CN106947550A - A kind of Fuel Petroleum and preparation method thereof - Google Patents

A kind of Fuel Petroleum and preparation method thereof Download PDF

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Publication number
CN106947550A
CN106947550A CN201710290776.5A CN201710290776A CN106947550A CN 106947550 A CN106947550 A CN 106947550A CN 201710290776 A CN201710290776 A CN 201710290776A CN 106947550 A CN106947550 A CN 106947550A
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parts
fuel petroleum
additive
modifying agent
alcohol
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赵龙龙
赵伟
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Individual
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1258—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof hydrogen peroxide, oxygenated water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1811—Organic compounds containing oxygen peroxides; ozonides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224—Amides; Imides carboxylic acid amides, imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention provides a kind of Fuel Petroleum and preparation method thereof, Fuel Petroleum of the present invention is mainly prepared by the alcohol of specific usage ratio, solvent naphtha, modifying agent and additive, and raw material is easy to get, low cost, octane number is high, no pinking, and cleannes are high, it is not leaded, no sulphur, basic zero-emission, it is pollution-free to air, good stability corrosion-free to oil supply system, good endurance, not stratified, nondiscolouring, burning is thorough, and engine, can increasing service life of engine substantially without carbon distribution.The preparation method technique of Fuel Petroleum of the present invention is simple, and the cycle is short, can be prepared by the way that raw material is directly mixed, suitable for large-scale production.

Description

A kind of Fuel Petroleum and preparation method thereof
Technical field
The present invention relates to synthetic fuel technical field, in particular to a kind of Fuel Petroleum and preparation method thereof.
Background technology
English entitled Gasoline (U.S.)/Petrol (English) of gasoline, outward appearance is transparency liquid, flammable, and boiling range is 30 DEG C To 220 DEG C, gasoline has a higher octane number (Ulva Pertusa combustibility), and by the height of octane number be divided into No. 90, No. 93,95 Number, the trades mark such as No. 97.Direct steaming gasoline component that gasoline is obtained by petroleum refining, catalytically cracked gasoline component, catalytic reforming gasoline The difference gasoline component such as component is made after refined with antiknock component through reconciling, and is mainly used as automobile ignition internal combustion engine Fuel.
But China be one it is oil-poor beat, the imbalance between supply and demand stone flour of gasoline is protruded, and the shortage of the energy is restriction China The bottleneck problem of economic development；In addition, the gasoline products in correlation technique, often have high cost, octane number is low, cleannes Low, containing pollutant component, tail gas severe contamination environment, stability is poor, and long-term use can corrode engine and automobile oil supply system, It is difficult to thoroughly burning, easily produces carbon on engine, influences the shortcoming of service life of aeroengine.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of Fuel Petroleum, and described Fuel Petroleum low cost, octane number is high, nothing Pinking, cleannes are high, not leaded, no sulphur, and basic zero-emission is pollution-free to air, good stability corrosion-free to oil supply system, Good endurance, not stratified, nondiscolouring, burning is thorough, and engine, can increasing service life of engine substantially without carbon distribution.
The second object of the present invention is to provide a kind of preparation method of described Fuel Petroleum, and this method technique is simple, Cycle is short, suitable for large-scale production.
In order to realize the above-mentioned purpose of the present invention, spy uses following technical scheme：
A kind of Fuel Petroleum, the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
0.5-3 parts of 70-90 parts of alcohol, 30-40 parts of solvent naphtha, 2-8 parts of modifying agent and additive.
Fuel Petroleum of the present invention is mainly prepared by the alcohol of specific usage ratio, solvent naphtha, modifying agent and additive, former Material is easy to get, low cost, and octane number is high, no pinking, and cleannes are high, not leaded, no sulphur, and basic zero-emission is pollution-free to air, right Oil supply system is corrosion-free, good stability, and good endurance is not stratified, nondiscolouring, and burning is thorough, and engine can prolong substantially without carbon distribution Long service life of aeroengine.
Preferably, the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
1-3 parts of 75-85 parts of alcohol, 32-38 parts of solvent naphtha, 4-6 parts of modifying agent and additive.
It is further preferred that the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
2 parts of 80 parts of alcohol, 35 parts of solvent naphtha, 5 parts of modifying agent and additive.
Alternatively, the modifying agent is mainly prepared by the raw material of following mass fraction：
20-40 parts of BHT, 25-45 parts of acetone, 10-30 parts of hydrogen peroxide, 8-15 parts of sulfonate and lightweight It is oily 6-13 parts.
Preferably, the modifying agent is mainly prepared by the raw material of following mass fraction：
25-35 parts of BHT, 30-40 parts of acetone, 15-25 parts of hydrogen peroxide, 10-14 parts of sulfonate and lightweight It is oily 8-12 parts.
It is further preferred that the modifying agent is mainly prepared by the raw material of following mass fraction：
10 parts of 30 parts of BHT, 35 parts of acetone, 20 parts of hydrogen peroxide, 12 parts of sulfonate and light oil.
Preferably, the BHT includes BHT.
Preferably, the sulfonate includes lignosulfonates.
Alternatively, the additive is mainly prepared by the raw material of following mass fraction：
15-30 parts of isopropanol, 10-30 parts of ethylene glycol, N, 2-8 parts of N- diisopropyl p-phenylenediamine, succimide 20-40 Part, 25-50 parts of carbon hydrocarbon compound, 2-8 parts of hyperis and 10-22 parts of the tert-butyl alcohol.
Preferably, the additive is mainly prepared by the raw material of following mass fraction：
20-24 parts of isopropanol, 15-25 parts of ethylene glycol, N, 4-6 parts of N- diisopropyl p-phenylenediamine, succimide 25-35 Part, 32-42 parts of carbon hydrocarbon compound, 4-6 parts of hyperis and 14-18 parts of the tert-butyl alcohol.
It is further preferred that the additive is mainly prepared by the raw material of following mass fraction：
22 parts of isopropanol, 20 parts of ethylene glycol, N, 5 parts of N- diisopropyls p-phenylenediamine, 30 parts of succimide, carbon hydrocarbonylation are closed 16 parts of 37 parts of thing, 5 parts of hyperis and the tert-butyl alcohol.
Preferably, the carbon hydrocarbon compound includes the one or more in alkane, alkene, alkynes and aromatic hydrocarbon, preferably wraps The one or more in C5-C16 hydrocarbon are included, further preferably include the one or more in C5-C12 hydrocarbon.
Alternatively, the alcohol includes the one or more in C1-C10 alcohol, preferably includes methanol, ethanol, propyl alcohol and butanol In one or more, further preferably include bio-ethanol or Ethanol.
A kind of preparation method of above-mentioned Fuel Petroleum, in proportion mixes alcohol, solvent naphtha, modifying agent and additive Uniformly, a kind of Fuel Petroleum is obtained.
The preparation method technique of Fuel Petroleum of the present invention is simple, and the cycle is short, can be by the way that raw material directly to be mixed to preparation Obtain, suitable for large-scale production.
Preferably, alcohol is added in proportion and starts stirring in container, modifying agent, solvent naphtha and addition are sequentially added afterwards Agent, mixing and stirring obtains a kind of Fuel Petroleum.
Alternatively, mixing time is more than 30min, more preferably preferably 30-60min, 40min.
Alternatively, the preparation method of the modifying agent includes：
In proportion by BHT, acetone, hydrogen peroxide, sulfonate and light oil mixing and stirring, obtain Modifying agent.
Preferably, acetone, hydrogen peroxide and light oil are added in proportion and starts stirring in container, add di-t-butyl Paracresol and sulfonate, heat mixing and stirring, and cooling obtains modifying agent.
It is further preferred that the temperature of the heating is more than 45 DEG C, more preferably preferably 45-50 DEG C, 48 DEG C.
It is further preferred that the cooling includes natural cooling.
Preferably, mixing time is more than 30min, more preferably preferably 30-120min, 60min.
Alternatively, the preparation method of the additive includes：
In proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbon compound, isopropyl Base hydrogen peroxide and tert-butyl alcohol mixing and stirring, obtain additive.
Preferably, in proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbonylation are closed Thing, hyperis and the tert-butyl alcohol are added in container, heat mixing and stirring, and cooling obtains additive.
It is further preferred that the temperature of the heating is more than 50 DEG C, more preferably preferably 50-55 DEG C, 52 DEG C.
It is further preferred that the cooling includes natural cooling.
Preferably, mixing time is more than 30min, more preferably preferably 30-60min, 40min.
Compared with prior art, beneficial effects of the present invention are：
Fuel Petroleum of the present invention is mainly prepared by the alcohol of specific usage ratio, solvent naphtha, modifying agent and additive, former Material is easy to get, low cost, and octane number is high, no pinking, and cleannes are high, not leaded, no sulphur, and basic zero-emission is pollution-free to air, right Oil supply system is corrosion-free, good stability, and good endurance is not stratified, nondiscolouring, and burning is thorough, and engine can prolong substantially without carbon distribution Long service life of aeroengine.The preparation method technique of Fuel Petroleum of the present invention is simple, and the cycle is short, can be by the way that raw material is directly mixed Stirring is prepared, suitable for large-scale production.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, but ability Field technique personnel will be understood that, following described embodiment is a part of embodiment of the invention, rather than whole embodiments, The present invention is merely to illustrate, and is not construed as limiting the scope of the present invention.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.Unreceipted actual conditions person in embodiment, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or instrument Unreceipted production firm person, is the conventional products that can be obtained by commercially available purchase.
The invention provides a kind of Fuel Petroleum, the Fuel Petroleum is mainly prepared into by the raw material of following mass fraction Arrive：
0.5-3 parts of 70-90 parts of alcohol, 30-40 parts of solvent naphtha, 2-8 parts of modifying agent and additive.
Fuel Petroleum of the present invention is mainly prepared by the alcohol of specific usage ratio, solvent naphtha, modifying agent and additive, former Material is easy to get, low cost, and octane number is high, no pinking, and cleannes are high, not leaded, no sulphur, and basic zero-emission is pollution-free to air, right Oil supply system is corrosion-free, good stability, and good endurance is not stratified, nondiscolouring, and burning is thorough, and engine can prolong substantially without carbon distribution Long service life of aeroengine.
Preferably, the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
1-3 parts of 75-85 parts of alcohol, 32-38 parts of solvent naphtha, 4-6 parts of modifying agent and additive.
It is further preferred that the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
2 parts of 80 parts of alcohol, 35 parts of solvent naphtha, 5 parts of modifying agent and additive.
Using the alcohol of specific usage ratio, solvent naphtha, modifying agent and additive, help further to improve gained gasoline combustion The combination properties such as octane number, cleannes, the stability of material, while avoiding gained Fuel Petroleum to engine and automobile oil supply system Corrosion is caused, improves the fuel efficiency performance of gained Fuel Petroleum, makes its burning more thoroughly, carbon deposition phenomenon is reduced, extension engine Service life.
In a kind of preferred embodiment of the present invention, prepared by the main raw material by following mass fraction of the modifying agent Obtain：
20-40 parts of BHT, 25-45 parts of acetone, 10-30 parts of hydrogen peroxide, 8-15 parts of sulfonate and lightweight It is oily 6-13 parts.
Preferably, the modifying agent is mainly prepared by the raw material of following mass fraction：
25-35 parts of BHT, 30-40 parts of acetone, 15-25 parts of hydrogen peroxide, 10-14 parts of sulfonate and lightweight It is oily 8-12 parts.
It is further preferred that the modifying agent is mainly prepared by the raw material of following mass fraction：
10 parts of 30 parts of BHT, 35 parts of acetone, 20 parts of hydrogen peroxide, 12 parts of sulfonate and light oil.
Modifying agent is prepared using specified raw material and usage ratio, the stabilization of gained Fuel Petroleum can be further improved Property etc. combination property, while improve gained Fuel Petroleum fuel efficiency performance, make its burning more thoroughly, make its burning more thoroughly, subtract Few carbon deposition phenomenon, extends the service life of engine.
Preferably, the BHT includes BHT.
The stability and durability of gained Fuel Petroleum are favorably improved using specific BHT, it is long-term to stand Not stratified, nondiscolouring.
Preferably, the sulfonate includes lignosulfonates.
Using specific sulfonate, help to improve the clean-up performance of gained Fuel Petroleum, while promoting each composition of modifying agent Between fully dissolve each other, promote Fuel Petroleum each component between mutually dissolving each other, further improve gained Fuel Petroleum it is comprehensive Energy.
In a kind of preferred embodiment of the present invention, prepared by the main raw material by following mass fraction of the additive Obtain：
15-30 parts of isopropanol, 10-30 parts of ethylene glycol, N, 2-8 parts of N- diisopropyl p-phenylenediamine, succimide 20-40 Part, 25-50 parts of carbon hydrocarbon compound, 2-8 parts of hyperis and 10-22 parts of the tert-butyl alcohol.
Preferably, the additive is mainly prepared by the raw material of following mass fraction：
20-24 parts of isopropanol, 15-25 parts of ethylene glycol, N, 4-6 parts of N- diisopropyl p-phenylenediamine, succimide 25-35 Part, 32-42 parts of carbon hydrocarbon compound, 4-6 parts of hyperis and 14-18 parts of the tert-butyl alcohol.
It is further preferred that the additive is mainly prepared by the raw material of following mass fraction：
22 parts of isopropanol, 20 parts of ethylene glycol, N, 5 parts of N- diisopropyls p-phenylenediamine, 30 parts of succimide, carbon hydrocarbonylation are closed 16 parts of 37 parts of thing, 5 parts of hyperis and the tert-butyl alcohol.
Additive is prepared using specified raw material and usage ratio, the stabilization of gained Fuel Petroleum can be further improved Property etc. combination property, improve Fuel Petroleum each component low temperature dispersity and high-temperature stability, solid pollutant can be made with colloid State is suspended in the chemicals in oil, prevents the electrodeposition substances such as greasy filth, paint film and sludge on engine components, it is to avoid gained vapour Oil fuel causes corrosion to engine and automobile oil supply system, while improving the fuel efficiency performance of gained Fuel Petroleum, it is burnt More thoroughly, make its burning more thoroughly, reduce carbon deposition phenomenon, extend the service life of engine.
Preferably, the carbon hydrocarbon compound includes the one or more in alkane, alkene, alkynes and aromatic hydrocarbon, preferably wraps The one or more in C5-C16 hydrocarbon are included, further preferably include the one or more in C5-C12 hydrocarbon.
Using particular kind of carbon hydrocarbon compound, the other compositions of additive and Fuel Petroleum can be promoted uniformly miscible, Improve the lubricity of gained Fuel Petroleum simultaneously, reduce component wear.
In a kind of preferred embodiment of the present invention, the alcohol includes the one or more in C1-C10 alcohol, preferably Including the one or more in methanol, ethanol, propyl alcohol and butanol, further preferably include bio-ethanol or Ethanol.
Using specific alcohol, while as fuel main body, improving combustibility, gained Fuel Petroleum can be made as solvent Burning more thoroughly, reduces carbon deposition phenomenon, extends the service life of engine.
Bio-ethanol refers to various biomass are converted into fuel alcohol by the fermentation of microorganism, using Ethanol as Fuel, high combustion efficiency introduces the pollutants such as lead, sulphur while avoiding using other fuel feedstocks.
A kind of preparation method of above-mentioned Fuel Petroleum, in proportion mixes alcohol, solvent naphtha, modifying agent and additive Uniformly, a kind of Fuel Petroleum is obtained.
The preparation method technique of Fuel Petroleum of the present invention is simple, and the cycle is short, can be by the way that raw material directly to be mixed to preparation Obtain, suitable for large-scale production.
Preferably, alcohol is added in proportion and starts stirring in container, modifying agent, solvent naphtha and addition are sequentially added afterwards Agent, mixing and stirring obtains a kind of Fuel Petroleum.
Using specific charging sequence, contribute to each component full and uniform miscible, improve production efficiency.
In a kind of preferred embodiment of the present invention, mixing time is more than 30min, preferably 30-60min, is entered One step is preferably 40min.
It using specific mixing time, ensure that each component is full and uniform miscible, further improve gained Fuel Petroleum Combination property.
In a kind of preferred embodiment of the present invention, the preparation method of the modifying agent includes：
In proportion by BHT, acetone, hydrogen peroxide, sulfonate and light oil mixing and stirring, obtain Modifying agent.
Preferably, acetone, hydrogen peroxide and light oil are added in proportion and starts stirring in container, add di-t-butyl Paracresol and sulfonate, heat mixing and stirring, and cooling obtains modifying agent.
Using specific preparation technology, contribute to each component full and uniform miscible, improve production efficiency, obtain stable in properties Modifying agent.
It is further preferred that the temperature of the heating is more than 45 DEG C, more preferably preferably 45-50 DEG C, 48 DEG C.
By the way of specified temp is heated, contribute to modifying agent each component rapid full and uniform miscible.
It is further preferred that the cooling includes natural cooling.
Preferably, mixing time is more than 30min, more preferably preferably 30-120min, 60min.
It using specific mixing time, ensure that each component is full and uniform miscible, further improve gained Fuel Petroleum Combination property.
In a kind of preferred embodiment of the present invention, the preparation method of the additive includes：
In proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbon compound, isopropyl Base hydrogen peroxide and tert-butyl alcohol mixing and stirring, obtain additive.
Preferably, in proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbonylation are closed Thing, hyperis and the tert-butyl alcohol are added in container, heat mixing and stirring, and cooling obtains additive.
Using specific preparation technology, contribute to each component full and uniform miscible, improve production efficiency, obtain stable in properties Additive.
It is further preferred that the temperature of the heating is more than 50 DEG C, more preferably preferably 50-55 DEG C, 52 DEG C.
By the way of specified temp is heated, contribute to additive each component rapid full and uniform miscible.
It is further preferred that the cooling includes natural cooling.
Preferably, mixing time is more than 30min, more preferably preferably 30-60min, 40min.
It using specific mixing time, ensure that each component is full and uniform miscible, further improve gained Fuel Petroleum Combination property.
Embodiment 1
A kind of preparation method of Fuel Petroleum, including：
(1) preparation of modifying agent：
Acetone 25kg, hydrogen peroxide 10kg and light oil 6kg are added and start stirring in container, the tertiary fourths of 2,6- bis- are added Base paracresol 20kg and lignosulfonates 8kg, is heated to 45 DEG C, and 30min is mixed at this temperature, and natural cooling is obtained Modifying agent；
(2) preparation of additive：
By isopropanol 15kg, ethylene glycol 10kg, N, N- diisopropyl p-phenylenediamine 2kg, T154 succimides 20kg, carbon Hydrocarbon compound 25kg, hyperis 2kg and tert-butyl alcohol 10kg are added in container, are heated to 50 DEG C, are mixed at this temperature Stirring 30min is closed, natural cooling obtains additive；
(3) preparation of Fuel Petroleum：
Bio-ethanol 70kg is added and be started stirring in container, modifying agent 2kg obtained by step (1) is sequentially added afterwards, molten Agent oil 30kg and step (2) gained additive 0.5kg, mixes 30min, obtains a kind of Fuel Petroleum.
Embodiment 2
A kind of preparation method of Fuel Petroleum, including：
(1) preparation of modifying agent：
Acetone 45kg, hydrogen peroxide 30kg and light oil 13kg are added and start stirring in container, the uncles of 2,6- bis- are added Butyl paracresol 40kg and lignosulfonates 15kg, is heated to 50 DEG C, and 120min, natural cooling are mixed at this temperature Obtain modifying agent；
(2) preparation of additive：
By isopropanol 30kg, ethylene glycol 30kg, N, N- diisopropyl p-phenylenediamine 8kg, T154 succimides 40kg, carbon Hydrocarbon compound 50kg, hyperis 8kg and tert-butyl alcohol 22kg are added in container, are heated to 55 DEG C, are mixed at this temperature Stirring 60min is closed, natural cooling obtains additive；
(3) preparation of Fuel Petroleum：
Bio-ethanol 90kg is added and be started stirring in container, modifying agent 8kg obtained by step (1) is sequentially added afterwards, molten Agent oil 40kg and step (2) gained additive 3kg, mixes 60min, obtains a kind of Fuel Petroleum.
Embodiment 3
A kind of preparation method of Fuel Petroleum, including：
(1) preparation of modifying agent：
Acetone 30kg, hydrogen peroxide 15kg and light oil 8kg are added and start stirring in container, the tertiary fourths of 2,6- bis- are added Base paracresol 25kg and lignosulfonates 10kg, is heated to 47 DEG C, and 30min is mixed at this temperature, and natural cooling is obtained To modifying agent；
(2) preparation of additive：
By isopropanol 20kg, ethylene glycol 15kg, N, N- diisopropyl p-phenylenediamine 4kg, T154 succimides 25kg, carbon Hydrocarbon compound 32kg, hyperis 4kg and tert-butyl alcohol 14kg are added in container, are heated to 51 DEG C, are mixed at this temperature Stirring 30min is closed, natural cooling obtains additive；
(3) preparation of Fuel Petroleum：
Bio-ethanol 75kg is added and be started stirring in container, modifying agent 4kg obtained by step (1) is sequentially added afterwards, molten Agent oil 32kg and step (2) gained additive 1kg, mixes 30min, obtains a kind of Fuel Petroleum.
Embodiment 4
A kind of preparation method of Fuel Petroleum, including：
(1) preparation of modifying agent：
Acetone 40kg, hydrogen peroxide 25kg and light oil 12kg are added and start stirring in container, the uncles of 2,6- bis- are added Butyl paracresol 35kg and lignosulfonates 14kg, is heated to 49 DEG C, and 90min, natural cooling are mixed at this temperature Obtain modifying agent；
(2) preparation of additive：
By isopropanol 24kg, ethylene glycol 25kg, N, N- diisopropyl p-phenylenediamine 6kg, T154 succimides 35kg, carbon Hydrocarbon compound 42kg, hyperis 6kg and tert-butyl alcohol 18kg are added in container, are heated to 53 DEG C, are mixed at this temperature Stirring 50min is closed, natural cooling obtains additive；
(3) preparation of Fuel Petroleum：
Bio-ethanol 85kg is added and be started stirring in container, modifying agent 6kg obtained by step (1) is sequentially added afterwards, molten Agent oil 38kg and step (2) gained additive 3kg, mixes 50min, obtains a kind of Fuel Petroleum.
Embodiment 5
A kind of preparation method of Fuel Petroleum, including：
(1) preparation of modifying agent：
Acetone 35kg, hydrogen peroxide 20kg and light oil 10kg are added and start stirring in container, the uncles of 2,6- bis- are added Butyl paracresol 30kg and lignosulfonates 12kg, is heated to 48 DEG C, and 60min, natural cooling are mixed at this temperature Obtain modifying agent；
(2) preparation of additive：
By isopropanol 22kg, ethylene glycol 20kg, N, N- diisopropyl p-phenylenediamine kg, T154 succimides 30kg, carbon Hydrocarbon compound 37kg, hyperis 5kg and tert-butyl alcohol 16kg are added in container, are heated to 52 DEG C, are mixed at this temperature Stirring 40min is closed, natural cooling obtains additive；
(3) preparation of Fuel Petroleum：
Bio-ethanol 80kg is added and be started stirring in container, modifying agent 5kg obtained by step (1) is sequentially added afterwards, molten Agent oil 35kg and step (2) gained additive 2kg, mixes 40min, obtains a kind of Fuel Petroleum.
Quality testing is carried out to Fuel Petroleum obtained by embodiment of the present invention 1-5, as a result as shown in table 1：
The Fuel Petroleum quality measurements of the present invention of table 1
It can be seen from Table 1 that, Fuel Petroleum octane number of the present invention is high, no phenomenon of detonation, and gum level is low, miscellaneous without machinery Matter, cleannes are high, lead, sulphur, manganese, iron content it is low, water content is low, without water soluble acid or alkali, good stability, good endurance, It is not stratified, nondiscolouring, carbon monoxide, non-methane hydro carbons, methane and hydronitrogen discharge capacity it is low, basic zero-emission Put, pollution-free to air, corrosion-free to oil supply system, burning is thorough, and engine can extend engine and use the longevity substantially without carbon distribution Life.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that various embodiments above is only used To illustrate technical scheme, rather than its limitations；It will be understood by those within the art that：Without departing substantially from this hair In the case of bright spirit and scope, the technical scheme described in foregoing embodiments can be modified, or to wherein Some or all of technical characteristic carries out equivalent；And these modifications or replacement, do not make the essence of appropriate technical solution Depart from the scope of various embodiments of the present invention technical scheme；It is, therefore, intended that including belonging to the present invention in the following claims In the range of all these substitutions and modifications.

Claims (10)

1. a kind of Fuel Petroleum, it is characterised in that the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
0.5-3 parts of 70-90 parts of alcohol, 30-40 parts of solvent naphtha, 2-8 parts of modifying agent and additive；
Preferably, the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
1-3 parts of 75-85 parts of alcohol, 32-38 parts of solvent naphtha, 4-6 parts of modifying agent and additive；
It is further preferred that the Fuel Petroleum is mainly prepared by the raw material of following mass fraction：
2 parts of 80 parts of alcohol, 35 parts of solvent naphtha, 5 parts of modifying agent and additive.
2. a kind of Fuel Petroleum according to claim 1, it is characterised in that the modifying agent is main by following mass fraction Raw material prepare：
20-40 parts of BHT, 25-45 parts of acetone, 10-30 parts of hydrogen peroxide, 8-15 parts of sulfonate and light oil 6- 13 parts；
Preferably, the modifying agent is mainly prepared by the raw material of following mass fraction：
25-35 parts of BHT, 30-40 parts of acetone, 15-25 parts of hydrogen peroxide, 10-14 parts of sulfonate and light oil 8- 12 parts；
It is further preferred that the modifying agent is mainly prepared by the raw material of following mass fraction：
10 parts of 30 parts of BHT, 35 parts of acetone, 20 parts of hydrogen peroxide, 12 parts of sulfonate and light oil.
3. a kind of Fuel Petroleum according to claim 2, it is characterised in that the BHT includes 2,6- bis- Butylated Hydroxytoluene；
Preferably, the sulfonate includes lignosulfonates.
4. a kind of Fuel Petroleum according to claim 1, it is characterised in that the additive is main by following mass fraction Raw material prepare：
15-30 parts of isopropanol, 10-30 parts of ethylene glycol, N, 2-8 parts of N- diisopropyl p-phenylenediamine, 20-40 parts of succimide, 10-22 parts of 25-50 parts of carbon hydrocarbon compound, 2-8 parts of hyperis and the tert-butyl alcohol；
Preferably, the additive is mainly prepared by the raw material of following mass fraction：
20-24 parts of isopropanol, 15-25 parts of ethylene glycol, N, 4-6 parts of N- diisopropyl p-phenylenediamine, 25-35 parts of succimide, 14-18 parts of 32-42 parts of carbon hydrocarbon compound, 4-6 parts of hyperis and the tert-butyl alcohol；
It is further preferred that the additive is mainly prepared by the raw material of following mass fraction：
22 parts of isopropanol, 20 parts of ethylene glycol, N, 5 parts of N- diisopropyls p-phenylenediamine, 30 parts of succimide, carbon hydrocarbon compound 37 16 parts of part, 5 parts of hyperis and the tert-butyl alcohol.
5. a kind of Fuel Petroleum according to claim 4, it is characterised in that the carbon hydrocarbon compound include alkane, alkene, One or more in alkynes and aromatic hydrocarbon, preferably include the one or more in C5-C16 hydrocarbon, further preferably including C5- One or more in C12 hydrocarbon.
6. a kind of Fuel Petroleum according to claim 1, it is characterised in that the alcohol include one kind in C1-C10 alcohol or It is a variety of, the one or more in methanol, ethanol, propyl alcohol and butanol are preferably included, further preferably include bio-ethanol or biology Alcohol.
7. a kind of preparation method of Fuel Petroleum as described in claim 1-6 is any, it is characterised in that in proportion by alcohol, molten Agent oil, modifying agent and additive mixing and stirring, obtain a kind of Fuel Petroleum；
Preferably, alcohol is added in proportion and starts stirring in container, modifying agent, solvent naphtha and additive are sequentially added afterwards, mixed Conjunction stirs, and obtains a kind of Fuel Petroleum.
8. a kind of preparation method of Fuel Petroleum according to claim 7, it is characterised in that mixing time be 30min with On, preferably 30-60min, more preferably 40min.
9. a kind of preparation method of Fuel Petroleum according to claim 7, it is characterised in that the preparation side of the modifying agent Method includes：
In proportion by BHT, acetone, hydrogen peroxide, sulfonate and light oil mixing and stirring, it is modified Agent；
Preferably, acetone, hydrogen peroxide and light oil are added in proportion and starts stirring in container, add di-t-butyl to first Phenol and sulfonate, heat mixing and stirring, and cooling obtains modifying agent；
It is further preferred that the temperature of the heating is more than 45 DEG C, more preferably preferably 45-50 DEG C, 48 DEG C；
It is further preferred that the cooling includes natural cooling；
Preferably, mixing time is more than 30min, more preferably preferably 30-120min, 60min.
10. a kind of preparation method of Fuel Petroleum according to claim 7, it is characterised in that the preparation of the additive Method includes：
In proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbon compound, isopropyl mistake Hydrogen oxide and tert-butyl alcohol mixing and stirring, obtain additive；
Preferably, in proportion by isopropanol, ethylene glycol, N, N- diisopropyls p-phenylenediamine, succimide, carbon hydrocarbon compound, Hyperis and the tert-butyl alcohol are added in container, heat mixing and stirring, and cooling obtains additive；
It is further preferred that the temperature of the heating is more than 50 DEG C, more preferably preferably 50-55 DEG C, 52 DEG C；
It is further preferred that the cooling includes natural cooling；
Preferably, mixing time is more than 30min, more preferably preferably 30-60min, 40min.
CN201710290776.5A 2017-04-28 2017-04-28 A kind of Fuel Petroleum and preparation method thereof Pending CN106947550A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1621499A (en) * 2003-11-30 2005-06-01 魏军 Synthetic gasoline
CN104017615A (en) * 2014-06-03 2014-09-03 赵龙龙 Synthetic gasoline and preparing method thereof
CN104789279A (en) * 2015-04-29 2015-07-22 安徽中禄新能源科技开发有限公司 High-cleanness alcohol hydrogen oil for compression-ignition internal combustion engines and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1621499A (en) * 2003-11-30 2005-06-01 魏军 Synthetic gasoline
CN104017615A (en) * 2014-06-03 2014-09-03 赵龙龙 Synthetic gasoline and preparing method thereof
CN104789279A (en) * 2015-04-29 2015-07-22 安徽中禄新能源科技开发有限公司 High-cleanness alcohol hydrogen oil for compression-ignition internal combustion engines and preparation method thereof

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Application publication date: 20170714