CN107022408A - A kind of production method of the cosmetic oil based on papaya seed - Google Patents
A kind of production method of the cosmetic oil based on papaya seed Download PDFInfo
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- CN107022408A CN107022408A CN201710250920.2A CN201710250920A CN107022408A CN 107022408 A CN107022408 A CN 107022408A CN 201710250920 A CN201710250920 A CN 201710250920A CN 107022408 A CN107022408 A CN 107022408A
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- China
- Prior art keywords
- papaya seed
- ethanol
- extraction
- ethyl acetate
- oil
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0092—Mixtures
Abstract
A kind of production method of the cosmetic oil based on papaya seed, belongs to cosmetics processing technique field.The inventive method by papaya seed by drying, be crushed to certain particle size；Add after ethanol and the pretreatment of ethyl acetate microwave radiation technology, supercritical CO is carried out using ethanol and ethyl acetate as entrainer2Extraction, pressure is extraction under the conditions of 20~30MPa, 45~50 DEG C of temperature；Then separated in knockout drum at pressure 3MPa~6MPa, 25~30 DEG C of temperature.After reclaiming ethanol and ethyl acetate through vacuum distillation, extraction oil obtains anti-oxidant papaya seed oil by adding carnosine, Tea Polyphenols and lycopene composite antioxidant after solubilising.This method extraction rate is fast, recovery rate is high, no solvent residue, and the high quality oils water activity of acquisition is low, with anti-oxidant and vegetative cell function, and water retention property and Storage are all good, can be used as in cosmetics of super quality base starting material.
Description
Technical field
The present invention relates to the production method of cosmetic oil, belong to cosmetics processing technique field.
Background technology
General principle：Papaya seed fat oil about oil-containing 30-50%, grease contains abundant trace element, and oil is by 9 kinds of fat
Fat acid composition.Based on linoleic acid, palmitic acid, oleic acid and stearic acid.Monounsaturated fatty acids content and polyunsaturated fatty acid
Saturated fatty acid content is enriched.Therefore, multiple biological activities composition is also contained in papaya seed oil, can make softness for cosmetics
Lubrication, the effect of skin nutrition cell.Lycopene can promote the growth and regeneration of cell, and beauty Eradicates wrinkles maintain skin health,
The effects such as anti-aging, skin allergy can be substantially improved, eliminate dry skin and scratchiness because caused by allergic, order
People's feeling relaxed is happy.Carnosine can be removed makes activity formed by the aliphatic acid over oxidation of cell membrane during oxidative stress
Oxygen radical（ROS）And alpha-beta unsaturated aldehyde.The effect that the aging and skin that skin can be prevented are brightened, carnosine can prevent trip
Produced from base, repair skin injury, the function with vegetative cell.
The principle of microwave treatment is to penetrate spe medium using frequency electromagnetic waves, reaches the inside for being extracted material, microwave
Heat energy can be quickly converted to and make the temperature rapid increase of cell interior.When the pressure of cell interior exceedes the ability to bear of cell
When, cell will rupture, and active ingredient is i.e. from intracellular outflow, and be dissolved in spe medium at a lower temperature.
Supercritical CO2The principle of fluid extraction separation is the relation of the solvability using supercritical fluid and its density,
Influence i.e. using pressure and temperature to supercritical fluid solvability and extract.In the supercritical state, will be overcritical
Fluid is contacted with material to be separated, make its selectively polarity size, boiling point height it is different with molecular size range into
Divide and extract successively.Certainly, the extract obtained by each pressure limit of correspondence is unlikely to be single, but can be with control condition
The blending constituent of optimal proportion is obtained, then supercritical fluid is become common gases by the method for decompression, heating, is extracted
Material is then wholly or substantially separated out, so that the purpose of separating-purifying is reached, so supercritical CO2Fluid extraction process is by extracting
Combined with separation process.Supercritical CO2The sharpest edges of fluid extraction are no solvent residues, and natural active matter is obtained
It is effectively maintained.In the present invention, ethanol and ethyl acetate are in supercritical CO2Play entrainer during fluid extraction,
Extraction efficiency can be improved.And different from general organic solvent, provide that ethanol and ethyl acetate are fair according to GB 2760-96
Perhaps the flavorant used, for cosmetics more without toxic side effect.Extraction under the conditions of 45-60 DEG C, high vacuum carry out
The recyclable ethanol of vacuum distillation and ethyl acetate obtain product.The grease extracted at the process conditions has the same of bioactivity
When, its antioxidation activity is low, easy oxidation deterioration.Carnosine, Tea Polyphenols and tomato red have extraordinary antioxygenic property, three
Also there is synergy in the presence of simultaneously, antioxidation activity is greatly improved.But carnosine and Tea Polyphenols do not dissolve in grease, kind
Lycopene is water insoluble, it is impossible to which three is directly added into grease, finds carnosine and Tea Polyphenols being dissolved in after water by studying, plus
The binary compound emulsifying agent for entering HLB value 5-6 monoglyceride and HLB value 12-15 nonionic polyoxyethylene monolaurate can
To promote lycopene to dissolve, add in grease and form the particulate of Water-In-Oil and dispersed, effect very well, then uses ultrasonic wave
Concussion is uniformly mixed so as to obtain the papaya seed oil with antioxidation activity high bioactivity, and it contains abundant nutriment, can be used as
The matrix of cosmetics.
The content of the invention
It is an object of the invention to provide a kind of production method of the cosmetic oil based on papaya seed, made up for producing
The matrix oil of product.Supercritical CO after being pre-processed by microwave radiation technology2Fluid extraction papaya seed oil, addition carnosine, Tea Polyphenols
Antioxidation activity is improved with lycopene, the active papaya seed oil of antioxidation biology of functionalization is obtained.
This method by papaya seed by drying, being crushed to after certain particle size；Add ethanol and ethyl acetate microwave radiation technology
Pretreatment, uses supercritical CO under certain process conditions afterwards2Fluid extraction vegetable oil and active ingredient, vacuum distillation are reclaimed
After ethanol and ethyl acetate, then using raising antioxidation activities such as certain method addition Tea Polyphenols, obtain with antioxidation activity
The papaya seed oil of high bioactivity.The major advantage of this method is supercritical CO at the process conditions2Obtained by fluid extraction
Papaya seed oil, bioactive substance content is high, loses small.Adding after carnosine, Tea Polyphenols and lycopene has well
Anti-oxidation characteristics, the grease produced with this method can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
The present invention is achieved by the following technical solutions.
A kind of production method of cosmetic oil based on papaya seed of the present invention, as follows：
1）By papaya seed by drying, be crushed to certain particle size.
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology.
3）Using ethanol and ethyl acetate as entrainer supercritical CO2Fluid extraction.
4）Ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Add carnosine, Tea Polyphenols and lycopene and improve anti-oxidation characteristics.
The microwave radiation technology pretreatment, refers to and is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
The supercritical CO2Fluid extraction, refers in extractor under the conditions of pressure is 20~30MPa, 45~50 DEG C of temperature
Extraction；Separated in knockout drum at pressure 3MPa~5MPa, 25~30 DEG C of temperature.
The raising inoxidizability.Refer to and carnosine and Tea Polyphenols are dissolved in distilled water, add HLB value 5-6 monoglyceride and HLB
The binary compound emulsifying agent of value 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C,
It is allowed to be completely dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the papaya seed oil obtained by extraction and quickly stir, disperse
Into uniform single-phase oily liquids, mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Matter
Amount ratio）It is not less than 0.01%, obtains the active papaya seed oil of antioxidation biology of functionalization.
Its main principle steps：1. by papaya seed by drying, be crushed to certain particle size；2. ethanol and ethyl acetate
Microwave radiation technology is pre-processed；3. carry out supercritical CO using ethanol and ethyl acetate as entrainer in certain process conditions2Fluid extracts
Take.4. ethanol and ethyl acetate are reclaimed in vacuum distillation；5. adding carnosine, Tea Polyphenols and lycopene improves anti-oxidation characteristics.With
The major advantage of this method is supercritical CO at the process conditions2Papaya seed oil obtained by fluid extraction, biological active matter
Matter content is high, loses small, adding has high anti-oxidation characteristic after carnosine, Tea Polyphenols and lycopene, improves storage phase, prevents from becoming
Matter.The grease of this method production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
Beneficial effects of the present invention：The present invention provides a kind of objectively high bioactivity cosmetics with antioxidation activity
With the production method of oil.This method can efficiently extract high activity papaya seed oil with objective, have nothing compared to solvent extraction
The characteristic of dissolvent residual, has high anti-oxidation activity by adding composite antioxidant, can be used for cosmetic base oil
Production.
Embodiment
The present invention will be described further by following examples.
Embodiment 1.
1）By papaya seed by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, Microwave Extraction reaction system is used（The SOS- of French PR OLABO companies
1100 series of products）Handled 5-10 minutes in 2450MHz.
3）Then by said mixture supercritical CO2Equipment（Guangzhou U.S. morning 300L type）Extract 3h, extraction conditions：Extraction
Pressure is extraction under the conditions of 25MPa, 45~50 DEG C of temperature in tank；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 40-50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C, make
Be completely dissolved, above-mentioned solution is slowly added dropwise into the 3rd）Walk in the papaya seed oil obtained by extraction and quickly stir, be dispersed into
Uniform single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Quality
Than）It is not less than 0.01%, obtains the active papaya seed oil of antioxidation biology of functionalization.
Embodiment 2.
1）By papaya seed by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, Microwave Extraction reaction system is used（The SOS- of French PR OLABO companies
1100 series of products）Handled 8 minutes in 2450MHz.
3）Then by said mixture supercritical CO2Equipment（Guangzhou U.S. morning 300L type）Extract 2h, extraction conditions：Extraction
Pressure is extraction under the conditions of 25MPa, temperature 45 C in tank；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 40 DEG C, be allowed to
Fully dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the papaya seed oil obtained by extraction and quickly stir, be dispersed into uniform
Single-phase oily liquids, mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）No
Less than 0.3%, the active papaya seed oil of antioxidation biology of functionalization is obtained.
Claims (1)
1. a kind of production method of the cosmetic oil based on papaya seed, its characterization step is as follows：
（1）By papaya seed by drying, be crushed to certain particle size；
（2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology：Appropriate ethanol and acetic acid second are added in the papaya seed of crushing
Ester, Microwave Pretreatment 3-10 minutes, makes breaking-wall cell；
（3）Supercritical extract papaya seed oil：By step（2）The mixture of gained is used using ethanol and ethyl acetate as entrainer
Supercritical CO2With extraction under the conditions of 20~30MPa of pressure, 45~50 DEG C of temperature in extractor；Then in knockout drum with
Separated at pressure 3MPa~4MPa, 25~30 DEG C of temperature；
（4）By step（3）Grease is obtained, at 45-60 DEG C, pumping high vacuum carries out vacuum distillation and reclaims removing ethanol and acetic acid second
Ester, obtains papaya seed oil；
（5）Improve inoxidizability：Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value 12-15 is added
Nonionic polyoxyethylene monolaurate binary compound emulsifying agent, add lycopene heat 30-40 DEG C, be allowed to complete
Dissolving, above-mentioned solution is slowly added dropwise into step（4）Stir in papaya seed oil obtained by extraction and quickly, be dispersed into uniform
Single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene mass ratio of total content in grease is not low
In 0.01%, the active papaya seed oil of antioxidation biology of functionalization is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250920.2A CN107022408A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on papaya seed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250920.2A CN107022408A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on papaya seed |
Publications (1)
| Publication Number | Publication Date |
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| CN107022408A true CN107022408A (en) | 2017-08-08 |
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ID=59526530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710250920.2A Withdrawn CN107022408A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on papaya seed |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611182A (en) * | 2018-06-29 | 2018-10-02 | 成都纺织高等专科学校 | A kind of supercritical CO2Extract the method and system of Boxthorn Seed Oil |
-
2017
- 2017-04-18 CN CN201710250920.2A patent/CN107022408A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611182A (en) * | 2018-06-29 | 2018-10-02 | 成都纺织高等专科学校 | A kind of supercritical CO2Extract the method and system of Boxthorn Seed Oil |
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