23 parts of acrylic acid, 95 parts of acetone, plasticizer
163 parts, 104 parts of emulsifying agent, 47 parts of fire retardant, 40 parts of colouring agent.
Wherein, the concentration of the xylene solution is 22.5%.
Wherein, the pigment is iron oxide red, lithopone, lead chromate yellow or barba hispanica.
The preparation method of the polystyrene coating of the present invention is as follows, comprises the following steps：
Step one：Polystyrene is dispersed to using sand mill in 10um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 66 DEG C, stirred while adding pentaerythrite and rosin
Solution, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 2h, is warming up to 110
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
The product of above-described embodiment is as follows for the effect test of coating：
Wherein, inventor is drawn by substantial amounts of experiment, on polystyrene coating property of the invention substantially and poly-vinegar
Sour vac emulsion is identical, and temperature in use is widened, and with frost resistance, overcoming polyvinyl acetate emulsion, performance changes at low temperature
Become, reduce the cushion of cohesion, storage condition of being constructed when having widened timber processing.Its preparation technology is simple, with discarded polyphenyl
Vinyl plastics are raw material, the theory for meet environmental protection and energy saving, recycling.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art,
Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this
Within the protection domain of invention.
Claims (4)
1. a kind of polystyrene coating, it is characterised in that：Include by weight:340-385 parts of polystyrene, titanium dioxide 52-
96 parts, 120-150 parts of lithopone, 85-104 parts of talcum powder, 46-76 parts of xylene solution, 163-184 parts of pentaerythrite, rosin
It is 220-253 parts of solution, 12-37 parts of acrylic acid, 82-104 parts of acetone, 150-175 parts of plasticizer, 93-110 parts of emulsifying agent, fire-retardant
45-85 parts of agent, 22-43 parts of colouring agent.
2. a kind of polystyrene coating according to claim 1, it is characterised in that：The concentration of the xylene solution is
20%.
3. a kind of polystyrene coating according to claim 1, it is characterised in that：The pigment is iron oxide red, zinc
Barium white, lead chromate yellow or barba hispanica.
4. the preparation method of the polystyrene coating according to claim any one of 1-3, it is characterised in that：Including following
Step：
Step one：Polystyrene is dispersed to using sand mill in 10-20um fineness, input material-compound tank and adds titanium dioxide,
In lithopone, talcum powder, input material-compound tank, being stirring evenly and then adding into xylene solution is used to adjust viscosity, standby；
Step 2：Intermediate product made from upper step is heated to 60-80 DEG C, stirred while adding pentaerythrite and rosin is molten
Liquid, until solution is as clear as crystal, keeping temperature is constant to be added dropwise acrylic acid and acetone, the completion of dropping in 1.5h, is warming up to 120
DEG C, addition plasticizer, emulsifying agent, fire retardant and colouring agent are eventually adding, that is, polystyrene coating is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710457788.2A CN107189566A (en) | 2017-06-16 | 2017-06-16 | A kind of polystyrene coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710457788.2A CN107189566A (en) | 2017-06-16 | 2017-06-16 | A kind of polystyrene coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189566A true CN107189566A (en) | 2017-09-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710457788.2A Withdrawn CN107189566A (en) | 2017-06-16 | 2017-06-16 | A kind of polystyrene coating and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050394A (en) * | 1990-10-10 | 1991-04-03 | 邹晶明 | Polystyrene varnish and manufacture method thereof |
| CN1233636A (en) * | 1998-04-27 | 1999-11-03 | 陈民英 | Multi-purpose color water-proof coating made of poly styrene wastes |
| CN103146267A (en) * | 2013-03-15 | 2013-06-12 | 成钢 | Waste polystyrene-prepared multifunctional dope capable of releasing microelement anions |
| CN103305067A (en) * | 2013-06-26 | 2013-09-18 | 关锦池 | Multifunctional coating capable of releasing trace element anions |
| CN103305069A (en) * | 2013-07-03 | 2013-09-18 | 内蒙古大学 | Method for preparing coating from waste polystyrene foam |
| CN105713515A (en) * | 2015-11-09 | 2016-06-29 | 南通蛇类治疗研究所 | Process for producing functional paint from waste rubber and plastics |
-
2017
- 2017-06-16 CN CN201710457788.2A patent/CN107189566A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050394A (en) * | 1990-10-10 | 1991-04-03 | 邹晶明 | Polystyrene varnish and manufacture method thereof |
| CN1233636A (en) * | 1998-04-27 | 1999-11-03 | 陈民英 | Multi-purpose color water-proof coating made of poly styrene wastes |
| CN103146267A (en) * | 2013-03-15 | 2013-06-12 | 成钢 | Waste polystyrene-prepared multifunctional dope capable of releasing microelement anions |
| CN103305067A (en) * | 2013-06-26 | 2013-09-18 | 关锦池 | Multifunctional coating capable of releasing trace element anions |
| CN103305069A (en) * | 2013-07-03 | 2013-09-18 | 内蒙古大学 | Method for preparing coating from waste polystyrene foam |
| CN105713515A (en) * | 2015-11-09 | 2016-06-29 | 南通蛇类治疗研究所 | Process for producing functional paint from waste rubber and plastics |
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Application publication date: 20170922 |