CN107157789A - Isolate harm ray make-up composition - Google Patents

Isolate harm ray make-up composition Download PDF

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Publication number
CN107157789A
CN107157789A CN201710109843.9A CN201710109843A CN107157789A CN 107157789 A CN107157789 A CN 107157789A CN 201710109843 A CN201710109843 A CN 201710109843A CN 107157789 A CN107157789 A CN 107157789A
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CN
China
Prior art keywords
composition
make
isolation
light
harm ray
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Pending
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CN201710109843.9A
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Chinese (zh)
Inventor
尹慧仁
金享俊
朴贞银
蔡秉根
金善暎
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Amore Pacific Ltd By Share Ltd
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Amore Pacific Ltd By Share Ltd
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Priority claimed from KR1020170023924A external-priority patent/KR20170101799A/en
Application filed by Amore Pacific Ltd By Share Ltd filed Critical Amore Pacific Ltd By Share Ltd
Publication of CN107157789A publication Critical patent/CN107157789A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4966Triazines or their condensed derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27Zinc; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/411Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Isolate harm ray make-up composition the invention discloses one kind, in more detail, be related to isolation purple light and the effective make-up composition of blue light.The make-up composition of the present invention isolates composition as active ingredient including organic uv, is capable of the light of the blue region of the special purple light for isolating the 380~430nm for being difficult to isolate in the prior art and 430~500nm, so as to protect skin.

Description

Isolate harm ray make-up composition
Technical field
The present invention relates to isolation harm ray make-up composition, in more detail, be related to has to isolation purple light and blue light The make-up composition of effect.
Background technology
In general, " light " described in us refer to human eye in various electromagnetic waves it can be seen that visible ray (380~ 780nm).Generally, blue light (Blue light) refer to wavelength be 380~500nm human eye it can be seen that visible ray, i.e. arrive Light medium wavelength up to retina is most short and energy most strong light, more specifically, divides into 380~430nm regions for purple light (Violet light), 430~500nm regions are blue light (Blue light).
The influence that the light (such as visible ray) of other wavelength outside ultraviolet is caused to the skin of people is almost undisclosed, but Investigating the harmfulness of purple light and blue light to skin recently.
On this, according to paper (the THE JOURNAL OF BIOLOGICAL CHEMISTRY once delivered Vol.280, No.22, Issue of June 3, pp.21061-21066,2005 " Blue Light Induces Mitochondrial DNA Damage and Free Radical Production in Epithelial Cell ") middle finger The mitochondrial DNA of epithelial cell can be damaged and generate active oxygen (ROS) by going out blue light, cause cell dysfunction, cell senescence and The generation of tumour.
Also, other papers (Journal of Investigative Dermatology (2010) 130,259~269 " Blue-Light Irradiation Regulates Proliferation and Differentiation in Human Skin Cells ") in also indicate that the light of 412~453nm wavelength can control keratinocyte (Keratinocytes) and skin The propagation of middle endothelial cell (Skin-derived endothelial cell) and differentiation, another paper (PLoS One.2013Sep 17;8(9)e73678″Violet Light Down-Regulates the Expression of Specific Differentiation Markers through Rhodopsin inNormal Human Epidermal Keratinocytes ") point out that purple light in blue region (410nm) can cause the keratinocyte of skin (Keratinocytes) the mRNA overexpressions of the rhodopsin in the photoreceptor of expression, reduce CREB (cAMP Responsive element-binding protein) phosphorylation, the differentiation mark for reducing specific horn cell is Keratin-10 (K10) and Keratin-1 (K1) mRNA expression levels, reduce human keratinous formation cell (Keratinocytes) differentiation, postpones the recovery of damaged skin barrier.
In addition to influence of the published blue light to skin, blue light can also suppress the epiphysin of guiding sleep (Melatonin) secretory volume, increase makes one the secretory volume of the thrombocytin (Serotonin) of awakening, triggers sleep-disorder, and The generation of retina and stimulation melanin (Melanin) is directly reached, the reason for as obscure skin, long spot is caused.
Especially, this purple light and blue light are more is present in as the smart mobile phone of modern's necessity, notebook computer, shows Show in the light-emitting diode display and LED illumination of device etc., therefore can not avoid being in contact with it in the living environment of modern society, therefore examination Figure is isolated from many aspects.But, it is this to attempt, any blue light isolation for isolating composition on ultraviolet is not yet disclosed The content of effect, therefore the present inventor passes through long-term research, finds the particular combination of ultraviolet isolation composition to isolation blue light Effectively, therefore the present invention is proposed.
The content of the invention
Solar energy mainly comes the earth in the form of electromagnetic wave (Electricity magnetic Gas ripples), the electromagnetic wave according to wavelength length, according to It is secondary to include the radioactive ray of all wavelengths such as radio wave, very high frequency(VHF), infrared ray, visible ray, ultraviolet, X-ray and gamma-rays.For Focus is all concentrated on prevention by sun-proof (Sunscreen) product of major part protected skin from sunshine (solar energy) and developed Skin damage caused by UVB regions (290~320nm) and UVA regions (320~400nm).But sunshine middle-ultraviolet lamp is occupied Proportion it is less, the visible ray in the region outside ultraviolet included by sunshine, the especially indigo plant with 380~500nm wavelength Light and violet region can most cause skin damage.Accordingly, an object of the invention is offer one kind can isolate except ultraviolet it Outside, the isolation harm ray make-up composition of the blue violet light for the visible region being harmful to skin is belonged to.
Specifically, the present invention provides a kind of isolation harm ray make-up composition, including double-ethyl hexyl oxy phenol first Oxygen phenyl triazine (Bis-Ethylhexyloxypheno Methoxyphenyl Triazine) and lignocaine oxybenzene formoxyl Hexyl-benzoate (Diethylamino Hydroxybenzoyl Hexyl Benzoate).
It can also be added including zinc oxide (Zinc Oxide in the combination:ZnO).
Preferably, counted using make-up composition gross weight as 100wt%, include 1~10wt% double-ethyl hexyl oxygen benzene Phenol anisyl triazine.
Preferably, counted using make-up composition gross weight as 100wt%, include 1~10wt% lignocaine oxybenzene The own ester of formylbenzoate.
Preferably, counted using make-up composition gross weight as 100wt%, include 3~15wt% zinc oxide.
Preferably, the BEMT and the lignocaine oxybenzene formoxyl The weight ratio of hexyl-benzoate is 1: 0.5~5.
Preferably, the BEMT, lignocaine oxybenzene formylbenzoate The weight ratio of own ester and zinc oxide is 1: 0.5~5: 0.5~5.
Preferably, the harm ray includes the purple light that wavelength is 380~430nm.
Preferably, the harm ray includes the blue light that wavelength is 430~500nm.
With prior art, the present invention has the advantages that:Such as be applicable the present invention make-up composition, can it is special every The blue light (Blue light) of purple light (Violet light) and 430~500nm from the 380~430nm for being difficult to isolate in the past The light in region, so as to protect skin.
Embodiment
The technical terms and scientific words used in this specification except have it is specifically defined in addition to, with skill belonging to the present invention The meaning that the those of ordinary skill in art field can be commonly understood by.Therefore, omit to technical pattern as in the past and effect The content mutually repeated.
The present invention relates to isolation harm ray make-up composition, in more detail, be related to has to isolation purple light and blue light The make-up composition of effect.Harm ray in this specification include the purple light and wavelength that wavelength is 380~430nm be 430~ 500nm blue light.
The present invention provides a kind of make-up composition, and its active ingredient is to purple light (Violet light) and blue light (Blue Light) there is the BEMT (Bis-Ethylhexyloxypheno of good isolation effect Methoxyphenyl Triazine) and Uvinul A Plus (Diethylamino Hydroxybenzoyl Hexyl Benzoate) combination.
The BEMT and the Uvinul A Plus are that have Machine ultraviolet isolates one kind of composition, belongs to the functional raw material of food pharmaceuticals safe place bulletin, the double-ethyl hexyl oxygen benzene Phenol anisyl triazine is while acting on UV-B and the organic uv isolation composition in ultraviolet light,long wave region, lignocaine hydroxyl Benzoyl hexyl-benzoate is the organic uv isolation composition to ultraviolet light,long wave with effect.
Ultraviolet can be divided into ultraviolet C (UVC), the ultraviolet that wavelength is 280~315nm that wavelength is 100~280nm B (UVB), wavelength are 315~380nm ultraviolet light,long wave (UVA), and above-mentioned organic uv, which is isolated into, to be allocated as functional cosmetic The composition of product, main isolation ultraviolet A and UV-B.
But recently, because a length of 380~430nm of visible region medium wave purple light and wavelength be 430~500nm blue light pair The harmfulness of skin is confirmed, it is intended to which developing a kind of can isolate the make-up composition of these light.
In numerous ultraviolets isolation composition, the BEMT and the diethyl are found The combination of the own ester of amino oxybenzene formylbenzoate can be effectively isolated harm ray, so as to propose the present invention.
Generally, the action principle of organic uv isolation composition is to be absorbed to the energy up to the ultraviolet of skin.When described When the use of organic uv isolation composition exceeds standard value, skin can be caused to stimulate, therefore define service limits, together When, the composition that UV-B is absorbed in the composition is more.
The BEMT and Uvinul A Plus of the present invention is having The main composition for absorbing the ultraviolet light,long wave for belonging to long wavelength region in machine ultraviolet isolation composition, therefore, with to visible region In belong to the purple light in short wavelength region and the isolation effect of blue light.
According to the present invention, BEMT can be accounted in the overall weight % of make-up composition 100 1 to 10 weight %.If the content of the BEMT is less than 1 weight %, isolate harm ray Have little effect, if more than 10 weight %, skin may be stimulated.As described above, it is contemplated that harm ray isolation effect and skin Skin, which is stimulated, to be minimized, content preferably 2 to the 7 weight %, more preferably 3 to 5 weights of the BEMT Measure %.
Also, the Uvinul A Plus can account for 1 in the overall weight % of make-up composition 100 To 10 weight %.If the content of the Uvinul A Plus is less than 1 weight %, isolate harm ray Have little effect, if more than 10 weight %, skin may be stimulated.As described above, it is contemplated that harm ray isolation effect and skin Skin, which is stimulated, to be minimized, content preferably 2 to the 7 weight %, more preferably 3 to 5 of the Uvinul A Plus Weight %.
Also, the isolation harm ray of the present invention may also include zinc oxide (Zinc Oxide with make-up composition:ZnO). The zinc oxide is one kind that inorganic UV isolates composition, can be scattered the ultraviolet of arrival skin, especially, can It is effectively isolated ultraviolet light,long wave.
If here, the zinc oxide accounts for 3 to 15 weight % in the overall weight % of make-up composition 100, it is possible to increase have Evil ray isolation effect.If the content of the zinc oxide is less than 3 weight %, harm ray isolation effect increase rate is little, if More than 15 weight %, then it may stimulate skin or produce muddy effect and be unfavorable for use feeling or attractive in appearance.As described above, it is contemplated that Improve harm ray isolation effect and prevent turbid phenomenon, content preferably 5 to the 12 weight % of the zinc oxide, more preferably 7 to 10 weight %.
The BEMT, Uvinul A Plus and zinc oxide Weight ratio be 1: 0.5 to 5: 0.5 to 5, preferably 1: 0.7 to 4: 0.7 to 4, more preferably 1: 0.8 to 2: 0.8 to 2.
If here, the BEMT and Uvinul A Plus Weight ratio less than 1: 0.5 or more than 1: 5, harm ray isolation effect can be reduced.
If also, the weight ratio of the BEMT and zinc oxide is less than 1: 0.5, can drop Low harm ray isolation effect, if more than 1: 5, skin may be stimulated or turbid phenomenon is produced.Especially, the double-ethyl hexyl Oxy phenol anisyl triazine and the weight of zinc oxide ratio then more can improve skin harm ray isolation effect closer to same amount ratio And minimal skin irritation can be made.
The isolation harm ray make-up composition of the present invention can be manufactured into any formulation generally manufactured in this area, For example, can formulation turn to solution, suspension, emulsion, paste, creams, dew, elite, foam, facial mask, soap, oil, gel, spray The variforms such as mist, powder, wax, balm, as one, can formulation turn to toner, conditioning liquid, toner, astringent lotion, breast Liquid, milky lotion, moisturizing emulsion, nutrient lotion, creams, massage cream, moisturizer, moisture frost, hand lotion, foundation cream, Essence, taste Support elite, facial mask, soap, face cleaning foam, makeup removing breast, makeup removing frost, body frost, body lotion, body oil, body beautification elite, shower cream, Suncream, sun protection gel, ultra light sun block lotion etc..
Also, the present invention make-up composition may include fatty material, organic solvent, lytic agent, concentrating agents, gelatinizing agent, Softening agent, antioxidant, suspending agent, stabilizer, foaming agent (foaming agent), aromatic, surfactant, water, ion Type or nonionic emulsifier, filler, metal ion masking agent, chelating agent, preservative agent, vitamin, interleaving agent, wetting agent, Essential oil, dyestuff, pigment, hydrophily or lipophile activating agent, lipid vesicle are commonly used to the change such as any other compositions of cosmetics The auxiliary agent generally used in cosmetic or Dermatology field.The usage amount of the auxiliary agent is cosmeceutical or Dermatology field In the amount that typically uses.
When the formulation is paste, creams or during gel, as carrier components, can be used animality oil, plant oil, Wax, paraffin, starch, bassora gum, cellulose derivative, polyethylene glycol, silicon, bentonite, silica, talcum or zinc oxide etc..
When the formulation is powder or spraying, as carrier components, moisturizing factor, talcum, silica, hydroxide can be used Aluminium, calcium silicates or polyamide powder, especially, when the formulation is spraying, can be added including chlorofluorocarbon, propane/butane Or the propellant such as dimethyl ether.
When the formulation is solution or emulsion, as carrier components, solvent, solubilizer or demulsifier, example can be used Such as water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzylalcohol, Ergol, propane diols, 1,3- butyl glycols oil, third The fatty acid ester of triol aliphatic ester, polyethylene glycol or sorbitan.
When the formulation is suspension, as carrier components, the liquid diluent such as usable water, ethanol or propane diols, Suspending agent, microcrystalline cellulose, the aluminium hydroxides such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitan ester and polyethylene glycol sorbitan ester (aluminum metahydroxide), bentonite, agar or bassora gum etc..
Below according to specific embodiment, the present invention is described in detail.But, the present invention is not limited to following implementation Example, for those of ordinary skills, can carry out various deformation or amendment in the range of the technological thought of the present invention It is obvious.
The combination recorded according to following [table 1] and [table 2], is manufactured by the method described in following examples and comparative example Go out oil-in-water (O/W) make-up composition.The content of [table 1] and [table 2] is all weight %.
【Table 1】
【Table 2】
Embodiment 1
Under conditions of 75 DEG C, organic uv interleaving agent composition, oil-phase component described in the mixing table 1 and table 2 And emulsifying agent, produce the first mixture.Here, the organic uv interleaving agent composition is using make-up composition gross weight as base Standard, Uvinul A Plus and double-ethyl hexyl oxy phenol anisyl three respectively including 4.5 weight % Piperazine.
At 75 DEG C, water-phase component is all put into after pure water and mixed, produce the second mixture.
With homogenizer (Homogenizer) make first mixture scattered and obtain put it into after aqueous dispersion it is described Second mixture, is then emulsified with homogenizer, produces oil-in-water (O/W) make-up composition.
Embodiment 2
Method same as Example 1 produces with make-up composition gross weight benchmark having containing 3 weight % respectively Machine UV-screens composition Uvinul A Plus, BEMT and Inorganic UV isolates oil-in-water (O/W) make-up composition of composition zinc oxide.
Comparative example 1
Method same as Example 1 is produced with make-up composition gross weight benchmark respectively containing 4.5 weight %'s The oil-in-water (O/W) of organic uv interleaving agent composition ethylhexyl methoxy cinnamate and Neo Heliopan E1000 is changed Composition for cosmetics.
Comparative example 2
Method same as Example 1 is produced with make-up composition gross weight benchmark respectively containing 4.5 weight %'s The oil-in-water of organic uv interleaving agent composition ethylhexyl methoxy cinnamate and BEMT (O/W) make-up composition.
Comparative example 3
Method same as Example 1 is produced with make-up composition gross weight benchmark respectively containing 4.5 weight %'s Oil-in-water (O/W) make-up composition of Neo Heliopan E1000 and Uvinul A Plus.
Comparative example 4
Method same as Example 1 is produced with make-up composition gross weight benchmark containing 9 weight % organic purple Oil-in-water (O/W) make-up composition of outside line interleaving agent composition BEMT.
Comparative example 5
Method same as Example 1 is produced with make-up composition gross weight benchmark containing 9 weight % diethylamino Oil-in-water (O/W) make-up composition of the own ester of base oxybenzene formylbenzoate.
Blue light and the test of purple light isolation effect
In order to confirm the embodiment 1,2 of the combination manufacture by the table 1 and table 2 and the make-up composition of comparative example 1~5 Blue violet light isolation effect, respectively by the formulation of embodiment and comparative example with 2mg/cm2Amount be coated in quartz or bandpass filter On, then irradiation include the light source of blue light/violet region, with SPR-4001 spectroradiometers (Spectroradiometer, Luzchem, Cancada) determine the blue violet light wavelength region (400~500nm) passed through.
[table 3] is purple light (Violet light) isolation rate and blue light (Blue light) isolation to the measure below The result of rate.
【Table 3】
Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Comparative example 5 Embodiment 1 Embodiment 2
Purple light isolation rate 0% 17% 19% 33% 38% 45% 55%
Blue light isolation rate 0% 9% 11% 18% 20% 28% 38%
With reference to the table 3, comparative example 1 first does not almost isolate the effect of purple light and blue light, comparative example 2 and comparative example 3 Numerical value show and have not been able to be effectively isolated.Although compared to comparative example 2 and comparative example 3, the isolation rate of comparative example 4 and comparative example 5 is omited There are increase, but and not up to satisfied isolation effect.
Meanwhile, embodiment 1 all increases compared to comparative example 2 to comparative example 5, purple light isolation rate and blue light isolation rate, says It is bright to improve the purpose of the present invention i.e. harm ray isolation rate on the whole.Also, compared to embodiment 1, the purple light of embodiment 2 is isolated Rate improves about 20%, and the isolation rate of blue light improves about 30%, reaches the purpose of the present invention and most effectively isolates harm ray.
Thereby confirm that with BEMT and Uvinul A Plus Be combined as neccessary composition and appropriately combined zinc oxide, it becomes possible to be effectively isolated purple light and blue light.

Claims (9)

1. one kind isolation harm ray make-up composition, it is characterised in that the composition includes:Double-ethyl hexyl oxy phenol Anisyl triazine and Uvinul A Plus.
2. isolation harm ray make-up composition according to claim 1, it is characterised in that the composition is also wrapped Include:Zinc oxide.
3. isolation harm ray make-up composition according to claim 1, it is characterised in that with make-up composition gross weight Counted for 100wt%, include 1~10wt% BEMT.
4. isolation harm ray make-up composition according to claim 1, it is characterised in that with make-up composition gross weight Counted for 100wt%, include 1~10wt% Uvinul A Plus.
5. isolation harm ray make-up composition according to claim 2, it is characterised in that with make-up composition gross weight Counted for 100wt%, include 3~15wt% zinc oxide.
6. isolation harm ray make-up composition according to claim 1, it is characterised in that the double-ethyl hexyl oxygen Phenol anisyl triazine and the weight of Uvinul A Plus ratio are 1: 0.5~5.
7. isolation harm ray make-up composition according to claim 6, it is characterised in that the double-ethyl hexyl oxygen The weight ratio of phenol anisyl triazine, Uvinul A Plus and zinc oxide be 1: 0.5~5: 0.5~ 5。
8. isolation harm ray make-up composition according to claim 1, it is characterised in that the harm ray includes Wavelength is 380~430nm purple light.
9. isolation harm ray make-up composition according to claim 1, it is characterised in that the harm ray includes Wavelength is 430~500nm blue light.
CN201710109843.9A 2016-02-29 2017-02-27 Isolate harm ray make-up composition Pending CN107157789A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20160024036 2016-02-29
KR10-2016-0024036 2016-02-29
KR10-2017-0023924 2017-02-23
KR1020170023924A KR20170101799A (en) 2016-02-29 2017-02-23 Cosmetic Composition for Harmful Rays Screening

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111787847A (en) * 2018-02-26 2020-10-16 株式会社爱茉莉太平洋 Skin change measuring device and method using blue light, and blue light irradiation device

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CN1256121A (en) * 1998-11-02 2000-06-14 Basf公司 Cosmetic or medicinal preparation containing 1,3,5-triazine derivative and zinc oxide
WO2005094769A1 (en) * 2004-02-17 2005-10-13 Basf Aktiengesellschaft Cosmetic or dermatological preparations containing a mixture of a uv-a filter, a uv-b filter, and a metal oxide
TW201110990A (en) * 2009-09-29 2011-04-01 Shiseido Co Ltd Oil-in-water type emulsion composition
KR20110072639A (en) * 2009-12-23 2011-06-29 웅진코웨이주식회사 Transparent solid-type cosmetic composition for inhibiting uv
CN102186452A (en) * 2008-10-17 2011-09-14 巴斯夫欧洲公司 Sunscreen and personal care compositions comprising a random terpolymer
CN103083203A (en) * 2013-01-30 2013-05-08 曼秀雷敦(中国)药业有限公司 Sunscreen composition and preparation method thereof
CN104921965A (en) * 2014-03-18 2015-09-23 西姆莱斯股份公司 Coated titanium dioxide to reduce whitening effect on skin
CN105534737A (en) * 2015-12-31 2016-05-04 广州市科能化妆品科研有限公司 Fresh and cool sun-resistant composition with grease controlling function

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1256121A (en) * 1998-11-02 2000-06-14 Basf公司 Cosmetic or medicinal preparation containing 1,3,5-triazine derivative and zinc oxide
WO2005094769A1 (en) * 2004-02-17 2005-10-13 Basf Aktiengesellschaft Cosmetic or dermatological preparations containing a mixture of a uv-a filter, a uv-b filter, and a metal oxide
CN102186452A (en) * 2008-10-17 2011-09-14 巴斯夫欧洲公司 Sunscreen and personal care compositions comprising a random terpolymer
TW201110990A (en) * 2009-09-29 2011-04-01 Shiseido Co Ltd Oil-in-water type emulsion composition
KR20110072639A (en) * 2009-12-23 2011-06-29 웅진코웨이주식회사 Transparent solid-type cosmetic composition for inhibiting uv
CN103083203A (en) * 2013-01-30 2013-05-08 曼秀雷敦(中国)药业有限公司 Sunscreen composition and preparation method thereof
CN104921965A (en) * 2014-03-18 2015-09-23 西姆莱斯股份公司 Coated titanium dioxide to reduce whitening effect on skin
CN105534737A (en) * 2015-12-31 2016-05-04 广州市科能化妆品科研有限公司 Fresh and cool sun-resistant composition with grease controlling function

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111787847A (en) * 2018-02-26 2020-10-16 株式会社爱茉莉太平洋 Skin change measuring device and method using blue light, and blue light irradiation device

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