CN107033684A - A kind of high efficient water-proof painting material and preparation method thereof - Google Patents
A kind of high efficient water-proof painting material and preparation method thereof Download PDFInfo
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- CN107033684A CN107033684A CN201710350996.2A CN201710350996A CN107033684A CN 107033684 A CN107033684 A CN 107033684A CN 201710350996 A CN201710350996 A CN 201710350996A CN 107033684 A CN107033684 A CN 107033684A
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- proof
- high efficient
- feed liquid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of high efficient water-proof painting material, the water-repellent paint includes the component of following mass parts:35 55 parts of styrene-acrylic emulsion, 15 25 parts of lime, 5 10 parts of coarse whiting, 35 parts of photochemical catalyst, 57 parts of air microcapsules, 5 15 parts of potassium oxide, 15 25 parts of age resistor, 10 15 parts of defoamer, 10 15 parts of talcum powder, 5 15 parts of titanium dioxide, 5 10 parts of polyvinyl alcohol, 5 10 parts of calgon, 25 45 parts of water.Instant invention overcomes coating water-proof effect in the prior art is good, easy aging the problems such as, improve coating intrinsic propesties, physics selective penetrated property of the coating molecule to structure trunk is enhanced, it can keep preferable water resistance, vapor-proof performance in a long time, meet actual operation requirements.In addition, adding the performance that air microcapsules are used to improve water-repellent paint heat-insulating and energy-saving.
Description
Technical field
The present invention relates to a kind of high efficient water-proof painting material and preparation method thereof, belong to coating and fabricating technology field.
Background technology
Building coating as a class be used for house decoration coating products, some buildings to mould proof, fire prevention, insulation,
Corrosion-resistant etc. to have particular/special requirement, some buildings have particular/special requirement to waterproof, antifreeze, cracking resistance, have to being decorated with particular/special requirement.Occupy
Firmly property improves function mainly for indoor application, just contributes to improve the function of living environment, such as sound-proofing, sound-absorbing
Property, anti-condensation etc..Being applied to body surface can form with protection decoration or property(Such as insulation, anti-corrosion, mark)'s
A class I liquid I or the general name of solid material for solid coated film.
The coating variety of inner-outer wall is more, especially the appearance of macromolecule emulsion material, is that the kind of coating is added perhaps
Many new varieties.Its waterproof, oxidation resistance enhancing;However, existing water-repellent paint can not rainwater-proof, anti-impact long-term effectively
Brush.Therefore, be frequently seen decoration and brush neat and artistic building cannot stand wind and rain wash away with moisture etch and color is mottled.
Mainly lack stable chemical performance in these coating, water insoluble inorganic substances, thing of the coating molecule to structure trunk
Manage selective penetrated property poor.Thus, its comprehensive waterproof capability effect is not good, easy aging.
The content of the invention
The present invention exactly in view of the deficienciess of the prior art, provide a kind of high efficient water-proof painting material and preparation method thereof, gram
The problems such as not good coating water-proof effect in the prior art, easy aging has been taken, coating intrinsic propesties is improved, coating molecule is enhanced
To the physics selective penetrated property of structure trunk, it can keep preferable water resistance, vapor-proof performance in a long time, meet
Actual operation requirements.
To solve the above problems, the technical solution used in the present invention is as follows:
A kind of high efficient water-proof painting material, the water-repellent paint includes the component of following mass parts:35-55 parts of styrene-acrylic emulsion, lime 15-
25 parts, 5-10 parts of coarse whiting, 3-5 parts of photochemical catalyst, 5-7 parts of air microcapsules, 5-15 parts of potassium oxide, 15-25 parts of age resistor, froth breaking
10-15 parts of agent, 10-15 parts of talcum powder, 5-15 parts of titanium dioxide, 5-10 parts of polyvinyl alcohol, 5-10 parts of calgon, water 25-45
Part.
As the improvement of above-mentioned technical proposal, described styrene-acrylic emulsion is styrene, acrylate copolymer emulsion, or benzene
Ethene, acrylate and acrylate copolymer emulsion.
As the improvement of above-mentioned technical proposal, the photochemical catalyst is titanic oxide nano photochemical catalyst, and the light
The percentage by weight that catalyst charge accounts for water-repellent paint is 1-10%.
As the improvement of above-mentioned technical proposal, the percentage by weight that the additions of the air microcapsules accounts for water-repellent paint is
5-10%。
Specifically, a kind of preparation method of high efficient water-proof painting material is as follows:
Step(1), mixing, steam heating:It is styrene-acrylic emulsion, lime, coarse whiting, photochemical catalyst, air microcapsules, potassium oxide, anti-old
After agent, defoamer, talcum powder, titanium dioxide, polyvinyl alcohol, calgon, water are mixed by proportioning, it is passed through water vapour and adds
Heat, to reach it is transparent untill;
Step(2), broken wall:By step(1)Middle mixture even in feeding wet crushing mill, is carried out at broken, mashing to mixture
Reason, is then quickly stirred under conditions of 75-95 DEG C, is reused nano-shearing machine and is carried out shear treatment, is formed and apply feed liquid;
Step(3), induction:To step(2)Obtained painting feed liquid carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(2)Abandoning supernatant after the painting feed liquid centrifugal treating of acquisition, takes after centrifugation
Painting feed liquid insert on the bottom electrode medium of plasma device, voltage 18kV, under electric current 1.5mA, gap 2mm operating condition
Irradiation 5~15 seconds, forms and applies feed liquid;
Step(4), it is air-cooled:By step(3)After obtained painting feed liquid progress is air-cooled, you can obtain water-repellent paint of the present invention.
It is used as the improvement of above-mentioned technical proposal, step(2)In time for quickly being stirred under conditions of 75-95 DEG C be
1-3 hours.
Compared with prior art, implementation result of the invention is as follows by the present invention:
The invention provides a kind of high efficient water-proof painting material and preparation method thereof, overcome in the prior art that coating water-proof effect is not
The problems such as good, easy aging, coating intrinsic propesties is improved, enhance coating molecule and the physics of structure trunk is selected to pass through
Property, it can keep preferable water resistance, vapor-proof performance in a long time, meet actual operation requirements.In addition, adding air
Microcapsules are used for the performance for improving water-repellent paint heat-insulating and energy-saving.
Note:Invention achieves economizing on resources, the good social effect of environmental protection.
Embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
Embodiment 1
A kind of high efficient water-proof painting material, the water-repellent paint includes the component of following mass parts:35 parts of styrene-acrylic emulsion, 15 parts of lime,
5 parts of coarse whiting, 3 parts of photochemical catalyst, 5 parts of air microcapsules, 5 parts of potassium oxide, 15 parts of age resistor, 10 parts of defoamer, 10 parts of talcum powder,
5 parts of titanium dioxide, 5 parts of polyvinyl alcohol, 5 parts of calgon, 25 parts of water.
Further with improvement, described styrene-acrylic emulsion is styrene, acrylate copolymer emulsion, or styrene, propylene
Sour fat and acrylate copolymer emulsion;The photochemical catalyst be titanic oxide nano photochemical catalyst, and the photochemical catalyst add
The percentage by weight that amount accounts for water-repellent paint is 1%;The percentage by weight that the addition of the air microcapsules accounts for water-repellent paint is
5%。
Specifically, a kind of preparation method of high efficient water-proof painting material is as follows:
Step(1), mixing, steam heating:It is styrene-acrylic emulsion, lime, coarse whiting, photochemical catalyst, air microcapsules, potassium oxide, anti-old
After agent, defoamer, talcum powder, titanium dioxide, polyvinyl alcohol, calgon, water are mixed by proportioning, it is passed through water vapour and adds
Heat, to reach it is transparent untill;
Step(2), broken wall:By step(1)Middle mixture even in feeding wet crushing mill, is carried out at broken, mashing to mixture
Reason, is then quickly stirred under conditions of 75 DEG C, is reused nano-shearing machine and is carried out shear treatment, is formed and apply feed liquid;
Step(3), induction:To step(2)Obtained painting feed liquid carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(2)Abandoning supernatant after the painting feed liquid centrifugal treating of acquisition, takes after centrifugation
Painting feed liquid insert on the bottom electrode medium of plasma device, voltage 18kV, under electric current 1.5mA, gap 2mm operating condition
Irradiation 5 seconds, forms and applies feed liquid;
Step(4), it is air-cooled:By step(3)After obtained painting feed liquid progress is air-cooled, you can obtain water-repellent paint of the present invention.
More specifically, step(2)In time for quickly being stirred under conditions of 75 DEG C be 1 hour.
Instant invention overcomes coating water-proof effect in the prior art is good, easy aging the problems such as, improve coating essence special
Property, physics selective penetrated property of the coating molecule to structure trunk is enhanced, it can keep preferable water proofing property in a long time
Energy, vapor-proof performance, meet actual operation requirements.In addition, adding air microcapsules is used to improve water-repellent paint heat-insulating and energy-saving
Performance.
Note:Invention achieves economizing on resources, the good social effect of environmental protection.
Embodiment 2
A kind of high efficient water-proof painting material, the water-repellent paint includes the component of following mass parts:45 parts of styrene-acrylic emulsion, 20 parts of lime,
7 parts of coarse whiting, 4 parts of photochemical catalyst, 6 parts of air microcapsules, 10 parts of potassium oxide, 20 parts of age resistor, 12 parts of defoamer, talcum powder 13
Part, 10 parts of titanium dioxide, 8 parts of polyvinyl alcohol, 8 parts of calgon, 35 parts of water.
Further with improvement, described styrene-acrylic emulsion is styrene, acrylate copolymer emulsion, or styrene, propylene
Sour fat and acrylate copolymer emulsion;The photochemical catalyst be titanic oxide nano photochemical catalyst, and the photochemical catalyst add
The percentage by weight that amount accounts for water-repellent paint is 5%;The percentage by weight that the addition of the air microcapsules accounts for water-repellent paint is
7%。
Specifically, a kind of preparation method of high efficient water-proof painting material is as follows:
Step(1), mixing, steam heating:It is styrene-acrylic emulsion, lime, coarse whiting, photochemical catalyst, air microcapsules, potassium oxide, anti-old
After agent, defoamer, talcum powder, titanium dioxide, polyvinyl alcohol, calgon, water are mixed by proportioning, it is passed through water vapour and adds
Heat, to reach it is transparent untill;
Step(2), broken wall:By step(1)Middle mixture even in feeding wet crushing mill, is carried out at broken, mashing to mixture
Reason, is then quickly stirred under conditions of 85 DEG C, is reused nano-shearing machine and is carried out shear treatment, is formed and apply feed liquid;
Step(3), induction:To step(2)Obtained painting feed liquid carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(2)Abandoning supernatant after the painting feed liquid centrifugal treating of acquisition, takes after centrifugation
Painting feed liquid insert on the bottom electrode medium of plasma device, voltage 18kV, under electric current 1.5mA, gap 2mm operating condition
Irradiation 10 seconds, forms and applies feed liquid;
Step(4), it is air-cooled:By step(3)After obtained painting feed liquid progress is air-cooled, you can obtain water-repellent paint of the present invention.
More specifically, step(2)In time for quickly being stirred under conditions of 85 DEG C be 2 hours.
Instant invention overcomes coating water-proof effect in the prior art is good, easy aging the problems such as, improve coating essence special
Property, physics selective penetrated property of the coating molecule to structure trunk is enhanced, it can keep preferable water proofing property in a long time
Energy, vapor-proof performance, meet actual operation requirements.In addition, adding air microcapsules is used to improve water-repellent paint heat-insulating and energy-saving
Performance.
Note:Invention achieves economizing on resources, the good social effect of environmental protection.
Embodiment 3
A kind of high efficient water-proof painting material, the water-repellent paint includes the component of following mass parts:55 parts of styrene-acrylic emulsion, 25 parts of lime,
10 parts of coarse whiting, 5 parts of photochemical catalyst, 7 parts of air microcapsules, 15 parts of potassium oxide, 25 parts of age resistor, 15 parts of defoamer, talcum powder 15
Part, 15 parts of titanium dioxide, 10 parts of polyvinyl alcohol, 10 parts of calgon, 45 parts of water.
Further with improvement, described styrene-acrylic emulsion is styrene, acrylate copolymer emulsion, or styrene, propylene
Sour fat and acrylate copolymer emulsion;The photochemical catalyst be titanic oxide nano photochemical catalyst, and the photochemical catalyst add
The percentage by weight that amount accounts for water-repellent paint is 10%;The percentage by weight that the addition of the air microcapsules accounts for water-repellent paint is
10%。
Specifically, a kind of preparation method of high efficient water-proof painting material is as follows:
Step(1), mixing, steam heating:It is styrene-acrylic emulsion, lime, coarse whiting, photochemical catalyst, air microcapsules, potassium oxide, anti-old
After agent, defoamer, talcum powder, titanium dioxide, polyvinyl alcohol, calgon, water are mixed by proportioning, it is passed through water vapour and adds
Heat, to reach it is transparent untill;
Step(2), broken wall:By step(1)Middle mixture even in feeding wet crushing mill, is carried out at broken, mashing to mixture
Reason, is then quickly stirred under conditions of 95 DEG C, is reused nano-shearing machine and is carried out shear treatment, is formed and apply feed liquid;
Step(3), induction:To step(2)Obtained painting feed liquid carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(2)Abandoning supernatant after the painting feed liquid centrifugal treating of acquisition, takes after centrifugation
Painting feed liquid insert on the bottom electrode medium of plasma device, voltage 18kV, under electric current 1.5mA, gap 2mm operating condition
Irradiation 15 seconds, forms and applies feed liquid;
Step(4), it is air-cooled:By step(3)After obtained painting feed liquid progress is air-cooled, you can obtain water-repellent paint of the present invention.
More specifically, step(2)In time for quickly being stirred under conditions of 95 DEG C be 3 hours.
Instant invention overcomes coating water-proof effect in the prior art is good, easy aging the problems such as, improve coating essence special
Property, physics selective penetrated property of the coating molecule to structure trunk is enhanced, it can keep preferable water proofing property in a long time
Energy, vapor-proof performance, meet actual operation requirements.In addition, adding air microcapsules is used to improve water-repellent paint heat-insulating and energy-saving
Performance.
Note:Invention achieves economizing on resources, the good social effect of environmental protection.
Above content is made for the present invention in conjunction with specific embodiments describes in detail, it is impossible to assert that the present invention is specific real
Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from
Put, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.
Claims (6)
1. a kind of high efficient water-proof painting material, it is characterised in that:The water-repellent paint includes the component of following mass parts:Styrene-acrylic emulsion
35-55 parts, it is 15-25 parts of lime, 5-10 parts of coarse whiting, 3-5 parts of photochemical catalyst, 5-7 parts of air microcapsules, 5-15 parts of potassium oxide, anti-
Old agent 15-25 parts, 10-15 parts of defoamer, 10-15 parts of talcum powder, 5-15 parts of titanium dioxide, 5-10 parts of polyvinyl alcohol, hexa metaphosphoric acid
5-10 parts of sodium, 25-45 parts of water.
2. a kind of high efficient water-proof painting material according to claim 1, it is characterised in that:Described styrene-acrylic emulsion is styrene, third
Olefin(e) acid fat copolymer emulsion, or styrene, acrylate and acrylate copolymer emulsion.
3. a kind of high efficient water-proof painting material according to claim 1, it is characterised in that:The photochemical catalyst is nano titania
Powder photochemical catalyst, and the photochemical catalyst addition accounts for the percentage by weight of water-repellent paint for 1-10%.
4. a kind of high efficient water-proof painting material according to claim 1, it is characterised in that:The addition of the air microcapsules accounts for anti-
The percentage by weight of water paint is 5-10%.
5. a kind of preparation method of high efficient water-proof painting material according to claim 1-4, it is characterised in that:The preparation method is such as
Under:
Step(1), mixing, steam heating:It is styrene-acrylic emulsion, lime, coarse whiting, photochemical catalyst, air microcapsules, potassium oxide, anti-old
After agent, defoamer, talcum powder, titanium dioxide, polyvinyl alcohol, calgon, water are mixed by proportioning, it is passed through water vapour and adds
Heat, to reach it is transparent untill;
Step(2), broken wall:By step(1)Middle mixture even in feeding wet crushing mill, is carried out at broken, mashing to mixture
Reason, is then quickly stirred under conditions of 75-95 DEG C, is reused nano-shearing machine and is carried out shear treatment, is formed and apply feed liquid;
Step(3), induction:To step(2)Obtained painting feed liquid carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(2)Abandoning supernatant after the painting feed liquid centrifugal treating of acquisition, takes after centrifugation
Painting feed liquid insert on the bottom electrode medium of plasma device, voltage 18kV, under electric current 1.5mA, gap 2mm operating condition
Irradiation 5~15 seconds, forms and applies feed liquid;
Step(4), it is air-cooled:By step(3)After obtained painting feed liquid progress is air-cooled, you can obtain water-repellent paint of the present invention.
6. a kind of preparation method of high efficient water-proof painting material according to claim 5, it is characterised in that:Step(2)In in 75-95
The time quickly stirred under conditions of DEG C is 1-3 hours.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107964290A (en) * | 2017-11-13 | 2018-04-27 | 青岛卓森纳生物工程有限公司 | A kind of anti-aging environmental protection coating material of high molecular nanometer |
CN108300233A (en) * | 2017-10-03 | 2018-07-20 | 镇江泽枫霖建筑材料有限公司 | A kind of efficient water-repellent paint formula |
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CN103087596A (en) * | 2011-11-04 | 2013-05-08 | 上海伯钰建材有限公司 | Waterproof paint |
CN104263101A (en) * | 2014-09-02 | 2015-01-07 | 陈俊辰 | Indoor building coating |
CN104227220A (en) * | 2014-09-12 | 2014-12-24 | 江苏大学 | Large-area laser impact spot welding method and device based on nano-particle reinforcement |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108300233A (en) * | 2017-10-03 | 2018-07-20 | 镇江泽枫霖建筑材料有限公司 | A kind of efficient water-repellent paint formula |
CN107964290A (en) * | 2017-11-13 | 2018-04-27 | 青岛卓森纳生物工程有限公司 | A kind of anti-aging environmental protection coating material of high molecular nanometer |
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Application publication date: 20170811 |