CN106987184A - It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof - Google Patents

It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof Download PDF

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CN106987184A
CN106987184A CN201710350990.5A CN201710350990A CN106987184A CN 106987184 A CN106987184 A CN 106987184A CN 201710350990 A CN201710350990 A CN 201710350990A CN 106987184 A CN106987184 A CN 106987184A
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building coating
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waterproof
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聂超
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    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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    • C08L2205/00Polymer mixtures characterised by other features
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Abstract

The invention discloses one kind it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, include the component of following mass parts:15 25 parts of polyvinyl alcohol, poly- 15 25 parts of acrylic emulsion, 10 20 parts of Ludox, 10 20 parts of polyamide, 10 20 parts of quick lime, 10 20 parts of castor oil, 10 20 parts of potassium oxide, 10 20 parts of zinc oxide, 5 15 parts of alundum (Al2O3), 5 15 parts of polyvinyl acetate, 5 15 parts of methyl methacrylate, 10 20 parts of phenolic resin, 5 15 parts of powdered whiting, 5 15 parts of bentonite, 15 25 parts of nano silicon, 15 25 parts of two fluororesin of segregation, 15 25 parts of acrylic resin, 10 20 parts of butyl, 10 20 parts of dimethylbenzene, 5 15 parts of saturation hydroxyl telechelic polyester resin, 35 parts of defoamer, 35 parts of plasticizer, 35 parts of dispersant, 35 parts of quick dry agent, 35 parts of coalescents, 35 parts of additive, 25 45 parts of deionized water.The features such as present invention improves waterproof effect, can on the basal plane of various material that is moist or drying construction waterproof it is functional, it is nontoxic, meet actual operation requirements.

Description

It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof
Technical field
The present invention relates to one kind it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, belong to coating and prepare work Skill technical field.
Background technology
Building coating as a class be used for house decoration coating products, some buildings to mould proof, fire prevention, insulation, Corrosion-resistant etc. to have particular/special requirement, some buildings have particular/special requirement to waterproof, antifreeze, cracking resistance, have to being decorated with particular/special requirement.Occupy Firmly property improves function mainly for indoor application, just contributes to improve the function of living environment, such as sound-proofing, sound-absorbing Property, anti-condensation etc..Being applied to body surface can form with protection decoration or property(Such as insulation, anti-corrosion, mark)'s A class I liquid I or the general name of solid material for solid coated film.Coating type is various, purposes is extremely wide, in national economy and people's lives In play an important role, year is the important indicator of a national living standard using coating content per capita.And with humanity concept Popularization, and new harmonious society composition, design a kind of covering power height, fast drying, water resistance, cracking resistance and resistance to wiping excellent Water resistance anti-crack building coating is very important.
At present, this coating of the prior art has larger harm to human body and environment, and easily causes aging, does The phenomenon such as split, deform, fractureing, being layered, for complex-shaped place, constructional difficulties, and to Seepage, quality is difficult to protect Card, every few years are it is necessary to spending substantial contribution and labour to be reprocessed so that cost is constantly soaring, and have impact on building The service life of thing.
The content of the invention
The present invention exactly in view of the deficienciess of the prior art, provide it is a kind of it is freeze proof split, waterproof, weather resistant building coating and Its preparation method, the building coating bonding force is strong, cracking resistance, and improves waterproof effect, can be in a variety of materials that are moist or drying Construction waterproof is functional on the basal plane of matter, nontoxic, and service life is long;And hard DEG C after coating film forming, it is water resistance, alkaline-resisting Property, rotproofness, weatherability and scrubbing resistance number of times performance indications are all improved, and meet actual operation requirements.
To solve the above problems, the technical solution used in the present invention is as follows:
It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, the building coating includes the group of following mass parts Point:15-25 parts of polyvinyl alcohol, poly- acrylic emulsion 15-25 parts, 10-20 parts of Ludox, 10-20 parts of polyamide, 10-20 parts of quick lime, 10-20 parts of castor oil, 10-20 parts of potassium oxide, 10-20 parts of zinc oxide, 5-15 parts of alundum (Al2O3), 5-15 parts of polyvinyl acetate, 5-15 parts of methyl methacrylate, 10-20 parts of phenolic resin, 5-15 parts of powdered whiting, 5-15 parts of bentonite, nanometer titanium dioxide 15-25 parts of silicon, 15-25 parts of two fluororesin of segregation, 15-25 parts of acrylic resin, 10-20 parts of butyl, dimethylbenzene 10- 20 parts, 5-15 parts of saturation hydroxyl telechelic polyester resin, 3-5 parts of defoamer, 3-5 parts of plasticizer, 3-5 parts of dispersant, quick dry agent 3-5 Part, 3-5 parts of coalescents, 3-5 parts of additive, 25-45 parts of deionized water.
As the improvement of above-mentioned technical proposal, the defoamer is any one in dimethicone, octanol or organosilicon Plant or several combinations;The plasticizer is dibutyl phthalate;The dispersant is neopelex;It is described fast Dry agent is propane diols;The coalescents are alcohol ester 12.
Specifically, it is described it is a kind of it is freeze proof split, waterproof, the preparation method of weather resistant building coating it is as follows:
Step(1):Polyvinyl alcohol, poly- acrylic emulsion, Ludox, polyamide, quick lime, castor oil, oxidation are taken according to material rate Potassium, zinc oxide, alundum (Al2O3), polyvinyl acetate, methyl methacrylate, phenolic resin, powdered whiting, bentonite are mixed It is sufficiently mixed in material machine, uniform compound A is made in crushing;
Step(2):According to material rate take nano silicon, the fluororesin of segregation two, acrylic resin, butyl, Dimethylbenzene, saturation hydroxyl telechelic polyester resin carry out being sufficiently mixed uniform, obtained compound B in batch mixer;
Step(3):To step(1)Obtained compound A and step(2)Obtained mixed material B carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(1)The compound A and step obtained(2)Obtained mixed material B is sufficiently mixed, so Insert on the bottom electrode medium of plasma device, voltage 22kV, irradiated under electric current 1.6mA, gap 2.4mm operating condition afterwards 16-32 seconds, then place 16-24 hours;
Step(4):The deionized water to be produced building coating weight 40-60% is added in foam material pond, then is passed through steam heating 12-16 hours, 55-75 DEG C of water temperature is controlled, by above-mentioned steps(3)Compound add, be uniformly mixing to obtain mixed liquor A;
Step(5):Cancel infusion, plasticizer, dispersant, quick dry agent, coalescents mixing, plus remaining weight according to raw material proportioning Deionized water, it is uniform in stirrer for mixing, uniform mixed liquid B is made;
Step(6):Mixed liquor A and mixed liquid B are well mixed, steam is passed through heating, liquid temperature DEG C is reached 80-90 DEG C, Add additive, must not have suspended impurity, reach it is transparent untill;
Step(7):To step(6)Gained mixture is press-formed, and the pressure of pressurization is 20MPa-30MPa, and pressing time is 6-8 Hour, 8-16 hours are stood after cooling, building coating is produced.
Compared with prior art, implementation result of the invention is as follows by the present invention:
The present invention provide it is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, the building coating passes through to dispensing PROCESS FOR TREATMENT so that dispensing has the characteristics of selective penetrated property is high, so that the coating prepared has, bonding force is strong, anti-open The features such as splitting, and improve waterproof effect, can on the basal plane of various material that is moist or drying construction waterproof it is functional, nothing Poison is harmless, and service life is long;And hard DEG C after coating film forming, water resistance, alkali resistance, rotproofness, weatherability and scrubbing resistance number of times Performance indications are all improved, and meet actual operation requirements.
Embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
Embodiment 1
It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, the building coating includes the group of following mass parts Point:15 parts of polyvinyl alcohol, 15 parts of poly- acrylic emulsion, 10 parts of Ludox, 10 parts of polyamide, 10 parts of quick lime, 10 parts of castor oil, oxidation 10 parts of potassium, 10 parts of zinc oxide, 5 parts of alundum (Al2O3), 5 parts of polyvinyl acetate, 5 parts of methyl methacrylate, 10 parts of phenolic resin, 5 parts of powdered whiting, 5 parts of bentonite, 15 parts of nano silicon, 15 parts of two fluororesin of segregation, 15 parts of acrylic resin, diethyl 10 parts of glycol butyl ether, 10 parts of dimethylbenzene, 5 parts of saturation hydroxyl telechelic polyester resin, 3 parts of defoamer, 3 parts of plasticizer, 3 parts of dispersant, 3 parts of quick dry agent, 3 parts of coalescents, 3 parts of additive, 25 parts of deionized water.
Specifically, the defoamer is any one or a few combination in dimethicone, octanol or organosilicon;It is described Plasticizer is dibutyl phthalate;The dispersant is neopelex;The quick dry agent is propane diols;It is described Coalescents are alcohol ester 12.
More specifically, it is described it is a kind of it is freeze proof split, waterproof, the preparation method of weather resistant building coating it is as follows:
Step(1):Polyvinyl alcohol, poly- acrylic emulsion, Ludox, polyamide, quick lime, castor oil, oxidation are taken according to material rate Potassium, zinc oxide, alundum (Al2O3), polyvinyl acetate, methyl methacrylate, phenolic resin, powdered whiting, bentonite are mixed It is sufficiently mixed in material machine, uniform compound A is made in crushing;
Step(2):According to material rate take nano silicon, the fluororesin of segregation two, acrylic resin, butyl, Dimethylbenzene, saturation hydroxyl telechelic polyester resin carry out being sufficiently mixed uniform, obtained compound B in batch mixer;
Step(3):To step(1)Obtained compound A and step(2)Obtained mixed material B carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(1)The compound A and step obtained(2)Obtained mixed material B is sufficiently mixed, so Insert on the bottom electrode medium of plasma device, voltage 22kV, irradiated under electric current 1.6mA, gap 2.4mm operating condition afterwards 16 seconds, then place 16 hours;
Step(4):The deionized water to be produced building coating weight 40% is added in foam material pond, then is passed through steam heating 12 Hour, 55 DEG C of water temperature is controlled, by above-mentioned steps(3)Compound add, be uniformly mixing to obtain mixed liquor A;
Step(5):Cancel infusion, plasticizer, dispersant, quick dry agent, coalescents mixing, plus remaining weight according to raw material proportioning Deionized water, it is uniform in stirrer for mixing, uniform mixed liquid B is made;
Step(6):Mixed liquor A and mixed liquid B are well mixed, steam is passed through heating, liquid temperature DEG C is reached 80 DEG C, addition Additive, must not there is suspended impurity, reach it is transparent untill;
Step(7):To step(6)Gained mixture is press-formed, and the pressure of pressurization is 20MPa, and pressing time is 6 hours, cold But 8 hours are stood afterwards, produces building coating.
The present invention passes through the PROCESS FOR TREATMENT to dispensing so that dispensing has the characteristics of selective penetrated property is high, so that system Standby coating has that bonding force is strong, cracking resistance, and the features such as improve waterproof effect, can be in various material that is moist or drying Construction waterproof is functional on basal plane, nontoxic, and service life is long.
Note:Hard DEG C after coating film forming of the present invention, water resistance, alkali resistance, rotproofness, weatherability and scrubbing resistance number of times Energy index is all improved, and meets actual operation requirements.
Embodiment 2
It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, the building coating includes the group of following mass parts Point:20 parts of polyvinyl alcohol, 20 parts of poly- acrylic emulsion, 15 parts of Ludox, 15 parts of polyamide, 15 parts of quick lime, 15 parts of castor oil, oxidation 15 parts of potassium, 15 parts of zinc oxide, 10 parts of alundum (Al2O3), 10 parts of polyvinyl acetate, 10 parts of methyl methacrylate, phenolic resin 15 Part, 10 parts of powdered whiting, 10 parts of bentonite, 20 parts of nano silicon, 20 parts of two fluororesin of segregation, acrylic resin 20 Part, 15 parts of butyl, 15 parts of dimethylbenzene, 10 parts of saturation hydroxyl telechelic polyester resin, 4 parts of defoamer, plasticizer 4 part, point 4 parts of powder, 4 parts of quick dry agent, 4 parts of coalescents, 4 parts of additive, 35 parts of deionized water.
Specifically, the defoamer is any one or a few combination in dimethicone, octanol or organosilicon;It is described Plasticizer is dibutyl phthalate;The dispersant is neopelex;The quick dry agent is propane diols;It is described Coalescents are alcohol ester 12.
More specifically, it is described it is a kind of it is freeze proof split, waterproof, the preparation method of weather resistant building coating it is as follows:
Step(1):Polyvinyl alcohol, poly- acrylic emulsion, Ludox, polyamide, quick lime, castor oil, oxidation are taken according to material rate Potassium, zinc oxide, alundum (Al2O3), polyvinyl acetate, methyl methacrylate, phenolic resin, powdered whiting, bentonite are mixed It is sufficiently mixed in material machine, uniform compound A is made in crushing;
Step(2):According to material rate take nano silicon, the fluororesin of segregation two, acrylic resin, butyl, Dimethylbenzene, saturation hydroxyl telechelic polyester resin carry out being sufficiently mixed uniform, obtained compound B in batch mixer;
Step(3):To step(1)Obtained compound A and step(2)Obtained mixed material B carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(1)The compound A and step obtained(2)Obtained mixed material B is sufficiently mixed, so Insert on the bottom electrode medium of plasma device, voltage 22kV, irradiated under electric current 1.6mA, gap 2.4mm operating condition afterwards 24 seconds, then place 20 hours;
Step(4):The deionized water to be produced building coating weight 50% is added in foam material pond, then is passed through steam heating 14 Hour, 65 DEG C of water temperature is controlled, by above-mentioned steps(3)Compound add, be uniformly mixing to obtain mixed liquor A;
Step(5):Cancel infusion, plasticizer, dispersant, quick dry agent, coalescents mixing, plus remaining weight according to raw material proportioning Deionized water, it is uniform in stirrer for mixing, uniform mixed liquid B is made;
Step(6):Mixed liquor A and mixed liquid B are well mixed, steam is passed through heating, liquid temperature DEG C is reached 85 DEG C, addition Additive, must not there is suspended impurity, reach it is transparent untill;
Step(7):To step(6)Gained mixture is press-formed, and the pressure of pressurization is 25MPa, and pressing time is 7 hours, cold But 12 DEG C of hours are stood afterwards, produces building coating.
The present invention passes through the PROCESS FOR TREATMENT to dispensing so that dispensing has the characteristics of selective penetrated property is high, so that system Standby coating has that bonding force is strong, cracking resistance, and the features such as improve waterproof effect, can be in various material that is moist or drying Construction waterproof is functional on basal plane, nontoxic, and service life is long.
Note:Hard DEG C after coating film forming of the present invention, water resistance, alkali resistance, rotproofness, weatherability and scrubbing resistance number of times Energy index is all improved, and meets actual operation requirements.
Embodiment 3
It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, the building coating includes the group of following mass parts Point:25 parts of polyvinyl alcohol, 25 parts of poly- acrylic emulsion, 20 parts of Ludox, 20 parts of polyamide, 20 parts of quick lime, 20 parts of castor oil, oxidation 20 parts of potassium, 20 parts of zinc oxide, 15 parts of alundum (Al2O3), 15 parts of polyvinyl acetate, 15 parts of methyl methacrylate, phenolic resin 20 Part, 15 parts of powdered whiting, 15 parts of bentonite, 25 parts of nano silicon, 25 parts of two fluororesin of segregation, acrylic resin 25 Part, 20 parts of butyl, 20 parts of dimethylbenzene, 15 parts of saturation hydroxyl telechelic polyester resin, 5 parts of defoamer, plasticizer 5 part, point 5 parts of powder, 5 parts of quick dry agent, 5 parts of coalescents, 5 parts of additive, 45 parts of deionized water.
Specifically, the defoamer is any one or a few combination in dimethicone, octanol or organosilicon;It is described Plasticizer is dibutyl phthalate;The dispersant is neopelex;The quick dry agent is propane diols;It is described Coalescents are alcohol ester 12.
More specifically, it is described it is a kind of it is freeze proof split, waterproof, the preparation method of weather resistant building coating it is as follows:
Step(1):Polyvinyl alcohol, poly- acrylic emulsion, Ludox, polyamide, quick lime, castor oil, oxidation are taken according to material rate Potassium, zinc oxide, alundum (Al2O3), polyvinyl acetate, methyl methacrylate, phenolic resin, powdered whiting, bentonite are mixed It is sufficiently mixed in material machine, uniform compound A is made in crushing;
Step(2):According to material rate take nano silicon, the fluororesin of segregation two, acrylic resin, butyl, Dimethylbenzene, saturation hydroxyl telechelic polyester resin carry out being sufficiently mixed uniform, obtained compound B in batch mixer;
Step(3):To step(1)Obtained compound A and step(2)Obtained mixed material B carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(1)The compound A and step obtained(2)Obtained mixed material B is sufficiently mixed, so Insert on the bottom electrode medium of plasma device, voltage 22kV, irradiated under electric current 1.6mA, gap 2.4mm operating condition afterwards 32 seconds, then place 24 hours;
Step(4):The deionized water to be produced building coating weight 60% is added in foam material pond, then is passed through steam heating 16 Hour, 75 DEG C of water temperature is controlled, by above-mentioned steps(3)Compound add, be uniformly mixing to obtain mixed liquor A;
Step(5):Cancel infusion, plasticizer, dispersant, quick dry agent, coalescents mixing, plus remaining weight according to raw material proportioning Deionized water, it is uniform in stirrer for mixing, uniform mixed liquid B is made;
Step(6):Mixed liquor A and mixed liquid B are well mixed, steam is passed through heating, liquid temperature DEG C is reached 90 DEG C, addition Additive, must not there is suspended impurity, reach it is transparent untill;
Step(7):To step(6)Gained mixture is press-formed, and the pressure of pressurization is 30MPa, and pressing time is 8 hours, cold But 16 hours are stood afterwards, produces building coating.
The present invention passes through the PROCESS FOR TREATMENT to dispensing so that dispensing has the characteristics of selective penetrated property is high, so that system Standby coating has that bonding force is strong, cracking resistance, and the features such as improve waterproof effect, can be in various material that is moist or drying Construction waterproof is functional on basal plane, nontoxic, and service life is long.
Note:Hard DEG C after coating film forming of the present invention, water resistance, alkali resistance, rotproofness, weatherability and scrubbing resistance number of times Energy index is all improved, and meets actual operation requirements.
Above content is made for the present invention in conjunction with specific embodiments describes in detail, it is impossible to assert that the present invention is specific real Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from Put, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.

Claims (3)

1. it is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, it is characterised in that:The building coating includes The component of following mass parts:15-25 parts of polyvinyl alcohol, poly- acrylic emulsion 15-25 parts, 10-20 parts of Ludox, 10-20 parts of polyamide, 10-20 parts of quick lime, 10-20 parts of castor oil, 10-20 parts of potassium oxide, 10-20 parts of zinc oxide, 5-15 parts of alundum (Al2O3), poly-vinegar Sour ethene 5-15 parts, 5-15 parts of methyl methacrylate, 10-20 parts of phenolic resin, 5-15 parts of powdered whiting, bentonite 5-15 Part, 15-25 parts of nano silicon, 15-25 parts of two fluororesin of segregation, 15-25 parts of acrylic resin, butyl 10- 20 parts, 10-20 parts of dimethylbenzene, 5-15 parts of saturation hydroxyl telechelic polyester resin, 3-5 parts of defoamer, 3-5 parts of plasticizer, dispersant 3-5 Part, 3-5 parts of quick dry agent, 3-5 parts of coalescents, 3-5 parts of additive, 25-45 parts of deionized water.
2. according to claim 1 it is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof, it is characterised in that: The defoamer is any one or a few combination in dimethicone, octanol or organosilicon;The plasticizer is adjacent benzene two Formic acid dibutyl ester;The dispersant is neopelex;The quick dry agent is propane diols;The coalescents are alcohol ester 12.
3. according to claim 1-2 it is a kind of it is freeze proof split, waterproof, the preparation method of weather resistant building coating, it is characterised in that: The preparation method is as follows:
Step(1):Polyvinyl alcohol, poly- acrylic emulsion, Ludox, polyamide, quick lime, castor oil, oxidation are taken according to material rate Potassium, zinc oxide, alundum (Al2O3), polyvinyl acetate, methyl methacrylate, phenolic resin, powdered whiting, bentonite are mixed It is sufficiently mixed in material machine, uniform compound A is made in crushing;
Step(2):According to material rate take nano silicon, the fluororesin of segregation two, acrylic resin, butyl, Dimethylbenzene, saturation hydroxyl telechelic polyester resin carry out being sufficiently mixed uniform, obtained compound B in batch mixer;
Step(3):To step(1)Obtained compound A and step(2)Obtained mixed material B carries out plasma-induced;
Wherein, it is described plasma-induced to be:By step(1)The compound A and step obtained(2)Obtained mixed material B is sufficiently mixed, so Insert on the bottom electrode medium of plasma device, voltage 22kV, irradiated under electric current 1.6mA, gap 2.4mm operating condition afterwards 16-32 seconds, then place 16-24 hours;
Step(4):The deionized water to be produced building coating weight 40-60% is added in foam material pond, then is passed through steam heating 12-16 hours, 55-75 DEG C of water temperature is controlled, by above-mentioned steps(3)Compound add, be uniformly mixing to obtain mixed liquor A;
Step(5):Cancel infusion, plasticizer, dispersant, quick dry agent, coalescents mixing, plus remaining weight according to raw material proportioning Deionized water, it is uniform in stirrer for mixing, uniform mixed liquid B is made;
Step(6):Mixed liquor A and mixed liquid B are well mixed, steam is passed through heating, liquid temperature DEG C is reached 80-90 DEG C, Add additive, must not have suspended impurity, reach it is transparent untill;
Step(7):To step(6)Gained mixture is press-formed, and the pressure of pressurization is 20MPa-30MPa, and pressing time is 6-8 Hour, 8-16 hours are stood after cooling, building coating is produced.
CN201710350990.5A 2017-05-18 2017-05-18 It is a kind of it is freeze proof split, waterproof, weather resistant building coating and preparation method thereof Pending CN106987184A (en)

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CN115926543A (en) * 2022-12-21 2023-04-07 华润水泥技术研发有限公司 Multifunctional waterproof coating and preparation and construction methods thereof

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Application publication date: 20170728