KR20170074848A - 벤젠폴리카복실산 및 이의 유도체의 수소화를 위한 개선된 방법 - Google Patents

벤젠폴리카복실산 및 이의 유도체의 수소화를 위한 개선된 방법 Download PDF

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KR20170074848A
KR20170074848A KR1020177005710A KR20177005710A KR20170074848A KR 20170074848 A KR20170074848 A KR 20170074848A KR 1020177005710 A KR1020177005710 A KR 1020177005710A KR 20177005710 A KR20177005710 A KR 20177005710A KR 20170074848 A KR20170074848 A KR 20170074848A
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South Korea
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catalyst
hydrogenation
ruthenium
rhodium
product
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KR1020177005710A
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English (en)
Korean (ko)
Inventor
스튜어트 솔레드
사바토 미세오
요셉 바움가르트너
크리스틴 클리워
한스 고리스
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엑손모빌 케미칼 패턴츠 인코포레이티드
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Publication of KR20170074848A publication Critical patent/KR20170074848A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020177005710A 2014-10-29 2015-10-09 벤젠폴리카복실산 및 이의 유도체의 수소화를 위한 개선된 방법 Withdrawn KR20170074848A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462072005P 2014-10-29 2014-10-29
US62/072,005 2014-10-29
EP15151010.4 2015-01-13
EP15151010 2015-01-13
PCT/EP2015/073488 WO2016066410A1 (en) 2014-10-29 2015-10-09 Improved process for hydrogenation of benzenepolycarboxylic acids and derivitives thereof

Publications (1)

Publication Number Publication Date
KR20170074848A true KR20170074848A (ko) 2017-06-30

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ID=52350001

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020177005710A Withdrawn KR20170074848A (ko) 2014-10-29 2015-10-09 벤젠폴리카복실산 및 이의 유도체의 수소화를 위한 개선된 방법

Country Status (6)

Country Link
US (1) US10017448B2 (enExample)
EP (1) EP3212605A1 (enExample)
JP (1) JP2018500273A (enExample)
KR (1) KR20170074848A (enExample)
CN (1) CN107074725A (enExample)
WO (1) WO2016066410A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2980014C (en) * 2015-03-20 2023-09-26 Solidia Technologies, Inc. Composite materials and bonding elements from carbonation of calcium silicate and methods thereof
WO2021126514A1 (en) * 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Alkyl-demethylation processes and catalyst compositions therefor
WO2021126437A1 (en) * 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Aikyl-demethylation processes and catalyst compositions therefor
WO2026083054A1 (en) * 2024-10-18 2026-04-23 Johnson Matthey Public Limited Company Bimetallic ammonia cracking catalyst containing ruthenium and rhodium

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2823165A1 (de) * 1978-05-26 1979-11-29 Bayer Ag Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern
US5399742A (en) * 1993-06-15 1995-03-21 Eastman Chemical Company Low pressure process for the manufacture of cyclohexanedicarboxylate esters
GB0227087D0 (en) 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
GB0227081D0 (en) 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Methods for preparing catalysts
GB0227086D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Hydrogenation processes
DE102004063637A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
KR101833077B1 (ko) * 2009-12-15 2018-02-27 바스프 에스이 방향족 화합물의 수소화를 위한 촉매 및 방법

Also Published As

Publication number Publication date
WO2016066410A1 (en) 2016-05-06
JP2018500273A (ja) 2018-01-11
US10017448B2 (en) 2018-07-10
US20170291867A1 (en) 2017-10-12
EP3212605A1 (en) 2017-09-06
CN107074725A (zh) 2017-08-18

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Patent event date: 20170228

Patent event code: PA01051R01D

Comment text: International Patent Application

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