CN107108766B - 经茂金属催化的聚乙烯树脂 - Google Patents

经茂金属催化的聚乙烯树脂 Download PDF

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Publication number
CN107108766B
CN107108766B CN201580071447.0A CN201580071447A CN107108766B CN 107108766 B CN107108766 B CN 107108766B CN 201580071447 A CN201580071447 A CN 201580071447A CN 107108766 B CN107108766 B CN 107108766B
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China
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product
polyvinyl resin
metallocene catalysis
fraction
resin
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Expired - Fee Related
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Chinese (zh)
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CN107108766A (zh
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A.范托姆
E.马齐尔斯
C.威洛克
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TotalEnergies Onetech Belgium SA
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Total Research and Technology Feluy SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
CN201580071447.0A 2014-11-13 2015-11-10 经茂金属催化的聚乙烯树脂 Expired - Fee Related CN107108766B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14193018 2014-11-13
EP14193018.0 2014-11-13
PCT/EP2015/076252 WO2016075163A1 (en) 2014-11-13 2015-11-10 Metallocene catalyzed polyethylene resin

Publications (2)

Publication Number Publication Date
CN107108766A CN107108766A (zh) 2017-08-29
CN107108766B true CN107108766B (zh) 2019-02-22

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Country Link
US (1) US10336892B2 (enExample)
EP (1) EP3157967B1 (enExample)
CN (1) CN107108766B (enExample)
BR (1) BR112017010044A2 (enExample)
DK (1) DK3157967T3 (enExample)
ES (1) ES2669506T3 (enExample)
NO (1) NO3157967T3 (enExample)
PL (1) PL3157967T4 (enExample)
SI (1) SI3157967T1 (enExample)
WO (1) WO2016075163A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5844023B2 (ja) * 2013-12-19 2016-01-13 東洋製罐グループホールディングス株式会社 プラスチックの成形方法
WO2018002196A1 (en) * 2016-07-01 2018-01-04 Total Research & Technology Feluy Polyethylene composition for artificial turf yarn
WO2018017180A1 (en) * 2016-07-21 2018-01-25 Exxonmobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
EP3487924B1 (en) 2016-07-21 2024-06-12 ExxonMobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
JP6987560B2 (ja) * 2017-07-25 2022-01-05 旭化成株式会社 架橋パイプ用ポリエチレン組成物、前記組成物の製造方法、及び架橋パイプ
US11565774B2 (en) 2018-10-03 2023-01-31 Adam Jon Noah Additive manufactured water resistant closed-cell lattice structure for marine hull cavities
US11530279B2 (en) 2019-04-05 2022-12-20 Exxonmobil Chemicals Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
EP3947480A1 (en) * 2019-04-05 2022-02-09 ExxonMobil Chemical Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
BE1027573B1 (fr) 2019-09-12 2021-04-13 Gd Consulting And Polymers S P R L Composition de polyethylene ayant un escr, une resistance aux chocs et une resistance a l'usure ameliores ainsi qu'un procede pour les preparer
ES3025971T3 (en) 2020-06-30 2025-06-10 Dow Global Technologies Llc Polyethylene compositions
US11578156B2 (en) 2020-10-20 2023-02-14 Chevron Phillips Chemical Company Lp Dual metallocene polyethylene with improved processability for lightweight blow molded products
PL4263701T3 (pl) * 2020-12-21 2024-12-16 Dow Global Technologies Llc Kompozycje polietylenu do produkcji zakrętek
JP7573675B2 (ja) 2022-04-06 2024-10-25 旭化成株式会社 超高分子量ポリエチレンパウダー及び成形体
CN116789882A (zh) * 2023-05-19 2023-09-22 中沙（天津）石化有限公司 一种基于双环管淤浆相聚乙烯工艺生产茂金属树脂的生产方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1328578A (zh) * 1998-08-19 2001-12-26 诺瓦化学品(国际)股份有限公司 用膦亚胺催化剂在双反应器中合成聚乙烯的方法
CN1376170A (zh) * 1999-09-24 2002-10-23 巴塞尔聚烯烃有限公司 具有改进的escr/劲度关系和改进的膨胀率的聚乙烯模塑料,生产它的方法和它的用途
US20050017409A1 (en) * 2003-07-24 2005-01-27 Nova Chemicals (International) S.A. Rotomolding process with reduced cycle times
US20050256271A1 (en) * 2002-10-01 2005-11-17 Arnold Lustiger Polyethylene compositions for injection molding
US20050256266A1 (en) * 2002-10-01 2005-11-17 Arnold Lustiger Polyethylene compositions for rotational molding
CN102574314A (zh) * 2009-08-28 2012-07-11 陶氏环球技术有限责任公司 旋转模塑制品及其制备方法
WO2014016318A1 (en) * 2012-07-27 2014-01-30 Total Research & Technology Feluy Process for preparing a polyethylene resin
CN103917592A (zh) * 2011-09-19 2014-07-09 诺瓦化学品(国际)股份有限公司 用于瓶的聚乙烯组合物和封盖

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1546252B1 (en) 2002-10-01 2010-03-03 ExxonMobil Chemical Patents, Inc. a Corporation of the State of Delaware Polyethylene compositions for injection molding

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1328578A (zh) * 1998-08-19 2001-12-26 诺瓦化学品(国际)股份有限公司 用膦亚胺催化剂在双反应器中合成聚乙烯的方法
CN1376170A (zh) * 1999-09-24 2002-10-23 巴塞尔聚烯烃有限公司 具有改进的escr/劲度关系和改进的膨胀率的聚乙烯模塑料,生产它的方法和它的用途
US20050256271A1 (en) * 2002-10-01 2005-11-17 Arnold Lustiger Polyethylene compositions for injection molding
US20050256266A1 (en) * 2002-10-01 2005-11-17 Arnold Lustiger Polyethylene compositions for rotational molding
US20050017409A1 (en) * 2003-07-24 2005-01-27 Nova Chemicals (International) S.A. Rotomolding process with reduced cycle times
CN102574314A (zh) * 2009-08-28 2012-07-11 陶氏环球技术有限责任公司 旋转模塑制品及其制备方法
CN103917592A (zh) * 2011-09-19 2014-07-09 诺瓦化学品(国际)股份有限公司 用于瓶的聚乙烯组合物和封盖
WO2014016318A1 (en) * 2012-07-27 2014-01-30 Total Research & Technology Feluy Process for preparing a polyethylene resin

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PL3157967T4 (pl) 2018-09-28
DK3157967T3 (en) 2018-05-22
WO2016075163A1 (en) 2016-05-19
BR112017010044A2 (pt) 2018-01-30
PL3157967T3 (pl) 2018-08-31
EP3157967A1 (en) 2017-04-26
ES2669506T3 (es) 2018-05-28
NO3157967T3 (enExample) 2018-08-11
US20170321047A1 (en) 2017-11-09
US10336892B2 (en) 2019-07-02
SI3157967T1 (en) 2018-06-29
EP3157967B1 (en) 2018-03-14
CN107108766A (zh) 2017-08-29

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