CN107074674A - Cartridge ignition agent - Google Patents
Cartridge ignition agent Download PDFInfo
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- CN107074674A CN107074674A CN201580034915.7A CN201580034915A CN107074674A CN 107074674 A CN107074674 A CN 107074674A CN 201580034915 A CN201580034915 A CN 201580034915A CN 107074674 A CN107074674 A CN 107074674A
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- Prior art keywords
- cartridge ignition
- agent according
- ignition agent
- weight
- cartridge
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 12
- JGZAFSFVZSXXCJ-ONEGZZNKSA-N (E)-bis(2H-tetrazol-5-yl)diazene Chemical compound N(=N\C1=NN=NN1)/C1=NN=NN1 JGZAFSFVZSXXCJ-ONEGZZNKSA-N 0.000 claims abstract description 9
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 6
- 150000001768 cations Chemical class 0.000 claims abstract description 4
- 230000000737 periodic effect Effects 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 150000001340 alkali metals Chemical class 0.000 claims description 11
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 11
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- -1 Plexigum Substances 0.000 claims description 8
- 150000004678 hydrides Chemical class 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000001070 adhesive effect Effects 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 239000002585 base Substances 0.000 claims description 5
- 230000005622 photoelectricity Effects 0.000 claims description 5
- 150000004655 tetrazenes Chemical class 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910010277 boron hydride Inorganic materials 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 229940007424 antimony trisulfide Drugs 0.000 claims description 3
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910021346 calcium silicide Inorganic materials 0.000 claims description 3
- 239000006063 cullet Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C7/00—Non-electric detonators; Blasting caps; Primers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Glass Compositions (AREA)
Abstract
Subject of the present invention is cartridge ignition agent, and it includes the basic salt of 5,5' azotetrazoles, and the basic salt has following general empirical formulas:Mm+ n(C2N10 2‑)p(CO3 2‑)q(OH‑)R,Wherein：M is that the atomic number of the race of periodic table the 3rd 12 is 21 80 element, (C2N10 2‑) it is with structure（AA）Azotetrazole dianion, m is the chemical valence of cation, n is 1 to 6 integer, p is 1 to 4 integer, and q is 0 to 8 integer, and r is 0 to 4 integer, and q+r ≠ 0, wherein, the ratio of alkaline azotetrazole salt component is 30 100 weight %, and the additive containing 0 70 weight % or the mixture of multiple additives.
Description
Subject of the present invention is cartridge ignition agent.
Cartridge ignition agent in the scope of the invention is can to play the material or mixture of substances of fireworks effects.
Subject of the present invention can be especially useful for the cartridge ignition agent of machinery, electronics or photoelectricity ignition system.
5, the 5'- azotetrazole salt explosives as known to the A1 of document DE 102010025104, it includes 5,5'- azotetrazoles
Molysite, cobalt salt, nickel salt, mantoquita, cadmium salt or dicyandiamidines salt or by least one 5,5'- azotetrazole salts and at least one double tetrazoliums
Base triazenes salt（triazenate）Or at least one other metal salt or dicyandiamidines the salt composition of 5,5'- azotetrazoles is mixed
Compound.The salt that wherein there is recorded is neutral, that is to say, that both nonacid nor alkalescence.According to document DE
102010025104 A1, the zinc salt and chromic salts of 5,5'- azotetrazoles are not stable storings.In addition, the pyrotechnics containing the tetrazene is mixed
The problem of there is the stability deficiency to heat in compound, because the tetrazene has just been decomposed at 120 DEG C.
It is an object of the invention to provide another cartridge ignition agent.Another object of the present invention is to provide to can be used for machine
The cartridge ignition agent of tool, electronics or photoelectricity ignition system.
According to the present invention, the purpose is surprisingly achieved by the feature of main claim.
Further expanding for the present invention illustrates in the dependent claims.
Surprisingly have discovered that the cigarette of the basic salt comprising the 5,5'- azotetrazoles with following general empirical formulas
Fiery igniting agent:
Mm+ n(C2N10 2-)p(CO3 2-)q(OH-)r
Wherein：
M is that the atomic number of periodic table 3-12 races is 21-80 element,
(C2N10 2-) it is the azotetrazole dianion with following structure
M is the chemical valence of cation,
N is 1 to 6 integer,
P is 1 to 4 integer,
Q is 0 to 8 integer,
R is 0 to 4 integer, and q+r ≠ 0,
Wherein, the ratio of alkaline azotetrazole salt component be 30-100 weight %, and the additive containing 0-70 weight % or
The mixture of multiple additives.Had according to the novel alkaline azotetrazole salt compound of the present invention in the range of 180 DEG C to 240 DEG C
Fuming-off temperature, the shock-sensitive degree of 0.1N to 1.0N sensitiveness to friction and 0.1J to 0.5J.Provide the alkali according to the present invention
The heat endurance of property azotetrazole salt compound.After being stored 28 days at 71 DEG C, according to the alkaline azotetrazole salinization of the present invention
Compound（Here it is particularly zinc compound）Decomposition is not shown.
Preferably, the cartridge ignition agent is the oxidant for containing 10 to 60 weight % as the reagent of additive, the oxygen
One or more of the agent in following：Nitrate, alkali metal and/or the alkaline earth of alkali metal and/or alkaline-earth metal and/or ammonium
Perchlorate, alkali metal and/or the alkaline-earth metal and/or the peroxide of zinc of metal and/or ammonium.
The particularly preferred sensitizer for including 0 to 10 weight % of the cartridge ignition agent, the preferably tetrazene, are used as additive.
0 to 20 weight % reducing agent is preferably comprised as additive according to the cartridge ignition agent of the present invention, the reduction
One or more of the agent in following：Aluminium, antimony trisulfide, calcium silicide, titanium, titantium hydride, boron, boron hydride, zirconium, zircoium hydride, silicon, stone
Ink, activated carbon, carbon black or rubbing agent, the preferred cullet of rubbing agent.
The cartridge ignition agent particularly preferably contains 0.1 to 5 weight % adhesive as additive, and described adhesive is selected from
One or more in following：Cellulose and its derivates, polyvinyl butyral resin, poly- trinitrobenzen
（Polynitropolyphenylen）, polynitrobenzene base ether, Plexgum, polyvinyl acetate and copolymer.
Very particularly preferably, the cartridge ignition agent is included
Zn2+ 2(C2N10 2-)(CO3 2-),
Zn2+ 3(C2N10 2-)2(CO3 2-),
Zn2+ 4(C2N10 2-)2(CO3 2-)(OH-)2,
Zn2+ 2(C2N10 2-)(OH-)2And/or
Zn2+ 3(C2N10 2-)2(OH-)2。
Machinery, electronics or photoelectricity ignition system are used for according to the cartridge ignition agent of the present invention.
It can be used as additive：
1. oxidant（Individually or as a mixture）, it is selected from：
The nitrate of alkali metal or alkaline-earth metal or ammonium, such as sodium nitrate, potassium nitrate or ammonium nitrate, alkali metal or alkaline-earth metal or ammonium
Perchlorate, the peroxide of alkali metal or alkaline-earth metal or zinc.
What 2. the energy of hexogen, HMX, nitrocellulose was enriched with gathers materials（Zuschläge）（Individually or with mixed
Solvate form）.
3. reducing agent（Individually or as a mixture）, it is selected from：
Aluminium, titanium, titantium hydride, boron, boron hydride, zirconium, zircoium hydride, silicon, graphite, activated carbon, carbon black.
4. adhesive（Individually or as a mixture）, it is selected from：
Cellulose and its derivates, polyvinyl butyral resin, poly- trinitrobenzen, polynitrobenzene base ether, Plexigum, poly- acetic acid second
Alkene ester, copolymer.
5. combustionregulator, stabilizer and processing aid（Individually or as a mixture）, it is selected from：
Zinc oxide, zinc carbonate, silicate, silica gel, silica-based, such as Aerosil（From Degussa companies）, boron nitride.
These materials are characterised by not leaded and barium, high firing power, short reaction time and appropriate sensitivity.
These properties make it possible explosive substance amount reduction, this is for needed for safer igniting.
Decomposition temperature, sensitiveness to friction and the shock-sensitive degree of selected embodiment are shown in table 1.Ground according to federal material
Study carefully institute（BAM）142 are reported in BAM-（1987）In the method that provides, measurement sensitiveness to friction and shock-sensitive degree, and decompose temperature
The measurement of degree dynamic differential calorimetry（DSC）（Mettler companies）Carried out with the rate of heat addition of 10K/minute.
Subject of the present invention is specifically：
The agent of-cartridge ignition, it contains the basic salt of 5, the 5'- azotetrazoles with following general empirical formulas：
Mm+ n(C2N10 2-)p(CO3 2-)q(OH-)r
Wherein：
M is that the atomic number of periodic table 3-12 races is 21-80 element,
(C2N10 2-) it is the azotetrazole dianion with following structure
M is the chemical valence of cation,
N is 1 to 6 integer,
P is 1 to 4 integer,
Q is 0 to 8 integer,
R is 0 to 4 integer, and q+r ≠ 0,
The ratio of wherein described alkaline azotetrazole salt component is 30 to 100 weight %, and contains 0 to 70 weight % addition
Agent or the mixture of multiple additives；
The agent of-cartridge ignition, it contains 10 to 60 weight % oxidant as additive, and the oxidant is in following
It is one or more：The height of the nitrate of alkali metal and/or alkaline-earth metal and/or ammonium, alkali metal and/or alkaline-earth metal and/or ammonium
The peroxide of chlorate, alkali metal and/or alkaline-earth metal and/or zinc;
The agent of-cartridge ignition, it contains 0-10 weight % sensitizer, preferably the tetrazene, is used as additive；
The agent of-cartridge ignition, it contains 0-20 weight % reducing agent as additive, the reducing agent in following one
Plant or a variety of：Aluminium, antimony trisulfide, calcium silicide, titanium, titantium hydride, boron, boron hydride, zirconium, zircoium hydride, silicon, graphite, activated carbon, carbon black or
Rubbing agent, the preferred cullet of rubbing agent；
The agent of-cartridge ignition, its adhesive comprising 0.1 to 5 weight % is as additive, and described adhesive is in following
It is one or more：Cellulose and its derivates, polyvinyl butyral resin, poly- trinitrobenzen, polynitrobenzene base ether, Plexigum,
Polyvinyl acetate and copolymer；
The agent of-cartridge ignition, it contains Zn2+ 2(C2N10 2-)(CO3 2-)；
The agent of-cartridge ignition, it contains Zn2+ 3(C2N10 2-)2(CO3 2-)；
The agent of-cartridge ignition, it contains Zn2+ 4(C2N10 2-)2(CO3 2-)(OH-)2；
The agent of-cartridge ignition, it contains Zn2+ 2(C2N10 2-)(OH-)2；
The agent of-cartridge ignition, it contains Zn2+ 3(C2N10 2-)2(OH-)2；
Purposes of-cartridge ignition the agent in machinery, electronics or photoelectricity ignition system.
The present invention is explained in more detail by following examples, but is not limited：
The composition of the basic salt of 5 kinds of different 5,5'- azotetrazoles is listed in table 1.
Table 1：Composition, fuming-off temperature and the sensitiveness to friction and shock-sensitive degree of the basic salt of the 5,5'- azotetrazoles of selection.
[a]：Fuming-off temperature; [b]：Sensitiveness to friction; [c]：Shock-sensitive degree.
Claims (11)
1. cartridge ignition agent, it is characterised in that it includes the basic salt of 5, the 5'- azotetrazoles with following general empirical formulas:
Mm+ n(C2N10 2-)p(CO3 2-)q(OH-)r
Wherein,
M is that the atomic number of periodic table 3-12 races is 21-80 element,
(C2N10 2-) it is the azotetrazole dianion with following structure
M is the chemical valence of cation,
N is 1 to 6 integer,
P is 1 to 4 integer,
Q is 0 to 8 integer,
R is 0 to 4 integer, and q+r ≠ 0,
The ratio of its neutral and alkali azotetrazole salt component is 30-100 weight %, and contains 0-70 weight % additive or many
Plant the mixture of additive.
2. cartridge ignition agent according to claim 1, it is characterised in that it includes 10-60 weight % oxidant conduct
Additive, one or more of the oxidant in following：Nitrate, the alkali of alkali metal and/or alkaline-earth metal and/or ammonium
Perchlorate, alkali metal and/or the alkaline-earth metal and/or the peroxide of zinc of metal and/or alkaline-earth metal and/or ammonium.
3. cartridge ignition agent according to claim 1, it is characterised in that it includes 0-10 weight % sensitizer, preferably
The tetrazene, is used as additive.
4. cartridge ignition agent according to claim 1, it is characterised in that its reducing agent comprising 0-20 weight % is as adding
Plus agent, one or more of the reducing agent in following：Aluminium, antimony trisulfide, calcium silicide, titanium, titantium hydride, boron, boron hydride,
Zirconium, zircoium hydride, silicon, graphite, activated carbon, carbon black or rubbing agent, the preferred cullet of rubbing agent.
5. cartridge ignition agent according to claim 1, it is characterised in that it contains 0.1 to 5 weight % adhesive conduct
Additive, one or more of the described adhesive in following：Cellulose and its derivates, polyvinyl butyral resin, poly- three
Nitrobenzene, polynitrobenzene base ether, Plexigum, polyvinyl acetate and copolymer.
6. the cartridge ignition agent according to one or more in claim 1 to 5, it is characterised in that it includes Zn2+ 2
(C2N10 2-)(CO3 2-)。
7. the cartridge ignition agent according to one or more in claim 1 to 5, it is characterised in that it includes Zn2+ 3
(C2N10 2-)2(CO3 2-)。
8. the cartridge ignition agent according to one or more in claim 1 to 5, it is characterised in that it includes Zn2+ 4
(C2N10 2-)2(CO3 2-)(OH-)2。
9. the cartridge ignition agent according to one or more in claim 1 to 5, it is characterised in that it includes Zn2+ 2
(C2N10 2-)(OH-)2。
10. the cartridge ignition agent according to one or more in claim 1 to 5, it is characterised in that it includes Zn2+ 3
(C2N10 2-)2(OH-)2。
11. the cartridge ignition agent according to one or more in claim 1 to 10 is in machinery, electronics or photoelectricity ignition system
In application.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014009807.9 | 2014-07-03 | ||
| DE102014009807 | 2014-07-03 | ||
| PCT/EP2015/064729 WO2016001161A1 (en) | 2014-07-03 | 2015-06-29 | Pyrotechnic igniting agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107074674A true CN107074674A (en) | 2017-08-18 |
| CN107074674B CN107074674B (en) | 2020-12-08 |
Family
ID=53514168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580034915.7A Active CN107074674B (en) | 2014-07-03 | 2015-06-29 | Pyrotechnic initiator |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20170137339A1 (en) |
| EP (1) | EP3164375B1 (en) |
| JP (1) | JP6559164B2 (en) |
| CN (1) | CN107074674B (en) |
| AU (1) | AU2015282658B2 (en) |
| BR (1) | BR112016030839B1 (en) |
| DK (1) | DK3164375T3 (en) |
| ES (1) | ES2757934T3 (en) |
| HR (1) | HRP20192094T1 (en) |
| HU (1) | HUE046300T2 (en) |
| LT (1) | LT3164375T (en) |
| PL (1) | PL3164375T3 (en) |
| PT (1) | PT3164375T (en) |
| RS (1) | RS60020B1 (en) |
| RU (1) | RU2695200C2 (en) |
| SI (1) | SI3164375T1 (en) |
| WO (1) | WO2016001161A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110937962A (en) * | 2019-12-03 | 2020-03-31 | 北京理工大学 | Alloy type carmine cold firework chemical and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108456126B (en) * | 2017-02-20 | 2020-02-21 | 比亚迪股份有限公司 | Transfer powder of gas generator, preparation method of transfer powder and gas generator for automobile safety airbag |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB195344A (en) * | 1922-03-27 | 1923-06-14 | Hans Rathsburg | Process for making priming compositions |
| US4566921A (en) * | 1985-02-08 | 1986-01-28 | L'etat Francais Represente Par Le Delegue Ministeriel Pour L'armement | Priming composition which is sensitive to percussion and a method for preparing it |
| CN101434617A (en) * | 2008-08-20 | 2009-05-20 | 西北大学 | Energetic coordination complex based on azo tetrazole azotetrazole and use thereof |
| EP2377840A2 (en) * | 2010-04-14 | 2011-10-19 | Diehl BGT Defence GmbH & Co.KG | 5,5'-azotetrazolate explosive |
| DE102010036950A1 (en) * | 2010-08-11 | 2012-02-16 | Nammo Germany Gmbh | New metal-tetrazole complex useful as initiating explosive for preparing an explosive, which is useful as blasting agent, propellant, fuel composition or ignition composition |
| CN102731425A (en) * | 2011-04-12 | 2012-10-17 | 南京理工大学 | Preparation method of zinc 5, 5'-azotetrazole |
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| FR2228043B1 (en) * | 1972-10-17 | 1977-03-04 | Poudres & Explosifs Ste Nale | |
| DE19505568A1 (en) * | 1995-02-18 | 1996-08-22 | Dynamit Nobel Ag | Gas generating mixtures |
| JP5388573B2 (en) * | 2005-06-02 | 2014-01-15 | ルアグ アモテック ゲゼルシャフト ミット ベシュレンクテル ハフツング | Pyrotechnical active substance |
| CZ2013858A3 (en) * | 2013-11-07 | 2015-09-02 | Sellier & Bellot | Bismuth-based energetic materials |
-
2015
- 2015-06-29 US US15/323,359 patent/US20170137339A1/en not_active Abandoned
- 2015-06-29 DK DK15734332T patent/DK3164375T3/en active
- 2015-06-29 ES ES15734332T patent/ES2757934T3/en active Active
- 2015-06-29 SI SI201531000T patent/SI3164375T1/en unknown
- 2015-06-29 BR BR112016030839-5A patent/BR112016030839B1/en active IP Right Grant
- 2015-06-29 CN CN201580034915.7A patent/CN107074674B/en active Active
- 2015-06-29 RU RU2017103493A patent/RU2695200C2/en active
- 2015-06-29 EP EP15734332.8A patent/EP3164375B1/en active Active
- 2015-06-29 PL PL15734332T patent/PL3164375T3/en unknown
- 2015-06-29 AU AU2015282658A patent/AU2015282658B2/en active Active
- 2015-06-29 RS RS20191481A patent/RS60020B1/en unknown
- 2015-06-29 HU HUE15734332A patent/HUE046300T2/en unknown
- 2015-06-29 PT PT157343328T patent/PT3164375T/en unknown
- 2015-06-29 WO PCT/EP2015/064729 patent/WO2016001161A1/en active Application Filing
- 2015-06-29 LT LT15734332T patent/LT3164375T/en unknown
- 2015-06-29 JP JP2016575851A patent/JP6559164B2/en active Active
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2019
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB195344A (en) * | 1922-03-27 | 1923-06-14 | Hans Rathsburg | Process for making priming compositions |
| US4566921A (en) * | 1985-02-08 | 1986-01-28 | L'etat Francais Represente Par Le Delegue Ministeriel Pour L'armement | Priming composition which is sensitive to percussion and a method for preparing it |
| CN101434617A (en) * | 2008-08-20 | 2009-05-20 | 西北大学 | Energetic coordination complex based on azo tetrazole azotetrazole and use thereof |
| EP2377840A2 (en) * | 2010-04-14 | 2011-10-19 | Diehl BGT Defence GmbH & Co.KG | 5,5'-azotetrazolate explosive |
| DE102010036950A1 (en) * | 2010-08-11 | 2012-02-16 | Nammo Germany Gmbh | New metal-tetrazole complex useful as initiating explosive for preparing an explosive, which is useful as blasting agent, propellant, fuel composition or ignition composition |
| CN102731425A (en) * | 2011-04-12 | 2012-10-17 | 南京理工大学 | Preparation method of zinc 5, 5'-azotetrazole |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110937962A (en) * | 2019-12-03 | 2020-03-31 | 北京理工大学 | Alloy type carmine cold firework chemical and preparation method thereof |
Also Published As
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| DK3164375T3 (en) | 2019-11-25 |
| RU2017103493A (en) | 2018-08-03 |
| BR112016030839A2 (en) | 2017-08-22 |
| HUE046300T2 (en) | 2020-02-28 |
| RU2695200C2 (en) | 2019-07-22 |
| CN107074674B (en) | 2020-12-08 |
| JP2017524638A (en) | 2017-08-31 |
| SI3164375T1 (en) | 2020-07-31 |
| PT3164375T (en) | 2019-12-02 |
| AU2015282658A1 (en) | 2017-02-02 |
| RS60020B1 (en) | 2020-04-30 |
| JP6559164B2 (en) | 2019-08-14 |
| PL3164375T3 (en) | 2020-06-01 |
| EP3164375B1 (en) | 2019-08-21 |
| WO2016001161A1 (en) | 2016-01-07 |
| EP3164375A1 (en) | 2017-05-10 |
| US20170137339A1 (en) | 2017-05-18 |
| ES2757934T3 (en) | 2020-04-30 |
| HRP20192094T1 (en) | 2020-02-21 |
| AU2015282658B2 (en) | 2019-10-10 |
| LT3164375T (en) | 2019-12-10 |
| BR112016030839B1 (en) | 2022-04-19 |
| RU2017103493A3 (en) | 2019-02-08 |
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