CN102796452A - Antifouling self-cleaning nano functional paint and preparation method thereof - Google Patents
Antifouling self-cleaning nano functional paint and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an antifouling self-cleaning nano functional paint and a preparation method thereof. The antifouling self-cleaning nano functional paint comprises a primer and a finish. The invention is characterized in that the primer is prepared by mixing a component A and a component B in a weight ratio of 10:(0.5-1); and the finish is prepared by mixing a component C and a component B in a weight ratio of 10:(1-2). The antifouling self-cleaning nano functional paint has the advantages of ultralow surface energy, superstrong hydrophobicity and oil stain resistance, can reduce the contact area between the water stain/dust and the base surface by more than 90%, and has very excellent automatic cleaning characteristic, so the water stain can roll off on the base surface like on a lotus leaf and can not leave any trace, thereby effectively prolonging the clean keeping time.
Description
Technical field
The present invention relates to a kind of coating and preparation technology thereof, particularly a kind of preparation method of anti-contamination self-cleaning nona functional paint.
Background technology
Utilize the two thin mechanism of the collaborative lotus leaf of nano material binary, use the nanotechnology in contemporary forward position to make the tinting pigment of minimum nano-scale, adopt special technique to handle to let that nano-sized pigments can be stablized, persistent remaining on painted in the slurry.Current technological nano dye is distributed in water or the MO usually, can't in paint, use.
The coating products that has certain automatically cleaning ability in the prior art, the one, be subject to water-borne coatings, the 2nd, the contact angle with water after the product film forming can't surpass 80 °, and therefore, self-cleaning function is very limited.
Summary of the invention
Goal of the invention of the present invention is in order to overcome the weak point of prior art; Provide self-cleaning function excellent; Surpass 120 ° with the contact angle of water, have excellent matrix adhesive force simultaneously, the resistance to weathering ability and the salt spray resistance of overlength; A kind of anti-contamination self-cleaning nona functional paint of remarkable guarantor's light, guarantor's look speciality, and a kind of effective preparation method of this coating.
Goal of the invention of the present invention realizes through following technical scheme: a kind of anti-contamination self-cleaning nona functional paint; Comprise priming paint and finish paint; Wherein comprise A component and B component in the priming paint, A component and B component mixing match are processed priming paint, and the proportioning of its weight is: A:B=10:0.5~1; Comprise C component and B component in the finish paint, C component and B component mixing match are processed finish paint, and the proportioning of its weight is: C:B=10:1~2;
Wherein each moity of A component with and the per-cent of weight be: silicone resin 1%~5%, fluororesin 40 %~50%, nano dye slurry 10~30%; Nano filling slurry 10%~30%, ultra-high molecular weight 32500 dispersion agents 0.1%~0.5%, stablizer 0.2%~0.5%; Flow agent 0.1%~0.3%, deaeration skimmer 0.1%~0.5%, deodovization agent 0.1%~0.5%; The self-cleaning promotor 0.1%~1% of GH-700, acetate butyl and YLENE mixed solvent 2%~10%;
Wherein each moity of B component with and the per-cent of weight be: isocyanic acid solidifying agent 80%~95%, promotor 5%~20%;
Wherein each moity of C component with and the per-cent of weight be:
Silicone resin 5%~10%, fluororesin 40 %~50%, nano dye slurry 5%~20%; Nano filling slurry 20%~40%, ultra-high molecular weight 32500 dispersion agents 0.1%~0.5%, stablizer 0.2%~0.5%; Flow agent 0.1%~0.3%, deaeration skimmer 0.1~0.5%, deodovization agent 0.1%~0.5%; GH-700 self-cleaning promotor 1.0%~5%, acetate butyl and YLENE mixed solvent 2%~10%.
The proportioning of wherein said acetate butyl and the YLENE mixed solvent weight between the two is: acetate butyl: YLENE=3:7.
The preparation method of anti-contamination self-cleaning nona functional paint of the present invention comprises the following steps:
1), preparation A component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller was 80~120 seconds (being coated with-4 glasss, 25 ℃).Filtering the back with 200 order spun silk cloth packs.
2), preparation B component:
Press proportional quantity with solidifying agent and promotor mixing and stirring, 200 orders filter and package.
3) A component and B component are stirred in the ratio proportioning of A:B=10:0.5~1 form priming paint.
4), preparation C component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller was 100~150 seconds (being coated with-4 glasss, 25 ℃).Filtering the back with 200 order spun silk cloth packs.
5), C component and B component are pressed C:B=10:1~2.The ratio proportioning stir and to form finish paint.
The invention has the beneficial effects as follows: the present invention uses high boiling point high flash point special solvent and adds stability protective agent, and the slurry of nano-scale that tinting pigment is ground to requirement is subsequent use.Merge adding and be difficult to form the special interpolation auxiliary agent of hi-tech that dirt is filmed, make film coated surface form the ultra-thin protective membrane that dirt is difficult to adhere to, have excellent self-cleaning function thereby further achieve paint film.Select the automatically cleaning ability after the high molecular synthetic resin with utmost point low surface energy further improves film forming for use; The present invention's success nano dye is applied in the painting; Film forming matter through selecting special low surface energy for use and add the special interpolation auxiliary agent of hi-tech, self-cleaning function increases substantially, with the contact angle of water above 120 °; The present invention simultaneously has excellent matrix adhesive force; The resistance to weathering ability and the salt spray resistance of overlength, remarkable guarantor's light, guarantor's look speciality reach more than 20 years work-ing life.
Embodiment
The present invention utilizes the two thin mechanism of the collaborative lotus leaf of nano material binary; Use the nanotechnology in contemporary forward position to make the tinting pigment of minimum nano-scale; Adopt special technique to handle to let the nano-sized pigments slurry can stablize, lastingly, thereby can make the shades of colour product; Select the automatically cleaning ability after the high molecular synthetic resin with utmost point low surface energy further improves film forming for use; Merge and to go into to be difficult to form the process means that dirt is filmed, thereby the achievement paint film has excellent self-cleaning function, powerful anti-dust and antifouling ability, the splendid sewage characteristic of becoming estranged, remarkable keeping clean for a long time do not stain performance.
Further specify patent of the present invention through specific embodiment below.
Embodiment 1:
The A set of dispense of priming paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 48.00 |
The nano dye slurry | 100~150 nanometers | 20.00 |
The Nano filling slurry | 100~150 nanometers | 25.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.30 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.30 |
The deaeration skimmer | SP-860 | 0.50 |
Deodovization agent | BIOPLUS1001 | 0.40 |
Self-cleaning promotor | GH-700 | 2.00 |
Silicone resin | W-303 | 3.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The B set of dispense of priming paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 85.00 |
Promotor | DC-2 | 15.00 |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 55.00 |
The nano dye slurry | 100~150 nanometers | 25.00 |
The Nano filling slurry | 100~150 nanometers | 10.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.40 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.40 |
The deaeration skimmer | SP-860 | 0.40 |
Deodovization agent | BIOPLUS1001 | 0.30 |
Self-cleaning promotor | GH-700 | 3.00 |
Silicone resin | W-303 | 5.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 85.00 |
Promotor | DC-2 | 15.00 |
Add up to | ? | 100.00 |
Example 2:
The A set of dispense of priming paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 50.00 |
The nano dye slurry | 100~150 nanometers | 15.00 |
The Nano filling slurry | 100~150 nanometers | 23.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.20 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.30 |
The deaeration skimmer | SP-860 | 0.50 |
Deodovization agent | BIOPLUS1001 | 0.50 |
Self-cleaning promotor | GH-700 | 4.00 |
Silicone resin | W-303 | 6.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The B set of dispense of priming paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 90.00 |
Promotor | DC-2 | 10.00 |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 60.00 |
The nano dye slurry | 100~150 nanometers | 15.00 |
The Nano filling slurry | 100~150 nanometers | 10.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.40 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.40 |
The deaeration skimmer | SP-860 | 0.40 |
Deodovization agent | BIOPLUS1001 | 0.30 |
Self-cleaning promotor | GH-700 | 3.00 |
Silicone resin | W-303 | 10.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 80.00 |
Promotor | DC-2 | 20.00 |
Add up to | ? | 100.00 |
Example 3:
The A set of dispense of priming paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 58.00 |
The nano dye slurry | 100~150 nanometers | 20.00 |
The Nano filling slurry | 100~150 nanometers | 20.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.30 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.30 |
The deaeration skimmer | SP-860 | 0.50 |
Deodovization agent | BIOPLUS1001 | 0.40 |
Self-cleaning promotor | GH-700 | 0.00 |
Silicone resin | W-303 | 0.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The B set of dispense of priming paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 95.00 |
Promotor | DC-2 | 5.00 |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 50.00 |
The nano dye slurry | 100~150 nanometers | 20.00 |
The Nano filling slurry | 100~150 nanometers | 0.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.40 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.40 |
The deaeration skimmer | SP-860 | 0.40 |
Deodovization agent | BIOPLUS1001 | 0.30 |
Self-cleaning promotor | GH-700 | 8.00 |
Silicone resin | W-303 | 20.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 75.00 |
Promotor | DC-2 | 25.00 |
Add up to | ? | 100.00 |
Example 4:
The A set of dispense of priming paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 70.00 |
The nano dye slurry | 100~150 nanometers | 20.00 |
The Nano filling slurry | 100~150 nanometers | 5.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.30 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.30 |
The deaeration skimmer | SP-860 | 0.50 |
Deodovization agent | BIOPLUS1001 | 0.40 |
Self-cleaning promotor | GH-700 | 1.00 |
Silicone resin | W-303 | 2.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The B set of dispense of priming paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 99.00 |
Promotor | DC-2 | 1.00 |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
Material name | Specification/model | Charging capacity (kg) |
Fluoro-resin | F-510 | 70.00 |
The nano dye slurry | 100~150 nanometers | 20.00 |
The Nano filling slurry | 100~150 nanometers | 0.00 |
The ultra-high molecular weight dispersion agent | 32500 | 0.40 |
Stablizer | ? | 0.50 |
Flow agent | ? | 0.40 |
The deaeration skimmer | SP-860 | 0.40 |
Deodovization agent | BIOPLUS1001 | 0.30 |
Self-cleaning promotor | GH-700 | 3.00 |
Silicone resin | W-303 | 5.00 |
Mixed solvent | ? | In right amount |
Add up to | ? | 100.00 |
The C set of dispense of finish paint is than showing:
The isocyanic acid solidifying agent | DS-61 | 80.00 |
Promotor | DC-2 | 20.00 |
Add up to | ? | 100.00 |
The foregoing description can prepare through following method: the preparation method comprises the following steps:
A), preparation A component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller was 80~120 seconds (being coated with-4 glasss, 25 ℃).Filtering the back with 200 order spun silk cloth packs.
B), preparation B component:
Press proportional quantity with solidifying agent and promotor mixing and stirring, 200 orders filter and package.
C) A component and B component are stirred in the ratio proportioning of A:B=10:0.5~1 form priming paint.
D), preparation C component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller was 100~150 seconds (being coated with-4 glasss, 25 ℃).Filtering the back with 200 order spun silk cloth packs.
E), C component and B component are pressed C:B=10:1~2.The ratio proportioning stir and to form finish paint.
Technical products quality examination result of the present invention:
? | Test item | Detected result |
1 | Paint film color and outward appearance | The conformance with standard colour table, smooth coating, color and luster is even |
?2 | Surface drying time (25 ℃) ,<=4h | 4h |
?3 | Do solid work the time (25 ℃) ,<=24h | 24h |
?4 | Completely solidified (25 ℃) ,<=7d | 7d |
?5 | Drying time (100 ℃)<=30min | 30min |
?6 | Sticking power (cross-hatching)<=1 grade | 1 grade |
?7 | Shock strength kg.cm 50 | Through |
?8 | Snappiness mm<=1 | 1 |
?9 | Water tolerance h >;=240 | Through |
?10 | The h of anti-artificial weathering the >;=3000 | Through |
?11 | Salt spray resistance h >;=2000 | Through |
?12 | Hydrophobicity contact angle >;=120 ° | Through |
Can find out that by detected result the present invention has following characteristics:
1, the excellent self-cleaning function of anti-contamination the, contact angle >=120 ° are far longer than 80 ° of levels that domestic present report coating reaches.
2, excellent physical and mechanical performance; The present invention adopts excellent fluoro-resin and organosilicon blend; Solve the application in solvent-thinned paint of nanometer face, filler, thereby obtained the very outstanding physicals of sticking power, snappiness, very agreed with anti-contamination of the present invention, durable requirement.
3, the outdoor use properties of excellence, salt spray resistance reaches more than 2000 hour, and work-ing life was up to 25~30 years.
4, safety non-toxic meets the current national relevant criterion.Be applicable to surface difficulty cleaning and the application of the matrix surface of construction again, as: the curtain wall aluminium-plastic panel of Highrise buildings is covered with paint, lacquer, colour wash, etc., high-rise permanent view reaches outer decoration for vertical face, large bridge protective coating etc.
Claims (2)
1. the anti-self-cleaning nona functional paint that stains comprises priming paint and finish paint, it is characterized in that wherein comprising A component and B component in the priming paint, and A component and B component mixing match are processed priming paint, and the proportioning of its weight is: A:B=10:0.5~1; Comprise C component and B component in the finish paint, C component and B component mixing match are processed finish paint, and the proportioning of its weight is: C:B=10:1~2;
Wherein each moity of A component with and the per-cent of weight be: silicone resin 1%~5%, fluororesin 40 %~50%, nano dye slurry 10~30%; Nano filling slurry 10%~30%, ultra-high molecular weight 32500 dispersion agents 0.1%~0.5%, stablizer 0.2%~0.5%; Flow agent 0.1%~0.3%, deaeration skimmer 0.1%~0.5%, deodovization agent 0.1%~0.5%; The self-cleaning promotor 0.1%~1% of GH-700, acetate butyl and YLENE mixed solvent 2%~10%;
Wherein each moity of B component with and the per-cent of weight be: isocyanic acid solidifying agent 80%~95%, promotor 5%~20%;
Wherein each moity of C component with and the per-cent of weight be:
Silicone resin 5%~10%, fluororesin 40 %~50%, nano dye slurry 5%~20%; Nano filling slurry 20%~40%, ultra-high molecular weight 32500 dispersion agents 0.1%~0.5%, stablizer 0.2%~0.5%; Flow agent 0.1%~0.3%, deaeration skimmer 0.1~0.5%, deodovization agent 0.1%~0.5%; The self-cleaning promotor 1.0%~5% of GH-700, acetate butyl and YLENE mixed solvent 2%~10%;
The proportioning of wherein said acetate butyl and the YLENE mixed solvent weight between the two is: acetate butyl: YLENE=3:7.
2. the preparation method of a kind of anti-contamination self-cleaning nona functional paint as claimed in claim 1 is characterized in that comprising the following steps:
1), preparation A component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller is filtered the back with 200 order spun silk cloth and is packed 80~120 seconds (being coated with-4 glasss, 25 ℃);
2), preparation B component:
Press proportional quantity with solidifying agent and promotor mixing and stirring, 200 orders filter and package;
3) A component and B component are stirred in the ratio proportioning of A:B=10:0.5~1 form priming paint;
4), preparation C component:
Press proportional quantity with organic fluorine, the nano dye slurry, Nano filling slurry, ultra-high molecular weight 32500 dispersion agents drop in the stainless steel scuffing of cylinder bore; High speed dispersion 30 minutes, stablizer, flow agent, deaeration skimmer are dropped in stirring at low speed limit in limit then; Deodovization agent, the self-cleaning promotor of GH-700 is dropped into silicone resin at last, and middling speed stirred 20 minutes; Regulate viscosity with acetate butyl and YLENE mixed solvent, viscosity controller is filtered the back with 200 order spun silk cloth and is packed 100~150 seconds (being coated with-4 glasss, 25 ℃);
5), C component and B component are stirred in the ratio proportioning of C:B=10:1~2 form finish paint.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105019383A (en) * | 2015-08-14 | 2015-11-04 | 宁波市江东明联物联科技有限公司 | Automatic bridge cleaning and maintaining device provided with caution light |
CN106366912A (en) * | 2016-09-09 | 2017-02-01 | 东南大学 | Transferable wearing-resistant flexible super-hydrophobic film and preparation method thereof |
CN107868533A (en) * | 2017-12-04 | 2018-04-03 | 陕西宝塔山油漆股份有限公司 | A kind of method of super hydrophobic coating and its making durability super-hydrophobic coat |
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JPH11148031A (en) * | 1997-11-17 | 1999-06-02 | Mitsubishi Rayon Co Ltd | Antifouling paint composition |
CN101955712A (en) * | 2009-09-01 | 2011-01-26 | 老虎粉末涂料制造(太仓)有限公司 | Oil-repellent thermosetting powder coating and preparation method and application thereof |
CN102051105A (en) * | 2010-12-17 | 2011-05-11 | 苏州吉人漆业有限公司 | Solvent-free coumarone modified epoxy heavy-duty anticorrosive coating |
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2012
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH11148031A (en) * | 1997-11-17 | 1999-06-02 | Mitsubishi Rayon Co Ltd | Antifouling paint composition |
CN101955712A (en) * | 2009-09-01 | 2011-01-26 | 老虎粉末涂料制造(太仓)有限公司 | Oil-repellent thermosetting powder coating and preparation method and application thereof |
CN102051105A (en) * | 2010-12-17 | 2011-05-11 | 苏州吉人漆业有限公司 | Solvent-free coumarone modified epoxy heavy-duty anticorrosive coating |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105019383A (en) * | 2015-08-14 | 2015-11-04 | 宁波市江东明联物联科技有限公司 | Automatic bridge cleaning and maintaining device provided with caution light |
CN106366912A (en) * | 2016-09-09 | 2017-02-01 | 东南大学 | Transferable wearing-resistant flexible super-hydrophobic film and preparation method thereof |
CN107868533A (en) * | 2017-12-04 | 2018-04-03 | 陕西宝塔山油漆股份有限公司 | A kind of method of super hydrophobic coating and its making durability super-hydrophobic coat |
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CN102796452B (en) | 2014-11-26 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SUZHOU JIREN HIGH-TECH MATERIALS CO., LTD. Free format text: FORMER NAME: JIREN PAINTS IND CO., LTD., SUZHOU |
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CP01 | Change in the name or title of a patent holder |
Address after: 215143 Jiangsu city in Suzhou Province town of Xiangcheng District Wong Tai Pan Yang Industrial Park Road, spring Patentee after: SUZHOU JIREN HIGH-TECH MATERIALS CO., LTD. Address before: 215143 Jiangsu city in Suzhou Province town of Xiangcheng District Wong Tai Pan Yang Industrial Park Road, spring Patentee before: Jiren Paints Ind Co., Ltd., Suzhou |