CN106962375B - Radix pseudostellariae kind root inorganic agent and its application - Google Patents

Radix pseudostellariae kind root inorganic agent and its application Download PDF

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CN106962375B
CN106962375B CN201710188456.9A CN201710188456A CN106962375B CN 106962375 B CN106962375 B CN 106962375B CN 201710188456 A CN201710188456 A CN 201710188456A CN 106962375 B CN106962375 B CN 106962375B
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radix pseudostellariae
root
inorganic agent
gram
bravo
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CN106962375A (en
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王华磊
赵致
刘红昌
罗春丽
李金玲
罗夫来
黄明进
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Guizhou University
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Guizhou University
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Abstract

The present invention provides a kind of radix pseudostellariae kind root inorganic agent and its application.Its constituent includes: paclobutrazol 0.0001%~0.1% by weight percentage;6-benzyl aminopurine 0.0001%~0.1%;Bravo 0.1%~1%;Fenvalerate 0.1%~1%;Remaining is water.Not handle kind of a root before solving the sowing of current radix pseudostellariae, cause the kind root infection for carrying germ without strain root, and subterranean stem is easy excessive growth, seriously affect the emergence of radix pseudostellariae, the problem of growth and yield.The invention belongs to radix pseudostellariae field of planting.

Description

Radix pseudostellariae kind root inorganic agent and its application
Technical field
The present invention relates to a kind of radix pseudostellariae kind root inorganic agents, relate in particular to a kind of raw for adjusting radix pseudostellariae kind root It is long, improve the inorganic agent of radix pseudostellariae yield.
Background technique
The former plant of radix pseudostellariae is pinkwort caryophyllaceous ginseng Pseudostellaria heterophylla (Miq.) Pax Ex Pax et Hoffm., alias: caryophyllaceous ginseng, Tong Can, lance asiabell root, rice ginseng etc..It is used as medicine with dried root, " Chinese Pharmacopoeia " goes through version It gives and recording;" Chinese Pharmacopoeia " 2015 version one title: radix pseudostellariae is sweet in flavor, slight bitter, mild-natured;Returns spleen, lung channel.It is strong with QI invigorating Spleen, promoting production of body fluid and nourishing the lung function.Tired, the loss of appetite for spleen deficiency body, sick eak after being ill, deficiency of both vital energy and Yin, spontaneous perspiration and thirst, dryness of the lung dry cough. It is distributed mainly on China Heilungkiang, Jilin, Liaoning, the Inner Mongol, Hebei, Shaanxi, Shandong, Tibet, Henan, Hubei, Hunan, river The provinces and regions such as Soviet Union, Anhui, Zhejiang, Jiangxi, Fujian, Sichuan;It is born in the dark and damp place of mountain valley hayashishita of 800~2700m of height above sea level.Crown prince participates in Introduce a fine variety the 1990s to Shibing, by development in more than 20 years, have developed to based on the southeast of Guizhou Province, radiation in the south of Guizhou Province, Zun Yi, The ground such as Tongren, Anshun, Kweiyang.Such as Shibing, Huangping, Danzhai, Wengan, Yuqing, Kaiyang etc. ground have commerial growing.At present It is usually that kind of a root broadcasts sowing in cultivation, kind of a root is not handled before sowing, the kind root for carrying germ is caused to infect without strain root, and And subterranean stem is easy excessive growth, seriously affects the emergence of radix pseudostellariae, growth and yield.
Summary of the invention
It is an object of the invention to: provide a kind of raw material be easy to get, it is simple production process, at low cost, efficient, less toxic and to ring The friendly inorganic agent for dressing seed before the sowing of radix pseudostellariae kind root in border.
To solve the above problems, such a radix pseudostellariae kind root inorganic agent of proposed adoption, constituent is by weight percentage Include:
Paclobutrazol 0.0001%~0.1%;
6-benzyl aminopurine 0.0001%~0.1%;
Bravo 0.1%~1%;
Fenvalerate 0.1%~1%;
Remaining is water.
The present invention also provides the application of above-mentioned kind of root inorganic agent, the seed dressing before radix pseudostellariae is sowed of this kind of root inorganic agent.
The raw materials used in the present invention is described below:
Paclobutrazol
Chinese nickname: PP333;Neoprene azoles
English name: Paclobutrazol;No. CAS: 76738-62-0;Molecular formula: C15H20ClN3O;Molecular weight: 293.79
Its structural formula:
Physico-chemical property: raw medicine is white solid, 165-166 DEG C of fusing point, vapour pressure 0.001mPa (20 DEG C), water solubility 26mg/L (20 DEG C), 20 DEG C save 2 years or more, and 50 DEG C or more save 6 months, and pH4-9 is not hydrolyzed, and is not decomposed under ultraviolet light (pH7,10 days).
Purposes: being used as plant growth regulator, can prevent rice shoot apical growth advantage, and lateral bud (tiller) is promoted to breed.Seedling Seedling appearance strengthens more tillers, well developed root system to be short.
6-benzyl aminopurine
Chinese nickname: 6- benzyl adenine, 6- (N- benzyl) adenine phosphate, 6- benzylaminopurine
English name: 6-Benzylaminopurine;
No. CAS: 1214-39-7;Molecular formula: C12H11N5;Molecular weight: 225.25
Its structural formula:
Physico-chemical property: being insoluble in water, is slightly soluble in ethyl alcohol, stablizes in acid, alkali.Solubility in water: 0.44g/L (15 DEG C), It is dissolved in 50% ethyl alcohol.
Purposes: it is main that there is the decomposition for inhibiting leaves of plants inner chlorophyll, nucleic acid, protein, it protects green anti-old;By amino acid, life Element, inorganic salts etc. are grown to a variety of efficiency such as treatment site allocation and transportation.
Bravo
Chinese nickname: termil;Bravo colloidal suspending agent;Bravo suspending agent;Chlorothalonil smoke
English name: chlorothalonil;Chlorothalonil suspensoid;Chlorothalonil fumigant
No. CAS: 1897-45-6;Molecular formula: C8Cl4N2;Molecular weight: 265.911
Its structural formula:
Physico-chemical property: sterling is that white feather shape crystallizes, is odorless, and yellowish or fluffy white powder is presented in industrial goods, slightly It is irritant, density 1.71g/cm3, fusing point is 250-251 DEG C, and boiling point is 350 DEG C (under 760mmHg), and 40 DEG C of vapour pressures are less than 1.3332 pas, almost insoluble in water, solubility is larger in dimethylbenzene, acetone, dimethylformamide.
Purposes: belong to the fungicide new varieties of high-efficiency low-toxicity, low-residual, be widely used in the fungal disease of agriculture, forestry Prevention and treatment, using at most especially on the industrial crops such as veterinary antibiotics, the application such as crops such as tomato, cucumber, wheat is more, can 13 kinds of diseases such as controlling disease such as mildew, powdery mildew, carbon jaundice disease, shot hole.It industrially can be used as mould proof, anticorrosive additive, Also act as the anti-algae, antifouling and fruit fresh-keeping of ship, fishnet.
Fenvalerate
Chinese nickname: nitrile benzene phenothrin, Belmark, Belmark, fenvalerate missible oil, speed are gone out pyrethroids
English name: Fenvalerate
No. CAS: 51630-58-1;Molecular formula: C25H22ClNO3;Molecular weight: 419.90
Its structural formula:
Physico-chemical property: 20 DEG C of steam pressure is 3.1*10-8kpa, and 25 DEG C of vapour pressure is 3.7*10-8kpa, 20 DEG C Solubility: water < 1mg/L, hexane 77g/L, acetone, ethyl alcohol, chloroform, dimethylbenzene, cyclohexanone are all larger than 450g/L.Thermostabilization Property it is good, 75 DEG C of prevention and treatment 100h formulas are decomposed without obvious;It is stable in acid condition, it is unstable in the alkaline medium of ph > 8.
Purposes: desinsection, potent calcineurin (protein phosphatase 2B) inhibitor.
Compared with prior art, it advantage for present invention and has the beneficial effect that:
1. emergence rate and branch amount that the present invention greatly improves radix pseudostellariae kind root;
2. the present invention can control radix pseudostellariae subterranean stem elongation growth, increase radix pseudostellariae subterranean stem joint number;
3. the fairly simple wherein paclobutrazol of production method of the present invention, 6-benzyl aminopurine, Bravo, fenvalerate can arrive It buys, is then uniformly mixed each component in the market;
4. the present invention to people and animals low toxicity, it is environmentally friendly, the present composition other than a small amount of hormone and hormone inhibitors, It is exactly less toxic sterilizing insecticide, therefore nontoxic or less toxic;
5. application method of the present invention is simple, easy to spread.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below invention will be made further to retouch in detail It states.
Following raw materials used sources of embodiment:
Paclobutrazol: Shanghai Sangon Biological Engineering Technology And Service Co., Ltd;
6-benzyl aminopurine: then Biotechnology Co., Ltd, Hisense is gone up;
Bravo: Syngenta Co., Ltd;
Fenvalerate: Syngenta Co., Ltd;
Sterile water: distilled water is made after pressure cooker sterilizes.
Prepare embodiment 1
It is 0.1 gram of fenvalerate, molten by 0.0001 gram of paclobutrazol, 0.0001 gram of 6-benzyl aminopurine, 0.1 gram of Bravo Solution, mixing, adds water to 100 milliliters, the homogeneous in homogenizer is configured to kind of a root inorganic agent 1.
Prepare embodiment 2
It by 0.001 gram of paclobutrazol, 0.1 gram of 6-benzyl aminopurine, 0.1 gram of Bravo, 0.1 gram of fenvalerate, dissolves, mixes It closes, adds water to 100 milliliters, the homogeneous in homogenizer is configured to kind of a root inorganic agent 2.
Prepare embodiment 3
It by 0.1 gram of paclobutrazol, 0.001 gram of 6-benzyl aminopurine, 0.1 gram of Bravo, 0.1 gram of fenvalerate, dissolves, mixes It closes, adds water to 100 milliliters, the homogeneous in homogenizer is configured to kind of a root inorganic agent 3.
Prepare embodiment 4
It by 0.0001 gram of paclobutrazol, 0.0001 gram of 6-benzyl aminopurine, 1 gram of Bravo, 1 gram of fenvalerate, dissolves, mixes It closes, adds water to 100 milliliters, the homogeneous in homogenizer is configured to kind of a root inorganic agent 4.
Prepare embodiment 5
It by 0.1 gram of paclobutrazol, 0.1 gram of 6-benzyl aminopurine, 0.1 gram of Bravo, 0.1 gram of fenvalerate, dissolves, mixing, 100 milliliters are added water to, the homogeneous in homogenizer is configured to kind of a root inorganic agent 5.
Prepare embodiment 6
It by 0.1 gram of paclobutrazol, 0.1 gram of 6-benzyl aminopurine, 1 gram of Bravo, 0.1 gram of fenvalerate, dissolves, mixing adds Water is to 100 milliliters, the homogeneous in homogenizer, is configured to kind of a root inorganic agent 6.
Prepare embodiment 7
It by 0.01 gram of paclobutrazol, 0.01 gram of 6-benzyl aminopurine, 1 gram of Bravo, 1 gram of fenvalerate, dissolves, mixing adds Water is to 100 milliliters, the homogeneous in homogenizer, is configured to kind of a root inorganic agent 7.
EXPERIMENTAL EXAMPLE 1
5 kilograms of radix pseudostellariae kind roots are divided into 5 parts, 1 kilogram every part, are placed in clean basin, wherein being separately added into 1 in four parts Kind of 1,1 liter of root inorganic agent, 2,1 liters of kind root inorganic agent, 3,1 liters of kind root inorganic agents 4 of kind root inorganic agent are risen, the 5th part with water process to be made For blank control, flood goes out root of dressing seed after ten minutes, dries, and the radix pseudostellariae kind root sowing after seed dressing is planted in whole good radix pseudostellariae Tanaka.6 centimetres of thickness of earth-fill cover, other field management routinely manage.Seeding stage counts emergence rate, and growth medium is statistically lower to be saved Between number, the yield of radix pseudostellariae is counted after radix pseudostellariae sprout tumble.Each processing sets 3 repetitions (the results are shown in Table 1).
EXPERIMENTAL EXAMPLE 2
4 kilograms of radix pseudostellariae kind roots are divided into 4 parts, 1 kilogram every part, are placed in clean basin, wherein three parts are separately added into 1 liter Kind 5,1 liters of root inorganic agent, 6,1 liters of kind root inorganic agent kind root inorganic agent 7, the 4th part to use water process as blank control, seed dressing root Flood goes out after ten minutes, dries, and the radix pseudostellariae kind root sowing after seed dressing is planted Tanaka in whole good radix pseudostellariae, and 6 lis of thickness of earth-fill cover Rice, other field management routinely manage.Seeding stage counts 1 square metre of emergence rate, and growth medium takes 10 plants of statistically lower sections It counts, the yield of 3-5 square metres of statistics radix pseudostellariae is randomly selected after radix pseudostellariae sprout tumble.Each processing, which sets 3 repetitions, (the results are shown in Table 1)。
Experimental result of a kind of root inorganic agent of table to the emergence of radix pseudostellariae kind root, underground joint number yield effect
Kind root inorganic agent 1 2 3 4 5 6 7 Control
Emergence rate/% (average three times) 96 96 95 98 96 97 95 91
Underground joint number/(average three times) 5 5 5 6 5 6 6 4
Output of fresh/kilogram (average three times) 8.35 8.42 8.21 8.10 8.30 7.63 7.48 7.20
The result shows that (being shown in Table 1), the present invention, which prepares the kind root inorganic agent that embodiment 1-5 is prepared, can remarkably promote crown prince Ginseng emergence, increases radix pseudostellariae underground joint number, improves radix pseudostellariae yield.The kind root inorganic agent that preparation embodiment 6,7 is prepared also can Promote radix pseudostellariae emergence, increase radix pseudostellariae underground joint number, improves radix pseudostellariae yield.

Claims (2)

1. radix pseudostellariae kind root inorganic agent, which is characterized in that its constituent includes: by weight percentage
Paclobutrazol 0.0001%~0.1%;
6-benzyl aminopurine 0.0001%~0.1%;
Bravo 0.1%~1%;
Fenvalerate 0.1%~1%;
Remaining is water.
2. planting the application of root inorganic agent described in claim 1, it is characterised in that: this kind of root inorganic agent is mixed before radix pseudostellariae sowing Kind.
CN201710188456.9A 2017-03-27 2017-03-27 Radix pseudostellariae kind root inorganic agent and its application Active CN106962375B (en)

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