CN107154426A - A kind of device architecture and implementation method for improving silicon substrate GaN HEMT breakdown voltages - Google Patents

A kind of device architecture and implementation method for improving silicon substrate GaN HEMT breakdown voltages Download PDF

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CN107154426A
CN107154426A CN201610117876.3A CN201610117876A CN107154426A CN 107154426 A CN107154426 A CN 107154426A CN 201610117876 A CN201610117876 A CN 201610117876A CN 107154426 A CN107154426 A CN 107154426A
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silicon substrate
electrode
source
gan
gan hemt
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王茂俊
陶明
郝龙
郝一龙
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Peking University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66431Unipolar field-effect transistors with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
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  • Junction Field-Effect Transistors (AREA)

Abstract

The invention discloses a kind of device architecture for improving silicon substrate GaN HEMT breakdown voltages and preparation method thereof, the structure includes silicon substrate, carbon doping GaN or AlN cushion, GaN channel layers, AlGaN potential barrier, insulation gate dielectric layer, gate electrode, dielectric passivation layer, source Schottky ohm mixed electrode and drain terminal Ohmic electrode.Epitaxial growth AlGaN/GaN heterojunction materials, and being formed on this structure after insulation gate dielectric layer, active area, source and drain Ohmic contact and grid metal on a silicon substrate, form source Schottky ohm mixed electrode.Schottky contact structure serves certain shielding action to high pressure, reduces the electric current for being injected into drain terminal via device channel barrier layer or cushion from source, and then improve the breakdown voltage of device.Implementation method of the present invention is simple, increases substantially GaN HEMT breakdown voltage, widens its application in power switch field.

Description

A kind of device architecture and implementation method for improving silicon substrate GaN HEMT breakdown voltages
Technical field
The invention belongs to microelectronics technology, it is related to the making of GaN base power electronic devices
Background technology
In recent years, wide bandgap semiconductor GaN is received significant attention with the superior material property such as its high electron mobility, high breakdown field strength.In addition, due to strong spontaneous polarization effect, in the two-dimensional electron gas of the conventional naturally occurring high concentration of AlGaN/GaN heterojunction boundaries.Therefore in theory for, AlGaN/GaN HEMTs (HEMT) have extremely wide application prospect in fields such as high frequency, high-voltage circuit breakers.
The backing material of GaN device is generally silicon, carborundum, three kinds of sapphire, and wherein silicon substrate AlGaN/GaN HEMT enjoy favor because of low, the good wafer size scalability of its price.Although good material property and heterojunction characteristics, silicon substrate GaN HEMT breakdown voltage is still far below theoretic limiting value, and this significantly limit its application in high-voltage switch gear field.
In silicon substrate GaN HEMT, because substrate silicon is completely insulated not as carborundum, sapphire, so its OFF state breakdown characteristics is different from conventional HEMT device:Silicon substrate GaN HEMT breakdown voltage is as gradually saturation is understood in the increase of grid leak spacing rather than gradually increases.The size of saturation breakdown voltage has direct relation when grid leak spacing is not very big with the epitaxy layer thickness in vertical direction.Based on considering for flexibility under lattice mismatch and big wafer size etc., epitaxial layer can not be too thick, therefore with certain challenge in terms of silicon substrate GaN HEMT breakdown voltage is improved.
Improving the method for silicon substrate GaN HEMT breakdown voltages at present mainly has:1. the local silicon substrate removed under source and drain areas;2. substrate transfer technology:After original silicon substrate is all removed, HEMT-structure is allowed to be transferred on the carrier wafer of an insulation, though this method can be completely eliminated limitation of the silicon substrate to GaN HEMT breakdown voltages, and it is more complicated cumbersome and cost is higher;3. the electric leakage of vertical direction can also be controlled so as to obtain high breakdown voltage by improving the thickness of cushion to a certain extent, the method is simple but improves limitation.
The content of the invention
It is an object of the invention to silicon substrate GaN HEMT breakdown voltage is improved with simpler method.On the basis of further investigation silicon substrate GaN HEMT OFF state punctures mechanism, from the angle of device structure design, it is improved in traditional silicon substrate GaN HEMT-structures, in source formation source mixing Schottky-ohmic electrode structure, to realize the silicon substrate GaN HEMT of high-breakdown-voltage, application demand of the GaN base power electronic devices to high switching voltage is met.
The technical thought of the present invention is as follows:The discovery in mechanism is punctured using leakage injection Research on measuring technique silicon substrate GaN HEMT OFF state, when grid leak spacing is larger (such as 10um), breakdown voltage is pulled up a horse with device pinch off and risen to a very high value, but as the further negative sense of grid voltage is moved, breakdown voltage is slowly reduced to after a constant value, this pinch off showed with conventional device again saturation or gradually rises equal difference immediately.Found in the two ends breakdown voltages test carried out therewith, if some two-dimensional electron gas (as shown in Figure 1) beside Ohmic electrode, its breakdown voltage is apparently higher than no two-dimensional electron gas.It is possible thereby to illustrate that two-dimensional electron gas serves certain shielding action to high pressure, also Just because of this, in three terminal device voltage-withstand test, can just have and be moved with grid voltage negative sense, two-dimensional electron gas is gradually depleted, and shielding action weakens, and breakdown voltage is also just gradually reduced after pinch off, after being depleted at utmost, pressure-resistant saturation.Ohm injection that this explanation silicon substrate GaN HEMT OFF state punctures with source is relevant, and damage originally will be produced in source Ohmic contact forming process, in high-pressure process, and Injection Current can be very big, so that causing the breakdown voltage of device reduces.Puncture mechanism along this, silicon substrate GaN HEMT source Ohmic contact can be modified to source Schottky-ohm mixing contact, i.e. on the basis of Ohmic contact, add one section of Schottky contacts, the metal of the Schottky contacts serves the shielding action played the same tune on different musical instruments with two-dimensional electron gas, and when device is subject to high pressure, the influence of a part of high pressure has been fallen in the metallic shield of this section of Schottky contacts, the injection of source Ohmic contact is reduced, so as to improve silicon substrate GaN HEMT breakdown voltage.
According to above-mentioned technical thought, in order to improve silicon substrate GaN HEMT breakdown voltages, a kind of new device structure of utilization source Schottky-ohm mixing contact, including following preparation process:
(1) on a silicon substrate according to GaN the or AlN cushions of certain growth conditions successively Growth of Carbon Doped, intrinsic GaN channel layers, intrinsic AlGaN potential barrier;
(2) the AlGaN/GaN material good to epitaxial growth carries out organic washing, and HCl: H is put into after being cleaned with the deionized water of flowing21~2min is cleaned in O=1: 10 solution, then one layer of thin gate dielectric layer is formed on its surface using PECVD, ICPCVD or LPCVD;
(3) photoetching is carried out to the AlGaN/GaN materials for forming gate dielectric layer, etch source and drain ohmic contact regions, metal ohmic contact is prepared by electron beam evaporation or magnetron sputtering and peeled off, last (800~900 DEG C of rapid thermal annealing in nitrogen environment, 30s), Ohmic contact is formed;
(4) formed after Ohmic contact, further photoetching defines active area, the method injected using Planar Ion and (be generally fluorine ion) or etched realizes the active area isolation of device;
(5) after isolation is formed, photoetching gate electrode region, deposited by electron beam evaporation or observing and controlling sputtering prepare metal gate electrode material, and then carrying out stripping technology processing to device forms gate electrode;
(6) after gate electrode is formed, chemical wet etching formation source Schottky contact area, deposited by electron beam evaporation or observing and controlling sputtering prepare source Schottky contact metal material, and stripping technology processing formation source Schottky-ohm mixing is then carried out to device and is contacted;
(7) after the completion of device is preliminary, the dielectric passivation layer of a thickness is formed on its surface using PECVD, ICPCVD or LPCVD;
(8) after dielectric passivation layer is formed, chemical wet etching goes out grid, source electrode and the test of drain electrode electrode zone, and finally whole wafer is made annealing treatment in a nitrogen environment, completes the preparation of integral device.
The invention has the advantages that:
(1) devices use source Schottky of the present invention-ohm mixing contact structures, so that device is in OFF state breakdown process, the influence of high pressure of source schottky metal partly shielding effect, reduces the leakage current injection of source Ohmic contact, so as to improve silicon substrate GaN HEMT breakdown voltage;
(2) angle of the invention from device structure design, the breakdown voltage for raising silicon substrate GaN HEMT provides a kind of new thinking, can be considered with reference to more excellent techniques, develop high performance silicon substrate GaN HEMT power electronic devices;
(3) implementation method of the invention is more simple compared to the pressure-resistant methods of other raising silicon substrate GaN HEMT, it is easy to accomplish, by regulating and controlling the length of source Schottky contact metal in the horizontal, the pressure-resistant scopes of silicon substrate GaN HEMT can be regulated and controled.
Brief description of the drawings
The principle and its structure of device of the present invention can be more fully hereinafter illustrated by referring to accompanying drawing, and further describes the exemplary embodiment of the present invention, in the accompanying drawings:
Fig. 1 is two ends voltage-withstand test structure (having two-dimensional electron gas at Ohm contact electrode), helps preferably to illustrate the mentality of designing of the present invention;
Fig. 2 is the overall cross-sectional view of device of the present invention;
Fig. 3~Fig. 8 is the cross-sectional view after each step manufacturing process of new structure silicon substrate GaN HEMT in the present invention, reflects the technique manufacturing process of the present invention.
Embodiment
Hereinafter, the present invention is more fully described with reference to the accompanying drawings, embodiment and its implementation process is shown in the drawings, described embodiment is only that a kind of way of realization in the present invention, the i.e. present invention should not be construed as limited to embodiment set forth herein.Based on the embodiment, those skilled in the art are fully conveyed the scope of the present invention to.
Hereinafter, the exemplary embodiment of the present invention is more fully described with reference to the accompanying drawings.
Reference picture 2, the order of the device architecture from bottom to top includes silicon-based substrate, GaN the or AlN cushions of carbon doping, intrinsic GaN channel layers, intrinsic AlGaN potential barrier, insulation gate dielectric layer, gate electrode, dielectric passivation layer, source Schottky-ohm mixed electrode and drain terminal Ohmic electrode successively.Its preparation method includes step in detail below:
(1) as shown in Figure 3, first in silicon-based substrate, GaN the or AlN cushions of one layer of carbon doping are grown with MOCVD, then the intrinsic GaN channel layers of one layer of regrowth, intrinsic AlGaN potential barrier is grown above, so far completes the epitaxial growth of silicon substrate AlGaN/GaN materials;
(2) the AlGaN/GaN material good to epitaxial growth in (1) carries out organic washing, and HCl: H is put into after being cleaned with the deionized water of flowing21~2min is cleaned in O=1: 10 solution, then one layer of 20nm Si is formed on its surface using PECVD, ICPCVD or LPCVD3N4Gate dielectric layer, as shown in Figure 4;
(3) photoetching is being carried out shown in Fig. 4 on architecture basics, etch source and drain ohmic contact regions, metal ohmic contact (Ti/Al/Ni/Au=20nm/150nm/50nm/80nm) is prepared by electron beam evaporation and peeled off, last (850 DEG C of rapid thermal annealing in nitrogen environment, 30s), Ohmic contact is formed, as shown in Figure 5;
(4) formed shown in Fig. 5 after structure, further photoetching defines active area, inject the isolation to be formed between device with fluorine ion, fluorine ion energy injection (80kev, 40kev, 20kev) in three times, dosage is 1E14;
(5) after isolation is formed, photoetching gate electrode region, deposited by electron beam evaporation prepares gate metal (Ni/Au=50nm/250nm) and peeled off, and the device cross after formation grid metal is as shown in Figure 6;
(6) after gate electrode is formed, lithographic definition goes out source Schottky contact area, first with the Si that deposit is formed in RIE dry etchings (2)3N4, then deposited by electron beam evaporation prepare source Schottky contact metal and (Ni/Au=50nm/150nm) and peeled off, the device cross so far formed is as shown in Figure 7;
(7) on architecture basics as shown in Figure 7,200nm Si is formed on its surface with PECVD3N4Dielectric passivation layer, as shown in Figure 8;
(8) in the structure shown in Fig. 8, RIE etches grid, source electrode and the test of drain electrode electrode, (400 DEG C, 10min) processing of finally being annealed in a nitrogen environment to whole wafer;
(9) the new structure silicon substrate GaN HEMT devices prepared by above step are pressure-resistant to improve many for conventional structure.

Claims (11)

1. a kind of device architecture and implementation method for improving silicon substrate GaN HEMT breakdown voltages, it is characterised in that:It is described Structure include silicon substrate, GaN the or AlN cushions of carbon doping, intrinsic GaN channel layers, intrinsic AlGaN potential barrier, absolutely Edge gate dielectric layer, gate electrode, dielectric passivation layer, source Schottky-ohm mixed electrode and drain terminal Ohmic electrode;The insulation Gate dielectric layer, source Schottky-ohm mixed electrode and drain terminal Ohmic electrode are respectively positioned on intrinsic AlGaN potential barrier, grid Electrode is located on insulation gate dielectric layer, and dielectric passivation layer is then located at the superiors;In silicon-based substrate Epitaxial growth containing carbon doping AlGaN/GaN heterojunction materials, and formed on the heterojunction material mos gate pole, source Schottky-ohm mixed electrode with And drain terminal Ohmic electrode, finally deposit the passivation that passivation layer realizes device.
2. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:Backing material therein is Si.
3. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The material of the insulation gate dielectric layer is any one in following material:Si3N4、Al2O3、AlN、HfO2、 SiO2、HfTiO、Sc2O3、Ga2O3And SiNO.
4. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The gate metal is one or more combinations of following conductive material:Platinum, iridium, nickel, gold, molybdenum, palladium, Selenium, beryllium, TiN, polysilicon, ITO.
5. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The source electrode and the metal ohmic contact of drain electrode are:Titanium, aluminium, nickel, gold, platinum, iridium, molybdenum, tantalum, niobium, One or more alloys in cobalt, zirconium, tungsten etc..
6. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The Schottky contact metal material of source Schottky-ohm mixed electrode for following conductive material one kind or A variety of combinations:Platinum, iridium, nickel, gold, molybdenum, palladium, selenium, beryllium, TiN, polysilicon, ITO.
7. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The material of the dielectric passivation layer is any one in material:Si3N4、AlN、Al2O3、SiO2
8. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The metal of source Schottky contacts serves certain shielding action to high pressure, punctures so as to reduce in OFF state During source Ohmic contact leakage current injection, so that silicon substrate GaN HEMT breakdown voltage is improved, according to this Shielding action principle, its structure also can be MOS- ohm of mixing contact electrodes of source.
9. the device architecture and implementation method according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:The length that source schottky metal spills metal ohmic contact can adjust to reach regulation silicon substrate GaN The purpose of HEMT device breakdown voltage, length range is 1.5~3um.
10. the device architecture according to claim 1 for improving silicon substrate GaN HEMT breakdown voltages and realization side Method, it is characterised in that including step is implemented as described below:
(1) on a silicon substrate according to GaN the or AlN cushions of certain growth conditions successively Growth of Carbon Doped, intrinsic GaN Channel layer, intrinsic AlGaN potential barrier;
(2) the AlGaN/GaN material good to epitaxial growth carries out organic washing, and HCl is put into after being cleaned with the deionized water of flowing: H21~2min is cleaned in O=1: 10 solution, then one is formed on its surface using PECVD, ICPCVD or LPCVD The thin gate dielectric layer of layer;
(3) photoetching is carried out to the AlGaN/GaN materials for forming gate dielectric layer, etches source and drain ohmic contact regions, pass through electricity Beamlet evaporates or magnetron sputtering prepares metal ohmic contact and peeled off, finally the rapid thermal annealing in nitrogen environment (800~900 DEG C, 30s), form Ohmic contact;
(4) formed after Ohmic contact, further photoetching defines active area, injected using Planar Ion (generally fluorine from Son) or the method for etching realize the active area isolation of device;
(5) after isolation is formed, photoetching gate electrode region, deposited by electron beam evaporation or observing and controlling sputtering prepare metal gate electrode material, Stripping technology processing then is carried out to device and forms gate electrode;
(6) after gate electrode is formed, chemical wet etching formation source Schottky contact area, deposited by electron beam evaporation or observing and controlling sputtering are made Standby source Schottky contact metal material, stripping technology processing is then carried out to device and forms source Schottky-ohm mixing contact;
(7) after the completion of device is preliminary, the medium of a thickness is formed on its surface using PECVD, ICPCVD or LPCVD Passivation layer;
(8) after dielectric passivation layer is formed, chemical wet etching goes out grid, source electrode and the test of drain electrode electrode zone, finally in nitrogen Whole wafer is made annealing treatment under environment (400 DEG C, 10min).
11. the device architecture and implementation method according to claim 9 for improving silicon substrate GaN HEMT breakdown voltages, It is characterized in that:Source electrode and the test electrode zone of drain electrode can pass through ICP or RIE dry etchings in the step (8) Realize.
CN201610117876.3A 2016-03-03 2016-03-03 A kind of device architecture and implementation method for improving silicon substrate GaN HEMT breakdown voltages Pending CN107154426A (en)

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Cited By (5)

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CN108508333A (en) * 2018-03-21 2018-09-07 长江存储科技有限责任公司 The reliability estimation method of rear end dielectric material
CN109712888A (en) * 2018-12-28 2019-05-03 张家港意发功率半导体有限公司 GaNHEMT device and its manufacturing method
CN111952356A (en) * 2020-07-13 2020-11-17 中国电子产品可靠性与环境试验研究所((工业和信息化部电子第五研究所)(中国赛宝实验室)) HEMT device structure and preparation method thereof
CN111952365A (en) * 2020-08-14 2020-11-17 中国科学院半导体研究所 Carbon-doped and controlled GaN-based HEMT epitaxial structure and manufacturing method thereof
WO2023092855A1 (en) * 2021-11-24 2023-06-01 华南理工大学 N-polarity gan/algan-based radio frequency rectifier and preparation method therefor

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108508333A (en) * 2018-03-21 2018-09-07 长江存储科技有限责任公司 The reliability estimation method of rear end dielectric material
CN108508333B (en) * 2018-03-21 2020-04-10 长江存储科技有限责任公司 Reliability evaluation method of back-end dielectric material
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CN111952365A (en) * 2020-08-14 2020-11-17 中国科学院半导体研究所 Carbon-doped and controlled GaN-based HEMT epitaxial structure and manufacturing method thereof
WO2023092855A1 (en) * 2021-11-24 2023-06-01 华南理工大学 N-polarity gan/algan-based radio frequency rectifier and preparation method therefor

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Application publication date: 20170912