CN107164074A - A kind of production method of the cosmetic oil based on hair Lai seeds - Google Patents
A kind of production method of the cosmetic oil based on hair Lai seeds Download PDFInfo
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- CN107164074A CN107164074A CN201710250936.3A CN201710250936A CN107164074A CN 107164074 A CN107164074 A CN 107164074A CN 201710250936 A CN201710250936 A CN 201710250936A CN 107164074 A CN107164074 A CN 107164074A
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- Prior art keywords
- seeds
- ethyl acetate
- ethanol
- oil
- extraction
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0092—Mixtures
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
A kind of production method of the cosmetic oil based on hair Lai seeds, belongs to cosmetics processing technique field.The inventive method by hair Lai seeds by drying, be crushed to certain particle size；Add after ethanol and the pretreatment of ethyl acetate microwave radiation technology, supercritical CO is carried out using ethanol and ethyl acetate as entrainer2Extraction, pressure is extraction under the conditions of 20~30MPa, 45~50 DEG C of temperature；Then separated in knockout drum at pressure 3MPa~6MPa, 25~30 DEG C of temperature.After reclaiming ethanol and ethyl acetate through vacuum distillation, extraction oil obtains anti-oxidant hair Lai seeds oil by adding carnosine, Tea Polyphenols and lycopene composite antioxidant after solubilising.Extraction rate of the present invention is fast, recovery rate is high, no solvent residue, and the high quality oils water activity of acquisition is low, with anti-oxidant and vegetative cell function, and water retention property and Storage are all good, can be used as in cosmetics of super quality base starting material.
Description
Technical field
The invention belongs to cosmetics processing technique field, it is related to the production method of cosmetic oil.
Background technology
General principle：Hair Lai seed fruits oil-containing more than 30%.The oily unsaturated fatty acid content of hair Lai seeds enriches, hair Lai seeds oil
In based on α-leukotrienes and α-linoleic acid, wherein palmitoleic acid is more rare, and palmitoleic acid is mainly derived from whale oil and fish
The valuable abyssal fishes grease such as liver oil is wherein generally unrighted acid, meanwhile, also containing abundant sterol, palmitic acid pohytol
Etc. multiple biological activities composition, therefore, for cosmetics can make soft lubrication, skin nutrition cell effect.Lycopene energy
Promote the growth and regeneration of cell, beauty Eradicates wrinkles, the effects such as maintaining skin health, anti-aging can substantially improve allergic
Disease, eliminates dry skin and scratchiness because caused by allergic, makes us feeling relaxed happy.Carnosine can be removed should in oxidation
Make active oxygen radical formed by the aliphatic acid over oxidation of cell membrane during swashing（ROS）And alpha-beta unsaturated aldehyde.Can be with
The effect that the aging and skin for preventing skin are brightened, carnosine can prevent free radical from producing, and skin injury be repaired, with vegetative cell
Function.
The principle of microwave treatment is to penetrate spe medium using frequency electromagnetic waves, reaches the inside for being extracted material, microwave
Heat energy can be quickly converted to and make the temperature rapid increase of cell interior.When the pressure of cell interior exceedes the ability to bear of cell
When, cell will rupture, and active ingredient is i.e. from intracellular outflow, and be dissolved in spe medium at a lower temperature.
Supercritical CO2The principle of fluid extraction separation is the relation of the solvability using supercritical fluid and its density,
Influence i.e. using pressure and temperature to supercritical fluid solvability and extract.In the supercritical state, will be overcritical
Fluid is contacted with material to be separated, make its selectively polarity size, boiling point height it is different with molecular size range into
Divide and extract successively.Certainly, the extract obtained by each pressure limit of correspondence is unlikely to be single, but can be with control condition
The blending constituent of optimal proportion is obtained, then supercritical fluid is become common gases by the method for decompression, heating, is extracted
Material is then wholly or substantially separated out, so that the purpose of separating-purifying is reached, so supercritical CO2Fluid extraction process is by extracting
Combined with separation process.Supercritical CO2The sharpest edges of fluid extraction are no solvent residues, and natural active matter is obtained
It is effectively maintained.In the present invention, ethanol and ethyl acetate are in supercritical CO2Play entrainer during fluid extraction,
Extraction efficiency can be improved.And different from general organic solvent, provide that ethanol and ethyl acetate are fair according to GB 2760-96
Perhaps the flavorant used, for cosmetics more without toxic side effect.Extraction under the conditions of 45-60 DEG C, high vacuum carry out
The recyclable ethanol of vacuum distillation and ethyl acetate obtain product.The grease extracted at the process conditions has the same of bioactivity
When, its antioxidation activity is low, easy oxidation deterioration.Carnosine, Tea Polyphenols and tomato red have extraordinary antioxygenic property, three
Also there is synergy in the presence of simultaneously, antioxidation activity is greatly improved.But carnosine and Tea Polyphenols do not dissolve in grease, kind
Lycopene is water insoluble, it is impossible to which three is directly added into grease, finds carnosine and Tea Polyphenols being dissolved in after water by studying, plus
The binary compound emulsifying agent for entering HLB value 5-6 monoglyceride and HLB value 12-15 nonionic polyoxyethylene monolaurate can
To promote lycopene to dissolve, add in grease and form the particulate of Water-In-Oil and dispersed, effect very well, then uses ultrasonic wave
Concussion is uniformly mixed so as to obtain the hair Lai seeds oil with antioxidation activity high bioactivity, and it contains abundant nutriment, can be used as
The matrix of cosmetic.
The content of the invention
It is an object of the invention to provide a kind of production method of the cosmetic oil based on hair Lai seeds, for producing cosmetics
Matrix oil.Supercritical CO after being pre-processed by microwave radiation technology2Fluid extraction hair Lai seeds oil, addition carnosine, Tea Polyphenols and kind
Lycopene improves antioxidation activity, obtains the antioxidation biology activity hair Lai seeds oil of functionalization.
This method by hair Lai seeds by drying, being crushed to after certain particle size；Add ethanol and ethyl acetate microwave radiation technology is pre-
Processing, uses supercritical CO under certain process conditions afterwards2Second is reclaimed in fluid extraction vegetable oil and active ingredient, vacuum distillation
After alcohol and ethyl acetate, then using raising antioxidation activities such as certain method addition Tea Polyphenols, obtain high with antioxidation activity
The hair Lai seeds oil of bioactivity.The major advantage of this method is supercritical CO at the process conditions2Hair obtained by fluid extraction
Lai seeds oil, bioactive substance content is high, loses small.Adding has well anti-oxidant after carnosine, Tea Polyphenols and lycopene
Characteristic, the grease produced with this method can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
The present invention is achieved by the following technical solutions.
A kind of production method of cosmetic oil based on hair Lai seeds of the present invention, as follows.
1）By hair Lai seeds by drying, be crushed to certain particle size.
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology.
3）Using ethanol and ethyl acetate as entrainer supercritical CO2Fluid extraction.
4）Ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Add carnosine, Tea Polyphenols and lycopene and improve anti-oxidation characteristics.
The microwave radiation technology pretreatment, refers to and is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
The supercritical CO2Fluid extraction, refers in extractor under the conditions of pressure is 20~30MPa, 45~50 DEG C of temperature
Extraction；Separated in knockout drum at pressure 3MPa~5MPa, 25~30 DEG C of temperature.
The raising inoxidizability.Refer to and carnosine and Tea Polyphenols are dissolved in distilled water, add HLB value 5-6 monoglyceride and HLB
The binary compound emulsifying agent of value 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C,
It is allowed to be completely dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the oil of the hair Lai seeds obtained by extraction and quickly stir, be dispersed into
Uniform single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Quality
Than）It is not less than 0.01%, obtains the antioxidation biology activity hair Lai seeds oil of functionalization.
Its main principle steps：1. by hair Lai seeds by drying, be crushed to certain particle size；2. ethanol and ethyl acetate are micro-
Ripple auxiliary pretreatment；3. carry out supercritical CO using ethanol and ethyl acetate as entrainer in certain process conditions2Fluid extraction.
4. ethanol and ethyl acetate are reclaimed in vacuum distillation；5. adding carnosine, Tea Polyphenols and lycopene improves anti-oxidation characteristics.Use the party
The major advantage of method is supercritical CO at the process conditions2Hair Lai seeds oil obtained by fluid extraction, bioactive substance content
Height, loses small, adding has high anti-oxidation characteristic after carnosine, Tea Polyphenols and lycopene, improves storage phase, prevent from going bad.Should
The grease of method production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
Beneficial effects of the present invention：The present invention provides a kind of objectively high bioactivity cosmetics with antioxidation activity
With the production method of oil.This method can efficiently extract high activity hair Lai seed oil with objective, have compared to solvent extraction without molten
The characteristic of agent residual, has high anti-oxidation activity by adding composite antioxidant, can be used for the life of cosmetic base oil
Production.
Embodiment
The present invention will be described further by following examples.
Embodiment 1.
1）By hair Lai seeds by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, Microwave Extraction reaction system is used（Such as the SOS- of French PR OLABO companies
1100 series of products）Handled 5-10 minutes in 2450MHz.
3）Then by said mixture supercritical CO2Equipment（Such as the U.S. morning 300L type in Guangzhou）Extract 3h, extraction conditions：Extraction
It is extraction under the conditions of 25MPa, 45~50 DEG C of temperature to take pressure in tank；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 40-50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C, make
Be completely dissolved, above-mentioned solution is slowly added dropwise into the 3rd）Walk in the oil of the hair Lai seeds obtained by extraction and quickly stir, be dispersed into
Even single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）
It is not less than 0.01%, obtains the antioxidation biology activity hair Lai seeds oil of functionalization.
Embodiment 2.
1）By hair Lai seeds by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, Microwave Extraction reaction system is used（Such as the SOS- of French PR OLABO companies
1100 series of products）Handled 8 minutes in 2450MHz.
3）Then by said mixture supercritical CO2Equipment（Such as the U.S. morning 300L type in Guangzhou）Extract 2h, extraction conditions：Extraction
It is extraction under the conditions of 25MPa, temperature 45 C to take pressure in tank；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 40 DEG C, be allowed to
Fully dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the oil of the hair Lai seeds obtained by extraction and quickly stir, be dispersed into uniform
Single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）It is not low
In 0.3%, the antioxidation biology activity hair Lai seeds oil of functionalization is obtained.
Claims (1)
1. a kind of production method of the cosmetic oil based on hair Lai seeds, it is characterized in that as follows：
1）By hair Lai seeds by drying, be crushed to certain particle size；
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology：Appropriate ethanol and ethyl acetate is added in the hair Lai seeds of crushing,
Microwave Pretreatment 3-10 minutes, makes breaking-wall cell；
3）Supercritical extract hair Lai seed oil：By step（2）The mixture of gained is faced using ethanol and ethyl acetate as entrainer with super
Boundary CO2With extraction under the conditions of 20~30MPa of pressure, 45~50 DEG C of temperature in extractor；Then with pressure 3 in knockout drum
Separated at MPa~4MPa, 25~30 DEG C of temperature；
4）By step（3）Grease is obtained, at 45-60 DEG C, pumping high vacuum carries out vacuum distillation and reclaims removing ethanol and ethyl acetate,
Obtain a mao Lai seeds oil；
5）Improve inoxidizability：Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value 12-15 is added
Nonionic polyoxyethylene monolaurate binary compound emulsifying agent, add lycopene heat 30-40 DEG C, be allowed to complete
Dissolving, above-mentioned solution is slowly added dropwise into step（4）Stir in hair Lai seeds oil obtained by extraction and quickly, be dispersed into uniform list
Phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene mass ratio of total content in grease are not less than
0.01%, obtain the antioxidation biology activity hair Lai seeds oil of functionalization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250936.3A CN107164074A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on hair Lai seeds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250936.3A CN107164074A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on hair Lai seeds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107164074A true CN107164074A (en) | 2017-09-15 |
Family
ID=59849692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710250936.3A Withdrawn CN107164074A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on hair Lai seeds |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107164074A (en) |
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2017
- 2017-04-18 CN CN201710250936.3A patent/CN107164074A/en not_active Withdrawn
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Application publication date: 20170915 |
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| WW01 | Invention patent application withdrawn after publication |