CN105567346B - High-definition test oil and preparation method thereof - Google Patents
High-definition test oil and preparation method thereof Download PDFInfo
- Publication number
- CN105567346B CN105567346B CN201610080656.8A CN201610080656A CN105567346B CN 105567346 B CN105567346 B CN 105567346B CN 201610080656 A CN201610080656 A CN 201610080656A CN 105567346 B CN105567346 B CN 105567346B
- Authority
- CN
- China
- Prior art keywords
- less
- test oil
- oil
- high definition
- definition test
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1835—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom having at least two hydroxy substituted non condensed benzene rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/08—Inhibitors
- C10L2230/081—Anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/08—Inhibitors
- C10L2230/085—Metal deactivators
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/20—Function and purpose of a components of a fuel or the composition as a whole for improving conductivity
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention relates to high-definition test oil and a preparation method thereof. The high-definition test oil is mainly prepared from, by weight, 10-20 parts of liquid paraffin and 2-8 parts of solvent oil. The preparation method comprises the steps of adding the materials into a blending tank according to the proportion and performing even mixing. The high-definition test oil is stable in quality and high in cleanliness, meanwhile has very good oxidation stability and low-temperature startability and can meet the use and testing requirements under the harsh environmental conditions. The preparation method has the advantages that operation is easy and convenient, and the finished product is stable.
Description
Technical field
The invention belongs to oil product technical field, and in particular to a kind of high definition test oil and preparation method thereof.
Background technology
When new car is offline, generally require to inject a certain amount of fuel oil, i.e. first charge of oil, because new car is from offline, to being sent to use
In the handss of family, it may be necessary to the long period, and vehicle sells to the area of Different climate condition, therefore just charge of oil may be in new car oil
The storage long time in case, and can suffer from high temperature, the test of severe cold area condition.If first charge of oil poor quality, stability
Difference, then be easy to the parts such as, generation colloid rotten in new car fuel system internal oxidition, blocking fuel screen, atomizer, causes to send out
Motivation failure.In addition, if vehicle is in severe cold area, due to oil product long-term frozen, vehicle may be difficult to start.Further, for a long time
The oil product of storage also easily corrodes fuel system, erosion blocking filter screen and atomizer, causes engine failure.
In addition, car manufactures or research and development institution need to make in automobile engine, car load research and development, test and internal demarcation
With test oil, the quality of test oil has considerable influence to the accuracy of test result.
Present inventor has found that existing diesel oil exists when using existing diesel oil as first charge of oil and test oil
It is inadequate as stability, cleannes, oxidation stability and low-temperature startup during first charge of oil, it is impossible to meet in different regions harshness ring
The requirement used under the conditions of border, and when as test oil, also because cleannes, oxidation stability are not enough, it is impossible to meet examination
Test the requirement with oil.
The content of the invention
In order to solve the problems referred to above of prior art presence, the invention provides a kind of high definition test oil and its preparation side
Method, the high definition test oil steady quality, cleannes are high, while having good oxidation stability and low-temperature startup, energy
Enough meet and used and test requirements document under harsh environmental conditions;The preparation method has the advantages that easy to operate, finished product is stable.
The technical solution adopted in the present invention is:A kind of high definition test oil, is mainly made up of the raw material of following weight portion:
Liquid paraffin 10-20 parts and solvent naphtha 2-8 parts.
Preferably, the liquid paraffin includes liquid paraffin 2#, light paraffinic and middle matter paraffin, wherein the liquid paraffin
The mass ratio of 2#, light paraffinic and middle matter paraffin is 40-60:20-30:20-30.
It should be noted that heretofore described liquid paraffin 2#, light paraffinic and middle matter paraffin are roots in invention
Voluntarily name according to property of raw material, be not the adopted name in industry, the scope of each raw material is limited, with described in description
Appearance is defined.
In the present invention, the liquid paraffin and solvent naphtha are synthesized by F- T synthesis, F- T synthesis (Fischer-
Tropsch synthesis) it is one of ICL for Indirect Coal Liquefaction technology, with synthesis gas as raw material is in catalyst (mainly ferrum system) and fits
When the technical process for synthesizing the liquid fuel based on paraffin hydrocarbon under reaction condition.Its course of reaction can be represented with following formula:nCO
+2nH2- → [- CH2-] n+nH2O。
The technological process of F- T synthesis mainly includes that coal gasification, gas purification, conversion and reformation, synthesis and product purification change
The parts such as matter.Hydrogen in synthesis gas is required in 2-2.5 with the mol ratio of carbon monoxide.Reactor is using fixed bed or fluid bed
Two kinds of forms.Reaction temperature 320-340 DEG C, pressure 2.0-2.2MPa.Product form is methane 11%, C2-C4 hydrocarbon 33%, C5-
C8 hydrocarbon 44%, more than C9 hydrocarbon 6%, and oxygenatedchemicalss 6%.
Adopt the advantage of F- T synthesis for:Using the Determination of Alkane Content in the liquid paraffin and solvent naphtha of F- T synthesis it is high, ten
Six alkane values are high, cold filter plugging point and freezing point are low, are substantially free of the element such as aromatic hydrocarbons and sulfur, nitrogen, oxygen, and the more general oil product of quality is more excellent
Matter.
The high definition test oil is compared with common diesel:During as test oil, delay period shortens 14-30%, in advance
Mixed combustion heat release peak value is relatively low, and maximum combustion pressure is lower slightly, and legislation discharge and non-regulation noxious emission are obtained for and significantly drop
Low, wherein NOx and PM averagely reduces respectively 13% and 26%.For Diesel engine or car load emission testing, in tail gas
The indexs such as oxynitride, Hydrocarbon, carbon monoxide and particulate pollutant fully achieve the discharge standard of state five;With
When first charge of oil, act on well for ensureing that new car fuel system and engine performance have, exhaust emissions reaches Europe V marks
It is accurate.
It should be noted that because of the premium properties of heretofore described high definition test oil, the high definition test oil
Can apply and be used as first charge of oil.
Preferably, the high definition test oil also includes following raw material:Antistatic additive, antiwear additive, antioxidant and metallic blunt
Agent.
Vapour, diesel oil easily produce electrostatic accumulation in production, handling and transportation, when electrostatic accumulation is to a certain amount of, hold
Fire hazardous accident.Add micro antistatic additive, the electric conductivity of oil product can be improved, in time derive electrostatic, can in case
Only electrostatic accumulation, it is to avoid fire incident;Antiwear additive is used to improve the abrasion resistance of oil product, reduces the abrasion of oil pump;Antioxidant energy
Enough increase the oxidation stability of the high definition test oil;The matal deactivator can metal surface formed inert coating or with gold
Category ion forms chelate, prevents metal oxidation, with catalysis acceleration of the suppression metal to oxidation reaction, meanwhile, with suitable
Equivalent is combined with antioxidant and shows excellent potentiation, greatly reduces the consumption of antioxidant.
Preferably, the weight portion of the antistatic additive, antiwear additive, antioxidant and matal deactivator is:Antistatic additive
0.0002-0.002 parts, antiwear additive 0.02-0.03 parts, antioxidant 0.02-0.03 parts, matal deactivator 0.002-0.003 parts.
Preferably, the liquid paraffin 2# be alkanes mixture, initial boiling point not less than 175 DEG C, T5 not less than 185 DEG C,
The end point of distillation is not more than 295 DEG C;Not higher than -45 DEG C of freezing point;Sulfur content is not more than 5ppm;Carbon number distribution is C7-C22;Isomeric alkane
Content is not less than 85%;N-alkanes content is not more than 15%.
Preferably, the solvent naphtha is No. 130 solvent naphthas, is alkane and cycloalkane mixture, and initial boiling point is not less than 260
DEG C, T5 not less than 265 DEG C, the end point of distillation be not more than 298 DEG C;Not higher than -20 DEG C of freezing point;Sulfur content is not more than 5ppm;Bromine index
No more than 50mgBr/100g.
Preferably, the light paraffinic be alkanes mixture, initial boiling point not less than 168 DEG C, T50 not less than 225 DEG C,
T90 is not more than 290 DEG C not less than 270 DEG C, T95 not less than 280 DEG C, the end point of distillation;Not higher than -25 DEG C of freezing point;Sulfur content is little
In 6ppm;Cetane lndex is not less than 50.
Preferably, the middle matter paraffin be alkanes mixture, initial boiling point not less than 168 DEG C, T50 not less than 250 DEG C,
T90 is not more than 330 DEG C not less than 305 DEG C, T95 not less than 320 DEG C, the end point of distillation;Not higher than -30 DEG C of freezing point;Sulfur content is little
In 6ppm;Cetane lndex is not less than 70.
It should be noted that heretofore described T5, T50, T90, T95 is the general distillation term of petroleum industry:
T5 represent distillation account for cumulative volume as 5% when temperature, T50 represent distillation account for cumulative volume as 50% when temperature, T90 represent
Distillation accounts for temperature when cumulative volume is 90%, T95 represent distillation account for cumulative volume as 95% when temperature.
Preferably, the antistatic additive is the ashless diesel oil antistatic additive of polysulfones/polyamine type;Water separation index is not less than 70,
Electrical conductivity is not less than 200ps/m.
Preferably, the antiwear additive is fatty acid ester antiwear additive, and its acid number is not more than 2mgKOH/g, condensation point not higher than-
16 DEG C, sulfur content is not more than 100mg/kg, such as in R665, Beijing of profit English connection unit into CY102D, with carbon number as 12-18
Fatty acid and polyhydric alcohol be raw material, esterification is carried out under catalyst action, obtain fatty acid of the purity more than 95%
Polyol ester.
Preferably, the antioxidant is 2,6 ditertiary butyl p cresol, and its just fusing point is 69-70 DEG C, free cresol
No more than 0.015% (m/m).DBPC 2,6 ditertiary butyl p cresol is to adopt the oil product addition obtained in raw material of paracresol and isobutene.
Agent, the agent oil-soluble is good, water insoluble and caustic soda.
Preferably, the matal deactivator is benzotriazole derivant, and 20 DEG C of density are 910-1040kg/m3,50 DEG C of motions
Viscosity 10-14mm2/ s, base number 210-230mgKOH/g, oxidation test (increment) are not less than 90min.
It should be noted that the first charge of oil in the present invention is industrial product, it is raw materials used be the commercially available raw material of industry or
The satisfactory raw material of homemade parameter.Although industrial products generally mixture, but as long as meeting the parameter, it becomes possible to protect
The final end product quality of card, so the protection domain beyond application claims can not be considered as.
Present invention also offers a kind of preparation method of the high definition test oil, comprises the following steps:
The raw material is added in Mixer pot according to aforementioned proportion, mix homogeneously.
Because the most of raw material for the commercially available raw material of industry, different brands and batch of raw material that the present invention is adopted, even if
Model is the same, also has qualitative fluctuation, thus for ensure final finished quality, the present invention in preparation method contain
The step of detection:After mix homogeneously, then sample, after analysis is qualified the high definition test oil is obtained.
If no special instructions, in the present invention, all of part, percentage ratio are unit of weight, all of equipment and raw material etc.
It is commercially available or the industry is conventional.
Beneficial effects of the present invention are:
1st, the invention provides a kind of high definition test oil, the high definition test oil steady quality, cleannes are high, while
With good oxidation stability and low-temperature startup, disclosure satisfy that and used and test requirements document under harsh environmental conditions.
2nd, when the high definition test oil in the present invention is as test oil, delay period shortens 14-30%, and premixed combustion is put
Thermal peak is relatively low, and maximum combustion pressure is lower slightly, and legislation discharge and non-regulation noxious emission are obtained for and are greatly lowered, wherein
NOx and PM averagely reduce respectively 13% and 26%.For Diesel engine or car load emission testing, the nitrogen oxidation in tail gas is closed
The indexs such as thing, Hydrocarbon, carbon monoxide and particulate pollutant fully achieve the discharge standard of state five;For first charge of oil
When, acting on well for ensureing that new car fuel system and engine performance have, exhaust emissions reaches Europe V standards.
3rd, the first charge of oil component in the present invention is pure clean, and harmful substance is such as:Harmful metal elements, sulfur, phosphorus, chlorine, machinery
Impurity particle equal size is extremely low, thus oil corrosion is extremely low, and detergency very well, is conducive to protecting electromotor to use function.
4th, the first charge of oil in the present invention, raw material is easy to get, and directly can buy from market.
5th, the preparation method in the present invention, has the advantages that easy to operate, finished product is stable.
Specific embodiment
With reference to embodiment, present disclosure is further illustrated.It should be appreciated that the enforcement of the present invention is not limited to
In the following examples, any pro forma flexible and/or change made to the present invention falls within the scope of the present invention.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, and all of equipment and raw material etc. are
It is commercially available or the industry is conventional.Method in following embodiments, if no special instructions, is the routine of this area
Method.
The species and consumption of raw material, specifically refers to table 1 in list below explanation embodiment 1-6
Table 1:Embodiment 1-6 materials table
According to the materials of each component in upper table, it is prepared as follows:
The raw material is added in Mixer pot according to aforementioned proportion, then mix homogeneously samples, obtained after analysis is qualified
The high definition test oil.
It should be noted that raw material used meets the parameter request of description.In addition, in embodiment 4 and 5:It is described anti-
Electrostatic agent is Ashless type antistatic additive T1502, and the antiwear additive is the R665 for moistening English connection;Antistatic additive used in embodiment 6
For Ashless type antistatic additive T1503, the antiwear additive be in Beijing unit into CY102D;In embodiment 4-6, the antioxidant is
T501, the matal deactivator is T551.
In order to further verify the product quality of first charge of oil in the present invention, spy does following detection, and concrete testing result is shown in Table
2:
Table 2:Testing result table
As can be seen from Table 1 and Table 2, in each component amount ranges given by the present invention, indices are obtained equal
The high-quality oil product of weighing apparatus.The oil product has advantage following prominent:
1st, due to the antioxidant and matal deactivator of introducing in the high definition test oil, thus with thermally-stabilised well
Property and non-oxidizability, be not likely to produce colloid etc harmful substance, it is ensured that sealing storage more than 1 year, oil product never degenerates;
2nd, high definition test oil totality fraction is partially lighter than ordinary diesel oil, and with extremely low cold filter plugging point, thus low temperature
Startability is very good, is particularly suitable for severe cold area use in winter, it is ensured that vehicle launch is smooth;
3rd, the component in the high definition test oil is very pure, substantially without alkene and aromatic hydrocarbons, harmful substance (metal unit
Element, sulfur, particulate matter) content is extremely low, thus oil corrosion is extremely low, detergency very well, is conducive to protecting electromotor.
Commercial production is implemented with the scheme of example 6, the multiple batches of examination and test of products the results are shown in Table 3.
Table 3:Different batches testing result table
Never with production batch from the point of view of, product quality is highly stable, from June 30th, 2015 start commercial production, to mesh
It is front to have produced 12 batches,.
Domestic certain Automobile Enterprises test oil, Tianjin with the Europe five of the high definition test oil in the present invention, European import respectively
The diesel oil of state five of petrochemical industry and Yanshan Petrochemical carries out under the same test conditions emission testing, and result of the test is shown in Table 4.
Table 4:Emission testing testing result table
As shown in Table 4, compared with the 0# diesel oil of European Europe five, Plant of Tianjin Petrochemical Company and the 0# oil products of Yanshan Petrochemical state five are to each of discharge
Pollutant effect is higher, affects maximum to CO, thus it is believed that the 0# oil products of state five of above-mentioned two company are not useable for discharge
Test;High definition test oil in the present invention is higher to NOx 9.16%, PM low 53.75%, and remaining discharges pollutants and can be considered
Without impact, thus it is believed that this oil product can be used for emission testing.
It should be noted last that, above example is only unrestricted to illustrate technical scheme, although ginseng
The present invention is described in detail according to preferred embodiment, should be understood that and be the foregoing is only being embodied as the present invention
Mode, the protection domain being not intended to limit the present invention, it is all within the spirit and principles in the present invention, done any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (5)
1. a kind of high definition test oil, it is characterised in that be mainly made up of the raw material of following weight portion:Liquid paraffin 10-20 parts
With solvent naphtha 2-8 parts;
The liquid paraffin includes liquid paraffin 2#, light paraffinic and middle matter paraffin, wherein the liquid paraffin 2#, light paraffinic
It is 40-60 with the mass ratio of middle matter paraffin:20-30:20-30;
The liquid paraffin 2# is alkanes mixture, and initial boiling point is not more than not less than 175 DEG C, T5 not less than 185 DEG C, the end point of distillation
295℃;Not higher than -45 DEG C of freezing point;Sulfur content is not more than 5ppm;Carbon number distribution is C7-C22;Isomeric alkane content is not less than
85%;N-alkanes content is not more than 15%;
The light paraffinic is alkanes mixture, and initial boiling point is not less than 270 not less than 168 DEG C, T50 not less than 225 DEG C, T90
DEG C, T95 not less than 280 DEG C, the end point of distillation be not more than 290 DEG C;Not higher than -25 DEG C of freezing point;Sulfur content is not more than 6ppm;Hexadecane
Index is not less than 50;
The middle matter paraffin is alkanes mixture, and initial boiling point is not less than 305 not less than 168 DEG C, T50 not less than 250 DEG C, T90
DEG C, T95 not less than 320 DEG C, the end point of distillation be not more than 330 DEG C;Not higher than -30 DEG C of freezing point;Sulfur content is not more than 6ppm;Hexadecane
Index is not less than 70;
The solvent naphtha is No. 130 solvent naphthas, is alkane and cycloalkane mixture, and initial boiling point is not less than not less than 260 DEG C, T5
265 DEG C, the end point of distillation be not more than 298 DEG C;Not higher than -20 DEG C of freezing point;Sulfur content is not more than 5ppm;Bromine index is not more than
50mgBr/100g。
2. high definition test oil according to claim 1, it is characterised in that also including following raw material:It is antistatic additive, wear-resistant
Agent, antioxidant and matal deactivator.
3. high definition test oil according to claim 2, it is characterised in that the antistatic additive, antiwear additive, antioxidant and
The weight portion of matal deactivator is:Antistatic additive 0.0002-0.002 parts, antiwear additive 0.02-0.03 parts, antioxidant 0.02-0.03
Part and matal deactivator 0.002-0.003 parts.
4. the high definition test oil according to Claims 2 or 3, it is characterised in that the antistatic additive is polysulfones/polyamine type
Ashless diesel oil antistatic additive;The antiwear additive is fatty acid ester antiwear additive;The antioxidant is 2,6 ditertiary butyl p cresol;
The matal deactivator is benzotriazole derivant.
5. the preparation method of the arbitrary described high definition test oil of a kind of claim 1-3, it is characterised in that including following step
Suddenly:
The raw material is added in Mixer pot according to aforementioned proportion, mix homogeneously.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610080656.8A CN105567346B (en) | 2016-02-04 | 2016-02-04 | High-definition test oil and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610080656.8A CN105567346B (en) | 2016-02-04 | 2016-02-04 | High-definition test oil and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105567346A CN105567346A (en) | 2016-05-11 |
CN105567346B true CN105567346B (en) | 2017-04-26 |
Family
ID=55877987
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610080656.8A Active CN105567346B (en) | 2016-02-04 | 2016-02-04 | High-definition test oil and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105567346B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108329957B (en) * | 2018-04-25 | 2020-02-07 | 河北帅征清洁能源有限公司 | Vehicle diesel suitable for plateau area and preparation method thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20021131A1 (en) * | 2002-05-24 | 2003-11-24 | Agip Petroli | ESSENTIAL HYDROCARBON COMPOSITIONS USED AS FUELS WITH IMPROVED LUBRICANT PROPERTIES |
WO2007024747A2 (en) * | 2005-08-22 | 2007-03-01 | Shell Internationale Research Maatschappij B.V. | A diesel fuel and a method of operating a diesel engine |
EP2011851A4 (en) * | 2006-03-31 | 2011-05-25 | Nippon Oil Corp | Light oil compositions |
EP2046923B1 (en) * | 2006-07-27 | 2016-12-28 | Shell Internationale Research Maatschappij B.V. | Use of fuel compositions |
US8152866B2 (en) * | 2009-05-13 | 2012-04-10 | GM Global Technology Operations LLC | Synthetic diesel fuel compositions |
-
2016
- 2016-02-04 CN CN201610080656.8A patent/CN105567346B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN105567346A (en) | 2016-05-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR20130036355A (en) | Biodiesel fuels | |
US8748678B2 (en) | Formula for joint synthetic jet, rocket, and diesel fuel | |
CN103666595A (en) | Clean gasoline for replacing ethanol and methanol gasoline and preparation method of clean gasoline | |
CN101914393B (en) | Methanol gasoline for vehicles and preparation method thereof | |
CN101906329A (en) | Methanol gasoline for vehicles and preparation method thereof | |
CN101240200B (en) | Vehicular methanol cleaning fuel | |
CN100545245C (en) | A kind of composite gasoline additive and preparation method thereof | |
CN101851534B (en) | Dissolution-assisting and upgrading agent for M30 methanol gasoline | |
CN102766490A (en) | Composite biodiesel | |
CN105567346B (en) | High-definition test oil and preparation method thereof | |
CN101580747A (en) | Fuel composition capable of meeting motor vehicle pollutant emission limit | |
CN104611075A (en) | Blended gasoline and preparation method thereof | |
SG172323A1 (en) | Fuel compositions | |
EP3022278B1 (en) | High power fuel compositions | |
CN106893613A (en) | A kind of combined diesel oil | |
CN106987286B (en) | A kind of ether-base gasoline of clean and environmental protection and preparation method thereof | |
CN107099347B (en) | A kind of ether diesel oil of clean and environmental protection and preparation method thereof | |
CN100467569C (en) | Biochemical alcohol, fuel generated by far-infrared technology and production method thereof | |
CN104194843B (en) | High energy Alcohol group biodiesel and preparation method thereof | |
CN104109564A (en) | High-cleanness pure blended gasoline and preparation method thereof | |
Al-Bayati et al. | Determination of the Optimum formula for Composite Motor Gasoline Octane Number Blending Enhancer | |
CN101497825A (en) | Methanol diesel | |
CN101760255A (en) | Methanol gasoline and preparation method thereof | |
EP2370557A1 (en) | Fuel compositions | |
US10407637B2 (en) | Fuel composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20161213 Address after: 102500 Yanshan Fangshan District Beijing South Road, No. 2 Applicant after: Beijing Zhongyan Hengcheng Energy Co. Ltd. Address before: 102400 Yanshan Fangshan District Beijing South Road, No. 2 Applicant before: BEIJING ZHONGYUANCHENG ENERGY TECHNOLOGY CO., LTD. |
|
GR01 | Patent grant | ||
GR01 | Patent grant |