CN107114821A - The apparatus and method that a kind of hot trapping prepares smoke spices - Google Patents
The apparatus and method that a kind of hot trapping prepares smoke spices Download PDFInfo
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- CN107114821A CN107114821A CN201710552513.7A CN201710552513A CN107114821A CN 107114821 A CN107114821 A CN 107114821A CN 201710552513 A CN201710552513 A CN 201710552513A CN 107114821 A CN107114821 A CN 107114821A
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- solvent
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
- A24B15/26—Use of organic solvents for extraction
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/20—Biochemical treatment
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Abstract
The invention provides the device that a kind of hot trapping prepares smoke spices, including pyrolysis installation and capturing device；Pyrolysis installation includes setting volume control device on sample heating device, the sample bearing device being arranged on the sample heating device, the source of the gas by pipeline being connected with sample bearing device, pipeline；Capturing device includes smoke inlet and exports the solvent bogey being connected, the solvent heater for heating the solvent bogey with sample heating device and be arranged at the solvent bogey, and the condensing unit being connected with solvent bogey steam (vapor) outlet.The solvent refluxing capturing device that the present invention is used can improve arresting efficiency compared with normal temperature or low-temperature solvent cold hydrazine absorption plant, save solvent usage amount, improve fragrance matter concentration in trapping solution, tobacco tar quality is improved, realizes and traps a large amount of products with a small amount of solvent, reduce the frequency for changing dissolving.Apparatus of the present invention simple economy, easily realizes industrialized mass production, there is good application prospect.
Description
Technical field
The present invention relates to technical field of cigarettes, the apparatus and method that smoke spices is prepared more particularly, to a kind of hot trapping.
Background technology
Traditional cigarette meets consumer demand by lighting pipe tobacco generation flue gas, is waved during cigarette burning by material
Hair, pyrolysis and high―temperature nuclei, make have up to more than 7300 to plant compound in flue gas, wherein by (nearly 900 DEG C of maximum temperature) production of burning
Raw material has 2740 kinds, and these material parts are relevant with cigarette characteristic chicken flavor, but have moieties it is harmful (such as CO,
Benzo [α] pyrene, condensed-nuclei aromatics etc.).
Due to smoking and environment, anti-smoking campaign lasting surging and smoker for healthy demand, low tar,
Less harmful cigarette is more paid attention to, while also being flourished without the novel tobacco product of burning.By using electronic cigarette or
Heating does not burn cigarette to replace traditional cigarette to be current Field of Tobacco developing direction.Do not burnt cigarette in electronic cigarette and heating
In, (usually less than 500 DEG C) can be just transferred in flue gas at a lower temperature for nicotine and most tobacco flavor compositions, because
This will not produce harmful substance and the side-stream smoke that cigarette is produced by high-temp combustion, and cigarette can be greatly reduced to health
Harm and the pollution to environment.
Electronic cigarette or the heating cigarette etc. that do not burn have smog but incombustible novel tobacco product principle is：By heating,
By present in the mist formation such as glycerine, propane diols material, alkaloid, tobacco or additional aroma substance, other flavoring ingredients together
Evaporate to form aerosol, enjoyed for smoker.Although these products technically have been achieved for rapid progress, mesh
These products of preceding in the market generally have larger gap on taste and aromatic style with traditional cigarette.Its reason is to lack tradition
Cigarette burning and high-temperature retorting pyrolytic process, also just have lost based on distinctive fragrance in the flue gas produced by these processes into
Point, it is difficult to make smoker obtain the distinctive pleasure of the senses of traditional cigarette, and add traditional tobacco extract and existing essence and flavoring agent
Method can not make up this defect.
Therefore, people are handled tobacco using the mode of high temperature pyrolysis, imitate conventional cigarette and enter in combustion
The complex reaction process such as capable thermal cracking, Mei Lade, obtains tobacco response product and for novel tobacco product, can be in certain journey
Make up electronic cigarette on degree or the do not burn novel tobacco product such as cigarette insufficient fragrance, smoke feature of heating lacks or unobvious etc. lacked
Fall into.
But the research of the relevant tobacco pyrolysis of prior art is concentrated mainly on pyrolysis temperature to Product safety and organoleptic attribute
Influence.Existing mode of heating can cause the heated inequality of tobacco-containing material, wherein it is higher with the portion temperature of heater contacts, far
Portion temperature from heater is relatively low, the phenomenon being easily charred, and influences the mouthfeel of destructive distillation cut.Meanwhile, prior art is often
It is pyrolyzed using in closed container, offal is easy to blackening in anaerobic high-temperature heating process, is also easy to produce the tobacco tar of black, obtains
Product smoke is overweight.Meanwhile, there is the problem of arresting efficiency is poor in prior art.
The content of the invention
In view of this, the technical problem to be solved in the present invention is to provide the device that a kind of hot trapping prepares smoke spices,
The smoke concentration of perfume that the device that the present invention is provided is prepared is big, and smoke is moderate while the content for preparing spices is high.
The invention provides the device that a kind of hot trapping prepares smoke spices, including pyrolysis installation and capturing device；
Pyrolysis installation includes：Sample heating device, the sample bearing device and sample being arranged on the sample heating device
Volume control device is set on the source of the gas that product bogey is connected by pipeline, pipeline；
Capturing device includes：Smoke inlet exports the solvent bogey being connected, for heating with sample heating device
State the solvent heater of solvent bogey and be arranged on the solvent bogey, and go out with solvent bogey steam
The connected condensing unit of mouth.
It is preferred that, the sample heating device is heater；The sample bearing device is flask；The flow control dress
It is set to flow valve.
It is preferred that, the solvent bogey is arranged on the solvent heater.
It is preferred that, the solvent bogey is solvent bottle；The condensing unit is condenser pipe.
It is preferred that, the sample bearing device is connected with solvent bogey by connecting tube, is set in the connecting tube
There is switch valve.
The invention provides a kind of method that hot trapping prepares smoke spices, including：
Tobacco sample is placed on sample bearing device, is pyrolyzed through sample heating device, the flue gas after being pyrolyzed；
After the gas that source of the gas is provided adjusts flow through volume control device, carry the flue gas after pyrolysis and carry dress into solvent
Put, with by solvent heating devices heat solvent obtain solvent vapo(u)r mix, condensing unit condensation, the solvent in solvent bogey
Absorb, obtain smoke spices.
It is preferred that, the solvent is selected from water, ethanol, ether, acetone, petroleum ether, solvent naphtha, n-hexane, hexamethylene, penta
One or more in alkane, dichloromethane and ethyl acetate.
It is preferred that, the gas that the source of the gas is provided is inert gas.
It is preferred that, the tobacco sample is placed in before sample bearing device by pretreatment, and the pretreatment is using at enzyme
Manage tobacco sample, one or more of the enzyme in cellulase and pectase.
It is preferred that, the tobacco sample is placed in before sample bearing device by pretreatment, and the pretreatment is by tobacco sample
Product are mixed with Alevaire.
Compared with prior art, the invention provides the device that a kind of hot trapping prepares smoke spices, including pyrolysis installation
And capturing device；Pyrolysis installation include sample heating device, be arranged on the sample heating device sample bearing device, with
Volume control device is set on the source of the gas that sample bearing device is connected by pipeline, pipeline；Capturing device include smoke inlet with
Sample heating device exports connected solvent bogey, the solvent heater for heating the solvent bogey and set
It is placed on the solvent bogey, and the condensing unit being connected with solvent bogey steam (vapor) outlet.It is molten that the present invention is used
Agent flows back capturing device compared with normal temperature or low-temperature solvent cold hydrazine absorption plant, can improve arresting efficiency, saves solvent and uses
Amount, improves fragrance matter concentration in trapping solution, improves tobacco tar quality, realizes and traps a large amount of products with a small amount of solvent, reduces and change
The frequency of dissolving.Apparatus of the present invention simple economy, easily realizes industrialized mass production, there is good application prospect.
Brief description of the drawings
Fig. 1 is the device of the hot trapping preparation smoke spices described in one of embodiment of the invention.
Embodiment
The invention provides the device that a kind of hot trapping prepares smoke spices, including pyrolysis installation and capturing device；
Pyrolysis installation includes：Sample heating device, the sample bearing device and sample being arranged on the sample heating device
Volume control device is set on the source of the gas that product bogey is connected by pipeline, pipeline；
Capturing device includes：Smoke inlet exports the solvent bogey being connected, for heating with sample heating device
State the solvent heater of solvent bogey and be arranged on the solvent bogey, and go out with solvent bogey steam
The connected condensing unit of mouth.
The device for the preparation smoke spices that the present invention is provided includes pyrolysis installation.
Pyrolysis installation includes sample heating device, the sample bearing device and sample being arranged on the sample heating device
Volume control device is set on the source of the gas that product bogey is connected by pipeline, pipeline.
The pyrolysis installation that the present invention is provided is used to tobacco sample heat resolve producing flue gas.
According to the present invention, the pyrolysis installation includes sample heating device.The present invention for the heater without
Limit, the heater well known to those skilled in the art that sample can be heated.The sample heating device is preferably
Heater.The present invention is for mode of heating without restriction, including but not limited to electrical heating, microwave heating, infrared heating, electricity
Beamlet heating etc..
The pyrolysis installation includes sample bearing device.The present invention for the sample bearing device without limit, can
To carry sample.Preferably flask；Including but not limited to round-bottomed flask.
According to the present invention, the pyrolysis installation includes the source of the gas being connected with sample bearing device by pipeline,
The present invention for the source of the gas without limit, it is well known to those skilled in the art.In the source of the gas preferably
It is provided with inert gas, more preferably nitrogen.
The present invention is for the pipeline without restriction, pipeline well known to those skilled in the art.Gas can be produced
Body drives the flue gas of pyrolysis to enter solvent bogey.
Wherein, volume control device is set on the pipeline；The volume control device is preferably gas flow valve.
Pyrolysis of the present invention is pyrolysis under closed environment.
The capturing device that the present invention is provided includes：Smoke inlet exports the solvent being connected with sample heating device and carries dress
Put, the solvent heater for heating the solvent bogey and be arranged at the solvent bogey, and and solvent
The connected condensing unit of bogey steam (vapor) outlet.
According to the present invention, capturing device includes smoke inlet and exports the solvent bogey being connected with sample heating device.
Wherein, the solvent bogey is preferably disposed on the solvent heater.
The sample bearing device is connected with solvent bogey by connecting tube, and the present invention does not enter for the connecting tube
Row is limited, connecting tube well known to those skilled in the art.Wherein, it is preferably provided with switch valve in the connecting tube.
In the present invention, the solvent bogey is provided with smoke inlet and solvent bogey steam (vapor) outlet.
According to the present invention, the solvent bogey is preferably sample bottle；More preferably three-necked flask.
It is preferred that, in the solvent in the line end immersion solvent bogey of the smoke collecting cover outlet.
Solvent is provided with solvent bogey of the present invention；The solvent is preferably water, ethanol, ether, acetone, oil
One or more in ether, solvent naphtha, n-hexane, hexamethylene, pentane, dichloromethane and ethyl acetate.
According to the present invention, capturing device includes the solvent heater for being used to heat the solvent bogey；It is preferred that,
Solvent bogey of the present invention is arranged on the solvent heater.
The present invention for the solvent heater without limit, it is well known to those skilled in the art.Preferably
Adjustable thermostatic heater.Solvent can be heated so that solvent seethes with excitement, be steamed in device comprising solvent using said apparatus
Vapour, preferably absorbs to flue gas.
Flue gas of the present invention exists for aerosol form, using condensing trapping, normal temperature or low disclosed in prior art
Warm solvent absorption effect is poor.Because offal thermal decomposition product is the stronger aerosol of stability, room temperature or general low temperature are not
Easily condensation, normal temperature or low-temperature solvent assimilation effect are limited, and solubility is low, easily absorbs saturation, so absorbing liquid need to be often changed,
Solvent acquisition amount is big.
According to the present invention, capturing device include be arranged on the solvent bogey, and with solvent bogey steam
The connected condensing unit in outlet.
In the present invention, described condensing unit one end is connected with solvent bogey steam (vapor) outlet, and the other end sets for opening
Put.
The present invention to condensing unit without limiting, well known to those skilled in the art, preferably condenser pipe.This hair
The bright liquid in the condenser pipe is well known to those skilled in the art without limiting, and can be normal-temperature water or low
Warm solution.
One end of condenser pipe of the present invention is connected with bogey steam (vapor) outlet, for by solvent vapo(u)r and flue gas vapors
Condensation, the other end, which is opened, to be set, the gas for discharging source of the gas.
One end of the connecting tube of solvent bogey and sample bearing device of the present invention is preferably inserted into the solvent in solvent bottle
In, so as to improve arresting efficiency.
The invention provides the device that a kind of hot trapping prepares smoke spices, including pyrolysis installation and capturing device；Pyrolysis
Device includes sample heating device, the sample bearing device being arranged on the sample heating device, led to sample bearing device
Cross on the connected source of the gas of pipeline, pipeline and volume control device is set；Capturing device goes out including smoke inlet with sample heating device
Mouthful connected solvent bogey, the solvent heater for heating the solvent bogey and it is arranged at the solvent and holds
Carry and put, and the condensing unit being connected with solvent bogey steam (vapor) outlet.The solvent refluxing capturing device that the present invention is used
Compared with normal temperature or low-temperature solvent cold hydrazine absorption plant, arresting efficiency can be improved, solvent usage amount is saved, improved in trapping solution
Fragrance matter concentration, improves tobacco tar quality, realizes and traps a large amount of products with a small amount of solvent, reduces the frequency for changing dissolving.This hair
Bright device simple economy, easily realizes industrialized mass production, there is good application prospect.
Hot trapping described in the one of embodiment of the present invention prepares the device of smoke spices as shown in figure 1, Fig. 1 is this hair
Hot trapping described in bright one of embodiment prepares the device of smoke spices, wherein, 1 is sample heating device, and 2 hold for sample
Carry and put；3 be condensing unit；4 be solvent bogey, and 5 be solvent heater, and 6 be connecting tube；7 be switch valve, and 8 be stream
Amount control device, 9 be source of the gas.
The invention provides a kind of method that hot trapping prepares smoke spices, including：
Tobacco sample is placed on sample bearing device, is pyrolyzed through sample heating device, the flue gas after being pyrolyzed；
After the gas that source of the gas is provided adjusts flow through volume control device, carry the flue gas after pyrolysis and carry dress into solvent
Put, with by solvent heating devices heat solvent obtain solvent vapo(u)r mix, condensing unit condensation, the solvent in solvent bogey
Absorb, be absorbed liquid, and absorbing liquid is concentrated to obtain smoke spices.
Tobacco sample is placed on sample bearing device by the method that the hot trapping that the present invention is provided prepares smoke spices first,
It is pyrolyzed through sample heating device, the flue gas after being pyrolyzed.
The present invention, without limiting, can carry out the tobacco sample that pyrolysis prepares smoke spices for the tobacco sample,
To its shape without limiting, tobacco leaf, pipe tobacco and offal；Preferably offal.
In the present invention, the tobacco sample is placed in preferably through pretreatment before sample bearing device, and the pretreatment is excellent
Elect as using ferment treatment tobacco sample, one or more of the enzyme in cellulase and pectase.The ferment treatment
Mode is specially：
By offal moisture regulation to 15%-20%, then add and contain cellulase and pectin in complex enzyme, complex enzyme
The mass ratio of enzyme, cellulase and pectase is 1:1~10；It is preferred that, the mass ratio of cellulase and pectase is 1:1~5,
Wherein, the enzyme activity for using cellulase is 150,000 U/g, and the enzyme activity of used pectase is 30,000 U/g；Complex enzyme
Addition is the 0.01%~1.0% of offal quality, preferably 0.05%~1.0%；Hydrolysis temperature is 30~60 DEG C, preferably
40~50 DEG C；Enzymolysis time 4~24 hours, preferably 6~10 hours.
It is preferred that being specially：By offal moisture regulation to 18%, 0.005g complex enzyme (celluloses are then added with every gram of offal
The mass ratio of enzyme and pectase is 1:2), digested 8 hours under the conditions of 45 DEG C after mixing, enzymolysis is used to be pyrolyzed after terminating.With not
Directly it is pyrolyzed products therefrom using enzymolysis to compare, reheating solution products therefrom has denseer baking fragrant after enzymolysis, and mouthfeel is more
Comfortably.
After ferment treatment, moisture is preferably adjusted.Enzyme both degradable cell wall substance, makes fragrance matter be easier release,
Fragrance matter can be also produced after catabolite pyrolysis；Regulation moisture can make its moisture be maintained at certain value, in heating process
Fragrance matter is taken while middle moisture evaporation out of, while ensureing that tobacco-containing material can reach the temperature of needs within the identical time
Degree.
After ferment treatment, moisture is preferably adjusted.Enzyme both degradable cell wall substance, makes fragrance matter be easier release,
Fragrance matter can be also produced after catabolite pyrolysis；Regulation moisture can make its moisture be maintained at certain value, in heating process
Fragrance matter is taken while middle moisture evaporation out of, while ensureing that tobacco-containing material can reach the temperature of needs within the identical time
Degree.
Pretreatment of the present invention can also be to mix in offal material with Maillard reaction raw material, and regulation moisture contains
Amount.Maillard reaction raw material can be sugar and/or amino acid, be heated using the later stage, make between admixture or admixture and cigarette
Maillard reaction occurs between last chemical composition, fragrance matter is produced.
Pretreatment of the present invention can also adjust moisture to be mixed in offal material with Alevaire.Alevaire is
Propane diols or glycerine, Alevaire infiltration tobacco material, can reduce the burning that tobacco material coking is brought in pyrolytic process, simultaneously
It can be swelled its fibr tissue, be conducive to aroma component to volatilize, and Alevaire can dissolve aroma component, in pyrolysis installation
During middle atomization, aroma component can be also carried out.
The temperature of pyrolysis of the present invention is preferably 200 DEG C~450 DEG C；More preferably 250 DEG C~350 DEG C；The pyrolysis
Time be preferably 5~180min；More preferably 10~150min.
According to the present invention, the gas that source of the gas is provided adjusts flow through volume control device.The gas that source of the gas is provided herein is excellent
Elect inert gas or air as.By controlling gas flow, so as to control the flow velocity of the flue gas of gas carrying, the present invention is for institute
Gas flow is stated without restriction, depending on single unit system size, preferably solvent vapo(u)r and flue gas can be condensed well.
After the gas that source of the gas is provided adjusts flow through volume control device, carry the flue gas after pyrolysis and carry dress into solvent
Put, with by solvent heating devices heat solvent obtain solvent vapo(u)r mix, condensing unit condensation, the solvent in solvent bogey
Absorb, be absorbed liquid.
Wherein, solvent of the present invention is preferably water, ethanol, ether, acetone, petroleum ether, solvent naphtha, n-hexane, hexamethylene
One or more in alkane, pentane, dichloromethane and ethyl acetate；More preferably ethanol, ether, acetone, petroleum ether, solvent
One or more in oil, n-hexane and hexamethylene；Most preferably ethanol.
The concentration of the ethanol solution is preferably 90%~95%.The gas flow is preferably 100~120mL/min.
The preferred heated solvent of solvent heater extremely seethes with excitement.Temperature can be equal to or higher than solvent boiling point.The condensation dress
Put interior circulation liquid and be provided with water or low-temperature solvent.
It is absorbed after liquid, absorbing liquid is concentrated to obtain smoke spices.
Concrete mode of the invention for the concentration is well known to those skilled in the art without limiting.It is preferred that
To be concentrated under reduced pressure.
The present invention compared with normal temperature or low-temperature solvent absorption process, can improve arresting efficiency using solvent refluxing method of trapping,
Solvent usage amount is saved, fragrance matter concentration in trapping solution is improved, tobacco tar quality is improved, realizes and traps big volume production with a small amount of solvent
Thing, reduces the frequency for changing dissolving, and its principle is, the aerosol after offal pyrolysis mixes latter cold with entering with solvent vapo(u)r
Solidifying pipe, in mixed process Central Plains, the stability of aerosol is destroyed, and offal thermal decomposition product is in the solvent or solvent vapo(u)r of heat
In have bigger solubility, be back in the lump in solvent with the condensation of solvent vapo(u)r, so as to improve in arresting efficiency and tobacco tar fragrant
Taste material concentration.Offal pretreatment can improve product qualities.Thermal decomposition product is refined, pyrolysis residue is extracted and product is assembled
Offal raw material can be made full use of etc. subsequent treatment, product qualities also can be further improved.
The fragrance component of smoke spices of the present invention preferably by GC-MS to preparing is analyzed, and analysis condition is such as
Under：
Sample pre-treatments：A certain amount of anethole is added in trapping solution as internal standard, concentration crosses to be analyzed after film.
Gas chromatography-mass spectrography parameter：
Gas-chromatography：Analytical column is HP-5MS (30m × 0.25mm × 0.25um)；Carrier gas is helium, purity >=
99.999%；Constant current mode, flow velocity is 1.0mL/min；Injector temperature is 250 DEG C；Split ratio is 10:1；Column temperature takes program
Heating mode：50 DEG C of initial temperature, keeps 2min, is then warming up to 250 DEG C, holding, 30min with 5 DEG C/min.
Mass spectrum：250 DEG C of transmission line temperature；Ionization mode：Electron bombardment ionization source (EI+)；Monitoring mode：Full scan pattern is determined
Property, scanning range：33-550amu；Ionizing energy：70eV；200 DEG C of ion source temperature；Quadrupole rod temperature is：150℃；Solvent prolongs
Late：6.5min.
The present invention is by taking absorbing liquid with propane diols, glycerine by 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, please be special
Family smokes panel test.
In order to further illustrate the present invention, the device of preparations smoke spices provided with reference to embodiments the present invention with
Method is described in detail.
Embodiment 1
Device is connected according to of the present invention, is specially：Sample flask is placed on adjustable thermostatic heater, three mouthfuls of burnings
Bottle is placed on solvent heater, opens Nitrogen source gases, adjusting gas flow valve, smoke inlet and the sample flask gas of three-necked flask
Body outlet is connected, and steam (vapor) outlet is connected with condensing unit, and the condensing unit other end, which is opened, to be set.
Embodiment 2
Connected according to the embodiment of the present invention 1 and 60mL95% ethanol solutions are previously added in device, three-necked flask, closing is opened
Valve is closed, solvent heater is opened, and its temperature is set as 80 DEG C, 10 grams of offals are previously added in shuttle, solvent bottle is treated
In solvent come to life after, open switch valve, while open gas flow valve, make source of the gas provide nitrogen flow be 100mL/
Min, opens sample heating device and temperature is set as into 350 DEG C, be pyrolyzed 1 hour, pyrolysis uses 10mL95% ethanol solutions after terminating
The smoke condensate in connecting tube is washed out, and is merged with the solvent in solvent bottle, amalgamation liquid volume is supplied with 95% ethanol
80mL, take 20mL liquid it is concentrated, dry after its flavor component is analyzed with GC/MS, separately take 20mL liquid and propane diols, glycerine
By 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, asks expert to smoke panel test.
Comparative example 1
The present embodiment is substantially the same manner as Example 2, and difference is to use solvent cold trapping, is specially：Connecting tube (7)
One end with 3 series connection absorption bottles be connected, each absorption bottle is placed in -15 DEG C built with 20mL95% ethanol solutions, absorption bottle
In cold-trap, pyrolysis merges the solvent of 3 absorption bottles after terminating, and the flue gas washed out with 10mL95% ethanol solutions in connecting tube is cold
Condensate, 80mL is supplied with 95% ethanol by amalgamation liquid volume, take that 20mL liquid is concentrated, dry after that its is analyzed with GC/MS is fragrant
Taste composition, separately takes 20mL liquid with propane diols, glycerine by 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, asks expert to smoke panel test.
Embodiment 3
Connected according to the embodiment of the present invention 1 and 60mL95% ethanol solutions are previously added in device, three-necked flask, closing is opened
Valve is closed, solvent heater is opened, and its temperature is set as 80 DEG C, 10 grams of offals are previously added in shuttle, solvent bottle is treated
In solvent come to life after, open switch valve, while open gas flow valve, make source of the gas provide nitrogen flow be 100mL/
Min, opens sample heating device and temperature is set as into 350 DEG C, be pyrolyzed 1 hour, continuous in the case where being changed without trapping solvent
3 pyrolysis samples of trapping.Pyrolysis washes out the smoke condensate in connecting tube with 10mL95% ethanol solutions after terminating, with solvent bottle
In solvent merge, amalgamation liquid volume is supplied into 80mL with 95% ethanol, take 20mL liquid it is concentrated, dry after use GC/MS
Its flavor component is analyzed, separately takes 20mL liquid with propane diols, glycerine by 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, please
Expert smokes panel test.
Embodiment 4
Connected according to the embodiment of the present invention 1 and 60mL95% ethanol solutions are previously added in device, three-necked flask, closing is opened
Valve is closed, solvent heater is opened, and its temperature is set as 80 DEG C, 10 grams of cigarettes through enzymolysis processing are previously added in shuttle
End, the enzymolysis processing is specially：By offal moisture regulation to 18%, 0.005g complex enzymes are then added with every gram of offal (fine
The mass ratio of the plain enzyme of dimension and pectase is 1:2), digested 8 hours under the conditions of 45 DEG C after mixing, enzymolysis is used to be pyrolyzed after terminating.
After the solvent in solvent bottle comes to life, switch valve is opened, while gas flow valve is opened, the nitrogen flow that source of the gas is provided
For 100mL/min, open sample heating device and temperature is set as 350 DEG C, be pyrolyzed 1 hour, pyrolysis uses 10mL95% after terminating
Ethanol solution washes out the smoke condensate in connecting tube, and merges with the solvent in solvent bottle, will merge liquid with 95% ethanol
Product supplies 80mL, take that 20mL liquid is concentrated, dry after its flavor component is analyzed with GC/MS, separately take 20mL liquid and the third two
Alcohol, glycerine press 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, asks expert to smoke panel test.
Comparative example 2
The present embodiment and comparative example 2 are essentially identical, and difference is continuously to catch in the case where being changed without trapping solvent
3 pyrolysis samples of collection.Specially：One end of connecting tube (7) with 3 series connection absorption bottles be connected, each absorption bottle built with
20mL95% ethanol solutions, absorption bottle is placed in -15 DEG C of cold-traps, and pyrolysis merges the solvent of 3 absorption bottles after terminating, be changed without
Continuous 3 pyrolysis samples of trapping in the case of trapping solvent.And the flue gas washed out with 10mL95% ethanol solutions in connecting tube is cold
Condensate, 80mL is supplied with 95% ethanol by amalgamation liquid volume, take that 20mL liquid is concentrated, dry after that its is analyzed with GC/MS is fragrant
Taste composition, separately takes 20mL liquid with propane diols, glycerine by 1:1:It is used for electronic cigarette after 1 (volume ratio) mixing, asks expert to smoke panel test.
Embodiment 5
Expert's smoking result：When embodiment 2 and the products therefrom of comparative example 1 are applied in electronic cigarette, burnt odor, baking are respectively provided with
Fragrant, sootiness is fragrant, have main aroma style close to traditional cigarette with it is jealous, both differences are not obvious；Embodiment 3 and comparative example 2
When products therefrom is applied in electronic cigarette, it is respectively provided with stronger burnt odor, bakees fragrant, sootiness perfume, but the aroma strength of embodiment 2 is bright
It is aobvious to be more than comparative example 2；Embodiment 4 compared with Example 2, the products therefrom of embodiment 4 in electronic cigarette using when, with denseer
Bakee fragrant, mouthfeel is more comfortable, and its aesthetic quality is substantially better than embodiment 2.
GC/MS analyzes flavor component result and shown, main baking fragrant class material (such as furfural, 5- methyl chaffs of embodiment 4
Aldehyde, 5 hydroxymethyl furfural etc.) content is more than 1.2 times of embodiment 2；Using identical solvent, trapped using solvent vapo(u)r
Method, its arresting efficiency is apparently higher than solvent cold trapping method.The representative flavor component comparision contents result such as following table in part.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of hot trapping prepares the device of smoke spices, it is characterised in that including pyrolysis installation and capturing device；
Pyrolysis installation includes：Sample heating device, the sample bearing device being arranged on the sample heating device, hold with sample
Carry and volume control device is set on the source of the gas put and be connected by pipeline, pipeline；
Capturing device includes：Smoke inlet and sample heating device export the solvent bogey, described molten for heating being connected
The solvent heater of agent bogey and be arranged on the solvent bogey, and with solvent bogey steam (vapor) outlet phase
Condensing unit even.
2. device according to claim 1, it is characterised in that the sample heating device is heater；The sample is held
Carry and be set to flask；The volume control device is flow valve.
3. device according to claim 1, it is characterised in that the solvent bogey is arranged at the solvent heating dress
Put.
4. device according to claim 1, it is characterised in that the solvent bogey is solvent bottle；The condensation dress
It is set to condenser pipe.
5. device according to claim 1, it is characterised in that the sample bearing device passes through even with solvent bogey
Switch valve is provided with adapter connection, the connecting tube.
6. a kind of method that hot trapping prepares smoke spices, it is characterised in that including：
Tobacco sample is placed on sample bearing device, is pyrolyzed through sample heating device, the flue gas after being pyrolyzed；
After the gas that source of the gas is provided adjusts flow through volume control device, carry the flue gas after pyrolysis and enter solvent bogey,
Solvent vapo(u)r is mixed, condensing unit condensation, the solvent in solvent bogey are inhaled with being obtained by solvent heating devices heat solvent
Receive, obtain smoke spices.
7. method according to claim 6, it is characterised in that the solvent is selected from water, ethanol, ether, acetone, oil
One or more in ether, solvent naphtha, n-hexane, hexamethylene, pentane, dichloromethane and ethyl acetate.
8. method according to claim 6, it is characterised in that the gas that the source of the gas is provided is inert gas.
9. method according to claim 6, it is characterised in that the tobacco sample is placed in before sample bearing device by pre-
Processing, the pretreatment is to use ferment treatment tobacco sample, one or more of the enzyme in cellulase and pectase.
10. method according to claim 6, it is characterised in that the tobacco sample, which is placed in before sample bearing device, to be passed through
Pretreatment, the pretreatment is to mix tobacco sample with Alevaire.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189857A (en) * | 2017-07-07 | 2017-09-22 | 重庆中烟工业有限责任公司 | A kind of apparatus and method for preparing smoke spices |
| CN107699333A (en) * | 2017-11-08 | 2018-02-16 | 江苏恒森烟草机械有限公司 | A kind of high temperature extracts tobacco tar device |
| CN107898002A (en) * | 2017-11-29 | 2018-04-13 | 倪以秀 | A kind of apparatus and method for preparing smoke spices |
| CN110959891A (en) * | 2018-09-26 | 2020-04-07 | 浙江中烟工业有限责任公司 | Method for preparing functional tobacco shred fragrance raw material through immersion high-pressure low-temperature reaction |
| CN113727615A (en) * | 2019-06-05 | 2021-11-30 | 菲利普莫里斯生产公司 | Improved method for producing liquid tobacco extract |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3803004A (en) * | 1970-03-04 | 1974-04-09 | Tamag Basel Ag | Method for recovering steam-volatile organic bases,particularly alkaloids of tobacco |
| CN1491352A (en) * | 2001-02-07 | 2004-04-21 | 日本烟草产业株式会社 | Apparatus and method for extracting volatime components |
| CN203935633U (en) * | 2014-07-03 | 2014-11-12 | 浙江农林大学 | A kind of novel organic solvent recovery device |
| CN104621707A (en) * | 2015-01-29 | 2015-05-20 | 湖南中烟工业有限责任公司 | Aromatic tobacco extractive and electronic cigarette juice |
| CN104921287A (en) * | 2015-06-05 | 2015-09-23 | 浙江中烟工业有限责任公司 | Tobacco extract and preparing method and application thereof |
| CN105142430A (en) * | 2013-04-25 | 2015-12-09 | 日本烟草产业株式会社 | Process for producing constituent element for tasty thing containing flavoring ingredient, and constituent element for tasty thing containing flavoring ingredient |
| CN105595411A (en) * | 2016-02-01 | 2016-05-25 | 湖北中烟工业有限责任公司 | Method for preparing tobacco-characteristic-taste tobacco flavor material and electronic cigarette fluid containing tobacco flavor material |
| CN106028844A (en) * | 2014-02-26 | 2016-10-12 | 日本烟草产业株式会社 | Smoking flavor component extraction method and luxury food item constituent component manufacturing method |
| CN106028843A (en) * | 2014-02-26 | 2016-10-12 | 日本烟草产业株式会社 | Method for producing cigarette raw materials |
| CN106061295A (en) * | 2014-02-26 | 2016-10-26 | 日本烟草产业株式会社 | Smoking flavor component extraction method and luxury food item constituent-component manufacturing method |
| CN206880054U (en) * | 2017-07-07 | 2018-01-16 | 重庆中烟工业有限责任公司 | A kind of hot trapping prepares the device of smoke spices |
-
2017
- 2017-07-07 CN CN201710552513.7A patent/CN107114821B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3803004A (en) * | 1970-03-04 | 1974-04-09 | Tamag Basel Ag | Method for recovering steam-volatile organic bases,particularly alkaloids of tobacco |
| CN1491352A (en) * | 2001-02-07 | 2004-04-21 | 日本烟草产业株式会社 | Apparatus and method for extracting volatime components |
| CN105142430A (en) * | 2013-04-25 | 2015-12-09 | 日本烟草产业株式会社 | Process for producing constituent element for tasty thing containing flavoring ingredient, and constituent element for tasty thing containing flavoring ingredient |
| CN106028844A (en) * | 2014-02-26 | 2016-10-12 | 日本烟草产业株式会社 | Smoking flavor component extraction method and luxury food item constituent component manufacturing method |
| CN106028843A (en) * | 2014-02-26 | 2016-10-12 | 日本烟草产业株式会社 | Method for producing cigarette raw materials |
| CN106061295A (en) * | 2014-02-26 | 2016-10-26 | 日本烟草产业株式会社 | Smoking flavor component extraction method and luxury food item constituent-component manufacturing method |
| CN203935633U (en) * | 2014-07-03 | 2014-11-12 | 浙江农林大学 | A kind of novel organic solvent recovery device |
| CN104621707A (en) * | 2015-01-29 | 2015-05-20 | 湖南中烟工业有限责任公司 | Aromatic tobacco extractive and electronic cigarette juice |
| CN104921287A (en) * | 2015-06-05 | 2015-09-23 | 浙江中烟工业有限责任公司 | Tobacco extract and preparing method and application thereof |
| CN105595411A (en) * | 2016-02-01 | 2016-05-25 | 湖北中烟工业有限责任公司 | Method for preparing tobacco-characteristic-taste tobacco flavor material and electronic cigarette fluid containing tobacco flavor material |
| CN206880054U (en) * | 2017-07-07 | 2018-01-16 | 重庆中烟工业有限责任公司 | A kind of hot trapping prepares the device of smoke spices |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189857A (en) * | 2017-07-07 | 2017-09-22 | 重庆中烟工业有限责任公司 | A kind of apparatus and method for preparing smoke spices |
| CN107189857B (en) * | 2017-07-07 | 2023-10-27 | 重庆中烟工业有限责任公司 | Device and method for preparing smoke flavor |
| CN107699333A (en) * | 2017-11-08 | 2018-02-16 | 江苏恒森烟草机械有限公司 | A kind of high temperature extracts tobacco tar device |
| CN107898002A (en) * | 2017-11-29 | 2018-04-13 | 倪以秀 | A kind of apparatus and method for preparing smoke spices |
| CN107898002B (en) * | 2017-11-29 | 2020-09-25 | 苏州市信睦知识产权服务有限公司 | Device for preparing tobacco flavor spice |
| CN110959891A (en) * | 2018-09-26 | 2020-04-07 | 浙江中烟工业有限责任公司 | Method for preparing functional tobacco shred fragrance raw material through immersion high-pressure low-temperature reaction |
| CN113727615A (en) * | 2019-06-05 | 2021-11-30 | 菲利普莫里斯生产公司 | Improved method for producing liquid tobacco extract |
| CN113727615B (en) * | 2019-06-05 | 2023-09-05 | 菲利普莫里斯生产公司 | Improved method for producing liquid tobacco extract |
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