CN110172296A - A kind of production method of Environmental-protecwaterproof waterproof paint - Google Patents
A kind of production method of Environmental-protecwaterproof waterproof paint Download PDFInfo
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- CN110172296A CN110172296A CN201910380967.XA CN201910380967A CN110172296A CN 110172296 A CN110172296 A CN 110172296A CN 201910380967 A CN201910380967 A CN 201910380967A CN 110172296 A CN110172296 A CN 110172296A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- 239000003973 paint Substances 0.000 title claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 59
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 21
- 229920000180 Alkyd Polymers 0.000 claims abstract description 19
- 239000010445 mica Substances 0.000 claims abstract description 17
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 17
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000002518 antifoaming agent Substances 0.000 claims description 23
- 239000003822 epoxy resin Substances 0.000 claims description 20
- 229920000647 polyepoxide Polymers 0.000 claims description 20
- 230000003213 activating Effects 0.000 claims description 18
- 230000003712 anti-aging Effects 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 17
- 239000004014 plasticizer Substances 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 9
- 239000011268 mixed slurry Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 3
- VJHINFRRDQUWOJ-UHFFFAOYSA-N Dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001774 Perfluoroether Polymers 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-M benzoate Chemical compound [O-]C(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-M 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 229940031569 diisopropyl sebacate Drugs 0.000 claims description 3
- XFKBBSZEQRFVSL-UHFFFAOYSA-N dipropan-2-yl decanedioate Chemical compound CC(C)OC(=O)CCCCCCCCC(=O)OC(C)C XFKBBSZEQRFVSL-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000002000 scavenging Effects 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- PGIBJVOPLXHHGS-UHFFFAOYSA-N Di-n-decyl phthalate Chemical compound CCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCC PGIBJVOPLXHHGS-UHFFFAOYSA-N 0.000 claims description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N Propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 2
- 229940031954 dibutyl sebacate Drugs 0.000 claims description 2
- ONKUXPIBXRRIDU-UHFFFAOYSA-N diethyl decanedioate Chemical compound CCOC(=O)CCCCCCCCC(=O)OCC ONKUXPIBXRRIDU-UHFFFAOYSA-N 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 125000003700 epoxy group Chemical group 0.000 claims 2
- 239000004575 stone Substances 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N Phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Stearin Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 238000004078 waterproofing Methods 0.000 abstract description 4
- 230000002708 enhancing Effects 0.000 abstract description 3
- 230000000149 penetrating Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000003000 nontoxic Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 239000005871 repellent Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- HPSUPGAVFFFPMQ-UHFFFAOYSA-N 1,2,3,4,6,7,10-heptachlorododecane Chemical group CCC(Cl)CCC(Cl)C(Cl)CC(Cl)C(Cl)C(Cl)CCl HPSUPGAVFFFPMQ-UHFFFAOYSA-N 0.000 description 2
- VYESZYDIRODEBT-UHFFFAOYSA-N 1-O-(4,5,6,8,8-pentachlorooctyl) 4-O-(2,4,5-trichlorooctyl) benzene-1,4-dicarboxylate Chemical compound CCCC(Cl)C(Cl)CC(Cl)COC(=O)C1=CC=C(C(=O)OCCCC(Cl)C(Cl)C(Cl)CC(Cl)Cl)C=C1 VYESZYDIRODEBT-UHFFFAOYSA-N 0.000 description 2
- 229940108066 Coal Tar Drugs 0.000 description 2
- 229920000126 Latex Polymers 0.000 description 2
- 229920000305 Nylon 6,10 Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N Sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 210000003491 Skin Anatomy 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-M stearate Chemical class CCCCCCCCCCCCCCCCCC([O-])=O QIQXTHQIDYTFRH-UHFFFAOYSA-M 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 230000002588 toxic Effects 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N Icosane Chemical group CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- 210000004400 Mucous Membrane Anatomy 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000000711 cancerogenic Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of production methods of Environmental-protecwaterproof waterproof paint, with excellent environmental-protecting performance, it is non-toxic and tasteless, film coated surface will not generate penetrating odor after construction and construction, there is no any influence to the body of people, it is green safe, and there is good elasticity, flexibility, water resistance and waterproofness；Using polyurethane resin and alkyd resin as base-material, it is added with mica powder, alkyd resin and graphene, keep coating finer and close, coating is enhanced to the adhesive force of substrate, impact resistance, wearability and the corrosion resistance of dope layer is improved, enhances the service life of coating；And cooperating coalescing agent, obtained coating stable is tough and tensile, can firmly cohere on basal plane, generates permanent effective waterproofing protection effect；And coating manufacture craft of the invention is simple, can directly brush, easy to operate, flintiness is good, long service life.
Description
Technical field
The present invention relates to environmental protection coating material manufacture technology field, specially a kind of production method of Environmental-protecwaterproof waterproof paint.
Background technique
Coating is that one kind is coated on body surface and forms film under certain condition and play protection, decoration and specific
One class I liquid I of effect or fixed material, with the development of economy, coating obtains in industrial or agricultural, national defence, scientific research and people's lives
To being more and more widely used.With the development of industry, coating variety is increasing, and quality and performance are continuously improved, and applies material list
The pure requirement played protection and be no longer satisfied people, especially in the daily life of the people, waterproof, it is moisture-proof also increasingly
It is concerned, thus water-repellent paint will be following market demand trend；However contain toxic component in existing water-repellent paint, sternly
The health for affecting people of weight.
Water-repellent paint refers to a kind of coating that the film that coating is formed can prevent water from leaking.Shape after water-repellent paint is cured
At waterproofing membrane there is certain extensibility, elastoplasticity, crack resistance, impermeability and weatherability, waterproof can be played, anti-blend guarantor
Shield effect.Water-repellent paint has good thermal adaptability, easy to operate, for ease of maintenaince with maintenance.With domestic and international construction industry
The use of development, water-repellent paint is more extensive.
The main one kind of waterproof material in the market is polyurethanes water-repellent paint, and this kind of material is usually by polyurethane and coal
Tar is made as raw material.The tar gas toxicity that it is volatilized is big, and does not allow easy-clear, therefore banned in China in 2000
Only use.It is that pitch is used to replace coal tar as raw material still in the polyurethane waterproofing coating of sale.But using this coating
When, generally diluted using organic solvents such as containing toluene, dimethylbenzene, thus also containing toxic；It is common anti-currently on the market
Water paint is two-component type water-repellent paint, and one of ingredient is latex solution, in order to improve the filming performance of coating, usually in latex
It joined organic solvent in liquid, so that the content of volatile organic solvent and free formaldehyde is higher, in the construction process can
Penetrating odor is generated, stimulates the skin and respiratory system of people, danger stimulation human skin and mucous membrane, Long Term Contact is easily carcinogenic, danger
The health of victimization body.
Therefore, it is particularly important to develop a kind of Environmental-protecwaterproof waterproof paint.
Summary of the invention
The purpose of the present invention is to provide a kind of production methods of Environmental-protecwaterproof waterproof paint, to solve in above-mentioned background technique
The problem of proposition.
To achieve the above object, the invention provides the following technical scheme: a kind of production method of Environmental-protecwaterproof waterproof paint, packet
Include following steps:
S1, prepare production raw material, based on mass parts ratio, raw material is respectively as follows at being grouped as:
90-100 parts of polyurethane resin, 12-16 parts of epoxy resin, 4-10 parts of alkyd resin, 6-10 parts of graphene, mica powder
2-3 parts, 3-8 parts of activating agent, 2-4 parts of coalescing agent, 0.1-0.3 parts of defoaming agent, 2-7 parts of plasticizer, 0.5-1.5 parts of anti-aging agent,
5-20 parts of deionized water；
S2, production hybrid resin,
The polyurethane resin of 90-100 parts by weight and the alkyd resin of 4-10 parts by weight are mixed, in 40-50 DEG C of temperature
Under the conditions of stir evenly, it is spare to obtain hybrid resin；
S3, production aqueous epoxy resins,
The deionized water of the epoxy resin of 12-16 parts by weight and 5-20 parts by weight is mixed evenly, aqueous ring is obtained
Oxygen resin；
S4, cleaning graphene,
Using the graphene of deionized water ultrasonic cleaning 6-10 parts by weight, scavenging period 25-40min, and then set
Dry 4.5-6h, completes cleaning in 65-80 DEG C of constant temperature of drying box；
S5, filler component is prepared,
The mica powder of graphene after cleaning in step S4 and 2-3 parts by weight is added to aqueous obtained in step S3
In epoxy resin, heating stirring is reacted 10-20 minutes, and heating temperature is 40-45 DEG C, forms filler component；
S6, production mixed slurry,
Hybrid resin obtained in above-mentioned steps S2 is poured into agitator tank together with the filler component formed in step S5,
It is heated to 60-80 DEG C to be stirred, obtains mixed slurry；
S7, finished product coating is prepared,
By the activating agent of 3-8 parts by weight, the coalescing agent of 2-4 parts by weight, the defoaming agent of 0.1-0.3 parts by weight, 2-7 weight
The plasticizer of part and the anti-aging agent of 0.5-1.5 parts by weight are added in mixed slurry obtained in step S6, are warming up to 138-142
DEG C, adjustment revolving speed to 400-600r/min, constant temperature stirring stirring 1-2h obtains finished product coating.
As a preferred technical solution of the present invention, the raw material in the step S1 is respectively at being grouped as, by mass fraction
Than being calculated as: 90 parts of polyurethane resin, 12 parts of epoxy resin, 4 parts of alkyd resin, 6 parts of graphene, 2 parts of mica powder, 3 parts of activating agent,
2 parts of coalescing agent, 0.1 part of defoaming agent, 2 parts of plasticizer, 0.5 part of anti-aging agent, 5 parts of deionized water.
As a preferred technical solution of the present invention, the raw material in the step S1 is respectively at being grouped as, by mass fraction
Than being calculated as: 100 parts of polyurethane resin, 16 parts of epoxy resin, 10 parts of alkyd resin, 10 parts of graphene, 3 parts of mica powder, activating agent 8
Part, 4 parts of coalescing agent, 0.3 part of defoaming agent, 7 parts of plasticizer, 1.5 parts of anti-aging agent, 20 parts of deionized water.
As a preferred technical solution of the present invention, the raw material in the step S1 is respectively at being grouped as, by mass fraction
Than being calculated as: 95 parts of polyurethane resin, 14 parts of epoxy resin, 7 parts of alkyd resin, 8 parts of graphene, 2.5 parts of mica powder, activating agent 6
Part, 3 parts of coalescing agent, 0.2 part of defoaming agent, 4 parts of plasticizer, 1 part of anti-aging agent, 15 parts of deionized water.
As a preferred technical solution of the present invention, the activating agent is perfluoroalkoxy yl carboxylic acid.
As a preferred technical solution of the present invention, coalescing agent is benzoglycols, propandiol butyl ether, propylene glycol monomethyl ether
One of acetate.
As a preferred technical solution of the present invention, defoaming agent is that stearates defoaming agent or organic silicon defoam
Agent.
As a preferred technical solution of the present invention, plasticizer is chlorinated paraffin, dioctyl terephthalate or No. 150
One of solvent naphtha is a variety of；Didecyl phthalate, dinonyl phthalate, glycol benzoate, decanedioic acid two
The mixture of one or more of ethyl ester, diisopropyl sebacate, dibutyl sebacate, dioctyl sebacate.
As a preferred technical solution of the present invention, anti-aging agent 1,2- dihydro -2,2, the homopolymerization of 4- trimethylquinoline
Object.
Compared with prior art, the beneficial effects of the present invention are: a kind of production method of Environmental-protecwaterproof waterproof paint of the present invention,
Non-toxic and tasteless with excellent environmental-protecting performance, film coated surface will not generate penetrating odor after construction and construction, to the body of people
There is no any influence, it is green safe, and there is good elasticity, flexibility, water resistance and waterproofness；With polyurethane resin and
Alkyd resin is base-material, is added with mica powder, alkyd resin and graphene, keeps coating finer and close, enhances coating to substrate
Adhesive force, improve impact resistance, wearability and the corrosion resistance of dope layer, enhance the service life of coating；And cooperate
Coalescing agent, obtained coating stable is tough and tensile, can firmly cohere on basal plane, generates permanent effective waterproofing protection effect；
And coating manufacture craft of the invention is simple, can directly brush, easy to operate, flintiness is good, long service life.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment: the present invention provides a kind of technical solution: a kind of production method of Environmental-protecwaterproof waterproof paint, including following step
It is rapid:
S1, prepare production raw material, based on mass parts ratio, raw material is respectively as follows at being grouped as:
90-100 parts of polyurethane resin, 12-16 parts of epoxy resin, 4-10 parts of alkyd resin, 6-10 parts of graphene, mica powder
2-3 parts, 3-8 parts of activating agent, 2-4 parts of coalescing agent, 0.1-0.3 parts of defoaming agent, 2-7 parts of plasticizer, 0.5-1.5 parts of anti-aging agent,
5-20 parts of deionized water；
S2, production hybrid resin,
The polyurethane resin of 90-100 parts by weight and the alkyd resin of 4-10 parts by weight are mixed, in 40-50 DEG C of temperature
Under the conditions of stir evenly, it is spare to obtain hybrid resin；
S3, production aqueous epoxy resins,
The deionized water of the epoxy resin of 12-16 parts by weight and 5-20 parts by weight is mixed evenly, aqueous ring is obtained
Oxygen resin；
S4, cleaning graphene,
Using the graphene of deionized water ultrasonic cleaning 6-10 parts by weight, scavenging period 25-40min, and then set
Dry 4.5-6h, completes cleaning in 65-80 DEG C of constant temperature of drying box；
S5, filler component is prepared,
The mica powder of graphene after cleaning in step S4 and 2-3 parts by weight is added to aqueous obtained in step S3
In epoxy resin, heating stirring is reacted 10-20 minutes, and heating temperature is 40-45 DEG C, forms filler component；
S6, production mixed slurry,
Hybrid resin obtained in above-mentioned steps S2 is poured into agitator tank together with the filler component formed in step S5,
It is heated to 60-80 DEG C to be stirred, obtains mixed slurry；
S7, finished product coating is prepared,
By the activating agent of 3-8 parts by weight, the coalescing agent of 2-4 parts by weight, the defoaming agent of 0.1-0.3 parts by weight, 2-7 weight
The plasticizer of part and the anti-aging agent of 0.5-1.5 parts by weight are added in mixed slurry obtained in step S6, are warming up to 138-142
DEG C, adjustment revolving speed to 400-600r/min, constant temperature stirring stirring 1-2h obtains finished product coating.
Raw material in the step S1 is calculated as respectively at being grouped as by mass parts ratio: 90 parts of polyurethane resin, epoxy resin
12 parts, 4 parts of alkyd resin, 6 parts of graphene, 2 parts of mica powder, 3 parts of activating agent, 2 parts of coalescing agent, 0.1 part of defoaming agent, plasticizer
2 parts, 0.5 part of anti-aging agent, 5 parts of deionized water.
Raw material in the step S1 is calculated as respectively at being grouped as by mass parts ratio: 100 parts of polyurethane resin, asphalt mixtures modified by epoxy resin
16 parts of rouge, 10 parts of graphene, 3 parts of mica powder, 8 parts of activating agent, 4 parts of coalescing agent, 0.3 part of defoaming agent, increases 10 parts of alkyd resin
Mould 7 parts of agent, 1.5 parts of anti-aging agent, 20 parts of deionized water.
Raw material in the step S1 is calculated as respectively at being grouped as by mass parts ratio: 95 parts of polyurethane resin, epoxy resin
14 parts, 7 parts of alkyd resin, 8 parts of graphene, 2.5 parts of mica powder, 6 parts of activating agent, 3 parts of coalescing agent, 0.2 part of defoaming agent, plasticising
4 parts of agent, 1 part of anti-aging agent, 15 parts of deionized water.
The activating agent is perfluoroalkoxy yl carboxylic acid.
Coalescing agent is one of benzoglycols, propandiol butyl ether, propylene glycol methyl ether acetate.
Defoaming agent is stearates defoaming agent or organic silicon defoaming agent.
Plasticizer is one of chlorinated paraffin, dioctyl terephthalate or No. 150 solvent naphthas or a variety of；O-phthalic
Sour didecyl, dinonyl phthalate, glycol benzoate, diethyl sebacate, diisopropyl sebacate, two fourth of decanedioic acid
The mixture of one or more of ester, dioctyl sebacate.
Anti-aging agent is 1,2- dihydro -2,2, the homopolymer of 4- trimethylquinoline.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of production method of Environmental-protecwaterproof waterproof paint, which comprises the following steps:
S1, prepare production raw material, based on mass parts ratio, raw material is respectively as follows at being grouped as:
90-100 parts of polyurethane resin, 12-16 parts of epoxy resin, 4-10 parts of alkyd resin, 6-10 parts of graphene, mica powder 2-3
Part, 3-8 parts of activating agent, 2-4 parts of coalescing agent, 0.1-0.3 parts of defoaming agent, 2-7 parts of plasticizer, 0.5-1.5 parts of anti-aging agent, go from
Sub- water 5-20 parts；
S2, production hybrid resin,
The polyurethane resin of 90-100 parts by weight and the alkyd resin of 4-10 parts by weight are mixed, in the condition of 40-50 DEG C of temperature
Under stir evenly, it is spare to obtain hybrid resin；
S3, production aqueous epoxy resins,
The deionized water of the epoxy resin of 12-16 parts by weight and 5-20 parts by weight is mixed evenly, water-base epoxy tree is obtained
Rouge；
S4, cleaning graphene,
Using the graphene of deionized water ultrasonic cleaning 6-10 parts by weight, scavenging period 25-40min, and then it is placed in perseverance
Dry 4.5-6h, completes cleaning in warm 65-80 DEG C of drying box；
S5, filler component is prepared,
The mica powder of graphene after cleaning in step S4 and 2-3 parts by weight is added to water-base epoxy obtained in step S3
In resin, heating stirring is reacted 10-20 minutes, and heating temperature is 40-45 DEG C, forms filler component；
S6, production mixed slurry,
Hybrid resin obtained in above-mentioned steps S2 is poured into agitator tank together with the filler component formed in step S5, is heated
It is stirred to 60-80 DEG C, obtains mixed slurry；
S7, finished product coating is prepared,
By the activating agent of 3-8 parts by weight, the coalescing agent of 2-4 parts by weight, the defoaming agent of 0.1-0.3 parts by weight, 2-7 parts by weight
Plasticizer and the anti-aging agent of 0.5-1.5 parts by weight are added in mixed slurry obtained in step S6, are warming up to 138-142 DEG C, adjust
Turn over speed to 400-600r/min, constant temperature stirring stirs 1-2h, obtains finished product coating.
2. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that in the step S1
Raw material respectively at being grouped as, be calculated as by mass parts ratio: 90 parts of polyurethane resin, 12 parts of epoxy resin, 4 parts of alkyd resin, stone
6 parts of black alkene, 3 parts of activating agent, 2 parts of coalescing agent, 0.1 part of defoaming agent, 2 parts of plasticizer, 0.5 part of anti-aging agent, is gone 2 parts of mica powder
5 parts of ionized water.
3. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that in the step S1
Raw material respectively at being grouped as, be calculated as by mass parts ratio: 100 parts of polyurethane resin, 16 parts of epoxy resin, 10 parts of alkyd resin,
10 parts of graphene, 3 parts of mica powder, 8 parts of activating agent, 4 parts of coalescing agent, 0.3 part of defoaming agent, 7 parts of plasticizer, 1.5 parts of anti-aging agent,
20 parts of deionized water.
4. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that in the step S1
Raw material respectively at being grouped as, be calculated as by mass parts ratio: 95 parts of polyurethane resin, 14 parts of epoxy resin, 7 parts of alkyd resin, stone
8 parts of black alkene, 6 parts of activating agent, 3 parts of coalescing agent, 0.2 part of defoaming agent, 4 parts of plasticizer, 1 part of anti-aging agent, is gone 2.5 parts of mica powder
15 parts of ionized water.
5. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that the activating agent is
Perfluoroalkoxy yl carboxylic acid.
6. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that coalescing agent is benzene
One of ethylene glycol, propandiol butyl ether, propylene glycol methyl ether acetate.
7. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that defoaming agent is tristearin
Barbiturates defoaming agent or organic silicon defoaming agent.
8. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that plasticizer is chlorination
One of paraffin, dioctyl terephthalate or No. 150 solvent naphthas are a variety of；Didecyl phthalate, phthalic acid
Two nonyl esters, glycol benzoate, diethyl sebacate, diisopropyl sebacate, dibutyl sebacate, in dioctyl sebacate
One or more of mixtures.
9. a kind of production method of Environmental-protecwaterproof waterproof paint according to claim 1, which is characterized in that anti-aging agent 1,2-
Dihydro -2,2, the homopolymer of 4- trimethylquinoline.
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