CN107011983A - A kind of production method of the cosmetic oil based on purple perilla - Google Patents
A kind of production method of the cosmetic oil based on purple perilla Download PDFInfo
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- CN107011983A CN107011983A CN201710251027.1A CN201710251027A CN107011983A CN 107011983 A CN107011983 A CN 107011983A CN 201710251027 A CN201710251027 A CN 201710251027A CN 107011983 A CN107011983 A CN 107011983A
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- China
- Prior art keywords
- ethanol
- ethyl acetate
- extraction
- perilla
- purple perilla
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/12—Refining fats or fatty oils by distillation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0085—Substances of natural origin of unknown constitution, f.i. plant extracts
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Microbiology (AREA)
- Botany (AREA)
- Cosmetics (AREA)
Abstract
A kind of production method of the cosmetic oil based on purple perilla, belongs to cosmetics processing technique field.The present invention by purple perilla by drying, be crushed to certain particle size；Add after ethanol and the pretreatment of ethyl acetate microwave radiation technology, supercritical CO is carried out using ethanol and ethyl acetate as entrainer2Extraction, pressure is extraction under the conditions of 20~30MPa, 45~50 DEG C of temperature；Then separated in knockout drum at pressure 3MPa~6MPa, 25~30 DEG C of temperature.After reclaiming ethanol and ethyl acetate through vacuum distillation, extraction oil obtains anti-oxidant perilla herb oil by adding carnosine, Tea Polyphenols and lycopene composite antioxidant after solubilising.Extraction rate of the present invention is fast, recovery rate is high, no solvent residue, and the high quality oils water activity of acquisition is low, with anti-oxidant and vegetative cell function, and water retention property and Storage are all good, can be used as in cosmetics of super quality base starting material.
Description
Technical field
The invention belongs to cosmetics processing technique field, it is related to the production method of cosmetic oil.
Background technology
General principle：There are a variety of aliphatic acid in purple perilla fat oil about oil-containing 40-45%, oil, importantly linoleic acid, oleic acid
And palmitic acid.Containing saturated fatty acid, linoleic acid, and multivitamin, also containing sterol, flavones, chlorogenic acid, neochlorogenic acid, and
Olefine aldehydr, alkene -1- alcohol, linalool, tetradecanoic acid etc..Simultaneously as containing abundant carrotene, preventing free radical from invading
Cell is attacked, the effect with pre- preventing tumor.Therefore, multiple biological activities composition is contained in perilla herb oil, can be made for cosmetics soft
Soft lubrication, the effect of skin nutrition cell.Lycopene can promote the growth and regeneration of cell, and beauty Eradicates wrinkles maintain skin to be good for
The effects such as health, anti-aging, skin allergy can be substantially improved, eliminate dry skin and itch because caused by allergic
Sense, makes us feeling relaxed happy.Carnosine can remove the aliphatic acid over oxidation for making cell membrane during oxidative stress and be formed
Active oxygen radical（ROS）And alpha-beta unsaturated aldehyde.The effect that the aging and skin that skin can be prevented are brightened, carnosine can
Prevent free radical from producing, repair skin injury, the function with vegetative cell.
The principle of microwave treatment is to penetrate spe medium using frequency electromagnetic waves, reaches the inside for being extracted material, microwave
Heat energy can be quickly converted to and make the temperature rapid increase of cell interior.When the pressure of cell interior exceedes the ability to bear of cell
When, cell will rupture, and active ingredient is i.e. from intracellular outflow, and be dissolved in spe medium at a lower temperature.
Supercritical CO2The principle of fluid extraction separation is the relation of the solvability using supercritical fluid and its density,
Influence i.e. using pressure and temperature to supercritical fluid solvability and extract.In the supercritical state, will be overcritical
Fluid is contacted with material to be separated, make its selectively polarity size, boiling point height it is different with molecular size range into
Divide and extract successively.Certainly, the extract obtained by each pressure limit of correspondence is unlikely to be single, but can be with control condition
The blending constituent of optimal proportion is obtained, then supercritical fluid is become common gases by the method for decompression, heating, is extracted
Material is then wholly or substantially separated out, so that the purpose of separating-purifying is reached, so supercritical CO2Fluid extraction process is by extracting
Combined with separation process.Supercritical CO2The sharpest edges of fluid extraction are no solvent residues, and natural active matter is obtained
It is effectively maintained.In the present invention, ethanol and ethyl acetate are in supercritical CO2Play entrainer during fluid extraction,
Extraction efficiency can be improved.And different from general organic solvent, provide that ethanol and ethyl acetate are fair according to GB 2760-96
Perhaps the flavorant used, for cosmetics more without toxic side effect.Extraction under the conditions of 45-60 DEG C, high vacuum carry out
The recyclable ethanol of vacuum distillation and ethyl acetate obtain product.The grease extracted at the process conditions has the same of bioactivity
When, its antioxidation activity is low, easy oxidation deterioration.Carnosine, Tea Polyphenols and tomato red have extraordinary antioxygenic property, three
Also there is synergy in the presence of simultaneously, antioxidation activity is greatly improved.But carnosine and Tea Polyphenols do not dissolve in grease, kind
Lycopene is water insoluble, it is impossible to which three is directly added into grease, finds carnosine and Tea Polyphenols being dissolved in after water by studying, plus
The binary compound emulsifying agent for entering HLB value 5-6 monoglyceride and HLB value 12-15 nonionic polyoxyethylene monolaurate can
To promote lycopene to dissolve, add in grease and form the particulate of Water-In-Oil and dispersed, effect very well, then uses ultrasonic wave
Concussion is uniformly mixed so as to obtain the perilla herb oil with antioxidation activity high bioactivity, and it contains abundant nutriment, can be used as making up
The matrix of product.
The content of the invention
It is an object of the invention to provide a kind of production method of the cosmetic oil based on purple perilla, for producing cosmetics
Matrix oil.Supercritical CO after being pre-processed by microwave radiation technology2Fluid extraction perilla herb oil, addition carnosine, Tea Polyphenols and tomato red
Element improves antioxidation activity, obtains the active perilla herb oil of antioxidation biology of functionalization.
This method by purple perilla by drying, being crushed to after certain particle size；Add ethanol and ethyl acetate microwave radiation technology is located in advance
Reason, uses supercritical CO under certain process conditions afterwards2Ethanol is reclaimed in fluid extraction vegetable oil and active ingredient, vacuum distillation
Antioxidation activity is improved after ethyl acetate, then using certain method addition Tea Polyphenols etc., is obtained with antioxidation activity Gao Sheng
The perilla herb oil of thing activity.The major advantage of this method is supercritical CO at the process conditions2Perilla herb oil obtained by fluid extraction,
Bioactive substance content is high, loses small.Adding has good anti-oxidation characteristics after carnosine, Tea Polyphenols and lycopene, use
The grease of this method production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
The present invention is achieved by the following technical solutions.
A kind of production method of cosmetic oil based on purple perilla of the present invention, as follows.
1）By purple perilla seed by drying, be crushed to certain particle size.
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology.
3）Using ethanol and ethyl acetate as entrainer supercritical carbon dioxide extraction.
4）Ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Add carnosine, Tea Polyphenols and lycopene and improve anti-oxidation characteristics.
The microwave radiation technology pretreatment, refers to and is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
The supercritical CO2Fluid extraction, refers in extractor under the conditions of pressure is 20~30MPa, 45~50 DEG C of temperature
Extraction；Separated in knockout drum at pressure 3MPa~5MPa, 25~30 DEG C of temperature.
The raising inoxidizability.Refer to and carnosine and Tea Polyphenols are dissolved in distilled water, add HLB value 5-6 monoglyceride and HLB
The binary compound emulsifying agent of value 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C,
It is allowed to be completely dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the perilla herb oil obtained by extraction and quickly stir, be dispersed into
Even single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）
It is not less than 0.01%, obtains the active perilla herb oil of antioxidation biology of functionalization.
Its main principle steps：1. by purple perilla by drying, be crushed to certain particle size；2. ethanol and ethyl acetate microwave
Auxiliary pretreatment；3. carry out supercritical CO using ethanol and ethyl acetate as entrainer in certain process conditions2Fluid extraction.4.
Ethanol and ethyl acetate are reclaimed in vacuum distillation；5. adding carnosine, Tea Polyphenols and lycopene improves anti-oxidation characteristics.Use this method
Major advantage be supercritical CO at the process conditions2Perilla herb oil obtained by fluid extraction, bioactive substance content is high, damages
Mistake is small, and adding has high anti-oxidation characteristic after carnosine, Tea Polyphenols and lycopene, improves storage phase, prevents from going bad.This method is given birth to
The grease of production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
Beneficial effects of the present invention：The present invention provides a kind of objectively high bioactivity cosmetics with antioxidation activity
With the production method of oil.This method can efficiently extract high activity perilla herb oil with objective, have compared to solvent extraction solvent-free
The characteristic of residual, has high anti-oxidation activity by adding composite antioxidant, can be used for the production of cosmetic base oil.
Embodiment
The present invention will be described further by following examples.
Microwave Extraction reaction system used in the embodiment of the present invention is the SOS-1100 series of products of French PR OLABO companies,
Supercritical CO used2Equipment is the U.S. morning 300L type in Guangzhou.
Embodiment 1.
1）By purple perilla seed by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then by said mixture supercritical CO2Equipment extracts 3h, extraction conditions：Pressure is 25MP in extractor
Extracted under the conditions of a, 45~50 DEG C of temperature；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 40-50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C, make
Be completely dissolved, above-mentioned solution is slowly added dropwise into the 3rd）Walk in the perilla herb oil obtained by extraction and quickly stir, be dispersed into uniform
Single-phase oily liquids, mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）No
Less than 0.01%, the active perilla herb oil of antioxidation biology of functionalization is obtained.
Embodiment 2.
1）By purple perilla seed by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 8 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then by said mixture supercritical CO2Equipment extracts 2h, extraction conditions：Pressure is 25MP in extractor
Extracted under the conditions of a, temperature 45 C；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 40 DEG C, be allowed to
Fully dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the perilla herb oil obtained by extraction and quickly stir, be dispersed into uniform list
Phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）It is not less than
0.3%, obtain the active perilla herb oil of antioxidation biology of functionalization.
Claims (1)
1. a kind of production method of the cosmetic oil based on purple perilla, it is characterized in that as follows：
（1）By purple perilla seed by drying, be crushed to certain particle size；
（2）Appropriate ethanol and ethyl acetate is added in the purple perilla of crushing, Microwave Pretreatment 3-10 minutes makes breaking-wall cell；
（3）By step（2）The mixture of gained uses supercritical CO using ethanol and ethyl acetate as entrainer2With pressure in extractor
Extracted under the conditions of 20~30MPa of power, 45~50 DEG C of temperature；Then with pressure 3MPa~4MPa, temperature in knockout drum
Separated at 25~30 DEG C；
（4）By step（3）Grease is obtained, at 45-60 DEG C, pumping high vacuum carries out vacuum distillation and reclaims removing ethanol and acetic acid second
Ester, obtains perilla herb oil；
（5）Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride is added and the non-ionic of HLB value 12-15 is gathered
The binary compound emulsifying agent of oxygen ethene monolaurate, adds lycopene and heats 30-40 DEG C, be allowed to be completely dissolved, will be above-mentioned
Solution is slowly added dropwise into step（4）Stir in perilla herb oil obtained by extraction and quickly, be dispersed into uniform single-phase oily liquids, use
Ultrasonic oscillation is mixed；Carnosine, Tea Polyphenols and the lycopene mass ratio of total content in grease are not less than 0.01%, obtain work(
The active perilla herb oil of the antioxidation biology of energyization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251027.1A CN107011983A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on purple perilla |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251027.1A CN107011983A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on purple perilla |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107011983A true CN107011983A (en) | 2017-08-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710251027.1A Withdrawn CN107011983A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on purple perilla |
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| CN (1) | CN107011983A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114480015A (en) * | 2021-12-31 | 2022-05-13 | 安徽全康药业有限公司 | By using supercritical CO2Process for efficiently extracting perilla seed oil |
-
2017
- 2017-04-18 CN CN201710251027.1A patent/CN107011983A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114480015A (en) * | 2021-12-31 | 2022-05-13 | 安徽全康药业有限公司 | By using supercritical CO2Process for efficiently extracting perilla seed oil |
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Application publication date: 20170804 |