CN107001594B - 环氧树脂组合物、预浸料坯、纤维增强塑料材料及纤维增强塑料材料的制造方法 - Google Patents

环氧树脂组合物、预浸料坯、纤维增强塑料材料及纤维增强塑料材料的制造方法 Download PDF

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CN107001594B
CN107001594B CN201580065618.9A CN201580065618A CN107001594B CN 107001594 B CN107001594 B CN 107001594B CN 201580065618 A CN201580065618 A CN 201580065618A CN 107001594 B CN107001594 B CN 107001594B
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epoxy resin
acid
composition
type epoxy
composition epoxy
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Expired - Fee Related
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CN107001594A (zh
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J·休斯
藤原隆行
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Toray Industries Inc
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Toray Industries Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4223—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073—Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C08J2363/02—Polyglycidyl ethers of bis-phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201580065618.9A 2014-12-02 2015-12-01 环氧树脂组合物、预浸料坯、纤维增强塑料材料及纤维增强塑料材料的制造方法 Expired - Fee Related CN107001594B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462086428P 2014-12-02 2014-12-02
US62/086,428 2014-12-02
US201562248012P 2015-10-29 2015-10-29
US62/248,012 2015-10-29
PCT/IB2015/002421 WO2016087935A1 (en) 2014-12-02 2015-12-01 Epoxy resin composition, prepreg, fiber-reinforced plastic material, and manufacturing method for fiber-reinforced plastic material

Publications (2)

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CN107001594A CN107001594A (zh) 2017-08-01
CN107001594B true CN107001594B (zh) 2019-07-23

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Country Status (6)

Country Link
US (1) US20170362376A1 (enExample)
EP (1) EP3230339B1 (enExample)
JP (1) JP6658747B2 (enExample)
KR (1) KR20170091639A (enExample)
CN (1) CN107001594B (enExample)
WO (1) WO2016087935A1 (enExample)

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GB201514516D0 (en) * 2015-08-14 2015-09-30 Cytec Ind Inc Fast-cure pre-preg
GB201515715D0 (en) * 2015-09-04 2015-10-21 Gurit Uk Ltd Prepregs and production of composite material using prepregs
WO2017126307A1 (ja) * 2016-01-19 2017-07-27 三菱ケミカル株式会社 エポキシ樹脂組成物、繊維強化複合材料用プリプレグおよび繊維強化複合材料
EP3475348B1 (en) * 2016-06-27 2021-03-24 Dow Global Technologies LLC Storage stable epoxy prepregs from dicyandiamide solutions and methods for making the same
KR102428285B1 (ko) * 2016-09-13 2022-08-08 주식회사 테크위드 자전거 림을 위한 고온 수지 조성물 및 이를 이용한 자전거 림
FR3071789B1 (fr) * 2017-10-04 2020-07-17 Valeo Systemes Thermiques Boitier de support pour batterie
CN111278886B (zh) * 2017-11-16 2023-02-17 三菱化学株式会社 热固性树脂组合物、预浸料、纤维增强复合材料及其制造方法
GB2569614B (en) * 2017-12-21 2022-04-06 Hexcel Composites Ltd A curative composition and a resin composition containing the curative composition
TR201722994A2 (tr) * 2017-12-29 2019-07-22 Kordsa Teknik Tekstil As Bi̇r sicak eri̇yi̇k epoksi̇ reçi̇ne si̇stemi̇ ve yapimi i̇çi̇n proses
JP7209470B2 (ja) * 2018-03-13 2023-01-20 帝人株式会社 プリプレグ及び炭素繊維強化複合材料
CN108410134B (zh) * 2018-03-29 2021-04-20 苏州银禧新能源复合材料有限公司 一种纤维复合材料用环氧树脂组合物及其应用
GB2576875B (en) * 2018-08-30 2022-08-31 Hexcel Composites Ltd Improvements in or relating to curing agents
JP7178850B2 (ja) * 2018-09-28 2022-11-28 日鉄ケミカル＆マテリアル株式会社 繊維強化複合材料用エポキシ樹脂組成物、繊維強化複合材料及び成形体
GB2580087B (en) * 2018-12-20 2022-09-07 Hexcel Composites Ltd Improved thermocurable moulding process
CN113474393B (zh) * 2019-02-26 2024-01-16 富士胶片株式会社 内窥镜用粘接剂及其固化物、以及内窥镜及其制造方法
GB201905741D0 (en) 2019-04-24 2019-06-05 Hexcel Composites Ltd Improvements in or relating to curatives
GB201911998D0 (en) 2019-08-21 2019-10-02 Hexcel Composites Ltd Improved thermocurable moulding process
CN111138636A (zh) * 2019-12-31 2020-05-12 浙江华正新材料股份有限公司 一种树脂组合物、预浸料及层压板
JPWO2023053834A1 (enExample) * 2021-09-29 2023-04-06
KR102789355B1 (ko) * 2023-01-10 2025-04-03 한국화학연구원 디카르복실산을 이용하여 제조된 고유연성 경화제를 포함하는 에폭시 수지 조성물 및 이의 경화물

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JP2010195998A (ja) * 2009-02-27 2010-09-09 Panasonic Electric Works Co Ltd 半導体封止用エポキシ樹脂組成物、及び半導体装置
WO2014107725A1 (en) * 2013-01-07 2014-07-10 Toray Industries, Inc. Epoxy resin composition, prepreg, fiber reinforced plastic material, and manufacturing method for fiber reinforced plastic material

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US20170362376A1 (en) 2017-12-21
KR20170091639A (ko) 2017-08-09
EP3230339A1 (en) 2017-10-18
EP3230339A4 (en) 2018-06-27
WO2016087935A1 (en) 2016-06-09
JP2017536441A (ja) 2017-12-07
CN107001594A (zh) 2017-08-01
JP6658747B2 (ja) 2020-03-04
EP3230339B1 (en) 2022-03-23

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