CN107026120B - 一种阵列基板的制作方法 - Google Patents
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- 229910052751 metal Inorganic materials 0.000 claims abstract description 151
- 239000002184 metal Substances 0.000 claims abstract description 151
- 239000000126 substance Substances 0.000 claims abstract description 36
- 150000001768 cations Chemical class 0.000 claims abstract description 20
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 19
- 238000001039 wet etching Methods 0.000 claims abstract description 8
- 239000004065 semiconductor Substances 0.000 claims abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 239000011733 molybdenum Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- -1 molybdenum cation Chemical class 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 194
- 238000005260 corrosion Methods 0.000 description 11
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- 239000004973 liquid crystal related substance Substances 0.000 description 10
- 239000004020 conductor Substances 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
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- 239000002738 chelating agent Substances 0.000 description 2
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- 101100373011 Drosophila melanogaster wapl gene Proteins 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- JUZTWRXHHZRLED-UHFFFAOYSA-N [Si].[Cu].[Cu].[Cu].[Cu].[Cu] Chemical compound [Si].[Cu].[Cu].[Cu].[Cu].[Cu] JUZTWRXHHZRLED-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
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- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 1
- 229910021360 copper silicide Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
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Abstract
本发明提供一种阵列基板的制作方法,其包括:在衬底基板上依次形成第一金属层、栅极层、栅极绝缘层、半导体层、第二金属层,及在第二金属层上形成源极层与漏极层;其中,在第一金属层上形成栅极层,包括:在第一金属层上沉积栅极金属层;在栅极金属层上涂布光阻层,对栅极金属层进行曝光显影,并对栅极金属层进行湿蚀刻;使用第一剥离液去除栅极金属层上的光阻层,以形成栅极层;其中,第一剥离液中添加有化学腐蚀电位小于或等于第一金属层的化学腐蚀电位的第一金属阳离子。本发明解决了现有技术中,在使用剥离液对光阻进行剥夺的时候,会在栅极层和第一金属层接触的边缘发生掏空现象,形成裂缝,进而导致源极层、漏极层与栅极层短路的问题。
Description
【技术领域】
本发明涉及液晶显示领域,特别涉及一种阵列基板的制作方法。
【背景技术】
液晶显示装置(LCD,Liquid Crystal Display)具有机身薄、省电、无辐射等众多优点,得到了广泛的应用。通常液晶显示面板包括CF(Color Filter)基板、TFT(Thin FilmTransistor)阵列基板、及设于CF基板与TFT阵列基板之间的液晶(Liquid Crystal)。通过给TFT阵列基板供电与否来控制液晶分子改变方向,将背光模组的光线投射到CF基板产生画面。TFT阵列基板的性能特征和运行特性部分很大程度上取决于形成TFT阵列基板各元件的材料。在TFT阵列基板上布有金属导线,TFT阵列基板中的金属导线是将物理气相沉积在TFT阵列基板上的金属层通过蚀刻工艺制成,该蚀刻工艺可分为干式蚀刻和湿式蚀刻。
常规应用于TFT阵列基板中的金属导线为铝导线。随着电视等液晶显示终端的大尺寸化、高解析度以及驱动频率高速化的发展趋势及要求,液晶显示领域技术人员不得不面对TFT阵列基板中电阻及所造成的电阻/电容时间延迟问题。而铝导线具有较高的电阻率使得TFT阵列基板的像素电极层不能够充分充电,随着高频寻址(大于120Hz)液晶显示的广泛应用,这一现象更加明显。铜导线相对于铝导线具有较低的电阻率及良好的抗电迁移能力,因而被应用到TFT阵列基板上来解决上述铝导线产生的问题。
铜与玻璃具有差的粘附性,需要用下层金属层进行过渡,并且铜在200℃以下通过互扩散易与硅反应生成具有硅化铜(CuSi3)化合物,即铜会和TFT的半导体层产生反应,产生很高的接触电阻,因此也需要采用其它下层金属层进行过渡。目前较为常用的是采用难熔金属作为过渡的粘结层和阻挡层,例如钼(Mo),钛(Ti)以及相应元素的合金等。但是不同的阻挡层金属及合金在蚀刻后形成的外型不同,在对光阻进行剥夺的时候,会在铜和钼接触的边缘发生掏空现象,形成裂缝。此种掏空的现象会导致源、漏电极与栅电极的短路,显著的影响显示终端的良率。
图4为现有技术的一种阵列基板的制作方法中,栅极绝缘层15覆盖在栅极层13和第一金属层12上的整体结构的剖面示意图,从图4中可以看到,现有技术的衬底基板11上的栅极层13和第一金属层12的接触边缘存在裂缝14。
【发明内容】
本发明的目的在于提供一种阵列基板的制作方法,以解决现有技术中,在使用剥离液对光阻进行剥夺的时候,会在栅极层和第一金属层接触的边缘发生掏空现象,形成裂缝,进而导致源极层、漏极层与栅极层短路的问题。
本发明的技术方案如下:
一种阵列基板的制作方法,其包括:
在衬底基板上依次形成第一金属层、栅极层、栅极绝缘层、半导体层、第二金属层,及在所述第二金属层上形成源极层与漏极层;
其中,在所述第一金属层上形成所述栅极层,包括:
在所述第一金属层上沉积制作所述栅极层的栅极金属层;
在所述栅极金属层上涂布光阻层,对所述栅极金属层进行曝光显影,并对所述栅极金属层进行湿蚀刻,直至漏出所述第一金属层为止;
使用第一剥离液去除所述栅极金属层上的所述光阻层,以形成所述栅极层;
其中,所述第一剥离液中添加有化学腐蚀电位小于或等于所述第一金属层的化学腐蚀电位的第一金属阳离子。
优选地,其中,在所述第二金属层上形成所述源极层与所述漏极层,包括:
在所述第二金属层上沉积制作所述源极层与所述漏极层的源漏极金属层;
在所述源漏极金属层上涂布光阻层,对所述源漏极金属层进行曝光显影,并对所述源漏极金属层进行湿蚀刻,直至漏出所述第二金属层为止;
使用第二剥离液去除所述源漏极金属层上的所述光阻层,以形成所述源极层与漏极层;
其中,所述第二剥离液中添加有化学腐蚀电位小于或等于所述第二金属层的化学腐蚀电位的第二金属阳离子。
优选地,形成所述源极层与所述漏极层后,还包括:
在所述源极层与所述漏极层上形成平坦层;
在所述漏极层上方对应的所述平坦层上形成过孔,所述过孔与所述漏极层相通;
在所述平坦层上形成像素电极层,所述像素电极层通过所述过孔与所述漏极层连接。
优选地,所述栅极层的化学腐蚀电位高于所述第一金属层的化学腐蚀电位,且所述源极层与所述漏极层的化学腐蚀电位高于所述第二金属层的化学腐蚀电位。
优选地,所述第一金属层的厚度小于所述栅极层的厚度,且所述第二金属层的厚度小于所述源极层与所述漏极层的厚度。
优选地,所述栅极绝缘层的厚度小于所述栅极层的厚度,且所述栅极绝缘层的厚度为所述所述栅极层的厚度的三分之一。
优选地,所述第一金属层与所述第二金属层的制作材料均为钼金属材料,或均为化学腐蚀电位低于钼金属的化学腐蚀电位的金属材料。
优选地,所述第一剥离液与所述第二剥离液由剥离设备提供,该剥离设备设有化学腐蚀电位小于或等于所述第一金属层和所述第二金属层的化学腐蚀电位的金属网格,所述金属网格用于通过所述第一金属阳离子或所述第二金属阳离子。
优选地,所述第一金属阳离子与所述第二金属阳离子均为钼金属阳离子。
优选地,所述栅极层、所述源极层与所述漏极层的制作材料为铜金属材料。
本发明的有益效果:
本发明公开了一种阵列基板的制作方法,解决了现有技术中,在使用剥离液对光阻进行剥夺的时候,会在栅极层和第一金属层接触的边缘发生掏空现象,形成裂缝,进而导致源极层、漏极层与栅极层短路的问题。
【附图说明】
图1为本发明实施例的一种阵列基板的制作方法中,在第一金属层上形成所述栅极层的实施步骤流程图;
图2为本发明实施例的一种阵列基板的制作方法中,在第二金属层上形成源极层与漏极层实施步骤流程图;
图3为发明实施例的一种阵列基板的制作方法中,阵列基板的整体结构的剖面示意图;
图4为现有技术的一种阵列基板的制作方法中,栅极绝缘层覆盖在栅极层和第一金属层上的整体结构的剖面示意图。
【具体实施方式】
以下各实施例的说明是参考附加的图式,用以例示本发明可用以实施的特定实施例。本发明所提到的方向用语,例如「上」、「下」、「前」、「后」、「左」、「右」、「内」、「外」、「侧面」等,仅是参考附加图式的方向。因此,使用的方向用语是用以说明及理解本发明,而非用以限制本发明。在图中,结构相似的单元是以相同标号表示。
实施例一
请参考图1至图3,图1为本实施例的一种阵列基板的制作方法中,在第一金属层2上形成所述栅极层3的实施步骤流程图。
图2为本实施例的一种阵列基板的制作方法中,在第二金属层6上形成源极层7与漏极层8实施步骤流程图。
图3为发明实施例的一种阵列基板的制作方法中,阵列基板的整体结构的剖面示意图。
本实施例的阵列基板的制作方法,包括以下步骤:
第一,在衬底基板1上形成第一金属层2,其中衬底基板1优选为玻璃基板。
第二,在所述第一金属层2上形成栅极层3。
第三,在所述栅极层3上形成栅极绝缘层4。
第四,在所述栅极绝缘层4上形成半导体层5。
第五,在所述半导体层5上形成第二金属层6。
第六,在所述第二金属层6上形成源极层7与漏极层8。
在本实施例中,如图1所示,其中在所述第一金属层2上形成所述栅极层3,包括:
步骤S101:在所述第一金属层2上沉积制作所述栅极层3的栅极金属层。
步骤S102:在所述栅极金属层上涂布光阻层,对所述栅极金属层进行曝光显影,并对所述栅极金属层进行湿蚀刻,直至漏出所述第一金属层2为止。
步骤S103:使用第一剥离液去除所述栅极金属层上的所述光阻层,以形成所述栅极层3。其中,所述第一剥离液中添加有化学腐蚀电位小于或等于所述第一金属层2的化学腐蚀电位的第一金属阳离子。其中,所述第一剥离液包括阴离子,所述阴离子为螯合剂。
在本实施例中,如图2所示,其中在所述第二金属层6上形成所述源极层7与所述漏极层8,包括:
步骤S201:在所述第二金属层6上沉积制作所述源极层7与所述漏极层8的源漏极金属层。
步骤S202:在所述源漏极金属层上涂布光阻层,对所述源漏极金属层进行曝光显影,并对所述源漏极金属层进行湿蚀刻,直至漏出所述第二金属层6为止。
步骤S203:使用第二剥离液去除所述源漏极金属层上的所述光阻层,以形成所述源极层7与漏极层8。其中,所述第二剥离液包括阴离子,所述阴离子为螯合剂。
其中,所述第二剥离液中添加有化学腐蚀电位小于或等于所述第二金属层6的化学腐蚀电位的第二金属阳离子。
在本实施例中,形成所述源极层7与所述漏极层8后,还包括:
在所述源极层7与所述漏极层8上形成平坦层9。
在所述漏极层8上方对应的所述平坦层9上形成过孔,所述过孔与所述漏极层8相通。
在所述平坦层9上形成像素电极层10,所述像素电极层10通过所述过孔与所述漏极层8连接。
在本实施例中,所述栅极层3的化学腐蚀电位高于所述第一金属层2的化学腐蚀电位,且所述源极层7与所述漏极层8的化学腐蚀电位高于所述第二金属层6的化学腐蚀电位。
在本实施例中,所述第一金属层2的厚度小于所述栅极层3的厚度,且所述第二金属层6的厚度小于所述源极层7与所述漏极层8的厚度。
在本实施例中,所述栅极绝缘层4的厚度小于所述栅极层3的厚度,且所述栅极绝缘层4的厚度为所述所述栅极层3的厚度的三分之一。
在本实施例中,所述第一金属层2与所述第二金属层6的制作材料均为钼金属材料,或均为化学腐蚀电位低于钼金属的化学腐蚀电位的金属材料。
在本实施例中,所述第一剥离液与所述第二剥离液由剥离设备提供,该剥离设备设有化学腐蚀电位小于或等于所述第一金属层2和所述第二金属层6的化学腐蚀电位的金属网格,所述金属网格用于通过所述第一金属阳离子或所述第二金属阳离子。本发明的金属网格保证了活性金属持续地添加到所述第一剥离液与所述第二剥离液中,有效地抑制了上述栅极金属层和源漏极金属层的化学腐蚀。
在本实施例中,所述第一金属阳离子与所述第二金属阳离子均为钼金属阳离子。
在本实施例中,所述栅极层3、所述源极层7与所述漏极层8的制作材料为铜金属材料。
本发明所依据的原理如下所述:
下表为铜金属、钼金属和铜钼混合金属在一定范围的浓度条件下的腐蚀测试结果的曲线表,即腐蚀塔菲尔曲线。
其中,横坐标表示外加在被腐蚀金属上的电位,外加电位提高,则腐蚀加剧,外加电位降低,则腐蚀减慢。纵坐标表示在某种电位下发生的电流的对数值。铜金属和钼金属在溶解中具有不同的腐蚀电位(由于铜/钼金属活泼程度不同),在接触到导电溶液的时候(如蚀刻液,蚀刻后的水洗液),电偶腐蚀开始。由上表可见,处于导电液体中的不同金属,化学腐蚀电位越低的金属越容易被腐蚀,也是最先被腐蚀的。
根据以上原理,在使用第一剥离液剥离栅极金属层上的光阻层时,第一金属阳离子可以有效地抑制第一金属层2不被化学腐蚀掉,以致造成裂缝进而造成阵列基板短路的问题。同样,在使用第二剥离液剥离源漏极金属层上的光阻层时,第二金属阳离子可以有效地抑制第二金属层6不被化学腐蚀掉,以致造成裂缝进而造成阵列基板短路的问题。
本发明公开了一种阵列基板的制作方法,解决了现有技术中,在使用剥离液对光阻进行剥夺的时候,会在栅极层3和第一金属层2接触的边缘发生掏空现象,形成裂缝,进而导致源极层7、漏极层8与栅极层3短路的问题。
综上所述,虽然本发明已以优选实施例揭露如上,但上述优选实施例并非用以限制本发明,本领域的普通技术人员,在不脱离本发明的精神和范围内,均可作各种更动与润饰,因此本发明的保护范围以权利要求界定的范围为准。
Claims (8)
1.一种阵列基板的制作方法,其特征在于,其包括:
在衬底基板上依次形成第一金属层、栅极层、栅极绝缘层、半导体层、第二金属层,及在所述第二金属层上形成源极层与漏极层;
其中,在所述第一金属层上形成所述栅极层,包括:
在所述第一金属层上沉积制作所述栅极层的栅极金属层;
在所述栅极金属层上涂布光阻层,对所述栅极金属层进行曝光显影,并对所述栅极金属层进行湿蚀刻,直至露 出所述第一金属层为止;
使用第一剥离液去除所述栅极金属层上的所述光阻层,以形成所述栅极层;
其中,所述第一剥离液中添加有化学腐蚀电位小于或等于所述第一金属层的化学腐蚀电位的第一金属阳离子;
在所述第二金属层上形成所述源极层与所述漏极层,包括:
在所述第二金属层上沉积制作所述源极层与所述漏极层的源漏极金属层;
在所述源漏极金属层上涂布光阻层,对所述源漏极金属层进行曝光显影,并对所述源漏极金属层进行湿蚀刻,直至露 出所述第二金属层为止;
使用第二剥离液去除所述源漏极金属层上的所述光阻层,以形成所述源极层与漏极层;
其中,所述第二剥离液中添加有化学腐蚀电位小于或等于所述第二金属层的化学腐蚀电位的第二金属阳离子;
所述第一剥离液与所述第二剥离液由剥离设备提供,该剥离设备设有化学腐蚀电位小于或等于所述第一金属层和所述第二金属层的化学腐蚀电位的金属网格,所述金属网格用于通过所述第一金属阳离子或所述第二金属阳离子。
2.根据权利要求1所述的制作方法,其特征在于,形成所述源极层与所述漏极层后,还包括:
在所述源极层与所述漏极层上形成平坦层;
在所述漏极层上方对应的所述平坦层上形成过孔,所述过孔与所述漏极层相通;
在所述平坦层上形成像素电极层,所述像素电极层通过所述过孔与所述漏极层连接。
3.根据权利要求1所述的制作方法,其特征在于,所述栅极层的化学腐蚀电位高于所述第一金属层的化学腐蚀电位,且所述源极层与所述漏极层的化学腐蚀电位高于所述第二金属层的化学腐蚀电位。
4.根据权利要求1所述的制作方法,其特征在于,所述第一金属层的厚度小于所述栅极层的厚度,且所述第二金属层的厚度小于所述源极层与所述漏极层的厚度。
5.根据权利要求1所述的制作方法,其特征在于,所述栅极绝缘层的厚度小于所述栅极层的厚度,且所述栅极绝缘层的厚度为所述栅极层的厚度的三分之一。
6.根据权利要求1所述的制作方法,其特征在于,所述第一金属层与所述第二金属层的制作材料均为钼金属材料,或均为化学腐蚀电位低于钼金属的化学腐蚀电位的金属材料。
7.根据权利要求1所述的制作方法,其特征在于,所述第一金属阳离子与所述第二金属阳离子均为钼金属阳离子。
8.根据权利要求1所述的制作方法,其特征在于,所述栅极层、所述源极层与所述漏极层的制作材料为铜金属材料。
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