CN107151308A - 一种无卤热固性树脂组合物及使用它的预浸料、印制电路用层压板 - Google Patents
一种无卤热固性树脂组合物及使用它的预浸料、印制电路用层压板 Download PDFInfo
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Abstract
本发明涉及一种无卤热固性树脂组合物及使用它的预浸料、印制电路用层压板,所述无卤热固性树脂组合物,有机固形物按100重量份计,其包含:(A)无卤环氧树脂16‑42重量份;(B)具有二氢苯并噁嗪环的化合物1.5‑4.8重量份;(C)含磷双酚固化剂10‑28重量份,所述含磷双酚的重均分子量为1000‑6500;(D)二氧化硅30‑70重量份。本发明所提供的无卤热固性树脂组合物制成的半固化片及印制电路用层压板,具有高玻璃化转变温度、优异的介电性能、低吸水率、高耐热性和良好的工艺加工性,并能实现无卤阻燃,达到UL94 V‑0。
Description
技术领域
本发明涉及一种无卤热固性树脂组合物,尤其涉及该无卤热固性树脂组合物制成的半固化片及印制电路用层压板。
背景技术
传统的印制电路用层压板通常采用溴系阻燃剂来实现阻燃,特别是采用四溴双酚A型环氧树脂,这种溴化环氧树脂具有良好的阻燃性,但它在燃烧时会产生溴化氢气体。此外,近年来在含溴、氯等卤素的电子电气设备废弃物的燃烧产物中已检测出二噁英、二苯并呋喃等致癌物质,因此溴化环氧树脂的应用受到限制。2006年7月1日,欧盟的两份环保指令《关于报废电气电子设备指令》和《关于在电气电子设备中限制使用某些有害物质指令》正式实施,无卤阻燃覆铜箔层压板的开发成为业界的热点,各覆铜箔层压板厂家都纷纷推出自己的无卤阻燃覆铜箔层压板。
同时随着消费电子产品信息处理的高速化和多功能化,应用频率不断提高,除了环保的要求越来越高外,要求介电常数和介电损耗值越来越低,因此降低Dk/Df已成为基板业者的追逐热点。
CN1723243A和日本专利NO.2001/302,879中的组合物披露了反应型的膦酸酯,但均用作阻燃剂,只有膦酸酯的羟基能与环氧树脂反应,这种膦酸酯羟基当量高固化效率低,组合物需要另外添加固化剂如苯并噁嗪、酚醛等,而这些固化剂的添加都会恶化固化物的介电性能,难以满足热固性高速领域层压板对介电性能的要求,且苯并噁嗪含量较多,难以实现较低的介电性能。
此外,CN1723243A说明书中披露的膦酸酯要求磷含量大于约12%,这种膦酸酯磷含量过高且分布密集,固化物易吸水,用在印制线路层压板中易吸潮爆板。而且,CN1723243A并未对膦酸酯的分子量进行限定。
发明内容
本发明的目的在于提供一种新型的无卤热固性树脂组合物,以及使用它的预浸料、印制电路用层压板。使用该树脂组合物制作的印制电路用层压板具有较高的玻璃化转变温度、优异的介电性能、低吸水率、高耐热性和良好的工艺加工性,并能实现无卤阻燃,达到UL94V-0。
本发明人为实现上述目的进行了反复深入的研究,结果发现:通过将无卤环氧树脂、具有二氢苯并噁嗪环的化合物、含磷双酚、二氧化硅以及任选地其他物质进行适当混合制成的新型组合物,可达到上述目的。
即,本发明采用如下技术方案:一种无卤热固性树脂组合物,含有以下四种物质作为必要组分,有机固形物按100重量份计,其包含:
(A)无卤环氧树脂16-42重量份;
(B)具有二氢苯并噁嗪环的化合物1.5-4.8重量份;
(C)含磷双酚固化剂10-28重量份,所述含磷双酚的重均分子量为1000-6500;
(D)二氧化硅30-70重量份。
经发明人研究发现,一种有着特定结构的含磷双酚可用作环氧树脂的固化剂,其反应基团包括两端羟基和磷单元,且反应不产生二次羟基,固化物玻璃化转变温度高、介电性能和耐热性优异。此外,该含磷双酚的磷含量高,在用作固化剂的同时还有无卤阻燃的功效,无需额外添加阻燃剂。
本发明是采用一种磷含量在8wt%-10wt%的含磷双酚,其分子结构对称性高且磷分布均匀不密集,可用作环氧树脂的固化剂;其除了两端羟基可与环氧树脂环氧基反应外,在>175℃的条件下磷单元还可与二次羟基发生反应消除二次羟基,使得固化物交联密度高且二次羟基含量低,从而拥有高Tg和优异的介电性能。
本发明采用的是有着特定分子量的含磷双酚,该含磷双酚在特定分子量范围内有着较低的熔融粘度,从而使得组合物在保持合适的熔融粘度和良好的可加工性的前提下能添加较多的二氧化硅填料,提高固化物的模量和尺寸稳定性,同时也进一步降低了固化物的吸水率。
本发明所采用的含磷双酚与环氧树脂的反应过程如下所示。
本发明的无卤热固性树脂组合物采用了特定分子结构的无卤环氧树脂,其具有较高的官能度和良好的介电性能,其固化物Tg较高、吸水率低。
本发明的无卤热固性树脂组合物还采用了具有二氢苯并噁嗪环的化合物,该类化合物Tg高、介电性能和耐热性好、吸水率低。在上述无卤环氧树脂中加入具有二氢苯并噁嗪环的化合物,固化物不仅有着高Tg、高耐热性和低吸水率,还有着优异的介电性能及较高的模量,较高的模量能改善层压板在加工中胀缩的问题;此外,该类具有二氢苯并噁嗪环的化合物含有氮元素,氮元素和含磷双酚中的磷元素有协同阻燃的效果,能减少固化物阻燃性达到UL94V-0所需磷含量,进一步降低吸水率。
经发明人研究发现,本发明的无卤热固性树脂组合物中,具有二氢苯并噁嗪环的化合物在添加1.5-4.8重量份时,相比高于5重量份或低于1.5重量份的添加量,其更能与含磷双酚发挥协同固化阻燃的效果,并能进一步降低吸水率。
本发明的无卤热固性树脂组合物还包含有30%-70%的二氧化硅,不仅能解决含磷双酚熔融粘度低流胶大的问题,还可以降低固化物的热膨胀系数,提高模量和尺寸稳定性,进一步改善阻燃并降低介电损耗。
本发明还提供了通过使用上述的无卤热固性树脂组合物浸渍基料并随后加热干燥而制得的预浸料,所述的基料为无纺织物或其他织物。
本发明还提供了通过对一片或多片预浸料加热加压、使预浸料粘合而成的层压板和粘合在层压板的一面或两面以上的金属箔的印制电路用层压板。
与现有技术相比,本发明至少具有以下有益效果:
(1)本发明的无卤热固性树脂组合物采用特定分子结构的无卤环氧树脂,其具有较高的官能度和良好的介电性能,其固化物Tg较高、吸水率低;
(2)本发明的无卤热固性树脂组合物采用了具有二氢苯并噁嗪环的化合物,该类化合物Tg较高、吸水率低,大大改善了固化物的吸水性;此外,该类具有二氢苯并噁嗪环的化合物含有氮元素,氮元素和含磷双酚中的磷元素有协效阻燃的效果,能减少固化物阻燃性达到UL94V-0所需磷含量,进一步降低吸水率,尤其当其添加量控制在1.5-4.8重量份时,相比高于5重量份或低于1.5重量份的添加量,其更能与含磷双酚发挥协同固化阻燃的效果,并能进一步降低吸水率;
(3)本发明的无卤热固性树脂组合物以含磷双酚为固化剂和阻燃剂,该含磷双酚结构对称性高,两端羟基能与环氧树脂的环氧基反应,且磷酸酯结构能与环氧树脂的二次羟基反应,固化物Tg较高介电性能优异;同时,该含磷双酚磷含量高,能在不牺牲固化物Tg、介电性能、耐热性、耐湿性的前提下实现无卤阻燃,固化物阻燃性达到UL94V-0级:此外,该含磷双份分子量较小,熔融粘度低,对填料的浸润性优异,且填料比例较高时仍有着较低的熔融粘度,加工性好;
(4)本发明的无卤热固性树脂组合物还包含有30%-70%的二氧化硅,不仅能解决含磷双酚熔融粘度低流胶大的问题,还可以降低固化物的热膨胀系数,提高模量和尺寸稳定性,进一步改善阻燃并降低介电损耗;
(5)使用该树脂组合物制成的预浸料、印制电路用层压板具有高玻璃化转变温度,其玻璃化转变温度可达到185℃,优异的介电性能,其介电常数在3.53-3.60之间,低吸水率,其吸水性在0.07-0.08%范围内,具有大于120s的耐浸焊性能和良好的工艺加工性,并能实现无卤阻燃,达到UL94V-0级。
具体实施实例
本发明采用如下技术方案:一种无卤热固性树脂组合物,含有以下四种物质作为必要组分,有机固形物按100重量份计,其包含:
(A)无卤环氧树脂16-42重量份;
(B)具有二氢苯并噁嗪环的化合物1.5-4.8重量份;
(C)含磷双酚固化剂10-28重量份,所述含磷双酚的重均分子量为1000-6500;
(D)二氧化硅30-70重量份。
下面对各组分进行详细说明。
本发明中的组分(A),即为无卤环氧树脂,使用量为16-42重量份,例如为16重量份、18重量份、19重量份、20重量份、22重量份、23重量份、24重量份、25重量份、26重量份、27重量份、28重量份、29重量份、30重量份、32重量份、34重量份、36重量份、38重量份、40重量份或42重量份。
根据本发明,所述无卤环氧树脂可以选自双酚A型环氧树脂、双酚F型环氧树脂、邻甲酚酚醛环氧树脂、双酚A型酚醛环氧树脂、三酚型酚醛环氧树脂、双环戊二烯酚醛环氧树脂、联苯型酚醛环氧树脂、烷基苯型酚醛环氧树脂或萘酚型酚醛环氧树脂中的任意一种或至少两种的混合物。上述环氧树脂均为无卤的环氧树脂。
根据本发明,所述无卤环氧树脂优选自具有如下结构的环氧树脂:
式中,X1、X2、X3各自独立地选自R1选自氢原子、取代或未取代的C1-C5(例如C2、C3或C4)直链烷基或者取代或未取代的C1-C5(例如C2、C3或C4)支链烷基中的任意一种。
Y1、Y2各自独立地选自单键、-CH2-、 中的任意一种,其中R2选自氢原子、取代或未取代的C1-C5(例如C2、C3或C4)直链烷基或者取代或未取代的C1-C5(例如C2、C3或C4)支链烷基中的一种。
m为1-10的任意整数,例如2、3、4、5、6、7、8或9。
本发明无卤热固性树脂组合物采用上述特定分子结构的无卤环氧树脂,其具有较高的官能度和良好的介电性能,其固化物Tg较高,吸水率低。
本发明中所述的组分(B),即为具有二氢苯并噁嗪环的化合物,使用量为1.5-4.8重量份,例如1.5重量份、1.8重量份、2.1重量份、2.4重量份、2.7重量份、3.0重量份、3.3重量份、3.6重量份、3.9重量份、4.2重量份、4.5重量份或4.8重量份。若添加量小于1.5重量份,其降低固化物吸水率和与磷的协效阻燃效果不明显,若添加量大于4.8重量份,固化物介电性能差且脆性较大,加工性差。
根据本发明,所述具有二氢苯并噁嗪环的化合物可以选自式(Ⅰ)所示的双酚A型苯并噁嗪、式(Ⅱ)所示的双酚A型苯并噁嗪、双酚F型苯并噁嗪、MDA(4,4-二胺基二苯甲烷)型苯并噁嗪、酚酞型苯并噁嗪或双环戊二烯型苯并噁嗪中的任意一种或至少两种的混合物。
式中,R3独立地选自-CH2-、中的任意一种,R4为
本发明中所述的组分(C),即为含磷双酚,其同时用作固化剂和阻燃剂,使用量为10-28重量份,例如10重量份、12重量份、14重量份、16重量份、18重量份、20重量份、22重量份、24重量份、26重量份或28重量份。若添加过少,固化物介电性能和阻燃性差;若添加过多,固化物吸水率过高。
根据本发明,所述含磷双酚固化剂中磷含量占含磷双酚固化剂的8wt%-10wt%,例如8wt%、8.2wt%、8.3wt%、8.5wt%、8.8wt%、9wt%、9.2wt%、9.5wt%、9.8wt%和10wt%。
本发明通过采用磷含量在8wt%-10wt%的含磷双酚固化剂,其分子结构对称性高且磷分布均匀不密集,可用作环氧树脂的固化剂;其除了两端羟基可与环氧树脂环氧基反应外,在>175℃的条件下磷单元还可与二次羟基发生反应消除二次羟基,使得固化物交联密度高且二次羟基含量低,从而拥有高Tg和优异的介电性能。
根据本发明,所述含磷双酚具有如下结构:
式中,n为2-20的任意整数,例如3、4、5、6、7、8、10、12、13、15、17、18或20,优选n为3-10的任意整数。
根据本发明,所述含磷双酚的重均分子量为1000-6500,例如1000、1200、1500、、1800、2000、2200、2500、2800、3000、3500、4000、4500、4800、5100、5800、6000或6500,优选为1000-4500,进一步优选为1000-3000。当重均分子量小于1000时,固化物Tg低、耐热性差;当重均分子量大于6500时,所述含磷双酚在有机溶剂中的溶解性较差,无法得到良好、均一的胶液,从而难以满足覆铜板的工艺要求。
本发明中所述的组分(D),即为二氧化硅,其使用量为30-70重量份,例如30重量份、35重量份、40重量份、45重量份、50重量份、55重量份、60重量份、65重量份或70重量份。若添加过少,树脂组合物在加工过程中熔融粘度较低,流胶不易控制,且对固化物的模量和尺寸稳定性助益不明显;若添加过多,会导致熔融粘度过高工艺性差,不利于生产。
根据本发明,所述二氧化硅优选为熔融型二氧化硅。
根据本发明,所述二氧化硅的形状和粒径并无特别的限定,优选所述二氧化硅的中位粒径为0.01-50μm,例如1μm、6μm、11μm、16μm、21μm、26μm、31μm、36μm、41μm或46μm,优选为0.01-20μm,进一步优选为0.1-10μm,这种粒径范围的填料在胶液中更容易分散。
如有需要,本发明的无卤热固性树脂组合物还可包括组分(E)固化促进剂,本发明对所述固化促进剂没有特别的限定,只要能催化环氧官能团反应、降低固化体系的反应温度即可,优选咪唑类化合物及其衍生物、哌啶类化合物、路易斯酸或三苯基膦中的一种或至少两种的混合物。所述的咪唑类化合物可以列举有2-甲基咪唑、2-乙基-4-甲基咪唑、2-苯基咪唑、2-十一烷基咪唑中的任意一种或至少两种的混合物,所述的哌啶类化合物可以列举有2,3-二氨基哌啶、2,5-二氨基哌啶、2,6-二氨基哌啶、2-氨基-3-甲基哌啶、2-氨基-4-甲基哌啶、2-氨基-3-硝基哌啶、2-氨基-5-硝基哌啶或2-氨基-4,4-二甲基哌啶中的任意一种或至少两种的混合物。
优选地,以组分(A)、组分(B)、组分(C)、组分(D)的总重为100重量份计,所述组分(E)固化促进剂的添加量为0.01-1重量份,例如0.05重量份、0.1重量份、0.15重量份、0.2重量份、0.25重量份、0.3重量份、0.35重量份、0.4重量份、0.45重量份、0.5重量份、0.55重量份、0.6重量份、0.65重量份、0.7重量份、0.75重量份、0.8重量份、0.85重量份、0.9重量份或0.95重量份,优选为0.05-0.8重量份,进一步优选为0.05-0.6重量份。
本发明所述的“包括”,意指其除所述组份外,还可以包括其他组份,这些其他组份赋予所述无卤热固性树脂组合物不同的特性。除此之外,本发明所述的“包括”,还可以替换为封闭式的“为”或“由……组成”。
例如,所述无卤热固性树脂组合物还可以含有各种添加剂,作为具体例,可以举出含磷阻燃剂、抗氧剂、热稳定剂、抗静电剂、紫外线吸收剂、颜料、着色剂或润滑剂等。这些各种添加剂可以单独使用,也可以两种或者两种以上混合使用。
本发明的无卤热固性树脂组合物常规制备方法为:先将固形物放入,然后加入液态溶剂,搅拌至固形物完全溶解后,再加入液态树脂和促进剂,继续搅拌均匀即可。
作为本发明中的溶剂,没有特别的限定,作为具体例,可以列举出甲醇、乙醇、丁醇等醇类,乙基溶纤剂、丁基溶纤剂、乙二醇甲醚、卡必醇、丁基卡必醇等醚类,丙酮、丁酮、甲基乙基甲酮、环己酮等酮类;甲苯、二甲苯等芳香烃类;醋酸乙酯、乙氧基乙基乙酸酯等酯类;N,N-二甲基甲酰胺、N,N-二甲基乙酰胺等含氮类溶剂。以上溶剂可单独使用,也可两种或两种以上混合使用。优选丙酮、丁酮、甲基乙基甲酮、环己酮等酮类。所述溶剂的添加量由本领域技术人员根据自己经验来选择,使得树脂胶液达到适合使用的粘度即可。
本发明的预浸料包括增强材料及含浸干燥后附着在增强材料上的如上所述的无卤热固性树脂组合物,所使用的增强材料无特别的限定,可以为有机纤维、无机纤维编织布或无纺布。所述的有机纤维可以选择芳纶无纺布,所述的无机纤维编织布可以为E-玻纤布、D-玻纤布、S-玻纤布、T玻纤布、NE-玻纤布或石英布。所述增强材料的厚度无特别限定,处于层压板有良好的尺寸稳定性的考虑,所述编织布及无纺布厚度优选0.01-0.2mm,且最好是经过开纤处理及硅烷偶联剂表面处理的,为了提供良好的耐水性和耐热性,所述硅烷偶联剂优选为环氧硅烷偶联剂、氨基硅烷偶联剂或乙烯基硅烷偶联剂中的任意一种或至少两种的混合物。将增强材料通过含浸上述的无卤热固性树脂组合物,在100-250℃条件下,烘烤1-15分钟得到所述预浸料。
本发明的印制电路用层压板包括通过加热和加压、使一片或两片以上的预浸料粘合在一起而制成的层压板,以及粘合在层压板一面或两面以上的金属箔。所述的层压板是在热压机中固化制得,固化温度为150℃-250℃,固化压力为10-60Kg/cm2。所述的金属箔为铜箔、镍箔、铝箔及SUS箔等,其材质不限。
为了更好地说明本发明,便于理解本发明的技术方案,本发明的典型但非限制性的实施例如下:
针对上述制成的印制电路用层压板(8片预浸料,增强材料型号为106,厚度为0.05mm)测试其玻璃化转变温度、介电常数、介电损耗因素、吸水率、耐热性、阻燃性等性能,如下实施例进一步详细说明与描述。
请参阅实施例1-7和比较例1-11。下文中无特别说明,其“份”代表“重量份”,其“%”代表“重量%”。
(A)无卤环氧树脂:
(A-1)双环戊二烯型环氧树脂HP-7200H(日本DIC商品名,EEW:275g/eq)
(A-2)联苯型酚醛环氧树脂NC-3000H(日本化药商品名,EEW:288g/eq)
(B)苯并噁嗪树脂:
(B-1)双酚A型苯并噁嗪HUN 8290N62(HUNTSMAN商品名)
(B-2)双环戊二烯型苯并噁嗪HUN 8260N70(HUNTSMAN商品名)
(C)固化剂:
(C-1)含磷双酚FRX OL3001(美国FRX Polymers商品名,磷含量10%,重均分子量2400~3000)
(C-2)磷酸酯PX-200(日本大八化学商品名,磷含量9%),结构式如下:
(C-3)聚膦酸酯OL5000(美国FRX Polymers商品名,磷含量10.8%),结构式如下:
(C-4)双酚A双(磷酸二苯酯)FYROLFLEX BDP(美国Akzo Nobel商标,重均分子量<1000),结构式如下:
(C-5)聚伸苯甲基磷酸酯Fyrol PMP(以色列ICL商品名),结构式如下:
(D)填料:
(D1)熔融二氧化硅(平均粒径为1-10μm,纯度99%以上)
(D2)氢氧化铝(平均粒径为1-10μm,纯度99%以上)
(E)促进剂:2-苯基咪唑(日本四国化成)
表1-3是实施例1-7和比较例1-11的配方组成及其物性数据。
表1
表2
表3
以上特性的测试方法如下:
(a)玻璃化转变温度(Tg)
根据差示扫描量热法(DSC),按照IPC-TM-650 2.4.25所规定的DSC方法进行测定。
(b)介电常数、介电损耗因素
根据使用条状线的共振法,按照IPC-TM-650 2.5.5.5测定1GHz下的介电损耗、介电损耗因素。
(c)吸水性
按照IPC-TM-650 2.6.2.1方法进行测定。
(d)耐浸焊性
按照IPC-TM-650 2.4.13.1观察分层起泡时间。
(e)难燃烧性
依据UL94垂直燃烧法测定。
从表1-表3的物性数据可知,比较例1中使用含磷双酚和5份双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,所制成的覆铜板介电性能较差,且耐热性一般;比较例2中使用含磷双酚和双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,以氢氧化铝为填料,所制成的覆铜板介电性能和耐热性较差;比较例3中采用不含羟基的磷酸酯与双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,比较例4中采用不含羟基的磷酸酯与双环戊二烯型苯并噁嗪固化联苯型环氧树脂,所制成的覆铜板Tg较低、介电常数和介电损耗均较高,难以满足热固性高速领域层压板对介电性能的要求;比较例5中采用含有单羟基并且磷含量高于10%的聚膦酸酯与双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,比较例6中采用含有单羟基并且磷含量高于10%的聚膦酸酯与双环戊二烯型苯并噁嗪固化联苯型环氧树脂,所制成的覆铜板介电性能和耐热性较差,且吸水率较高;比较例7中采用20重量份双酚A型苯并噁嗪与含磷双酚固化双环戊二烯型环氧树脂,所制成的覆铜板介电性能、耐热性和阻燃均不理想;比较例8中采用双酚A型苯并噁嗪单独固化双环戊二烯型环氧树脂,所制成的覆铜板介电性能较差,耐热性和阻燃不足;比较例9中采用含磷双酚单独固化双环戊二烯型环氧树脂,所制成的覆铜板Tg高、介电性能优异,但吸水率太高,容易导致加工过程中吸潮爆板;比较例10中采用重均分子量<1000的含磷双酚与少量双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,所制得的覆铜板Tg太低且耐热性差;比较例11采用少量聚伸苯甲基磷酸酯与双酚A型苯并噁嗪(添加比例为2.5/10)固化双环戊二烯型环氧树脂,所制得的覆铜板介电性能一般,耐热性和阻燃较差。实施例1-6以含磷双酚与适量苯并噁嗪复合固化特定结构的无卤环氧树脂并搭配较高比例的填料,得到的层压板具有高玻璃化转变温度、优异的介电性能、低吸水率、高耐热性并实现了无卤阻燃,且阻燃能达到UL94V-0级。实施例7采用聚伸苯甲基磷酸酯与少量双酚A型苯并噁嗪固化双环戊二烯型环氧树脂,所制得的覆铜板Tg较高、介电性能较好,但由于聚伸苯甲基磷酸酯不含双酚A结构,磷反应单元分布密集,导致反应过快且容易形成空间位阻,固化后容易有反应基团残留,相比实施例2固化物Tg略低、介电性能和耐热性稍差。
如上所述,与一般的层压板相比,本发明的印制电路用层压板在具有更高的玻璃化转变温度、更优异的介电性能、耐湿性、耐热性,适用于热固性领域。另外卤素含量在JPCA无卤标准要求范围内能达到难燃性试验UL94中的V-0标准,有环保的功效。
以上所述,仅为本发明的较佳实施例,对于本领域的普通技术人员来说,可以根据本发明的技术方案和技术构思做出其他各种相应的改变和变形,而所有这些改变和变形都应属于本发明权利要求的范围。
Claims (10)
1.一种无卤热固性树脂组合物,有机固形物按100重量份计,其包含:
(A)无卤环氧树脂16-42重量份;
(B)具有二氢苯并噁嗪环的化合物1.5-4.8重量份;
(C)含磷双酚固化剂10-28重量份,所述含磷双酚的重均分子量为1000-6500;
(D)二氧化硅30-70重量份。
2.如权利要求1所述的无卤热固性树脂组合物,其特征在于,所述无卤环氧树脂为双酚A型环氧树脂、双酚F型环氧树脂、邻甲酚酚醛环氧树脂、双酚A型酚醛环氧树脂、三酚型酚醛环氧树脂、双环戊二烯酚醛环氧树脂、联苯型酚醛环氧树脂、烷基苯型酚醛环氧树脂或萘酚型酚醛环氧树脂中的任意一种或至少两种的混合物;
优选地,所述无卤环氧树脂选自具有如下结构的环氧树脂:
式中,X1、X2和X3各自独立地选自其中R1选自氢原子、取代或未取代的C1-C5直链烷基或者取代或未取代的C1-C5支链烷基中的任意一种;
Y1和Y2各自独立地选自单键、-CH2-、 中的任意一种,其中R2选自氢原子、取代或未取代的C1-C5直链烷基或者取代或未取代的C1-C5支链烷基中的任意一种;
m为1-10的任意整数。
3.如权利要求1或2所述的无卤热固性树脂组合物,其特征在于,所述具有二氢苯并噁嗪环的化合物选自式(Ⅰ)所示的双酚A型苯并噁嗪、式(Ⅱ)所示的双酚A型苯并噁嗪、双酚F型苯并噁嗪、MDA型苯并噁嗪、酚酞型苯并噁嗪或双环戊二烯型苯并噁嗪中的任意一种或至少两种的混合物;
式中,R3选自中的任意一种,R4为
4.如权利要求1-3之一所述的无卤热固性树脂组合物,其特征在于,所述含磷双酚固化剂中磷含量占含磷双酚固化剂的8wt%-10wt%。
5.如权利要求1-4之一所述的无卤热固性树脂组合物,其特征在于,所述含磷双酚具有如下结构:
式中,n为2-20的任意整数,优选n为3-10的任意整数;
优选地,所述含磷双酚的重均分子量为1000-4500,优选为1000-3000。
6.如权利要求1-5之一所述的无卤热固性树脂组合物,其特征在于,所述二氧化硅为熔融型二氧化硅;
优选地,所述二氧化硅的中位粒径为0.01-50μm,优选为0.01-20μm,进一步优选为0.1-10μm。
7.如权利要求1-6之一所述的无卤热固性树脂组合物,其特征在于,还包括组分(E)固化促进剂;
优选地,所述固化促进剂选自咪唑类化合物、咪唑类化合物的衍生物、哌啶类化合物、路易斯酸或三苯基膦中的任意一种或至少两种的混合物,优选为2-甲基咪唑、2-乙基-4-甲基咪唑、2-苯基咪唑或三苯基膦中的任意一种或至少两种的混合物;
优选地,所述咪唑类化合物为2-甲基咪唑、2-乙基-4-甲基咪唑、2-苯基咪唑或2-十一烷基咪唑中的任意一种或至少两种的混合物;
优选地,所述哌啶类化合物为2,3-二氨基哌啶、2,5-二氨基哌啶、2,6-二氨基哌啶、2-氨基-3-甲基哌啶、2-氨基-4-甲基哌啶、2-氨基-3-硝基哌啶、2-氨基-5-硝基哌啶或2-氨基-4,4-二甲基哌啶中的任意一种或至少两种的混合物;
优选地,以组分(A)、组分(B)、组分(C)、组分(D)的添加量之和为100重量份计,所述组分(E)固化促进剂的添加量为0.01-1重量份,优选为0.05-0.8重量份,进一步优选为0.05-0.6重量份。
8.一种预浸料,其包括增强材料及通过浸渍干燥后附着在其上的如权利要求1-7之一所述的无卤热固性树脂组合物。
9.一种层压板,所述层压板含有至少一张如权利要求8所述的预浸料。
10.一种无卤高频电路基板,所述基板含有至少一张如权利要求8所述的预浸料以及覆于叠合后的预浸料一侧或两侧的金属箔。
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CN104804377B (zh) * | 2015-01-28 | 2017-05-24 | 广东生益科技股份有限公司 | 一种无卤树脂组合物及用其制作的预浸料和层压板 |
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2016
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CN1723243A (zh) * | 2002-11-08 | 2006-01-18 | 阿克苏诺贝尔公司 | 含反应性阻燃剂膦酸酯低聚物和填料的环氧树脂组合物 |
CN103554437A (zh) * | 2013-09-04 | 2014-02-05 | 东莞联茂电子科技有限公司 | 一种ic封装用无卤环氧树脂组合物 |
CN105331053A (zh) * | 2014-07-22 | 2016-02-17 | 广东生益科技股份有限公司 | 一种无卤树脂组合物以及使用它的预浸料和印制电路用层压板 |
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US20180126701A1 (en) | 2018-05-10 |
EP3241868A4 (en) | 2018-09-05 |
CN107151308B (zh) | 2019-06-14 |
TWI596155B (zh) | 2017-08-21 |
KR101898365B1 (ko) | 2018-09-12 |
TW201809124A (zh) | 2018-03-16 |
EP3241868A1 (en) | 2017-11-08 |
WO2017148127A1 (zh) | 2017-09-08 |
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