CN111074619A - Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin - Google Patents

Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin Download PDF

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Publication number
CN111074619A
CN111074619A CN201811212786.8A CN201811212786A CN111074619A CN 111074619 A CN111074619 A CN 111074619A CN 201811212786 A CN201811212786 A CN 201811212786A CN 111074619 A CN111074619 A CN 111074619A
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clothes
medicine soaking
ironing
finishing
auxiliary medicine
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CN201811212786.8A
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陶晓华
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Jiangyin Chuangjiejia Clothing Co Ltd
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Jiangyin Chuangjiejia Clothing Co Ltd
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Priority to CN201811212786.8A priority Critical patent/CN111074619A/en
Publication of CN111074619A publication Critical patent/CN111074619A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention relates to a method for crease-resistant finishing of dihydroxyethylene urea resin on clothes, wherein the non-ironing finishing liquid consists of 80-100g/L dihydroxyethylene urea resin, 7-9g/L magnesium chloride, 0.1-0.2g/L formaldehyde catching agent and deionized water. The non-ironing after-finishing process comprises the steps of washing, stacking, dispensing, preparing, dipping, squeezing, drying in a constant humidity mode, shaping, pressing, baking and shaping, slow cooling and rewetting and cleaning.

Description

Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin
Technical Field
The invention relates to the technical field of garment processing, in particular to a method for crease-resist finishing of clothing by using dihydroxyethylene urea resin.
Background
Cotton fibers have very high moisture absorption and swelling properties. Cotton textiles, such as clothing, ladies, trousers or bed textiles, have a very high comfort; however, cotton textiles have the disadvantage of being prone to wrinkling and of shrinking severely under wet processing conditions due to swelling, in comparison with synthetic fiber textiles. While people seek to wear comfortable, the size and shape of the textile are also required to be stable and easy to care, so crease resistance, low temperature ironing, non-ironing and the like become very important additional properties of the clothes.
The non-ironing property is that the fabric has wrinkle resistance in the wearing process, and can still keep good flat state or pleat and stable form without ironing after washing, namely the finished fabric has excellent wrinkle resistance in a dry and wet state. At present, the domestic non-ironing technology mainly comprises liquid ammonia finishing, resin treatment and the like.
During liquid ammonia finishing, ammonia permeates into the fiber instantaneously, so that the fiber crystal structure of the cotton fiber is changed, the torsional stress in the fiber is reduced or disappears, the anti-wrinkle effect is achieved, the pulling strength and the tearing strength of the fabric are improved, the dimensional stability of the fabric is improved, the contractility of the fabric during washing is greatly improved, meanwhile, the smoothness among the fibers is enhanced, the surface is smooth, and the excellent softness of the cotton fiber is achieved. The hand feeling can be kept good even after repeated washing. However, due to the danger of the liquid ammonia, the technology is not adopted by general enterprises.
The resin treatment is to use resin and other additives to change the physical and chemical properties of the fiber and fabric and improve the shrink-proof and crease-resistant properties of the fabric. The resin and the hydroxyl groups in two cellulose molecules form covalent crosslinking to mutually link adjacent molecular chains, so that the deformation which cannot be immediately recovered due to the hydrogen bond disintegration is reduced, and the recovery capability of the fiber from the deformation is improved. Therefore, to improve the wrinkle recovery of pure cotton fabrics, it is most effective to introduce a suitable amount of stable cross-linking in the amorphous regions of the fibers. After the pure cotton fabric is treated by the special finishing agent, the finishing agent generates covalent cross bonds among molecular chains in an amorphous area in the form of single molecules or polycondensates, just as if the single molecules of the finishing agent extend out of two powerful 'big hands' to tightly hold the molecular chains in the amorphous area, the effects of restraining and fixing are generated among the molecular chains of fibers, so that the molecular chains of the fibers cannot generate relative displacement, and the deformation which cannot be immediately recovered is reduced, thereby improving the deformation recovery capability of the fibers and achieving the purposes of resisting wrinkles and avoiding ironing.
In order to obtain a better non-ironing effect of the final clothes, the non-ironing finishing liquid is required to fully react with fibers in the fabric. The currently commonly used after-finishing process comprises four steps: (1) washing the clothes with water; (2) fully soaking the fabric in a non-ironing finishing agent for washing; (3) statically hanging the washed clothes for a period of time; (4) and washing with water again to remove redundant reagents, drying and packaging. The clothes after-finishing process has the advantages of long production period, occupation of a large number of production plants, low utilization rate of the non-ironing finishing agent and overhigh production cost.
Disclosure of Invention
The invention aims to overcome the defects and provides a non-ironing after-finishing process of clothes, so that the after-finishing time of the clothes is greatly shortened while a better non-ironing effect is obtained.
The invention relates to a garment non-ironing finishing liquid, which is characterized in that: the effective components of the non-ironing finishing liquid comprise 80-100g/L dihydroxyethylene urea resin, 7-9g/L magnesium chloride and 0.1-0.2g/L formaldehyde catching agent, and the diluent of the non-ironing finishing liquid is deionized water.
The invention relates to a garment non-ironing finishing liquid, which is characterized in that: the non-ironing finishing liquid also comprises a D3 softening agent, and the dosage of the D3 softening agent is 0.8-2 g/L.
The garment non-ironing after-finishing process treated by the garment non-ironing finishing liquid comprises the following steps:
(1) washing with water: extracting the sewed clothes, washing with water, removing stains stained in the sewing process, and spin-drying;
(2) stacking: tiling and stacking the clothes piece by piece, and placing the clothes on a special auxiliary medicine soaking tool;
(3) dispensing: preparing the clothes non-ironing finishing liquid according to the invention, and adjusting the pH value of the non-ironing finishing liquid to 7.5;
(4) preparing: injecting the non-ironing finishing liquid in the step (3) into a medicine soaking pool, and then soaking the auxiliary medicine soaking tool in the step (2) and the clothes to be treated in the step (2) into the medicine soaking pool;
(5) medicine soaking: starting a control system of the auxiliary medicine soaking tool, and controlling the auxiliary medicine soaking tool through the control system, so that the auxiliary medicine soaking tool repeatedly extrudes the clothes stacked in the auxiliary medicine soaking tool at the frequency of 2-3 times per minute, the clothes are in an extruded and loosened state, and the medicine soaking time is maintained for 5-10 minutes;
(6) and (3) squeezing: the clothes and the auxiliary medicine soaking tool which are fully soaked with the non-ironing finishing liquid are lifted out of the medicine soaking pool and suspended above the medicine soaking pool, a control system of the auxiliary medicine soaking tool is started again, and the stacked clothes in the auxiliary medicine soaking tool are repeatedly extruded for 3-5 times, so that the liquid carrying rate of the clothes is reduced to 30% -45%;
(7) drying in a constant humidity mode: conveying the stacked clothes in the auxiliary medicine soaking tool into an oven through a conveying device, heating at 45-55 ℃, and controlling the liquid carrying rate of the clothes to be reduced to 10-20%;
(8) shaping and pressing: flatly paving the clothes processed in the step (7) into a pressing machine piece by piece, sizing and pressing by adopting the temperature of 160-170 ℃ and the pressure of 3kg/cm, wherein the pressing time is 8-10 seconds, so that the non-ironing finishing liquid and the fabric fibers are subjected to partial cross-linking reaction;
(9) baking and shaping: hanging the clothes processed in the step (8), and sending the clothes into a baking and forming machine for baking at the temperature of 140-150 ℃ for 5-6 minutes to enable the non-ironing finishing agent and fabric fibers to realize cross-linking reaction and form;
(10) slow cooling and rewetting: and (4) putting the clothes processed in the step (9) into a constant temperature and humidity chamber for slow cooling and moisture regaining, wherein the conditions of the constant temperature and humidity chamber are as follows: the temperature is 22 ℃, the relative humidity is 75 percent, and the treatment time is 4 hours;
(11) cleaning: putting the clothes treated in the step (10) into clear water with the water temperature of 30 ℃ for repeatedly cleaning for more than 2 times, removing solvents such as unreacted non-ironing finishing liquid and the like, and dehydrating and drying;
(12) and conveying the finished clothes after treatment to a next process through a conveying device.
Preferably, the formaldehyde scavenger in step (3) is MCH-680.
Preferably, the step (3) further comprises a D3 softening agent, and the dosage of the D3 softening agent is 0.8-2 g/L.
According to the invention, the control system of the auxiliary medicine soaking tool in the step 5 of the clothes non-ironing after-finishing process controls the extrusion frequency of the auxiliary medicine soaking tool, so that the liquid absorption rate of clothes stacked in the auxiliary medicine soaking tool is accelerated, the clothes are quickly soaked and balanced, and the medicine soaking time of the clothes is shortened. And 6, after the clothes are separated from the medicine soaking pool, the control system of the auxiliary medicine soaking tool is started again, so that the squeezing speed of the clothes can be quickly realized, and the reuse of the non-ironing finishing liquid can be more conveniently realized.
The clothes non-ironing after-finishing process step 7 adopts low-temperature baking treatment at the temperature of 45-55 ℃, so that the reaction rate of the non-ironing finishing liquid and the clothes can be further accelerated, the clothes are dried in a constant-humidity mode, and the liquid carrying rate of the clothes can be reduced to 10-20%. After the clothes are subjected to high-temperature shaping and pressing treatment in the step 8 of the non-ironing after-finishing process, the non-ironing finishing liquid and fabric fibers are subjected to partial cross-linking reaction, and the clothes are preliminarily shaped. And (3) hanging the clothes treated in the step (8), baking and reshaping the clothes in the step (9) of the non-ironing after-finishing process, and further enabling the non-ironing finishing agent and fabric fibers to completely generate a crosslinking reaction, so that the crease-resistant durability of the pure cotton clothes is improved.
Compared with the prior art, the invention has the beneficial effects that:
by adopting the after-finishing process, the pure cotton clothes with stable size and shape can be obtained, the crease resistance meets the requirement of the garment fabric of GB/T18863 + 2002 'easy care textiles', the after-finishing time of the clothes is greatly shortened, and the utilization rate of a production workshop is improved. The invention has simple process and can completely meet the requirements of customers on environmental protection and naturalness.
Detailed Description
The present invention will be further described with reference to the following examples.
Example 1:
a non-ironing after-finishing process for clothes comprises the following steps:
(1) washing with water: extracting the sewed clothes, washing with water, removing stains stained in the sewing process, and spin-drying;
(2) stacking: tiling and stacking the clothes piece by piece, and placing the clothes on a special auxiliary medicine soaking tool;
(3) dispensing: preparing a non-ironing finishing liquid, and adjusting the components of the non-ironing finishing liquid to reach the following concentrations by adding a diluent deionized water: 80g/L of dihydroxyethylene urea resin, 7g/L of magnesium chloride and 0.1/L of formaldehyde catching agent, and adjusting the pH of the non-ironing finishing liquid to be =7.5;
(4) preparing: injecting the non-ironing finishing liquid in the step (3) into a medicine soaking pool, and then soaking the auxiliary medicine soaking tool in the step (2) and the clothes to be treated in the step (2) into the medicine soaking pool;
(5) medicine soaking: starting a control system of the auxiliary medicine soaking tool, and controlling the auxiliary medicine soaking tool through the control system, so that the auxiliary medicine soaking tool repeatedly extrudes the clothes stacked in the auxiliary medicine soaking tool at the frequency of 3 times per minute, the clothes are in an extruded and loosened state, and the medicine soaking time is maintained for 10 minutes;
(6) and (3) squeezing: the clothes and the auxiliary medicine soaking tool which are fully soaked with the non-ironing finishing liquid are lifted out of the medicine soaking pool and suspended above the medicine soaking pool, a control system of the auxiliary medicine soaking tool is started again, and the stacked clothes in the auxiliary medicine soaking tool are repeatedly squeezed for 5 times, so that the liquid carrying rate of the clothes is reduced to 30%;
(7) drying in a constant humidity mode: conveying the stacked clothes in the auxiliary medicine soaking tool into an oven through a conveying device, and performing heating treatment at 45 ℃ to control the liquid carrying rate of the clothes to be reduced to 10%;
(8) shaping and pressing: flatly paving the clothes processed in the step (7) into a pressing machine piece by piece, sizing and pressing by adopting 170 ℃ and 3kg/cm of pressure, wherein the pressing time is 8 seconds, so that the non-ironing finishing liquid and fabric fibers are subjected to partial cross-linking reaction;
(9) baking and shaping: hanging the clothes processed in the step (8), and sending the clothes into a baking forming machine for baking at 150 ℃ for 5 minutes to enable the non-ironing finishing agent and the fabric fibers to realize cross-linking reaction and form;
(10) slow cooling and rewetting: and (4) putting the clothes processed in the step (9) into a constant temperature and humidity chamber for slow cooling and moisture regaining, wherein the conditions of the constant temperature and humidity chamber are as follows: the temperature is 22 ℃, the relative humidity is 75 percent, and the treatment time is 4 hours;
(11) cleaning: putting the clothes treated in the step (10) into clear water with the water temperature of 30 ℃ for repeated cleaning for 2 times, removing solvents such as unreacted non-ironing finishing liquid and the like, and dehydrating and drying;
(12) and conveying the finished clothes after treatment to a next process through a conveying device.
The clothes obtained by adopting the after-finishing process have the advantages that the size and the form stability of the clothes are obviously improved, the wrinkle resistance meets the requirement of GB/T18863 plus 2002 & ltnon-ironing textile & gt serving fabric, and the requirement of customers on pursuing environmental protection and nature can be completely met.
Example 2:
the non-ironing after-finishing process of clothes comprises the following steps:
a non-ironing after-finishing process for clothes comprises the following steps:
(1) washing with water: extracting the sewed clothes, washing with water, removing stains stained in the sewing process, and spin-drying;
(2) stacking: tiling and stacking the clothes piece by piece, and placing the clothes on a special auxiliary medicine soaking tool;
(3) dispensing: preparing a non-ironing finishing liquid, and adjusting the components of the non-ironing finishing liquid to reach the following concentrations by adding a diluent deionized water: 100g/L dihydroxyethylene urea resin, 9g/L magnesium chloride, 0.2g/L formaldehyde scavenger MCH-680 and 2g/LD3 softener, and the pH of the non-ironing finishing liquid is adjusted to be =7.5;
(4) preparing: injecting the non-ironing finishing liquid in the step (3) into a medicine soaking pool, and then soaking the auxiliary medicine soaking tool in the step (2) and the clothes to be treated in the step (2) into the medicine soaking pool;
(5) medicine soaking: starting a control system of the auxiliary medicine soaking tool, and controlling the auxiliary medicine soaking tool through the control system, so that the auxiliary medicine soaking tool repeatedly extrudes the clothes stacked in the auxiliary medicine soaking tool at a frequency of 2 times per minute, the clothes are in an extruded and loosened state, and the medicine soaking time is maintained for 5 minutes;
(6) and (3) squeezing: the clothes and the auxiliary medicine soaking tool which are fully soaked with the non-ironing finishing liquid are lifted out of the medicine soaking pool and suspended above the medicine soaking pool, a control system of the auxiliary medicine soaking tool is started again, and the stacked clothes in the auxiliary medicine soaking tool are repeatedly extruded for 3 times, so that the liquid carrying rate of the clothes is reduced to 45%;
(7) drying in a constant humidity mode: conveying the stacked clothes in the auxiliary medicine soaking tool into an oven through a conveying device, and performing heating treatment at 55 ℃ to control the liquid carrying rate of the clothes to be reduced to 20%;
(8) shaping and pressing: flatly paving the clothes processed in the step (7) into a pressing machine piece by piece, sizing and pressing by adopting 160 ℃ and 3kg/cm of pressure, wherein the pressing time is 10 seconds, so that the non-ironing finishing liquid and fabric fibers are subjected to partial cross-linking reaction;
(9) baking and shaping: hanging the clothes processed in the step (8), and sending the clothes into a baking forming machine for baking at 140 ℃ for 6 minutes to enable the non-ironing finishing agent and the fabric fibers to realize cross-linking reaction and form;
(10) slow cooling and rewetting: and (4) putting the clothes processed in the step (9) into a constant temperature and humidity chamber for slow cooling and moisture regaining, wherein the conditions of the constant temperature and humidity chamber are as follows: the temperature is 22 ℃, the relative humidity is 75 percent, and the treatment time is 4 hours;
(11) cleaning: putting the clothes treated in the step (10) into clear water with the water temperature of 30 ℃ for repeated cleaning for 3 times, removing solvents such as unreacted non-ironing finishing liquid and the like, and dehydrating and drying;
(12) and conveying the finished clothes after treatment to a next process through a conveying device.
The clothes obtained by adopting the after-finishing process have the advantages that the size and the form stability of the clothes are obviously improved, the wrinkle resistance meets the requirement of GB/T18863 plus 2002 & ltnon-ironing textile & gt serving fabric, and the requirement of customers on pursuing environmental protection and nature can be completely met.
While the preferred embodiments of the present invention have been described in detail, it will be understood by those skilled in the art that the invention is not limited thereto, and that various changes and modifications may be made without departing from the spirit of the invention, and the scope of the appended claims is to be accorded the full range of equivalents.

Claims (4)

1. The non-ironing finishing liquid for clothes is characterized in that: the effective components of the non-ironing finishing liquid comprise 80-100g/L dihydroxyethylene urea resin, 7-9g/L magnesium chloride and 0.1-0.2g/L formaldehyde catching agent, and the diluent of the non-ironing finishing liquid is deionized water.
2. The easy care finishing liquor for clothing according to claim 1, wherein: the non-ironing finishing liquid also comprises a D3 softening agent, and the dosage of the D3 softening agent is 0.8-2 g/L.
3. The easy-care finishing liquor for clothes according to claim 1 or 2, characterized in that: the formaldehyde scavenger is MCH-680.
4. A garment permanent-press after-finishing process for treating garments with the garment permanent-press finishing liquor of claim 1 or 2, characterized in that: the after-finishing process comprises the following steps:
(1) washing with water: extracting the sewed clothes, washing with water, removing stains stained in the sewing process, and spin-drying;
(2) stacking: tiling and stacking the clothes piece by piece, and placing the clothes on a special auxiliary medicine soaking tool;
(3) dispensing: preparing a clothes non-ironing finishing liquid, and adjusting the pH value of the non-ironing finishing liquid to 7.5;
(4) preparing: injecting the non-ironing finishing liquid in the step (3) into a medicine soaking pool, and then soaking the auxiliary medicine soaking tool in the step (2) and the clothes to be treated in the step (2) into the medicine soaking pool;
(5) medicine soaking: starting a control system of the auxiliary medicine soaking tool, and controlling the auxiliary medicine soaking tool through the control system, so that the auxiliary medicine soaking tool repeatedly extrudes the clothes stacked in the auxiliary medicine soaking tool at the frequency of 2-3 times per minute, the clothes are in an extruded and loosened state, and the medicine soaking time is maintained for 5-10 minutes;
(6) and (3) squeezing: the clothes and the auxiliary medicine soaking tool which are fully soaked with the non-ironing finishing liquid are lifted out of the medicine soaking pool and suspended above the medicine soaking pool, a control system of the auxiliary medicine soaking tool is started again, and the stacked clothes in the auxiliary medicine soaking tool are repeatedly extruded for 3-5 times, so that the liquid carrying rate of the clothes is reduced to 30% -45%;
(7) drying in a constant humidity mode: conveying the stacked clothes in the auxiliary medicine soaking tool into an oven through a conveying device, heating at 45-55 ℃, and controlling the liquid carrying rate of the clothes to be reduced to 10-20%;
(8) shaping and pressing: flatly paving the clothes processed in the step (7) into a pressing machine piece by piece, sizing and pressing by adopting the temperature of 160-170 ℃ and the pressure of 3kg/cm, wherein the pressing time is 8-10 seconds, so that the non-ironing finishing liquid and the fabric fibers are subjected to partial cross-linking reaction;
(9) baking and shaping: hanging the clothes processed in the step (8), and sending the clothes into a baking and forming machine for baking at the temperature of 140-150 ℃ for 5-6 minutes to enable the non-ironing finishing agent and fabric fibers to realize cross-linking reaction and form;
(10) slow cooling and rewetting: and (4) putting the clothes processed in the step (9) into a constant temperature and humidity chamber for slow cooling and moisture regaining, wherein the conditions of the constant temperature and humidity chamber are as follows: the temperature is 22 ℃, the relative humidity is 75 percent, and the treatment time is 4 hours;
(11) cleaning: putting the clothes treated in the step (10) into clear water with the water temperature of 30 ℃ for repeatedly cleaning for more than 2 times, removing solvents such as unreacted non-ironing finishing liquid and the like, and dehydrating and drying;
(12) and conveying the finished clothes after treatment to a next process through a conveying device.
CN201811212786.8A 2018-10-18 2018-10-18 Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin Withdrawn CN111074619A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811212786.8A CN111074619A (en) 2018-10-18 2018-10-18 Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin

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Application Number Priority Date Filing Date Title
CN201811212786.8A CN111074619A (en) 2018-10-18 2018-10-18 Method for crease-resistant finishing of clothing by using dihydroxyethylene urea resin

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CN111074619A true CN111074619A (en) 2020-04-28

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