CN107108783B - 用于捕集甲醛的聚合物材料 - Google Patents

用于捕集甲醛的聚合物材料 Download PDF

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CN107108783B
CN107108783B CN201580062169.2A CN201580062169A CN107108783B CN 107108783 B CN107108783 B CN 107108783B CN 201580062169 A CN201580062169 A CN 201580062169A CN 107108783 B CN107108783 B CN 107108783B
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hydrogen
polymer material
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CN107108783A (zh
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M·S·文德兰德
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/82—Solid phase processes with stationary reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/32—Monomers containing only one unsaturated aliphatic radical containing two or more rings
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
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    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN201580062169.2A 2014-11-17 2015-11-10 用于捕集甲醛的聚合物材料 Active CN107108783B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462080817P 2014-11-17 2014-11-17
US62/080,817 2014-11-17
PCT/US2015/059909 WO2016081226A1 (en) 2014-11-17 2015-11-10 Polymeric materials for capturing formaldehyde

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CN107108783A CN107108783A (zh) 2017-08-29
CN107108783B true CN107108783B (zh) 2019-08-30

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US (1) US10391471B2 (enExample)
EP (1) EP3221367A1 (enExample)
JP (1) JP6567052B2 (enExample)
KR (1) KR20170085550A (enExample)
CN (1) CN107108783B (enExample)
TW (1) TWI647009B (enExample)
WO (1) WO2016081226A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016205444A1 (en) 2015-06-19 2016-12-22 3M Innovative Properties Company Divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
US10464045B1 (en) 2015-06-19 2019-11-05 3M Innovative Properties Company Hydrolyzed divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
EP3389850B1 (en) 2015-12-18 2021-12-01 3M Innovative Properties Company Polymeric sorbents for reactive gases
WO2017106443A1 (en) 2015-12-18 2017-06-22 3M Innovative Properties Company Polymeric sorbents for carbon dioxide
TWI743071B (zh) 2015-12-18 2021-10-21 美商3M新設資產公司 用於醛之聚合性吸著劑
BR112018068677A2 (pt) 2016-03-14 2019-01-15 3M Innovative Properties Co filtros de ar compreendendo sorventes poliméricos para gases reativos
US10960341B2 (en) 2016-03-14 2021-03-30 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
WO2017160637A1 (en) 2016-03-14 2017-09-21 3M Innovative Properties Company Composite granules including polymeric sorbent for aldehydes
CN110719805B (zh) 2017-06-16 2022-12-27 3M创新有限公司 包含用于醛的聚合物吸附剂的空气过滤器
CN110740808B (zh) * 2017-06-16 2023-04-07 3M创新有限公司 醛的聚合物吸附剂
DE102018114351A1 (de) * 2017-06-30 2019-01-03 Mann+Hummel Gmbh Filtermedium
WO2019110557A1 (en) * 2017-12-04 2019-06-13 Stichting Voor De Technische Wetenschappen Macromolecular compositions comprising indene-derivatives, preparation thereof, and use thereof
CN110156930A (zh) * 2019-04-30 2019-08-23 昆明理工大学 一种化学吸附降解甲醛的水性丙烯酸树脂及其制备方法
WO2021038347A1 (en) * 2019-08-30 2021-03-04 3M Innovative Properties Company Polymeric sorbents for aldehydes and methods of making
CN114307986B (zh) * 2021-12-28 2023-05-12 南昌航空大学 一种钯离子吸附剂的制备方法

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1062541A (zh) * 1992-01-24 1992-07-08 中国林业科学院林产化学工业研究所 Au甲醛捕捉剂生产工艺
CN1548164A (zh) * 2003-05-22 2004-11-24 王永利 甲醛吸收剂及其制备方法
CN1569313A (zh) * 2004-04-30 2005-01-26 罗文圣 一种有害气体捕捉材料及其制备方法
CN103173004A (zh) * 2011-12-23 2013-06-26 烟台万华聚氨酯股份有限公司 具有甲醛反应性的水性聚氨酯分散体组合物及其制备和应用
WO2014052021A1 (en) * 2012-09-25 2014-04-03 3M Innovative Properties Company Polymerizable spirobisindane monomers and polymers prepared therefrom

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GB800639A (en) * 1955-07-08 1958-08-27 Wolfgang Muhlberg Manufacture of cation exchangers of the polystyrene-type
JP3953638B2 (ja) * 1997-09-11 2007-08-08 日本合成化学工業株式会社 アルデヒド吸着剤
CN104662054B (zh) * 2012-09-25 2017-02-22 3M创新有限公司 刚性且扭曲的二乙烯基交联剂
TWI490232B (zh) 2012-12-28 2015-07-01 Ind Tech Res Inst 甲醛捕捉劑及其製備方法
CN105229055B (zh) 2013-05-14 2017-04-26 3M创新有限公司 基于可自由基聚合的螺双茚单体的含磺酰基聚合物
KR20160009581A (ko) 2013-05-14 2016-01-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 경질의 뒤틀린 다이비닐 가교결합제를 갖는 아미노-함유 중합체 재료
CN106660039B (zh) 2014-06-13 2020-10-27 3M创新有限公司 含磺酸聚合物材料作为胺吸附剂

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062541A (zh) * 1992-01-24 1992-07-08 中国林业科学院林产化学工业研究所 Au甲醛捕捉剂生产工艺
CN1548164A (zh) * 2003-05-22 2004-11-24 王永利 甲醛吸收剂及其制备方法
CN1569313A (zh) * 2004-04-30 2005-01-26 罗文圣 一种有害气体捕捉材料及其制备方法
CN103173004A (zh) * 2011-12-23 2013-06-26 烟台万华聚氨酯股份有限公司 具有甲醛反应性的水性聚氨酯分散体组合物及其制备和应用
WO2014052021A1 (en) * 2012-09-25 2014-04-03 3M Innovative Properties Company Polymerizable spirobisindane monomers and polymers prepared therefrom

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JP6567052B2 (ja) 2019-08-28
US20170333870A1 (en) 2017-11-23
WO2016081226A1 (en) 2016-05-26
EP3221367A1 (en) 2017-09-27
TW201627066A (zh) 2016-08-01
US10391471B2 (en) 2019-08-27
CN107108783A (zh) 2017-08-29
JP2018501086A (ja) 2018-01-18
KR20170085550A (ko) 2017-07-24
TWI647009B (zh) 2019-01-11

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