CN107141938A - A kind of buildings decoration water-repellent paint and preparation method thereof - Google Patents
A kind of buildings decoration water-repellent paint and preparation method thereof Download PDFInfo
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- CN107141938A CN107141938A CN201710419425.XA CN201710419425A CN107141938A CN 107141938 A CN107141938 A CN 107141938A CN 201710419425 A CN201710419425 A CN 201710419425A CN 107141938 A CN107141938 A CN 107141938A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of buildings decoration water-repellent paint, belong to building material technical field, including liquid material and powder：Liquid material includes the raw material of following parts by weight：70 100 parts of acrylic emulsion, 0.5 1 parts of levelling agent, 23 parts of dispersant, 0.05 0.1 parts of wetting agent, 0.8 1 parts of defoamer, 12 parts of light stabilizer；Powder includes the raw material of following parts by weight：200 300 parts of cement, 80 150 parts of silica flour, 50 60 parts of butyl rubber, 10 20 parts of asphalt, 90 120 parts of powdered whiting, 5 10 parts of water reducer, 40 60 parts of waterproof powder, 10 20 parts of ultralight clay, 30 40 parts of diatomite, 5 10 parts of stearic acid, 8 12 parts of flyash；The invention also discloses a kind of preparation method of buildings decoration water-repellent paint；Waterproof ability chamber of the present invention, with preferably anti-cracking ability.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of buildings decoration water-repellent paint and its preparation side
Method.
Background technology
Decorative engineering refer to housing construction include plastering, paint, swabbing, glass, paper, facing, skin plate and
The engineering of the techniques such as floriation, it is last work progress of housing construction, its particular content include inside and outside metope and
Ceiling is plastered, the woodwork such as inside and outside wall facing and veneer, the facing of flooring, the installation of building facade floriation, door and window and
Paint swabbing of hard goods etc..
In decorative engineering, water-repellent paint can be commonly used, and the waterproof material of in the market has two major classes：One is polyurethanes
Water-repellent paint.This kind of material is usually to be made up of polyurethane with coal tar as raw material.The tar gas toxicity that it is volatilized is big,
And do not allow easy-clear, therefore be prohibited from using in 2000 in China.It is to use pitch generation still in the polyurethane waterproofing coating of sale
Raw material is used as coal tar.But it is general to be diluted using the organic solvents such as toluene, dimethylbenzene are contained when using this coating,
Thus also containing toxic；Another kind of is polymer cement-base waterproof coating.The emulsion that it is synthesized by a variety of waterborne polymerics is with mixing
It is made up of the high grade cement of various additives, polymer（Resin）Flexibility became one with the rigidity of cement so that it is resisting
Oozing property is excellent with being showed in terms of stability.Its advantage is easy construction, comprehensive cost low, short time limit, and asepsis environment-protecting.Cause
This, polyalcohol cement basis has become the leading role in water-repellent paint market.
Uneven however as real estate housing quality, easily there is crack in the place such as kitchen, toilet, basement, produces
Raw infiltration phenomenon.Although the existing JS water-repellent paints of in the market are with certain elongation percentage, film coated surface is also easy to produce small
The defects such as crackle, pin hole, so that effect of waterproof can not be played, ultimately result in waterproofing work failure.
In publication number CN104829207A open file, a kind of polymer cement waterproof paint, coating bag are disclosed
Include liquid material component and powder component, liquid material component includes macromolecule emulsion, triethanolamine, dispersant, preservative, defoamer, remaining
Measure as water；Powder component includes special cement, ultra-fine clinker, superfine steel slag, metakaolin, defoamer, water-soluble cellulose, powder
Body acrylamide, powder bisacrylamide, quick dissolved sodium silicate, aluminum stearate, surplus are 400 mesh powdered whitings, present invention tool
There is excellent anti-sag and anti-cracking performance, while having self-repair function, can have in inside concrete formation crystalline solid
Certain secondary impermeability function, but anti-cracking ability is still not enough, remains to be further strengthened.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art to be applied there is provided a kind of buildings decoration waterproof
Material, including liquid material and powder：
Liquid material includes the raw material of following parts by weight：70-100 parts of acrylic emulsion, 0.5-1 parts of levelling agent, 2-3 parts of dispersant, profit
0.05-0.1 parts of humectant, 0.8-1 parts of defoamer, 1-2 parts of light stabilizer；
Powder includes the raw material of following parts by weight：200-300 parts of cement, 80-150 parts of silica flour, 50-60 parts of butyl rubber, stone
10-20 parts of oil asphalt, 90-120 parts of powdered whiting, 5-10 parts of water reducer, 40-60 parts of waterproof powder, ultralight clay 10-20 parts,
30-40 parts of diatomite, 5-10 parts of stearic acid, 8-12 parts of flyash.
Preferably, acrylic emulsion is silicone acrylic emulsion, solid content is 40-50%.
Preferably, levelling agent is one kind or mixture of dimethyl silicone polymer and PSI, disperse
Agent is C16~C18 aliphatic alcohol polyethenoxies（10,20）Ether, wetting agent is silanol class nonionic surfactant, and defoamer is height
The mixture of carbon polyol fatty acid ester complexes and silicone emulsion.
Preferably, light stabilizer is the mixing that light covers agent, ultra-violet absorber and radical scavenger, photomask agent is
Carbon black, ultra-violet absorber is salicylic acid esters, and radical scavenger is hindered amine as light stabilizer HALS, and the match ratio of three is
3:1:3。
Preferably, cement is 42.5R Portland cements, the mesh number of silica flour is 200-400 mesh, and water reducer is wood
Mahogany sulfonate.
Preferably, ultralight clay includes the raw material of following parts by weight：It is 10-20 parts of paper pulp, 2-5 parts of PPG, poly-
Pva5-6 parts of vinyl alcohol, 3-8 parts of water.
Present invention also offers a kind of preparation method of buildings decoration water-repellent paint, comprise the following steps：
（1）, prepare waterproof powder：Industry sintering waste residue is well mixed with calcium hydroxide.Then fatty acid ammonium solution is added, fully
Stirring in the pasty state, just obtains waterproof powder after drying；
（2）, by above-mentioned parts by weight weigh various raw materials respectively；
（3）, liquid material poured into mixer, open mixer, it is 300-500r/min to make mixing speed, is then proportionally added into
Powder, stirring 5-10min are until generation rubber cement；
（4）, determine rubber cement pH, and make rubber cement pH value be 7-9, then proceed to stir 2-4min.
Wherein,
Step（3）Add before powder, asphalt and butyl rubber are first passed through into 140-170 DEG C of melting.
A kind of buildings decoration water-repellent paint that the present invention is provided and preparation method thereof, good water-proof effect, cracking resistance energy
Power is strong, with following beneficial effect：
（1）, by the addition of a certain proportion of light stabilizer, light stabilizer is that light covers agent, ultra-violet absorber and free radical and caught
The mixing of agent is obtained, can effectively increase the use time of inner wall putty；It is greasy that the addition of other additives can effectively improve interior wall
The performance of son；
（2）, contain a certain proportion of silica flour, waterproof powder, ultralight clay, diatomite in powder, this is significantly stronger, and interior wall is greasy
The waterproof ability of son, especially with the addition of waterproof powder, and the addition of ultralight clay, add the cementitiousness of inner wall putty, prevent
Only ftracture；Diatomite absorbability is strong, chemical property is stable, wear-resisting, heat-resisting, improves physical strength and the shock resistance of inner wall putty
Ability；
（3）, in preparation method, effectively adjust the pH of rubber cement, prevent that alkalescence is too high, be easy to the construction of inner wall putty.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1
A kind of buildings decoration water-repellent paint of the present embodiment, including liquid material and powder：
Liquid material includes the raw material of following parts by weight：70 parts of acrylic emulsion, 0.5 part of levelling agent, 2 parts of dispersant, wetting agent 0.05
Part, 0.8 part of defoamer, 1 part of light stabilizer；
Powder includes the raw material of following parts by weight：200 parts of cement, 80 parts of silica flour, 50 parts of butyl rubber, 10 parts of asphalt,
90 parts of powdered whiting, 5 parts of water reducer, 40 parts of waterproof powder, 10 parts of ultralight clay, 30 parts of diatomite, 5 parts of stearic acid, flyash 8
Part.
In the present embodiment, acrylic emulsion is silicone acrylic emulsion, and solid content is 40%.
In the present embodiment, levelling agent is one kind or mixture of dimethyl silicone polymer and PSI, point
Powder is C16~C18 aliphatic alcohol polyethenoxies（10,20）Ether, wetting agent is silanol class nonionic surfactant, and defoamer is
The mixture of the fatty acid ester compounded thing of higher alcohols and silicone emulsion.
In the present embodiment, light stabilizer is the mixing that light covers agent, ultra-violet absorber and radical scavenger, photomask agent
For carbon black, ultra-violet absorber is salicylic acid esters, and radical scavenger is hindered amine as light stabilizer HALS, the match ratio of three
For 3:1:3.
In the present embodiment, cement is 42.5R Portland cements, and the mesh number of silica flour is 200 mesh, and water reducer is wooden
Plain sulfonate.
In the present embodiment, ultralight clay includes the raw material of following parts by weight：10 parts of paper pulp, 2 parts of PPG, polyethylene
Pva5 parts of alcohol, 3 parts of water.
The present embodiment additionally provides a kind of preparation method of buildings decoration water-repellent paint, comprises the following steps：
（1）, prepare waterproof powder：Industry sintering waste residue is well mixed with calcium hydroxide.Then fatty acid ammonium solution is added, fully
Stirring in the pasty state, just obtains waterproof powder after drying；
（2）, by above-mentioned parts by weight weigh various raw materials respectively；
（3）, liquid material poured into mixer, open mixer, it is 300r/min to make mixing speed, is then proportionally added into powder
Material, stirring 5min are until generation rubber cement；
（4）, determine rubber cement pH, and make rubber cement pH value be 7, then proceed to stir 2min.
Wherein,
Step（3）Add before powder, asphalt and butyl rubber are first passed through into 140 DEG C of meltings.
Embodiment 2
A kind of buildings decoration water-repellent paint of the present embodiment, including liquid material and powder：
Liquid material includes the raw material of following parts by weight：85 parts of acrylic emulsion, 0.8 part of levelling agent, 2.5 parts of dispersant, wetting agent
0.08 part, 0.9 part of defoamer, 1.5 parts of light stabilizer；
Powder includes the raw material of following parts by weight：250 parts of cement, 100 parts of silica flour, 55 parts of butyl rubber, 15 parts of asphalt,
110 parts of powdered whiting, 7 parts of water reducer, 50 parts of waterproof powder, 15 parts of ultralight clay, 35 parts of diatomite, 7 parts of stearic acid, flyash
10 parts.
In the present embodiment, acrylic emulsion is silicone acrylic emulsion, and solid content is 45%.
In the present embodiment, levelling agent is one kind or mixture of dimethyl silicone polymer and PSI, point
Powder is C16~C18 aliphatic alcohol polyethenoxies（10,20）Ether, wetting agent is silanol class nonionic surfactant, and defoamer is
The mixture of the fatty acid ester compounded thing of higher alcohols and silicone emulsion.
In the present embodiment, light stabilizer is the mixing that light covers agent, ultra-violet absorber and radical scavenger, photomask agent
For carbon black, ultra-violet absorber is salicylic acid esters, and radical scavenger is hindered amine as light stabilizer HALS, the match ratio of three
For 3:1:3.
In the present embodiment, cement is 42.5R Portland cements, and the mesh number of silica flour is 200-400 mesh, and water reducer is
Lignosulfonates.
In the present embodiment, ultralight clay includes the raw material of following parts by weight：It is 10-20 parts of paper pulp, 3 parts of PPG, poly-
Pva5.5 parts of vinyl alcohol, 5 parts of water.
The present embodiment additionally provides a kind of preparation method of buildings decoration water-repellent paint, comprises the following steps：
（1）, prepare waterproof powder：Industry sintering waste residue is well mixed with calcium hydroxide.Then fatty acid ammonium solution is added, fully
Stirring in the pasty state, just obtains waterproof powder after drying；
（2）, by above-mentioned parts by weight weigh various raw materials respectively；
（3）, liquid material poured into mixer, open mixer, it is 400r/min to make mixing speed, is then proportionally added into powder
Material, stirring 8min are until generation rubber cement；
（4）, determine rubber cement pH, and make rubber cement pH value be 8, then proceed to stir 3min.
Wherein,
Step（3）Add before powder, asphalt and butyl rubber are first passed through into 150 DEG C of meltings.
Embodiment 3
A kind of buildings decoration water-repellent paint of the present embodiment, including liquid material and powder：
Liquid material includes the raw material of following parts by weight：100 parts of acrylic emulsion, 1 part of levelling agent, 3 parts of dispersant, 0.1 part of wetting agent,
1 part of defoamer, 2 parts of light stabilizer；
Powder includes the raw material of following parts by weight：300 parts of cement, 150 parts of silica flour, 60 parts of butyl rubber, 20 parts of asphalt,
120 parts of powdered whiting, 10 parts of water reducer, 60 parts of waterproof powder, 20 parts of ultralight clay, 40 parts of diatomite, 10 parts of stearic acid, fine coal
12 parts of ash.
In the present embodiment, acrylic emulsion is silicone acrylic emulsion, and solid content is 50%.
In the present embodiment, levelling agent is one kind or mixture of dimethyl silicone polymer and PSI, point
Powder is C16~C18 aliphatic alcohol polyethenoxies（10,20）Ether, wetting agent is silanol class nonionic surfactant, and defoamer is
The mixture of the fatty acid ester compounded thing of higher alcohols and silicone emulsion.
In the present embodiment, light stabilizer is the mixing that light covers agent, ultra-violet absorber and radical scavenger, photomask agent
For carbon black, ultra-violet absorber is salicylic acid esters, and radical scavenger is hindered amine as light stabilizer HALS, the match ratio of three
For 3:1:3.
In the present embodiment, cement is 42.5R Portland cements, and the mesh number of silica flour is 400 mesh, and water reducer is wooden
Plain sulfonate.
In the present embodiment, ultralight clay includes the raw material of following parts by weight：20 parts of paper pulp, 5 parts of PPG, polyethylene
Pva6 parts of alcohol, 8 parts of water.
The present embodiment additionally provides a kind of preparation method of buildings decoration water-repellent paint, comprises the following steps：
（1）, prepare waterproof powder：Industry sintering waste residue is well mixed with calcium hydroxide.Then fatty acid ammonium solution is added, fully
Stirring in the pasty state, just obtains waterproof powder after drying；
（2）, by above-mentioned parts by weight weigh various raw materials respectively；
（3）, liquid material poured into mixer, open mixer, it is 500r/min to make mixing speed, is then proportionally added into powder
Material, stirring 10min are until generation rubber cement；
（4）, determine rubber cement pH, and make rubber cement pH value be 9, then proceed to stir 4min.
Wherein,
Step（3）Add before powder, asphalt and butyl rubber are first passed through into 140-170 DEG C of melting.
Detection method in JC/T894-2001, embodiment 1-4 test experience data are as follows：
From the foregoing, it will be observed that the performance of inner wall putty is superior to I category alignment request in JC/T894-2001 in embodiment 1-3, with compared with
Good ground performance.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of buildings decoration water-repellent paint, it is characterised in that：Including liquid material and powder：
Liquid material includes the raw material of following parts by weight：70-100 parts of acrylic emulsion, 0.5-1 parts of levelling agent, 2-3 parts of dispersant, profit
0.05-0.1 parts of humectant, 0.8-1 parts of defoamer, 1-2 parts of light stabilizer；
Powder includes the raw material of following parts by weight：200-300 parts of cement, 80-150 parts of silica flour, 50-60 parts of butyl rubber, stone
10-20 parts of oil asphalt, 90-120 parts of powdered whiting, 5-10 parts of water reducer, 40-60 parts of waterproof powder, ultralight clay 10-20 parts,
30-40 parts of diatomite, 5-10 parts of stearic acid, 8-12 parts of flyash.
2. buildings decoration water-repellent paint according to claim 1, it is characterised in that：Acrylic emulsion is the breast of silicon third
Liquid, solid content is 40-50%.
3. buildings decoration water-repellent paint according to claim 1, it is characterised in that：Levelling agent is polydimethylsiloxanes
One kind or mixture of alkane and PSI, dispersant are C16~C18 aliphatic alcohol polyethenoxies（10,20）Ether, profit
Humectant is silanol class nonionic surfactant, and defoamer is the mixture of the fatty acid ester compounded thing of higher alcohols and silicone emulsion.
4. buildings decoration water-repellent paint according to claim 1, it is characterised in that：Light stabilizer is that light covers agent, purple
The mixing of ultraviolet absorbers and radical scavenger, photomask agent is carbon black, and ultra-violet absorber is salicylic acid esters, free radical
Capturing agent is hindered amine as light stabilizer HALS, and the match ratio of three is 3:1:3.
5. buildings decoration water-repellent paint according to claim 1, it is characterised in that：Cement is the common silicic acid of 42.5R
Salt cement, the mesh number of silica flour is 200-400 mesh, and water reducer is lignosulfonates.
6. buildings decoration water-repellent paint according to claim 1, it is characterised in that：Ultralight clay includes following weight
The raw material of part：10-20 parts of paper pulp, 2-5 parts of PPG, pva5-6 parts of polyvinyl alcohol, 3-8 parts of water.
7. a kind of preparation method of buildings decoration water-repellent paint according to claim 1-6, it is characterised in that：Including
Following steps：
（1）, prepare waterproof powder：Industry sintering waste residue is well mixed with calcium hydroxide；
Then fatty acid ammonium solution is added, is sufficiently stirred in the pasty state, waterproof powder just being obtained after drying；
（2）, by above-mentioned parts by weight weigh various raw materials respectively；
（3）, liquid material poured into mixer, open mixer, it is 300-500r/min to make mixing speed, is then proportionally added into
Powder, stirring 5-10min are until generation rubber cement；
（4）, determine rubber cement pH, and make rubber cement pH value be 7-9, then proceed to stir 2-4min.
8. the preparation method of buildings decoration water-repellent paint according to claim 7, it is characterised in that：Step（3）Plus
Enter before powder, asphalt and butyl rubber are first passed through into 140-170 DEG C of melting.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603372A (en) * | 2017-09-28 | 2018-01-19 | 马鞍山松鹤信息科技有限公司 | A kind of external wall specific complex coating and its preparation technology |
| CN107892835A (en) * | 2017-12-04 | 2018-04-10 | 薛银福 | A kind of preparation method of powder of lacquer putty for use on |
| CN108192392A (en) * | 2018-01-31 | 2018-06-22 | 南京安德丽涂料有限公司 | A kind of healthy functions type interior wall diatom ooze coating and preparation method thereof |
| CN109021799A (en) * | 2018-06-29 | 2018-12-18 | 深圳市艾贝比品牌管理咨询有限公司 | A kind of automobile-used paint for decoration |
| CN109824313A (en) * | 2019-03-27 | 2019-05-31 | 山东省环境保护科学研究设计院有限公司 | A kind of environmental project waterproof layer, preparation method and construction method |
| CN112707720A (en) * | 2021-01-31 | 2021-04-27 | 鞍山赛诺新材料有限公司 | Anhydrous converter large fabric with self-flowing effect |
| CN114656842A (en) * | 2022-04-27 | 2022-06-24 | 广东家实多集团有限公司 | Bridge waterproof coating |
| CN115895374A (en) * | 2022-12-09 | 2023-04-04 | 河南华瑞兴业防水科技有限公司 | Polymer cement waterproof coating for exterior wall decoration |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603372A (en) * | 2017-09-28 | 2018-01-19 | 马鞍山松鹤信息科技有限公司 | A kind of external wall specific complex coating and its preparation technology |
| CN107892835A (en) * | 2017-12-04 | 2018-04-10 | 薛银福 | A kind of preparation method of powder of lacquer putty for use on |
| CN108192392A (en) * | 2018-01-31 | 2018-06-22 | 南京安德丽涂料有限公司 | A kind of healthy functions type interior wall diatom ooze coating and preparation method thereof |
| CN108192392B (en) * | 2018-01-31 | 2020-09-29 | 南京安德丽新材料科技有限公司 | Healthy functional inorganic diatom ooze coating for interior wall and preparation method thereof |
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