CN107034669A - A kind of method that anti-crease finishing is carried out to bafta - Google Patents
A kind of method that anti-crease finishing is carried out to bafta Download PDFInfo
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- CN107034669A CN107034669A CN201710271000.9A CN201710271000A CN107034669A CN 107034669 A CN107034669 A CN 107034669A CN 201710271000 A CN201710271000 A CN 201710271000A CN 107034669 A CN107034669 A CN 107034669A
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- Prior art keywords
- bafta
- crease
- agent
- finishing
- malic acid
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
It is a kind of that the method without aldehyde anti-crease finishing is carried out to bafta, have steps of：Step one：Pure cotton cloth after scouringing and bleaching is put into malic acid, sodium hypophosphite, stearic acid triethanolamine ester quaternary softening agent, the mixed liquor of penetrating agent JFC and impregnated, two leachings two are rolled, it is 90 100% to control pick-up；Step 2：Drying, training are dried, then soap, dry.The present invention has advantages below：By regarding malic acid as crease-shedding finishing agent, addition simultaneously has the sodium hypophosphite and nontoxic softening agent and bleeding agent of catalytic effect and is made, anti-crease finishing for bafta is processed, while anti-wrinkle effect is ensured, improve the problem of conventional anti-crease finishing strength and larger wearability loss, while fabric is without yellowing phenomenon；By by the rational proportion of malic acid, catalyst, softening agent, bleeding agent formation crease-shedding finishing agent, environmental protection, will not the poisonous and harmful substance such as release formaldehyde, trust safely, and reduce production cost, in production with certain application value.
Description
Technical field
The present invention relates to a kind of method that anti-crease finishing is carried out to bafta, belong to dyeing and finishing technique field.
Background technology
Pure cotton fabric is comfortable and easy to wear, moisture absorption of breathing freely, and the advantages of soft, but bafta is existed in use
Poor flexibility, it is yielding, crease easily, wash after need flatiron etc. defect, cause bafta after washing kimonos use during can not keep flat
Whole outward appearance.Therefore, in order to improve outward appearance of the bafta in wearing process, the stability of its form is kept, it is improved and takes
Performance, it is very necessary to carry out anti-crease finishing to textile clothes fabric.
At present, the crease-shedding finishing agent commonly used in the anti-crease finishing is still based on ureaformaldehyde derivative species resin finishing agent, i.e.,
Contain N- hydroxymethyl derivative structures, such as 2D or modified 2D resinoids in structure.After this kind of resin finishing agent is arranged
The problem of fabric all has release formaldehyde.Therefore safer formaldehyde-free anti-crease finish is needed.
It is anti-that formaldehyde-free anti-crease finish includes glyoxal-amides compound, reactive organosilicon compound, water fever
The natural polymers such as type polyurethane, chitosan and Polycarboxylic acids are answered, wherein glyoxal-amide-type chemical combination
There is the defects such as yellowing, strength loss be serious or finishing effect is not good in the bafta that the formaldehydeless finishing agents such as thing are arranged, comprehensive
Consider many factors, polybasic carboxylic acid class such as wrinkle resistance, strength retention, environmental protection, cost and discoloration of fabric after arranging
Compound is considered as most possibly replacing N- methylol class finishing agents.It is presently used for the Polycarboxylic acids of anti-crease finishing
There are 1,2,3,4- BTCAs, citric acid, maleic acid, itaconic acid, poly etc., wherein most have application development prospect is
1,2,3,4- BTCA and citric acid, but 1,2,3,4- BTCA costs are higher to be unsuitable for large-scale application, and lemon
The easy yellowing of fabric of lemon acid treatment.Malic acid has crease-resistant effect, is difficult yellowing as a kind of polybasic carboxylic acid, processing fabric,
Formaldehydeless release, and it is cheap, but strength loss is big, has had a strong impact on its wearability.
The content of the invention
Goal of the invention：It is to overcome the shortcomings of present in prior art to carry out anti-crease finishing to bafta there is provided a kind of
Method, this method anti-wrinkle effect is good, will not release formaldehyde, not easy to change.
Technical scheme：To achieve these goals, technical scheme provides a kind of anti-without aldehyde to bafta progress
The method that wrinkle is arranged, has steps of：
Step one：Pure cotton cloth after scouringing and bleaching is put into malic acid, sodium hypophosphite, stearic acid triethanolamine ester quaternary is soft
Impregnated in agent, the mixed liquor of penetrating agent JFC, two leachings two are rolled, it is 90-100% to control pick-up；
Step 2：Drying, training are dried, then soap, dry.
In the step one, malic acid concentration is 2.0-10.0 wt%, and sodium hypophosphite is 2.0-10.0 wt%, stearic acid three
Monoethanolamine ester quat softening agent is 0.2 wt%, and penetrating agent JFC is 0.08 wt % and surplus is water.
In the step 2, the temperature of drying is 80-100 DEG C.
In the step 2, the time of drying is 2-11 min.
In the step 2, it is 120-200 DEG C that temperature is dried in training.
In the step 2, the training baking time is 1.5-3.0 min.
Beneficial effect：Compared with prior art, the present invention has advantages below：
Crease-resistant anti-deformation effect is good：The present invention by using malic acid as crease-shedding finishing agent, while addition is with catalytic effect
Sodium hypophosphite and nontoxic softening agent and bleeding agent and be made, the anti-crease finishing for bafta is processed, and is ensureing anti-wrinkle effect
Meanwhile, improve the problem of conventional anti-crease finishing strength and larger wearability loss, while fabric is without yellowing phenomenon.
It is economic and environment-friendly：The present invention by the rational proportion of malic acid, catalyst, softening agent, bleeding agent by forming crease-resistant whole
Manage agent, environmental protection, will not the poisonous and harmful substance such as release formaldehyde, trust safely, and reduce production cost, in production
With certain application value.
Embodiment
With reference to example, the present invention is described further, but the scope of protection of present invention is not limited to example
The scope of expression.
A kind of to carry out the method without aldehyde anti-crease finishing to bafta, embodiment is as follows：
Embodiment 1：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 2.0, sodium hypophosphite concentration is 5.0 wt%, stearic triethylenetetraminehexaacetic acid
Impregnated in the mixed liquor of hydramine ester quat softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled
It is 90% to control pick-up, and 2 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to
Standard GB/T/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 55.0% and creasy recovery angle
For 176 °.
Embodiment 2：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 10.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 61.6% and creasy recovery angle is
204°。
Embodiment 3：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 2.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 68.0% and creasy recovery angle is
164°。
Embodiment 4：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 10.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 58.6% and creasy recovery angle is
210°。
Embodiment 5：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 80 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to national standard
GB/T 3923.2-2013, the strength retention for measuring bafta is 57.2% and creasy recovery angle is 203 °.
Embodiment 6：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 58.5% and creasy recovery angle is
201°。
Embodiment 7：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 100%, and 11 min are dried at 100 DEG C, then dries 2 min in 180 DEG C of trainings, is finally soaped, dried.According to country
Standard GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 56.7% and creasy recovery angle is
209°。
Embodiment 8：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
It is 1 that pure cotton cloth after scouringing and bleaching is put into bath raio:50 are equipped with the wt% of malic acid 8.0, the wt % of sodium hypophosphite 5.0, firmly
Impregnated in the mixed liquor of resin acid triethanol amine ester quat softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus,
Two leachings two, which are rolled, controls pick-up to be 90%, dries 2 min at 100 DEG C, then dries 2 min in 120 DEG C of trainings, finally soaped,
Drying.According to standard GB/T/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 86.0% He
Creasy recovery angle is 152 °.
Embodiment 9：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, sodium hypophosphite 5.0wt %, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 2 min in 200 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 51.0% and creasy recovery angle is
247°。
Embodiment 10：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 1.5 min in 180 DEG C of trainings, is finally soaped, dried.According to country
Standard GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 61.7% and creasy recovery angle is
205°。
Embodiment 11：
The original ultimate strength of known pure cotton cloth is 895N and creasy recovery angle is 89 °.
Pure cotton cloth after scouringing and bleaching is put into the wt% of malic acid 8.0, the wt% of sodium hypophosphite 5.0, Triethanolamine Esters of Stearic Acid
Impregnated in the mixed liquor of quaternary ammonium salt softening agent 0.2 wt%, the wt% of penetrating agent JFC 0.08 and the water of surplus, two leachings two are rolled control and rolled
Remaining rate is 90%, and 2 min are dried at 100 DEG C, then dries 3 min in 180 DEG C of trainings, is finally soaped, dried.According to country's mark
Quasi- GB/T 3923.2-2013 and GB/T 3819, the strength retention for measuring bafta is 56.3% and creasy recovery angle is
206°。
Claims (6)
1. a kind of carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that has steps of：
Step one：Pure cotton cloth after scouringing and bleaching is put into malic acid, sodium hypophosphite, stearic acid triethanolamine ester quaternary is soft
Impregnated in agent, the mixed liquor of penetrating agent JFC, two leachings two are rolled, it is 90-100% to control pick-up；
Step 2：Drying, training are dried, then soap, dry.
2. as claimed in claim 1 carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that the step one
In, malic acid is 2.0-10.0 wt%, sodium hypophosphite for 2.0-10.0 wt%, stearic acid triethanolamine ester quaternary softening agent
For 0.2 wt%, penetrating agent JFC is 0.08 wt % and surplus is water.
3. as claimed in claim 1 carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that the step 2
In, the temperature of drying is 80-100 DEG C.
4. as claimed in claim 1 carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that the step 2
In, the time of drying is 2-11 min.
5. as claimed in claim 1 carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that the step 2
In, it is 120-200 DEG C that temperature is dried in training.
6. as claimed in claim 1 carry out the method without aldehyde anti-crease finishing to bafta, it is characterised in that the step 2
In, the training baking time is 1.5-3.0 min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710271000.9A CN107034669B (en) | 2017-04-24 | 2017-04-24 | Method for crease-resistant finishing of cotton fabric |
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| CN201710271000.9A CN107034669B (en) | 2017-04-24 | 2017-04-24 | Method for crease-resistant finishing of cotton fabric |
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| CN107034669A true CN107034669A (en) | 2017-08-11 |
| CN107034669B CN107034669B (en) | 2021-10-08 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419529A (en) * | 2017-09-15 | 2017-12-01 | 五邑大学 | A kind of sodolin crease-shedding finishing agent and its application |
| CN107558199A (en) * | 2017-09-15 | 2018-01-09 | 五邑大学 | A kind of cotton fabric crease-shedding finishing agent and its application |
| CN107700209A (en) * | 2017-09-25 | 2018-02-16 | 安徽华祺汽车装饰有限公司 | A kind of method for sorting of viscose fiber automobile cushion |
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| CN105200777A (en) * | 2015-09-23 | 2015-12-30 | 宿州学院 | Crease-resistant non-ironing finishing technology of pure cotton fabric |
| CN105256580A (en) * | 2015-10-26 | 2016-01-20 | 张作玮 | Crease-resistant finishing method for cellulosic fiber fabric |
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| CN104358116A (en) * | 2014-10-14 | 2015-02-18 | 东华大学 | Polybasic carboxylic acid non-ironing process washing-free method adopting urea as additive |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419529A (en) * | 2017-09-15 | 2017-12-01 | 五邑大学 | A kind of sodolin crease-shedding finishing agent and its application |
| CN107558199A (en) * | 2017-09-15 | 2018-01-09 | 五邑大学 | A kind of cotton fabric crease-shedding finishing agent and its application |
| CN107558199B (en) * | 2017-09-15 | 2021-05-28 | 五邑大学 | Cotton fabric crease-resistant finishing agent |
| CN107700209A (en) * | 2017-09-25 | 2018-02-16 | 安徽华祺汽车装饰有限公司 | A kind of method for sorting of viscose fiber automobile cushion |
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| CN107034669B (en) | 2021-10-08 |
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