CN107164054A - 一种金属磨削油及其制备方法 - Google Patents
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- 239000002184 metal Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims description 5
- 239000003921 oil Substances 0.000 claims abstract description 33
- 238000000227 grinding Methods 0.000 claims abstract description 16
- 239000002199 base oil Substances 0.000 claims abstract description 11
- 239000003595 mist Substances 0.000 claims abstract description 11
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 239000002530 phenolic antioxidant Substances 0.000 claims abstract description 10
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
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- 101100006584 Mus musculus Clnk gene Proteins 0.000 claims description 10
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- 238000003756 stirring Methods 0.000 description 7
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- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
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- -1 oleic acid glycol ester Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
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- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- OSPSWZSRKYCQPF-UHFFFAOYSA-N dibutoxy(oxo)phosphanium Chemical compound CCCCO[P+](=O)OCCCC OSPSWZSRKYCQPF-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000008130 triterpenoid saponins Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开一种金属磨削油，每100份磨削油由如下重量份的组分制成：两性聚醚消泡剂0.05‑0.2，路博润生产的ADDTAC油雾抑制剂0.5‑1.5，巴斯夫IRGANOX L135酚类抗氧剂0.5‑1.5，雅富顿POLARTECH XP 9530A润滑剂4‑5.5，60N基础油余量。与现有技术相比，本发明组分简单，成本低廉，性能指标符合国家标准。
Description
技术领域
本发明涉及金属加工液，具体是一种金属磨削油及其制备方法。
背景技术
传统的磨削油能够在磨轮和工件接触面上形成一种抗积压性能很强的油膜，减少工件和磨轮的摩擦，从而降低摩擦生热。
公开号为CN105838487A的发明专利公开了一种低油雾磨削油，由以下重量份的原料制备而成的：基础油精制15号工业白油70-80份、高分子聚合物5-20份、油酸乙二醇酯5-10份、抗氧化剂1-10份、防锈剂5-20份、抗磨剂亚磷酸二正丁酯1-5份和降凝剂烷基萘0.1-2份。
公开号为CN105838486A的发明专利公开了一种用于高硬度复合材料加工的磨削油，由以下重量份的原料制备而成的：26#白矿油57-60、苯并三氮唑2-4、六甲基磷酰胺0.4-0.7、二烷基二硫代磷酸锌5-7、三萜皂苷0.1-0.2、正硅酸乙酯1-2、癸二酸0.5-0.8、气相白炭黑0.3-1、氢氧化锂1.0-2.5、碳酸钙0.15-0.3、苯甲酸锌0.01-0.03、中性二壬基萘磺酸钡17-18、二苯胺13-14、甲基硫醇锡0.01-0.02、木杂酚油2-3、三压硬脂酸10-15、二甲基硅油0.1-0.13。
这两件专利的主要成分都是工业级白油，而白油是从基础油经过提纯、加氢饱和的正构窄馏分生产出来的，虽然运动粘度较小，但综合使用成本较高。
发明内容
本发明的目的是克服现有技术的不足，提供一种综合成本较低的磨削油。所采取的技术方案是：
这种金属磨削油，每100份磨削油由如下重量份的组分制成：
60N基础油 余量
两性聚醚消泡剂 0.05-0.2
路博润生产的ADDTAC油雾抑制剂 0.5-1.5
巴斯夫IRGANOX L135酚类抗氧剂 0.5-1.5
雅富顿POLARTECH XP 9530 A润滑剂 4-5.5。
进一步的优选方案是：
60N基础油 95.15
两性聚醚消泡剂 0.05
路博润生产的ADDTAC油雾抑制剂 0.5
巴斯夫IRGANOX L135酚类抗氧剂 0.5
雅富顿POLARTECH XP 9530 A润滑剂 4。
本发明还公开这种金属磨削油的制备方法，包含如下步骤：
(1)将60N基础油加入到调和釜中，升温至45℃；
(2)将油雾抑制剂、酚类抗氧剂加入混合，搅拌15分钟；
(3)将润滑剂加入混合，搅拌5分钟；
(4)最后加入消泡剂并不断搅拌至常温，过滤后得到磨削油。
与现有技术相比，本发明组分简单，成本低廉，性能指标符合国家标准。
具体实施方式
实施例1：
将60N基础油949公斤加入到调和釜中，升温至45℃；将5公斤路博润生产的ADDTAC油雾抑制剂、5公斤巴斯夫IRGANOX L135酚类抗氧剂加入混合，搅拌5分钟；将40公斤雅富顿POLART ECH XP 9530 A润滑剂加入混合，搅拌8分钟；最后加入1公斤两性聚醚消泡剂并不断搅拌至常温，过滤后得到磨削油。
实施例2：
将60N基础油934公斤加入到调和釜中，升温至45℃；将15公斤路博润生产的ADDTAC油雾抑制剂、10公斤巴斯夫IRGANOX L135酚类抗氧剂加入混合，搅拌5分钟；将40公斤雅富顿POLART ECH XP 9530A润滑剂加入混合，搅拌10分钟；最后加入1公斤两性聚醚消泡剂并不断搅拌至常温，过滤后得到磨削油。
实施例3：
将60N基础油934公斤加入到调和釜中，升温至45℃；将10公斤路博润生产的ADDTAC油雾抑制剂、10公斤巴斯夫IRGANOX L135酚类抗氧剂加入混合，搅拌15分钟；将45公斤雅富顿POLAR TECH XP 9530 A润滑剂加入混合，搅拌10分钟；最后加入1公斤两性聚醚消泡剂并不断搅拌至常温，过滤后得到磨削油。
对实施例1-3的磨削油进行性能测试，结果如下：
运动粘度反映油品沉降性，闪点反映油品安全性，最大无卡咬负荷反映油品抗磨性，从上表可以看出，本发明生产法的磨削油完全达到国家标准，但成本仅为现有磨削油的一半左右，且铅、锡等有害物质含量符合美国金属加工或金属切削液卫生与安全性标准，因此在环保方面完全达到或超过国内标准。
Claims (3)
1.一种金属磨削油，其特征在于每100份磨削油由如下重量份的组分制成：
60N基础油 余量
两性聚醚消泡剂0.05-0.2
路博润生产的ADDTAC油雾抑制剂0.5-1.5
巴斯夫IRGANOX L135酚类抗氧剂0.5-1.5
雅富顿POLARTECH XP 9530A润滑剂4-5.5。
2.根据权利要求1所述的一种金属磨削油，其特征在于每100份磨削油由如下重量份的组分制成：
60N基础油95.15
两性聚醚消泡剂0.05
路博润生产的ADDTAC油雾抑制剂0.5
巴斯夫IRGANOX L135酚类抗氧剂0.5
雅富顿POLARTECH XP 9530A润滑剂4。
3.权利要求1或2所述的一种金属磨削油的制备方法，其特征在于包含如下步骤：
(1)将60N基础油加入到调和釜中，升温至45℃；
(2)将油雾抑制剂、酚类抗氧剂加入混合，搅拌15分钟；
(3)将润滑剂加入混合，搅拌5分钟；
(4)最后加入消泡剂并不断搅拌至常温，过滤后得到磨削油。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982597A (zh) * | 2019-12-11 | 2020-04-10 | 富兰克润滑科技（太仓）有限公司 | 一种提升冷却性能的电子产品不锈钢零件切削油及方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701163A (zh) * | 2009-09-29 | 2010-05-05 | 武汉玻尔科技有限公司 | 一种低油雾齿轮磨削油组合物 |
| CN101717684A (zh) * | 2009-11-20 | 2010-06-02 | 东莞市安默琳节能环保技术有限公司 | 用于金属材料切削加工的喷雾供给方式切削油 |
| CN106560507A (zh) * | 2016-10-18 | 2017-04-12 | 深圳市宇田润滑剂有限公司 | 一种环境友好型极压切削油的制备方法 |
| CN106635291A (zh) * | 2016-09-21 | 2017-05-10 | 广西大学 | 环境友好普通碳素结构钢镗削加工切削液的组合物 |
| CN109504506A (zh) * | 2018-12-06 | 2019-03-22 | 汎宇化学（昆山）有限公司 | 非水溶性切削油及其制备方法 |
-
2017
- 2017-05-24 CN CN201710371649.8A patent/CN107164054A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101701163A (zh) * | 2009-09-29 | 2010-05-05 | 武汉玻尔科技有限公司 | 一种低油雾齿轮磨削油组合物 |
| CN101717684A (zh) * | 2009-11-20 | 2010-06-02 | 东莞市安默琳节能环保技术有限公司 | 用于金属材料切削加工的喷雾供给方式切削油 |
| CN106635291A (zh) * | 2016-09-21 | 2017-05-10 | 广西大学 | 环境友好普通碳素结构钢镗削加工切削液的组合物 |
| CN106560507A (zh) * | 2016-10-18 | 2017-04-12 | 深圳市宇田润滑剂有限公司 | 一种环境友好型极压切削油的制备方法 |
| CN109504506A (zh) * | 2018-12-06 | 2019-03-22 | 汎宇化学（昆山）有限公司 | 非水溶性切削油及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982597A (zh) * | 2019-12-11 | 2020-04-10 | 富兰克润滑科技（太仓）有限公司 | 一种提升冷却性能的电子产品不锈钢零件切削油及方法 |
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