CN107074725A - 苯多羧酸及其衍生物的改进氢化方法 - Google Patents

苯多羧酸及其衍生物的改进氢化方法 Download PDF

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Publication number
CN107074725A
CN107074725A CN201580051623.4A CN201580051623A CN107074725A CN 107074725 A CN107074725 A CN 107074725A CN 201580051623 A CN201580051623 A CN 201580051623A CN 107074725 A CN107074725 A CN 107074725A
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Prior art keywords
catalyst
hydrogenation
ruthenium
rhodium
product
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CN201580051623.4A
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English (en)
Chinese (zh)
Inventor
S·索莱德
S·米瑟欧
J·鲍姆加特纳
C·克里威尔
H·格里斯
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication of CN107074725A publication Critical patent/CN107074725A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201580051623.4A 2014-10-29 2015-10-09 苯多羧酸及其衍生物的改进氢化方法 Pending CN107074725A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462072005P 2014-10-29 2014-10-29
US62/072,005 2014-10-29
EP15151010 2015-01-13
EP15151010.4 2015-01-13
PCT/EP2015/073488 WO2016066410A1 (en) 2014-10-29 2015-10-09 Improved process for hydrogenation of benzenepolycarboxylic acids and derivitives thereof

Publications (1)

Publication Number Publication Date
CN107074725A true CN107074725A (zh) 2017-08-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580051623.4A Pending CN107074725A (zh) 2014-10-29 2015-10-09 苯多羧酸及其衍生物的改进氢化方法

Country Status (6)

Country Link
US (1) US10017448B2 (enExample)
EP (1) EP3212605A1 (enExample)
JP (1) JP2018500273A (enExample)
KR (1) KR20170074848A (enExample)
CN (1) CN107074725A (enExample)
WO (1) WO2016066410A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX374825B (es) * 2015-03-20 2025-03-06 Solidia Technologies Inc Clinkeres microestructurables de silicato de calcio carbonatado y metodos de los mismos.
WO2021126437A1 (en) * 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Aikyl-demethylation processes and catalyst compositions therefor
US20230023923A1 (en) * 2019-12-19 2023-01-26 Exxonmobil Chemical Patents Inc. Alkyl-Demethylation Processes and Catalyst Compositions Therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005737A1 (de) * 1978-05-26 1979-12-12 Bayer Ag Verfahren zur Herstellung von cycloaliphatischen Carbonsäureestern
CN1717279A (zh) * 2002-11-20 2006-01-04 埃克森美孚研究工程公司 氢化催化剂及其制备和采用该催化剂的氢化方法
CN1796353A (zh) * 2004-12-31 2006-07-05 奥克森诺奥勒芬化学股份有限公司 制备脂环族羧酸或它们的衍生物的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5399742A (en) * 1993-06-15 1995-03-21 Eastman Chemical Company Low pressure process for the manufacture of cyclohexanedicarboxylate esters
GB0227081D0 (en) 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Methods for preparing catalysts
GB0227087D0 (en) 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
JP5745538B2 (ja) * 2009-12-15 2015-07-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 芳香族化合物水素化用触媒とその方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005737A1 (de) * 1978-05-26 1979-12-12 Bayer Ag Verfahren zur Herstellung von cycloaliphatischen Carbonsäureestern
CN1717279A (zh) * 2002-11-20 2006-01-04 埃克森美孚研究工程公司 氢化催化剂及其制备和采用该催化剂的氢化方法
CN1796353A (zh) * 2004-12-31 2006-07-05 奥克森诺奥勒芬化学股份有限公司 制备脂环族羧酸或它们的衍生物的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘漫红编著，: "《纳米材料及其制备技术》", 31 August 2014, 冶金工业出版社2014年8月第1版 *

Also Published As

Publication number Publication date
EP3212605A1 (en) 2017-09-06
US20170291867A1 (en) 2017-10-12
WO2016066410A1 (en) 2016-05-06
KR20170074848A (ko) 2017-06-30
US10017448B2 (en) 2018-07-10
JP2018500273A (ja) 2018-01-11

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