CN106987308A - A kind of production method of the cosmetic oil based on almond - Google Patents
A kind of production method of the cosmetic oil based on almond Download PDFInfo
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- CN106987308A CN106987308A CN201710251051.5A CN201710251051A CN106987308A CN 106987308 A CN106987308 A CN 106987308A CN 201710251051 A CN201710251051 A CN 201710251051A CN 106987308 A CN106987308 A CN 106987308A
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- CN
- China
- Prior art keywords
- ethyl acetate
- almond
- ethanol
- extraction
- apricot kernel
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/12—Refining fats or fatty oils by distillation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0085—Substances of natural origin of unknown constitution, f.i. plant extracts
Abstract
A kind of production method of the cosmetic oil based on almond, belongs to cosmetics processing technique field.The present invention by almond by drying, be crushed to certain particle size；Add after ethanol and the pretreatment of ethyl acetate microwave radiation technology, supercritical CO is carried out using ethanol and ethyl acetate as entrainer2Extraction, pressure is extraction under the conditions of 20~30MPa, 45~50 DEG C of temperature；Then separated in knockout drum at pressure 3MPa~6MPa, 25~30 DEG C of temperature.After reclaiming ethanol and ethyl acetate through vacuum distillation, extraction oil obtains anti-oxidant apricot kernel oil by adding carnosine, Tea Polyphenols and lycopene composite antioxidant after solubilising.Extraction rate of the present invention is fast, recovery rate is high, no solvent residue, and the high quality oils water activity of acquisition is low, with anti-oxidant and vegetative cell function, and water retention property and Storage are all good, can be used as in cosmetics of super quality base starting material.
Description
Technical field
The invention belongs to cosmetics processing technique field, it is related to the production method of cosmetic oil.
Background technology
General principle：Almond be divided into it is a variety of, wherein, wild apricot almond fat oil about 30-50% has a variety of aliphatic acid in oil, main
What is wanted is linoleic acid, oleic acid and palmitic acid.Also contain chlorogenic acid, neochlorogenic acid, 3'- feruloylquinic acids, and volatile oil, wherein
Main component has：Trans -2- olefine aldehydrs, under alcohol, trans -2- alkene -1- alcohol, linalool, a- terpinols, tetradecanoic acid etc.
Deng.Almond antitumor action can enter blood mainly due to a kind of bioactive substance -- amarogentin is contained in semen armeniacae amarae
The special killing cancer cell of liquid, and healthy cell is not acted on, therefore the symptom of patients with advanced cancer, extension patient's existence can be improved
Phase.Simultaneously as containing abundant carrotene, free radical invasion cell is prevented, the effect with pre- preventing tumor.Therefore, almond
Contain multiple biological activities composition in oil, for cosmetics can make soft lubrication, skin nutrition cell effect.Lycopene energy
Promote the growth and regeneration of cell, beauty Eradicates wrinkles, the effects such as maintaining skin health, anti-aging can substantially improve allergic
Disease, eliminates dry skin and scratchiness because caused by allergic, makes us feeling relaxed happy.Carnosine can be removed should in oxidation
Make active oxygen radical formed by the aliphatic acid over oxidation of cell membrane during swashing（ROS）And alpha-beta unsaturated aldehyde.Can be with
The effect that the aging and skin for preventing skin are brightened, carnosine can prevent free radical from producing, and skin injury be repaired, with vegetative cell
Function.
The principle of microwave treatment is to penetrate spe medium using frequency electromagnetic waves, reaches the inside for being extracted material, microwave
Heat energy can be quickly converted to and make the temperature rapid increase of cell interior.When the pressure of cell interior exceedes the ability to bear of cell
When, cell will rupture, and active ingredient is i.e. from intracellular outflow, and be dissolved in spe medium at a lower temperature.
Supercritical CO2The principle of fluid extraction separation is the relation of the solvability using supercritical fluid and its density,
Influence i.e. using pressure and temperature to supercritical fluid solvability and extract.In the supercritical state, will be overcritical
Fluid is contacted with material to be separated, make its selectively polarity size, boiling point height it is different with molecular size range into
Divide and extract successively.Certainly, the extract obtained by each pressure limit of correspondence is unlikely to be single, but can be with control condition
The blending constituent of optimal proportion is obtained, then supercritical fluid is become common gases by the method for decompression, heating, is extracted
Material is then wholly or substantially separated out, so that the purpose of separating-purifying is reached, so supercritical CO2Fluid extraction process is by extracting
Combined with separation process.Supercritical CO2The sharpest edges of fluid extraction are no solvent residues, and natural active matter is obtained
It is effectively maintained.In the present invention, ethanol and ethyl acetate are in supercritical CO2Play entrainer during fluid extraction,
Extraction efficiency can be improved.And different from general organic solvent, provide that ethanol and ethyl acetate are fair according to GB 2760-96
Perhaps the flavorant used, for cosmetics more without toxic side effect.Extraction under the conditions of 45-60 DEG C, high vacuum carry out
The recyclable ethanol of vacuum distillation and ethyl acetate obtain product.The grease extracted at the process conditions has the same of bioactivity
When, its antioxidation activity is low, easy oxidation deterioration.Carnosine, Tea Polyphenols and tomato red have extraordinary antioxygenic property, three
Also there is synergy in the presence of simultaneously, antioxidation activity is greatly improved.But carnosine and Tea Polyphenols do not dissolve in grease, kind
Lycopene is water insoluble, it is impossible to which three is directly added into grease, finds carnosine and Tea Polyphenols being dissolved in after water by studying, plus
The binary compound emulsifying agent for entering HLB value 5-6 monoglyceride and HLB value 12-15 nonionic polyoxyethylene monolaurate can
To promote lycopene to dissolve, add in grease and form the particulate of Water-In-Oil and dispersed, effect very well, then uses ultrasonic wave
Concussion is uniformly mixed so as to obtain the apricot kernel oil with antioxidation activity high bioactivity, and it contains abundant nutriment, can be used as making up
The matrix of product.
The content of the invention
It is an object of the invention to provide a kind of production method of the cosmetic oil based on almond, for producing cosmetics
Matrix oil.Supercritical CO after being pre-processed by microwave radiation technology2Fluid extraction apricot kernel oil, addition carnosine, Tea Polyphenols and tomato red
Element improves antioxidation activity, obtains the active apricot kernel oil of antioxidation biology of functionalization.
This method by almond by drying, being crushed to after certain particle size；Add ethanol and ethyl acetate microwave radiation technology is located in advance
Reason, uses supercritical CO under certain process conditions afterwards2Ethanol is reclaimed in fluid extraction vegetable oil and active ingredient, vacuum distillation
Antioxidation activity is improved after ethyl acetate, then using certain method addition Tea Polyphenols etc., is obtained with antioxidation activity Gao Sheng
The apricot kernel oil of thing activity.The major advantage of this method is supercritical CO at the process conditions2Apricot kernel oil obtained by fluid extraction,
Bioactive substance content is high, loses small.Adding has good anti-oxidation characteristics after carnosine, Tea Polyphenols and lycopene, use
The grease of this method production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
The present invention is achieved by the following technical solutions.
A kind of production method of cosmetic oil based on almond of the present invention, as follows.
1）By almond by drying, be crushed to certain particle size.
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology.
3）Using ethanol and ethyl acetate as entrainer supercritical CO2Fluid extraction.
4）Ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Add carnosine, Tea Polyphenols and lycopene and improve anti-oxidation characteristics.
The microwave radiation technology pretreatment, refers to and is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
The supercritical CO2Fluid extraction, refers in extractor under the conditions of pressure is 20~30MPa, 45~50 DEG C of temperature
Extraction；Separated in knockout drum at pressure 3MPa~5MPa, 25~30 DEG C of temperature.
The raising inoxidizability.Refer to and carnosine and Tea Polyphenols are dissolved in distilled water, add HLB value 5-6 monoglyceride and HLB
The binary compound emulsifying agent of value 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C,
It is allowed to be completely dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the apricot kernel oil obtained by extraction and quickly stir, be dispersed into
Even single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）
It is not less than 0.1%, obtains the active apricot kernel oil of antioxidation biology of functionalization.
Its main principle steps：1. by almond by drying, be crushed to certain particle size；2. ethanol and ethyl acetate microwave
Auxiliary pretreatment；3. carry out supercritical CO using ethanol and ethyl acetate as entrainer in certain process conditions2Fluid extraction.4.
Ethanol and ethyl acetate are reclaimed in vacuum distillation；5. adding carnosine, Tea Polyphenols and lycopene improves anti-oxidation characteristics.Use this method
Major advantage be supercritical CO at the process conditions2Apricot kernel oil obtained by fluid extraction, bioactive substance content is high, damages
Mistake is small, and adding has high anti-oxidation characteristic after carnosine, Tea Polyphenols and lycopene, improves storage phase, prevents from going bad.This method is given birth to
The grease of production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
Beneficial effects of the present invention：The present invention provides a kind of objectively high bioactivity cosmetics with antioxidation activity
With the production method of oil.This method can efficiently extract high activity apricot kernel oil with objective, have compared to solvent extraction solvent-free
The characteristic of residual, has high anti-oxidation activity by adding composite antioxidant, can be used for the production of cosmetic base oil.
Embodiment
The present invention will be described further by following examples.
Microwave Extraction reaction system used in the embodiment of the present invention is the SOS-1100 series of products of French PR OLABO companies,
Supercritical CO2Equipment is the U.S. morning 300L type in Guangzhou.
Embodiment 1.
1）By almond by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then by said mixture supercritical CO2Equipment extracts 3h, extraction conditions：Pressure is 25MP in extractor
Extracted under the conditions of a, 45~50 DEG C of temperature；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 40-50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C, make
Be completely dissolved, above-mentioned solution is slowly added dropwise into the 3rd）Walk in the apricot kernel oil obtained by extraction and quickly stir, be dispersed into uniform
Single-phase oily liquids, mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）No
Less than 0.1%, the active apricot kernel oil of antioxidation biology of functionalization is obtained.
Embodiment 2.
1）By almond by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 8 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then by said mixture supercritical CO2Equipment extracts 2h, extraction conditions：Pressure is 25MP in extractor
Extracted under the conditions of a, temperature 45 C；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5) inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 40 DEG C, be allowed to
Fully dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the apricot kernel oil obtained by extraction and quickly stir, be dispersed into uniform list
Phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）It is not less than
0.3%, obtain the active apricot kernel oil of antioxidation biology of functionalization.
Claims (1)
1. a kind of production method of the cosmetic oil based on almond, it is characterized in that as follows：
1）By almond by drying, be crushed to certain particle size；
2）Appropriate ethanol and ethyl acetate is added in the almond of crushing, Microwave Pretreatment 3-10 minutes makes breaking-wall cell；
3）By step（2）The mixture of gained uses supercritical CO using ethanol and ethyl acetate as entrainer2With pressure in extractor
Extracted under the conditions of 20~30MPa of power, 45~50 DEG C of temperature；Then with pressure 3MPa~4MPa, temperature in knockout drum
Separated at 25~30 DEG C；
4）By step（3）Grease is obtained, at 45-60 DEG C, pumping high vacuum carries out vacuum distillation and reclaims removing ethanol and ethyl acetate,
Obtain apricot kernel oil；
5）Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value 12-15 non-ionic polyoxy is added
The binary compound emulsifying agent of ethene monolaurate, adds lycopene and heats 30-40 DEG C, be allowed to be completely dissolved, will be above-mentioned molten
Liquid is slowly added dropwise into step（4）Stir in apricot kernel oil obtained by extraction and quickly, be dispersed into uniform single-phase oily liquids, with super
Sound wave shock is mixed；Carnosine, Tea Polyphenols and the lycopene mass ratio of total content in grease are not less than 0.1%, obtain functionalization
The active apricot kernel oil of antioxidation biology.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251051.5A CN106987308A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on almond |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251051.5A CN106987308A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on almond |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106987308A true CN106987308A (en) | 2017-07-28 |
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ID=59415198
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710251051.5A Withdrawn CN106987308A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on almond |
Country Status (1)
| Country | Link |
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| CN (1) | CN106987308A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115154374A (en) * | 2022-08-05 | 2022-10-11 | 完美（广东）日用品有限公司 | High-efficiency almond oil for cosmetics as well as preparation method and application thereof |
| WO2023172982A3 (en) * | 2022-03-08 | 2023-11-09 | Trade Secret Chocolates | Systems and methods for rehabilitating alcohol compositions and naturally fermentable herbs |
-
2017
- 2017-04-18 CN CN201710251051.5A patent/CN106987308A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023172982A3 (en) * | 2022-03-08 | 2023-11-09 | Trade Secret Chocolates | Systems and methods for rehabilitating alcohol compositions and naturally fermentable herbs |
| CN115154374A (en) * | 2022-08-05 | 2022-10-11 | 完美（广东）日用品有限公司 | High-efficiency almond oil for cosmetics as well as preparation method and application thereof |
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Application publication date: 20170728 |
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