CN107109299B - 含有胺添加剂的洗衣液 - Google Patents

含有胺添加剂的洗衣液 Download PDF

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CN107109299B
CN107109299B CN201580053658.1A CN201580053658A CN107109299B CN 107109299 B CN107109299 B CN 107109299B CN 201580053658 A CN201580053658 A CN 201580053658A CN 107109299 B CN107109299 B CN 107109299B
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G·黛拉诺斯
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11D3/20—Organic compounds containing oxygen
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
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    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

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Abstract

一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物，和(c)2wt％到10wt％的胺，所述胺具有式(I)
Figure DDA0001260656920000011
其中R1为C1‑C4烷基或C1‑C4羟基烷基；或式(II)
Figure DDA0001260656920000012
其中R2是C1‑C4烷基且R3是C2‑C8烷基；或其组合；和(d)水。

Description

含有胺添加剂的洗衣液
技术领域
本发明大体上涉及一种含有胺的洗衣液组合物。
背景技术
典型地，洗衣液组合物是使用氢氧化钠调节到碱性pH。在一些情况下，其它碱已经用于此目的。举例来说，美国专利第5,035,838号揭露了使用三乙醇胺中和洗涤剂组合物。然而，这个参考文献未揭露本发明的组合物，本发明的组合物提供了改进的性能。
发明内容
本发明涉及一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物；(c)2wt％到10wt％的胺，所述胺具有式(I)
Figure BDA0001260656910000012
其中R1为C1-C4烷基或C1-C4羟基烷基；或式(II)
Figure BDA0001260656910000011
其中R2是C1-C4烷基且R3是C2-C8烷基；或其组合；和(d)水。
具体实施方式
除非另外指明，否则所有百分比均是重量百分比(wt％)，且所有温度均以℃为单位。除非另外说明，否则所有操作都在室温(20至25℃)下进行。如本文中所用，术语“柠檬酸盐”是指碱金属柠檬酸盐。优选的是，柠檬酸盐是钠盐、钾盐或锂盐；优选钠或钾盐；优选钠盐。柠檬酸盐的重量百分比是基于盐(包括金属离子)的实际重量。如本文中所用，术语“脂肪酸”是指具有十二到二十二个碳原子、优选十四到十八个碳原子的脂肪族羧酸。术语“无磷”是指组合物含有小于0.5wt％的磷(按元素磷计)，优选小于0.2wt％，优选小于0.1wt％，优选的是磷检测不到。洗涤剂组合物中的重量百分比是活性成分的百分比，即，排除可能存在于可商购的表面活性剂或其它成分中的任何水。
优选的是，具有式(I)的胺存在于洗衣液组合物中的量是至少3wt％；优选至少3.5wt％，优选至少4wt％，优选至少4.5wt％；优选不超过8wt％，优选不超过7wt％，优选不超过6.5wt％。
优选的是，R1是C1-C3烷基或C1-C3羟基烷基，优选C1-C2烷基或C1-C2羟基烷基；优选甲基、乙基或羟甲基。
优选的是，具有式(II)的胺存在于洗衣液组合物中的量是至少3.5wt％；优选至少4.5wt％，优选至少5wt％，优选至少5.5wt％，优选至少6wt％；优选不超过9.5wt％，优选不超过9wt％，优选不超过8.5wt％。
优选的是，R2是C1-C3烷基，优选甲基或乙基，优选乙基。优选的是，R3是C2-C6烷基，优选C3-C6烷基，优选C3-C5烷基，优选C4烷基，优选正丁基。
优选的是，胺在洗涤剂组合物中的总量是2.5wt％到9wt％，优选2.5wt％到8.5wt％，优选3wt％到8wt％。
优选的是，洗涤剂组合物包含至少5wt％的直链醇乙氧基化物，优选至少6wt％，优选至少7wt％；优选不超过17wt％，优选不超过16wt％，优选不超过15wt％。优选的是，直链醇乙氧基化物具有直链C6-C18烷基，优选C8-C16，优选C12-C15。烷基可以是不同烷基在指定范围内的混合基团。优选的是，直链醇乙氧基化物包含五到九个环氧乙烷聚合单元，优选六到八个，优选七个。
优选的是，洗涤剂组合物包含至少12wt％的直链烷基苯磺酸盐，优选至少13wt％，优选至少14wt％；优选不超过27wt％，优选不超过25wt％，优选不超过23wt％。优选的是，烷基苯磺酸盐具有C10-C14烷基。
优选的是，洗涤剂组合物包含1wt％到15wt％脂肪酸或其金属盐；优选至少3wt％，优选至少4wt％，优选至少5wt％；优选不超过13wt％，优选不超过12wt％，优选不超过11wt％。
优选的是，洗涤剂组合物包含0.5wt％到10wt％的柠檬酸盐，优选至少1wt％，优选至少1.5wt％；优选不超过8wt％，优选不超过6wt％，优选不超过5wt％。
优选的是，洗涤剂组合物包含1wt％到15wt％的醇和/或二醇溶剂，例如丙二醇和乙醇。优选的是，溶剂是丙二醇或乙醇。优选的是，洗涤剂组合物包含至少2wt％的溶剂，优选至少3wt％，优选至少4wt％；优选不超过12wt％，优选不超过10wt％，优选不超过9wt％。
优选的是，洗涤剂组合物包含30wt％到70wt％的水；优选至少35wt％，优选至少38wt％，优选至少41wt％，优选至少43wt％；优选不超过65wt％，优选不超过62wt％，优选不超过59wt％，优选不超过57wt％。
优选的是，洗涤剂组合物包含0.5wt％到10wt％水溶助溶剂或其盐，优选0.5wt％到6wt％，优选1wt％到5wt％。水溶增溶剂的优选实例是芳香族磺酸，优选甲苯磺酸。
洗涤剂组合物中的其它组分可以包括例如表面活性剂、氧气和/或氯气漂白剂、漂白剂活化剂、酶、泡沫抑制剂、颜料、芳香剂、抗细菌剂和填充剂。芳香剂、染料、泡沫抑制剂、酶和抗菌剂总计通常不超过组合物的5wt％。
优选的是，洗涤剂组合物具有7.5到10的pH，优选至少8，优选不超过9.5，优选不超过9。
洗涤剂组合物可以在任何典型的洗涤机中、在典型的操作条件下使用。洗涤过程中典型的水温优选20℃至85℃，优选25℃至70℃。按总液体在洗碗机中的百分比计的组合物典型浓度优选0.1wt％到1wt％，优选0.2wt％到0.7wt％。通过选择适当的产品形态和添加时间，组合物可以存在于预洗、主洗、倒数第二次冲洗、最后冲洗或这些循环的任何组合中。
优选的是，洗涤剂组合物基本上不含酶，即，其含有小于0.5wt％的酶，优选小于0.2wt％，优选小于0.1wt％，优选的是其含的酶检测不到。优选的是，洗涤剂组合物含有小于2wt％的胺氧化物表面活性剂，优选小于1wt％，优选小于0.5wt％，优选小于0.2wt％。优选的是，洗涤剂组合物基本上不含除式(I)和(II)胺之外的胺，即，这些其它胺存在的总量小于0.7wt％，优选小于0.5wt％，优选小于0.3wt％，优选小于0.2wt％。
实例
通过考虑初始清洁(去污)来研究陶氏高垢配制液(DOW High Duty Liquidformulation)中的氨基醇相对于传统中和剂(NaOH)中和各种污渍的益处(洗涤循环，30℃)。洗涤之前和洗涤之后测量每种污渍的色彩。
方案：
已经按以下配方添加各种氨基醇：
Figure BDA0001260656910000031
Figure BDA0001260656910000041
所用中和剂％(以便获得8.5的pH)：
Figure BDA0001260656910000042
测试所用的污渍监测剂如下：
污渍监测剂：得自测试材料中心(Center for Test Materials)-Ref MON DOW 7
污渍代码 污渍性质
H078 唇膏#1
H156 皮脂粉
H038 褐色鞋油
H150 大豆油/紫色染料
H013 脏马达油
H032 锈污
H084 妮维雅(nivea visage)面霜
H135 机械油脂
H082 含有碳黑的贝伊皮脂(Sebum bey)
H066 特芙娜(tapenada)，黑橄榄
H018 经研磨的土壤
H134 汉堡油脂
H126 含有紫色染料的Pura植物油
H056 地中海酱(Sauce Mediterranea)，橄榄酱
H162 烧烤鸡脂肪
H145 网球场粘土
每台机器装载有：
1种污渍监测剂+1SBL(土壤压载载荷是8g)
60g洗涤剂
3.3kg压载载荷
自来水：TH，约18°F
在30℃进行的六轮不同循环(每轮循环使用新的污渍监测剂)已经进行(＝6次重复)
测量
土壤释放效应已经通过每种污渍的Delta E(ΔE)测量。
Delta E定义为未洗涤的污渍与已洗涤的污渍之间的色差(在L*a*b*色空间内)。
在洗涤之前及之后，通过使用Epson扫描软件的Epson Perfection 4490Photo扫描仪，在以下设置下测量每种污渍：
■专业模式.
■文件类型：反射
■文件来源：文件表格
■自动曝光类型：光照
■图像类型：48位色彩
■扫描品质：最佳
■分辨率：400dpi
■无色彩校正
■防UV 400nm
接着，使用软件Image J 1.4.3.67版(获自因特网的自由软件)，使用提供L*a*b*色空间内的色彩信息的宏指令，分析每种污渍的色彩。
结景(6轮不同循环的平均值，30℃)
Delta E定义为未洗涤的污渍与已洗涤的污渍之间的色差(在L*a*b*色空间内)。
Figure BDA0001260656910000051
结果列表于下方。
Delta E
Figure BDA0001260656910000052
标准差
Figure BDA0001260656910000053

Claims (5)

1.一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物，和(c)2wt％到10wt％的胺，所述胺具有式(I)
Figure FDA0002203961520000011
其中R1为羟甲基；或式(II)
Figure FDA0002203961520000012
其中R2是乙基且R3是C4烷基；或其组合；和(d)水。
2.根据权利要求1所述的组合物，其包含30wt％到70wt％的水。
3.根据权利要求2所述的组合物，其包含1wt％到15wt％脂肪酸或其金属盐。
4.根据权利要求1所述的组合物，其中所述胺具有式(I)。
5.根据权利要求1所述的组合物，其中所述胺具有式(II)。
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4079078A (en) * 1974-06-21 1978-03-14 The Procter & Gamble Company Liquid detergent compositions
CN88103546A (zh) * 1987-06-10 1988-12-28 阿尔布赖特-威尔逊公司 液体洗涤组合物
US5035838A (en) * 1989-10-24 1991-07-30 Shell Oil Company Nonionic surfactant based liquid detergent formulation containing an alkenyl or alkyl carboxysulfonate component
WO2000020545A1 (en) * 1998-10-06 2000-04-13 Unilever Plc Hard surface cleaning bar
CN1332786A (zh) * 1998-11-06 2002-01-23 宝洁公司 含las的水性、液体洗衣用洗涤剂组合物的亲水指数
CN1806039A (zh) * 2003-06-16 2006-07-19 荷兰联合利华有限公司 洗涤剂组合物
CN101981171A (zh) * 2008-04-07 2011-02-23 埃科莱布有限公司 超浓缩液体脱脂剂组合物
CN103221525A (zh) * 2010-11-16 2013-07-24 陶氏环球技术有限责任公司 包含低voc、低气味烷醇胺的硬质表质面清洁剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3378637D1 (en) * 1982-07-27 1989-01-12 Procter & Gamble Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them
US4560492A (en) * 1984-11-02 1985-12-24 The Procter & Gamble Company Laundry detergent composition with enhanced stain removal
WO2011116243A1 (en) * 2010-03-17 2011-09-22 Method Products, Inc. Liquid cleaning compositions with lower freezing point
CA2821990C (en) * 2010-12-17 2015-11-24 The Procter & Gamble Company Cleaning compositions with amphoteric polycarboxylate polymers
BR112013029567B1 (pt) * 2011-05-20 2021-03-30 Dow Global Technologies Llc Mistura para promover desprendimento de sujeira de pano, método para promover desprendimento de sujeira de pano sujo e formulação de detergente para lavagem de roupa

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4079078A (en) * 1974-06-21 1978-03-14 The Procter & Gamble Company Liquid detergent compositions
CN88103546A (zh) * 1987-06-10 1988-12-28 阿尔布赖特-威尔逊公司 液体洗涤组合物
US5035838A (en) * 1989-10-24 1991-07-30 Shell Oil Company Nonionic surfactant based liquid detergent formulation containing an alkenyl or alkyl carboxysulfonate component
WO2000020545A1 (en) * 1998-10-06 2000-04-13 Unilever Plc Hard surface cleaning bar
CN1332786A (zh) * 1998-11-06 2002-01-23 宝洁公司 含las的水性、液体洗衣用洗涤剂组合物的亲水指数
CN1806039A (zh) * 2003-06-16 2006-07-19 荷兰联合利华有限公司 洗涤剂组合物
CN101981171A (zh) * 2008-04-07 2011-02-23 埃科莱布有限公司 超浓缩液体脱脂剂组合物
CN103221525A (zh) * 2010-11-16 2013-07-24 陶氏环球技术有限责任公司 包含低voc、低气味烷醇胺的硬质表质面清洁剂

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