DK3157967T3 - METALLOCEN CATALYZED POLYETHYLENE RESIN - Google Patents

METALLOCEN CATALYZED POLYETHYLENE RESIN Download PDF

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Publication number
DK3157967T3
DK3157967T3 DK15791649.5T DK15791649T DK3157967T3 DK 3157967 T3 DK3157967 T3 DK 3157967T3 DK 15791649 T DK15791649 T DK 15791649T DK 3157967 T3 DK3157967 T3 DK 3157967T3
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Denmark
Prior art keywords
polyethylene resin
metallocene
fraction
catalyzed polyethylene
density
Prior art date
Application number
DK15791649.5T
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Danish (da)
English (en)
Inventor
Aurélien Vantomme
Eric Maziers
Christopher Willocq
Original Assignee
Total Res & Technology Feluy
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Publication of DK3157967T3 publication Critical patent/DK3157967T3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
DK15791649.5T 2014-11-13 2015-11-10 METALLOCEN CATALYZED POLYETHYLENE RESIN DK3157967T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14193018 2014-11-13
PCT/EP2015/076252 WO2016075163A1 (en) 2014-11-13 2015-11-10 Metallocene catalyzed polyethylene resin

Publications (1)

Publication Number Publication Date
DK3157967T3 true DK3157967T3 (en) 2018-05-22

Family

ID=51870934

Family Applications (1)

Application Number Title Priority Date Filing Date
DK15791649.5T DK3157967T3 (en) 2014-11-13 2015-11-10 METALLOCEN CATALYZED POLYETHYLENE RESIN

Country Status (10)

Country Link
US (1) US10336892B2 (enExample)
EP (1) EP3157967B1 (enExample)
CN (1) CN107108766B (enExample)
BR (1) BR112017010044A2 (enExample)
DK (1) DK3157967T3 (enExample)
ES (1) ES2669506T3 (enExample)
NO (1) NO3157967T3 (enExample)
PL (1) PL3157967T4 (enExample)
SI (1) SI3157967T1 (enExample)
WO (1) WO2016075163A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5844023B2 (ja) * 2013-12-19 2016-01-13 東洋製罐グループホールディングス株式会社 プラスチックの成形方法
WO2018002196A1 (en) * 2016-07-01 2018-01-04 Total Research & Technology Feluy Polyethylene composition for artificial turf yarn
WO2018017180A1 (en) * 2016-07-21 2018-01-25 Exxonmobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
EP3487924B1 (en) 2016-07-21 2024-06-12 ExxonMobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
JP6987560B2 (ja) * 2017-07-25 2022-01-05 旭化成株式会社 架橋パイプ用ポリエチレン組成物、前記組成物の製造方法、及び架橋パイプ
US11565774B2 (en) 2018-10-03 2023-01-31 Adam Jon Noah Additive manufactured water resistant closed-cell lattice structure for marine hull cavities
US11530279B2 (en) 2019-04-05 2022-12-20 Exxonmobil Chemicals Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
EP3947480A1 (en) * 2019-04-05 2022-02-09 ExxonMobil Chemical Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
BE1027573B1 (fr) 2019-09-12 2021-04-13 Gd Consulting And Polymers S P R L Composition de polyethylene ayant un escr, une resistance aux chocs et une resistance a l'usure ameliores ainsi qu'un procede pour les preparer
ES3025971T3 (en) 2020-06-30 2025-06-10 Dow Global Technologies Llc Polyethylene compositions
US11578156B2 (en) 2020-10-20 2023-02-14 Chevron Phillips Chemical Company Lp Dual metallocene polyethylene with improved processability for lightweight blow molded products
PL4263701T3 (pl) * 2020-12-21 2024-12-16 Dow Global Technologies Llc Kompozycje polietylenu do produkcji zakrętek
JP7573675B2 (ja) 2022-04-06 2024-10-25 旭化成株式会社 超高分子量ポリエチレンパウダー及び成形体
CN116789882A (zh) * 2023-05-19 2023-09-22 中沙（天津）石化有限公司 一种基于双环管淤浆相聚乙烯工艺生产茂金属树脂的生产方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2245375C (en) 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
DE19945980A1 (de) * 1999-09-24 2001-03-29 Elenac Gmbh Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper
US7396881B2 (en) * 2002-10-01 2008-07-08 Exxonmobil Chemical Patents Inc. Polyethylene compositions for rotational molding
US7396878B2 (en) * 2002-10-01 2008-07-08 Exxonmobil Chemical Patents Inc. Polyethylene compositions for injection molding
EP1546252B1 (en) 2002-10-01 2010-03-03 ExxonMobil Chemical Patents, Inc. a Corporation of the State of Delaware Polyethylene compositions for injection molding
CA2435986C (en) * 2003-07-24 2011-08-30 Nova Chemicals Corporation Rotomolding process with reduced cycle times
ES2755903T3 (es) * 2009-08-28 2020-04-24 Dow Global Technologies Llc Artículos moldeados por moldeo rotacional, y método de fabricación de los mismos
CA2752407C (en) * 2011-09-19 2018-12-04 Nova Chemicals Corporation Polyethylene compositions and closures for bottles
EP2877502B1 (en) 2012-07-27 2019-11-13 Total Research & Technology Feluy Process for preparing a polyethylene resin

Also Published As

Publication number Publication date
PL3157967T4 (pl) 2018-09-28
CN107108766B (zh) 2019-02-22
WO2016075163A1 (en) 2016-05-19
BR112017010044A2 (pt) 2018-01-30
PL3157967T3 (pl) 2018-08-31
EP3157967A1 (en) 2017-04-26
ES2669506T3 (es) 2018-05-28
NO3157967T3 (enExample) 2018-08-11
US20170321047A1 (en) 2017-11-09
US10336892B2 (en) 2019-07-02
SI3157967T1 (en) 2018-06-29
EP3157967B1 (en) 2018-03-14
CN107108766A (zh) 2017-08-29

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