CN107177357A - Arenaceous qualitative soil conditioner that a kind of gypsum is made and preparation method thereof - Google Patents
Arenaceous qualitative soil conditioner that a kind of gypsum is made and preparation method thereof Download PDFInfo
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- CN107177357A CN107177357A CN201610140301.3A CN201610140301A CN107177357A CN 107177357 A CN107177357 A CN 107177357A CN 201610140301 A CN201610140301 A CN 201610140301A CN 107177357 A CN107177357 A CN 107177357A
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- gypsum
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
Abstract
Disclosed by the invention is the arenaceous qualitative soil conditioner that a kind of gypsum is made, and is made up of the raw material of following parts by weight：15~20 parts of gypsum, 12~16 parts of plant ash, 43~58 parts of sludge, 160~191 parts of rice washing water, 20~30 parts of cattle and sheep excrement, rotten 30~38 parts of straw, 12~19 parts of fertile soil, 1~5 part of jelly powder, 5~7 parts of sylvite, 2~4 parts of given activity microorganism formulation, 18~25 parts of phosphate fertilizer, 6~9 parts of bonding agent and appropriate water；The bonding agent includes the raw material of following parts by weight:10% 6~11 parts of ferrum sulfuricum oxydatum solutum, Tween 80：2~3 parts, 2~4 parts of 10% acetic acid solution, 3~5 parts of peanut plant oil, 0.3~1 part of isoamyl alcohol, 5~8 parts of methyl acrylate, 3~7 parts of ethanol and excess water.
Description
Technical field
The invention belongs to the technical field of soil conditioner, the chiltern being made in particular to a kind of gypsum
Change soil conditioner and preparation method thereof.
Background technology
Residue after excrement of animals and various organic domestic wastes are fermented is that a kind of particle diameter distribution is very wide
Organic colloid, being completely separated for its solid-liquid be difficult very big, and this causes zymotic fluid by traditional Land use systems
It is restricted to the fertilizer transformation of commercialization.To the organic wastewater of separate sources, with different processing sides
Method, such as aluminum sulfate and active silica, chitin and chitosan, polypropylene phthalein amine flocculating agent or wadding
Solidifying agent is reported much the treatment effect of suspension system, but is the theoretical research in laboratory mostly.
Residue after the manure fermentation of agricultural crop straw, the disposed waste in biology and livestock is broadly divided into
Nutriment, mineral matter and active material, nutriment therein be divided into again thick protein, crude fat,
Humic acid, crude fibre, NFE, mineral matter are divided into trace element and macroelement, activity again
Composition is substantially amino acid, plant hormone, B family vitamin, hydrolase and antibiotic, and above-mentioned substance contains
There is abundant nutrient and organic matter, and how each composition in fermented material to be fully utilized,
The problem of people will solve at present is become.
The content of the invention
Arenaceous qualitative soil conditioner being made the present invention is to provide a kind of gypsum and preparation method thereof, it is led
Being of syllabus makes each composition in fermented ingredient be fully utilized, so that soil conditioner is made.
The present invention, which is adopted the following technical scheme that, to be achieved：
The arenaceous qualitative soil conditioner that a kind of gypsum is made, is made up of the raw material of following parts by weight：Gypsum
15~20 parts, 12~16 parts of plant ash, 43~58 parts of sludge, 160~191 parts of rice washing water, cattle and sheep excrement 20~30
Part, 30~38 parts of the straw that rots, 12~19 parts of fertile soil, 1~5 part of jelly powder, 5~7 parts of sylvite, spy
Determine 2~4 parts of living microbe formulation, 18~25 parts of phosphate fertilizer, 6~9 parts of bonding agent and appropriate water；It is described
Bonding agent includes the raw material of following parts by weight:10% 6~11 parts of ferrum sulfuricum oxydatum solutum, Tween 80：2~3 parts,
10% 2~4 parts of acetic acid solution, 3~5 parts of peanut plant oil, 0.3~1 part of isoamyl alcohol, methyl acrylate 5~8
Part, 3~7 parts of ethanol and excess water.
The preparation method of the bonding agent is as follows：Second alcohol and water is mixed and poured into reactor, is then added
Methyl acrylate, is heated to 60~70 DEG C of stirring and dissolvings, then sequentially adds isoamyl alcohol, 10% ferric sulfate solution
Liquid, 10% acetic acid solution, keep temperature in the kettle, adjust 90~100r/min of rotating speed, stir 30min, finally
Tween 80 and peanut plant oil are added simultaneously, and insulated and stirred 30min passes through funnel suction filtration into uniform emulsion
Pulvis is obtained, pulvis bonding agent is produced after drying.
The arenaceous qualitative soil conditioner that a kind of gypsum is made, is made up of the raw material of following parts by weight：Gypsum 17
Part, 14 parts of plant ash, 50 parts of sludge, 175 parts of rice washing water, 25 parts of cattle and sheep excrement, rotten straw 34
Part, 15 parts of fertile soil, 3 parts of jelly powder, 6 parts of sylvite, 3 parts of given activity microorganism formulation, phosphate fertilizer
21 parts, 7 parts of bonding agent and appropriate water；The bonding agent includes the raw material of following parts by weight:10% sulfuric acid
8 parts of ferrous solution, Tween 80：2.5 parts, 3 parts of 10% acetic acid solution, peanut plant oily 4 parts, isoamyl
0.6 part of alcohol, 6 parts of methyl acrylate, 5 parts of ethanol and excess water.
A kind of preparation method for the arenaceous qualitative soil conditioner that gypsum is made, comprises the following steps：
(1) mixed gypsum, plant ash, sludge, cattle and sheep excrement, rotten straw and fertile soil, add rice washing
Water soaks 10~20min, and then ball milling 30min is poured into fermentation tank to homogenate is mixed, and carries out high temperature
Sterilization treatment, last natural cooling；
(2) water that given activity microbial bacterial agent is added into 4~5 times of its parts by weight dilutes, and is modulated into bacterium
In liquid, the fermentation tank for being then seeded to step (1), PH=5~7,26~30 DEG C of temperature are adjusted, and be passed through
Filtrated air is stirred completely, is fermented 7 days；
(3) treat after the completion of step (2), pour out zymotic fluid and add bonding agent, stir lOmin, stand
30~40min carries out voluntarily precipitation adsorption process, after the completion of filter out supernatant, obtain lower sediment part,
Pasty state is stirred into, it is standby；
(4) mixing jelly powder, sylvite, phosphate fertilizer and other residual components, are added to described in step (3)
In thickener, stir, finally by slurry-spraying pelletizing.
By experimental study iron chloride, aluminum sulfate, ferrous sulfate, ferric sulfate in the presence of gypsum liquid
To the coagulation of zymotic fluid, the first stage is by a kind of above elder generation of four kinds of flocculating agents and cattle and sheep excrement
Zymotic fluid is mixed, and is then added gypsum liquid and is carried out precipitation adsorption, all the components then are transferred into filtering
In bag, 3~5min is dried with centrifuge, crushes standby after resulting material is air-dried, after as condensing
Required fermented ingredient；
The above-mentioned additive that fermented ingredient as compound mixing fertilizer is made is added to urea-phosphorus of 1-1-1 ratios
In the tri compound complex fertilizer of acid dihydride amine-potassium chloride, planted for road ornamental plant, and routinely agriculture
Change the analysis method detection available nutrient of soil, wherein N is 77.4mg/kg, and P is 5.4mg/kg, and K is
196mg/kg, organic matter is 28.92g/kg, and PH is 5.5.
Compared with un-added soil, the compound mixing fertilizer volume increase 8~10.1% of product of the present invention is added, and
And 80% amount of nutrients mixed organic manure volume increase 11.5~13.4%, the Vc of road ornamental plant can also be made
Improve.
In separation test, by 4 kinds of coagulating agents for main component experiment in, it was demonstrated that use sulfuric acid
Iron is the main component of coagulating agent, reaches best condensation effect, is then used as condensation using 10% acetic acid
Medium has the separating effect of suitable facilitation to inorganic coagulant, but acetic acid and zymotic fluid reaction more
Slowly, during which some zymotic fluid is escaped with fine and close bubble, so adding when coagulating agent is prepared
Enter isoamyl alcohol as defoamer, it is stabilizer to add the minimum land plaster of particle diameter, make ferric sulfate and condense to promote
Each composition for entering effect is adsorbed under the cementation of methyl acrylate on the surface of landplaster particle, is owned
After the completion of composition absorption, coagulating agent particle phase can effectively be prevented by being eventually adding a certain amount of peanut plant oil
Mutually be sticked together, as the higher agglomerate of viscosity, influence and using effect, after the completion of particle
Coagulating agent can just be stored in the form of an entirety, transported and used, with positive effect.
The present invention is using liquid fermentation method fermentation, and the fermentation material component distributing of liquid is more uniform, is conducive to
The abundant contact and absorption of mushroom and trophosome, are easily controlled optimum temperature in reactor, PH, oxygen
Deng growth conditions, accumulation mycelium, polysaccharide and many skins can have the metabolism of physiologically active in the short time
Product, while substantially reducing fermentation period relative to solid fermentation material, with pollution microbes are difficult, sprouts
The features such as sending out fast.
Compared to the prior art, the invention has the advantages that：This arenaceous qualitative soil conditioner it is all come
Source is the discarded object in life, wide material sources and is easy to get, and sludge, which is that a kind of content of mineral substances is abundant, to be had
Machine and inorganic origin, fertile soil contain the organic acid after various plants are rotted, and all after mixing, add and wash in a pan
Meter Shui Qiu is milled to dilute homogenate state, the given activity microbial bacterial agent used in inoculation fermentation, is passed through nothing
Bacterium air, fermentation compared with common fermentation thoroughly, is used for the modifying agent of arenaceous qualitative soil after condensation, adds bright
Rubber powder improves glutinous bulk properties, is particularly suitable for road and ornamental plant plants the strong soil of suitable arenaceous qualitative viscosity
Earth.
Embodiment
Embodiment one
The arenaceous qualitative soil conditioner that a kind of gypsum is made, is made up of the raw material of following parts by weight：Gypsum 15
Part, 13 parts of plant ash, 46 parts of sludge, 170 parts of rice washing water, 28 parts of cattle and sheep excrement, rotten straw 31
Part, 17 parts of fertile soil, 3 parts of jelly powder, 5 parts of sylvite, 2 parts of given activity microorganism formulation, phosphate fertilizer
25 parts, 7 parts of bonding agent and appropriate water；The bonding agent includes the raw material of following parts by weight:10% sulfuric acid
7 parts of ferrous solution, Tween 80：2 parts, 3 parts of 10% acetic acid solution, peanut plant oily 3 parts, isoamyl alcohol
0.6 part, 5 parts of methyl acrylate, 5 parts of ethanol and excess water.
The preparation method of the bonding agent is as follows：Second alcohol and water is mixed and poured into reactor, is then added
Methyl acrylate, is heated to 60 DEG C of stirring and dissolvings, then sequentially add isoamyl alcohol, 10% ferrum sulfuricum oxydatum solutum,
10% acetic acid solution, keeps temperature in the kettle, adjusts rotating speed 90r/min, stirs 30min, finally adds simultaneously
Tween 80 and peanut plant oil, insulated and stirred 30min obtain pulvis into uniform emulsion by funnel suction filtration,
Pulvis bonding agent is produced after drying.
A kind of preparation method for the arenaceous qualitative soil conditioner that gypsum is made, comprises the following steps：
(1) mixed gypsum, plant ash, sludge, cattle and sheep excrement, rotten straw and fertile soil, add rice washing
Water soaks 12min, and then ball milling 30min is poured into fermentation tank to homogenate is mixed, and carries out high-temperature sterilization
Processing, last natural cooling；
(2) water that given activity microbial bacterial agent is added into 4 times of its parts by weight dilutes, and is modulated into bacterium solution,
Then in the fermentation tank for being seeded to step (1), adjust PH=5,27 DEG C of temperature, and be passed through filtrated air
Row stirring completely, ferments 7 days；
(3) treat after the completion of step (2), pour out zymotic fluid and add bonding agent, stir lOmin, stand
30min carries out voluntarily precipitation adsorption process, after the completion of filter out supernatant, obtain lower sediment part, stir
It is standby into pasty state；
(4) mixing jelly powder, sylvite, phosphate fertilizer and other residual components, are added to described in step (3)
In thickener, stir, finally by slurry-spraying pelletizing.
Embodiment two
The arenaceous qualitative soil conditioner that a kind of gypsum is made, is made up of the raw material of following parts by weight：Gypsum 17
Part, 14 parts of plant ash, 50 parts of sludge, 175 parts of rice washing water, 25 parts of cattle and sheep excrement, rotten straw 34
Part, 15 parts of fertile soil, 3 parts of jelly powder, 6 parts of sylvite, 3 parts of given activity microorganism formulation, phosphate fertilizer
21 parts, 7 parts of bonding agent and appropriate water；The bonding agent includes the raw material of following parts by weight:10% sulfuric acid
8 parts of ferrous solution, Tween 80：2.5 parts, 3 parts of 10% acetic acid solution, peanut plant oily 4 parts, isoamyl
0.6 part of alcohol, 6 parts of methyl acrylate, 5 parts of ethanol and excess water.
The preparation method of the bonding agent is as follows：Second alcohol and water is mixed and poured into reactor, is then added
Methyl acrylate, is heated to 65 DEG C of stirring and dissolvings, then sequentially add isoamyl alcohol, 10% ferrum sulfuricum oxydatum solutum,
10% acetic acid solution, keeps temperature in the kettle, adjusts rotating speed 95r/min, stirs 30min, finally adds simultaneously
Tween 80 and peanut plant oil, insulated and stirred 30min obtain pulvis into uniform emulsion by funnel suction filtration,
Pulvis bonding agent is produced after drying.
A kind of preparation method for the arenaceous qualitative soil conditioner that gypsum is made, comprises the following steps：
(1) mixed gypsum, plant ash, sludge, cattle and sheep excrement, rotten straw and fertile soil, add rice washing
Water soaks 15min, and then ball milling 30min is poured into fermentation tank to homogenate is mixed, and carries out high-temperature sterilization
Processing, last natural cooling；
(2) water that given activity microbial bacterial agent is added into 4.5 times of its parts by weight dilutes, and is modulated into bacterium solution,
Then in the fermentation tank for being seeded to step (1), adjust PH=6,28 DEG C of temperature, and be passed through filtrated air
Row stirring completely, ferments 7 days；
(3) treat after the completion of step (2), pour out zymotic fluid and add bonding agent, stir lOmin, stand
35min carries out voluntarily precipitation adsorption process, after the completion of filter out supernatant, obtain lower sediment part, stir
It is standby into pasty state；
(4) mixing jelly powder, sylvite, phosphate fertilizer and other residual components, are added to described in step (3)
In thickener, stir, finally by slurry-spraying pelletizing.
Embodiment three
The arenaceous qualitative soil conditioner that a kind of gypsum is made, is made up of the raw material of following parts by weight：Gypsum 20
Part, 16 parts of plant ash, 51 parts of sludge, 181 parts of rice washing water, 29 parts of cattle and sheep excrement, rotten straw 38
Part, 15 parts of fertile soil, 4 parts of jelly powder, 6 parts of sylvite, 4 parts of given activity microorganism formulation, phosphate fertilizer
19 parts, 9 parts of bonding agent and appropriate water；The bonding agent includes the raw material of following parts by weight:10% sulfuric acid
10 parts of ferrous solution, Tween 80：3 parts, 4 parts of 10% acetic acid solution, peanut plant oily 5 parts, isoamyl alcohol
0.8 part, 7 parts of methyl acrylate, 6 parts of ethanol and excess water.
The preparation method of the bonding agent is as follows：Second alcohol and water is mixed and poured into reactor, is then added
Methyl acrylate, is heated to 70 DEG C of stirring and dissolvings, then sequentially add isoamyl alcohol, 10% ferrum sulfuricum oxydatum solutum,
10% acetic acid solution, keeps temperature in the kettle, adjusts rotating speed 100r/min, stirs 30min, finally adds simultaneously
Enter Tween 80 and peanut plant oil, insulated and stirred 30min obtains pulvis into uniform emulsion by funnel suction filtration,
Pulvis bonding agent is produced after drying.
A kind of preparation method for the arenaceous qualitative soil conditioner that gypsum is made, comprises the following steps：
(1) mixed gypsum, plant ash, sludge, cattle and sheep excrement, rotten straw and fertile soil, add rice washing
Water soaks 20min, and then ball milling 30min is poured into fermentation tank to homogenate is mixed, and carries out high-temperature sterilization
Processing, last natural cooling；
(2) water that given activity microbial bacterial agent is added into 5 times of its parts by weight dilutes, and is modulated into bacterium solution,
Then in the fermentation tank for being seeded to step (1), adjust PH=7,30 DEG C of temperature, and be passed through filtrated air
Row stirring completely, ferments 7 days；
(3) treat after the completion of step (2), pour out zymotic fluid and add bonding agent, stir lOmin, stand
40min carries out voluntarily precipitation adsorption process, after the completion of filter out supernatant, obtain lower sediment part, stir
It is standby into pasty state；
(4) mixing jelly powder, sylvite, phosphate fertilizer and other residual components, are added to described in step (3)
In thickener, stir, finally by slurry-spraying pelletizing.
Product of the present invention is used for the special additive as plantation road and ornamental plant, 10 kilometers are selected
Town road both sides road plant as experimental group, by the way of spreading manuer in holes, by product of the present invention and bottom
Soil 1:Imposed on after 3 ratio mixing near plant roots, every square metre of 0.3~0.4 additive amount.Control
10 kilometers of group are without any processing or apply the road plant that fertilizer is replaced, other curing conditions and disease pest
Harmful prevents and treats all same, as a result shows that the Ornamental Plants growing way of experimental group is substantially better than control group, together
When can greatly reduce chemical fertilizer usage amount, effective soil protection structure, special loose ventilation, green
Environmental protection, raw material sources are various, and cost is relatively low, year economy raising 11%.
The embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto,
All changes for carrying out unsubstantiality to the present invention using this design, all should belong to the infringement scope of the present invention
Behavior.
Claims (4)
1. the arenaceous qualitative soil conditioner that a kind of gypsum is made, it is characterised in that:By the raw material system of following parts by weight
Into：15~20 parts of gypsum, 12~16 parts of plant ash, 43~58 parts of sludge, rice washing water 160~191
Part, 20~30 parts of cattle and sheep excrement, rotten 30~38 parts of straw, 12~19 parts of fertile soil, jelly powder 1~5
Part, 5~7 parts of sylvite, 2~4 parts of given activity microorganism formulation, 18~25 parts of phosphate fertilizer, bonding agent
6~9 parts and appropriate water；The bonding agent includes the raw material of following parts by weight:10% ferrum sulfuricum oxydatum solutum
6~11 parts, Tween 80：2~3 parts, 2~4 parts of 10% acetic acid solution, 3~5 parts of peanut plant oil,
0.3~1 part of isoamyl alcohol, 5~8 parts of methyl acrylate, 3~7 parts of ethanol and excess water.
2. the arenaceous qualitative soil conditioner that a kind of gypsum as claimed in claim is made, it is characterised in that：It is described
The preparation method of bonding agent is as follows：Second alcohol and water is mixed and poured into reactor, acrylic acid is then added
Methyl esters, is heated to 60~70 DEG C of stirring and dissolvings, then sequentially add isoamyl alcohol, 10% ferrum sulfuricum oxydatum solutum,
10% acetic acid solution, keeps temperature in the kettle, adjusts 90~100r/min of rotating speed, stirs 30min, finally
Tween 80 and peanut plant oil are added simultaneously, and insulated and stirred 30min passes through funnel into uniform emulsion
Suction filtration, which is obtained, produces pulvis bonding agent after pulvis, drying.
3. the arenaceous qualitative soil conditioner that a kind of gypsum as claimed in claim is made, it is characterised in that：By with
The raw material of lower parts by weight is made：17 parts of gypsum, 14 parts of plant ash, 50 parts of sludge, rice washing water 175
Part, 25 parts of cattle and sheep excrement, rotten 34 parts of straw, 15 parts of fertile soil, 3 parts of jelly powder, sylvite 6
Part, 3 parts of given activity microorganism formulation, 21 parts of phosphate fertilizer, 7 parts of bonding agent and appropriate water；Institute
State the raw material that bonding agent includes following parts by weight:10% 8 parts of ferrum sulfuricum oxydatum solutum, Tween 80：2.5 parts,
10% 3 parts of acetic acid solution, peanut plant oil 4 parts, 0.6 part of isoamyl alcohol, 6 parts of methyl acrylate,
5 parts of ethanol and excess water.
4. a kind of preparation method for the arenaceous qualitative soil conditioner that gypsum is made, it is characterised in that：Including following step
Suddenly：
(1) mixed gypsum, plant ash, sludge, cattle and sheep excrement, rotten straw and fertile soil, add and wash in a pan
Rice water soaks 10~20min, and then ball milling 30min pours into fermentation tank to homogenate is mixed
In, carry out high-temperature sterilization processing, last natural cooling；
(2) water that given activity microbial bacterial agent is added into 4~5 times of its parts by weight dilutes, and is modulated into
In bacterium solution, the fermentation tank for being then seeded to step (1), adjustment PH=5~7, temperature 26~
30 DEG C, and be passed through filtrated air and stirred completely, ferment 7 days；
(3) treat after the completion of step (2), pour out zymotic fluid and add bonding agent, stir lOmin, stand
30~40min carries out voluntarily precipitation adsorption process, after the completion of filter out supernatant, obtain lower floor
Sediment fraction, stirs into pasty state, standby；
(4) mixing jelly powder, sylvite, phosphate fertilizer and other residual components, are added to step (3) Suo Shu
Thickener in, stir, finally by slurry-spraying pelletizing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610140301.3A CN107177357A (en) | 2016-03-12 | 2016-03-12 | Arenaceous qualitative soil conditioner that a kind of gypsum is made and preparation method thereof |
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| CN201610140301.3A CN107177357A (en) | 2016-03-12 | 2016-03-12 | Arenaceous qualitative soil conditioner that a kind of gypsum is made and preparation method thereof |
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| CN105111008A (en) * | 2015-07-24 | 2015-12-02 | 定远县田包子种植业家庭农场 | Ficus carica L. planting soil modifier, and preparation method thereof |
| CN105175094A (en) * | 2015-07-24 | 2015-12-23 | 定远县田包子种植业家庭农场 | High-egg white fig cultivating fertilizer and preparation method therefor |
| CN105254419A (en) * | 2015-10-16 | 2016-01-20 | 阜南县阜合种养农民专业合作联合社 | Liquid fermentation type fertilizer for pear trees and preparation method of fertilizer |
| CN105272572A (en) * | 2015-10-16 | 2016-01-27 | 阜南县阜合种养农民专业合作联合社 | Cultivation base fertilizer for juvenile stage of pear trees and preparation method of base fertilizer |
-
2016
- 2016-03-12 CN CN201610140301.3A patent/CN107177357A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111008A (en) * | 2015-07-24 | 2015-12-02 | 定远县田包子种植业家庭农场 | Ficus carica L. planting soil modifier, and preparation method thereof |
| CN105175094A (en) * | 2015-07-24 | 2015-12-23 | 定远县田包子种植业家庭农场 | High-egg white fig cultivating fertilizer and preparation method therefor |
| CN105254419A (en) * | 2015-10-16 | 2016-01-20 | 阜南县阜合种养农民专业合作联合社 | Liquid fermentation type fertilizer for pear trees and preparation method of fertilizer |
| CN105272572A (en) * | 2015-10-16 | 2016-01-27 | 阜南县阜合种养农民专业合作联合社 | Cultivation base fertilizer for juvenile stage of pear trees and preparation method of base fertilizer |
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Effective date of registration: 20181101 Address after: 362100 Fujian Quanzhou Huian County East Bridge Town Spring Hui Petrochemical Park Applicant after: Quanzhou Yang Yu soil science and Technology Co., Ltd. Address before: 362100 Fujian Xiamen Torch High-tech Zone (Xiangan) Industrial Zone Taiwan science and technology enterprise breeding center C101, C102 room Applicant before: Xiamen city Lubaka Biological Technology Co. Ltd. |
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Application publication date: 20170919 |
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