CN107162040B - 饲料用氧化锌的生产方法 - Google Patents
饲料用氧化锌的生产方法 Download PDFInfo
- Publication number
- CN107162040B CN107162040B CN201710465666.8A CN201710465666A CN107162040B CN 107162040 B CN107162040 B CN 107162040B CN 201710465666 A CN201710465666 A CN 201710465666A CN 107162040 B CN107162040 B CN 107162040B
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- CN
- China
- Prior art keywords
- zinc oxide
- solution
- zinc
- feed
- production method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 35
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 33
- 239000000047 product Substances 0.000 claims abstract description 22
- 239000011701 zinc Substances 0.000 claims abstract description 22
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 21
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 21
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 10
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 10
- 239000013067 intermediate product Substances 0.000 claims abstract description 6
- 239000012535 impurity Substances 0.000 claims description 34
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 32
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 32
- 229960001763 zinc sulfate Drugs 0.000 claims description 29
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims description 24
- 238000001354 calcination Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 239000011667 zinc carbonate Substances 0.000 claims description 7
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 235000004416 zinc carbonate Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 23
- 229910052725 zinc Inorganic materials 0.000 abstract description 18
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000010792 warming Methods 0.000 description 8
- 230000001376 precipitating effect Effects 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910052793 cadmium Inorganic materials 0.000 description 6
- 229910052745 lead Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000004781 supercooling Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000001142 anti-diarrhea Effects 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 2
- 229940007718 zinc hydroxide Drugs 0.000 description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 2
- 239000007832 Na2SO4 Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- ONIOAEVPMYCHKX-UHFFFAOYSA-N carbonic acid;zinc Chemical compound [Zn].OC(O)=O ONIOAEVPMYCHKX-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/20—Inorganic substances, e.g. oligoelements
- A23K20/30—Oligoelements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K50/00—Feeding-stuffs specially adapted for particular animals
- A23K50/30—Feeding-stuffs specially adapted for particular animals for swines
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K50/00—Feeding-stuffs specially adapted for particular animals
- A23K50/60—Feeding-stuffs specially adapted for particular animals for weanlings
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Birds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201710465666.8A CN107162040B (zh) | 2017-06-19 | 2017-06-19 | 饲料用氧化锌的生产方法 |
Applications Claiming Priority (1)
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CN201710465666.8A CN107162040B (zh) | 2017-06-19 | 2017-06-19 | 饲料用氧化锌的生产方法 |
Publications (2)
Publication Number | Publication Date |
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CN107162040A CN107162040A (zh) | 2017-09-15 |
CN107162040B true CN107162040B (zh) | 2019-01-04 |
Family
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Family Applications (1)
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CN201710465666.8A Active CN107162040B (zh) | 2017-06-19 | 2017-06-19 | 饲料用氧化锌的生产方法 |
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CN (1) | CN107162040B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108185151A (zh) * | 2018-02-12 | 2018-06-22 | 广州科城环保科技有限公司 | 一种饲料级氧化锌及其制备方法 |
CN110903206A (zh) * | 2019-12-20 | 2020-03-24 | 上海永通生态工程股份有限公司 | 甲基甘氨酸二乙酸锌、甲基甘氨酸二乙酸锰及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1590302A (zh) * | 2003-08-29 | 2005-03-09 | 中国科学院过程工程研究所 | 一种制备具有高电导率的超细氧化锌粉体的共沉淀方法 |
CN103880063A (zh) * | 2014-03-14 | 2014-06-25 | 玉门市新蓝天金属再生利用有限公司 | 湿化学法制取高纯度活性氧化锌 |
CN105236467A (zh) * | 2014-08-01 | 2016-01-13 | 阜阳师范学院 | 一种大量制备纳米氧化锌的工艺及其应用 |
-
2017
- 2017-06-19 CN CN201710465666.8A patent/CN107162040B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1590302A (zh) * | 2003-08-29 | 2005-03-09 | 中国科学院过程工程研究所 | 一种制备具有高电导率的超细氧化锌粉体的共沉淀方法 |
CN103880063A (zh) * | 2014-03-14 | 2014-06-25 | 玉门市新蓝天金属再生利用有限公司 | 湿化学法制取高纯度活性氧化锌 |
CN105236467A (zh) * | 2014-08-01 | 2016-01-13 | 阜阳师范学院 | 一种大量制备纳米氧化锌的工艺及其应用 |
Non-Patent Citations (4)
Title |
---|
氧化锌矿制备饲料级氧化锌新工艺研究;田伟军等;《科技动态》;20071231;第32-34页 |
沉淀法制备ZnO超细粉及其对乙醇气敏性研究;曹建明;《化工新型材料》;20041231;第32卷(第12期);第44-46页 |
活性ZnO的制备及其表征;龚晓钟等;《合成化学》;20041231;第12卷;第259-305页 |
直接沉淀法制备ZnO超细粉末及其性质测定;曹建明;《广州化学》;20050331;第30卷(第1期);第5-11页 |
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Publication number | Publication date |
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CN107162040A (zh) | 2017-09-15 |
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Address after: 618300, Deyang City, Sichuan province Guanghan City goldfish town cold water village Patentee after: Sichuan jilongda Biotechnology Group Co.,Ltd. Address before: 618300 Sichuan city of Deyang Province Jin Xing Lu goldfish town of Guanghan City, No. 11 Patentee before: GUANGHAN LONGDA FEED Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Production method of zinc oxide for feed Effective date of registration: 20220629 Granted publication date: 20190104 Pledgee: Guanghan Sichuan rural commercial bank Limited by Share Ltd. Pledgor: Sichuan jilongda Biotechnology Group Co.,Ltd. Registration number: Y2022980009395 |
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Date of cancellation: 20230609 Granted publication date: 20190104 Pledgee: Guanghan Sichuan rural commercial bank Limited by Share Ltd. Pledgor: Sichuan jilongda Biotechnology Group Co.,Ltd. Registration number: Y2022980009395 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Production method of zinc oxide for feed Effective date of registration: 20230612 Granted publication date: 20190104 Pledgee: Guanghan Sichuan rural commercial bank Limited by Share Ltd. Pledgor: Sichuan jilongda Biotechnology Group Co.,Ltd. Registration number: Y2023510000145 |
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