CN108359501A - A kind of novel automobile coal alcohol compound bio fuel and preparation method thereof - Google Patents

A kind of novel automobile coal alcohol compound bio fuel and preparation method thereof Download PDF

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Publication number
CN108359501A
CN108359501A CN201810136669.1A CN201810136669A CN108359501A CN 108359501 A CN108359501 A CN 108359501A CN 201810136669 A CN201810136669 A CN 201810136669A CN 108359501 A CN108359501 A CN 108359501A
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parts
oil
novel automobile
complex biological
alcohol complex
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车春玲
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Shandong Lianxing Energy Group Co Ltd
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Shandong Lianxing Energy Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention belongs to bio-fuel technical fields, and in particular to a kind of novel automobile coal alcohol complex biological fuel includes the component of following parts by weight:30 40 parts of bio-ethanol, 20 30 parts of methanol, 15 25 parts of isomery oil, 15 25 parts of aromatization oil, 10 15 parts of C9 plus 15 20 parts of hydrogen light tar, 10 15 parts of food waste edible oil, 10 15 parts of glyceryl triacetate, 15 parts of MTBE10,5 10 parts of isobutanol, 5 10 parts of octanol, 10 15 parts of dimethoxym ethane.Novel automobile coal alcohol complex biological fuel each component of the present invention cooperates, and burning, fully thorough, combustion heat value is high, and fuel value is up to 46000kJ/kg.Novel automobile coal alcohol complex biological fuel provided by the invention is as alternative fuel efficiently, environmentally friendly with larger development potentiality and important economic benefit, social value.

Description

A kind of novel automobile coal alcohol compound bio fuel and preparation method thereof
Technical field
The invention belongs to bio-fuel technical fields, and in particular to a kind of novel automobile coal alcohol complex biological fuel and its Preparation method.
Background technology
Bio-fuel refers to the solid, liquid or gaseous fuel for being made of or extracting biomass, can substitute by oil system The gasoline and diesel oil taken is the important directions that regenerative resource develops and uses.Alcohol-based fuel has sanitation and hygiene, environmentally protective Advantage, however it has the shortcomings that calorific value is low, power is small.Coal derived fuel is with startup performance of engine is good, has good burning performance, moves The big advantage of power, however its burning will produce the pernicious gases such as nitrogen, sulfide, environmental pollution is larger.Therefore, a kind of energy is studied Comprehensive alcohol-based fuel and the bio-fuel of coal derived fuel advantage are of great significance.
Technical solution
To solve above-mentioned problems of the prior art, the present invention provides a kind of novel automobile coal alcohol complex biological fuel, Concrete scheme is as follows.
A kind of novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:30-40 parts of bio-ethanol, 20-30 parts of methanol, 15-25 parts of isomery oil, 15-25 parts of aromatization oil, 10-15 parts of C9 plus 15-20 parts of hydrogen light tar, food waste 10-15 parts of edible oil, 10-15 parts of glyceryl triacetate, MTBE10-15 parts, 5-10 parts of isobutanol, 5-10 parts of octanol, dimethoxym ethane 10-15 parts.
Preferably, the novel automobile coal alcohol complex biological fuel further includes 3-8 portions of combustion adjuvants, the combustion adjuvant It is 1 for weight ratio:1.5:3 hexyl ether, dimethyl ether, methyl tertiary butyl ether(MTBE)..
Preferably, the novel automobile coal alcohol complex biological fuel further includes 5-8 parts of stabilizers, the stabilizer It is di-tert-butyl p-cresol for weight ratio.
Preferably, the novel automobile coal alcohol complex biological fuel further includes 5-8 parts of anti-knock agents, the anti-knock agent For methyl cyclic diolefine manganese tricarbonyl.
Preferably, the novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:Biological second 30 parts of alcohol, 30 parts of methanol, 25 parts of isomery oil, 15 parts of aromatization oil, 10 parts of C9 plus 20 parts of hydrogen light tar, food waste edible oil 10 Part, 15 parts of glyceryl triacetate, MTBE15 parts, 5 parts of isobutanol, 5 parts of octanol, 10 parts, 3 portions combustion adjuvants of dimethoxym ethane, 5 parts of stabilizations Agent, 8 parts of anti-knock agents.
Preferably, the novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:Biological second 40 parts of alcohol, 20 parts of methanol, 15 parts of isomery oil, 25 parts of aromatization oil, 15 parts of C9 plus 15 parts of hydrogen light tar, food waste edible oil 15 Part, 10 parts of glyceryl triacetate, MTBE10 parts, 10 parts of isobutanol, 5 parts of octanol, 15 parts, 8 portions combustion adjuvants of dimethoxym ethane, 8 parts of stabilizations Agent, 5 parts of anti-knock agents.
Preferably, the novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:Biological second 35 parts of alcohol, 25 parts of methanol, 20 parts of isomery oil, 22 parts of aromatization oil, 11 parts of C9 plus 18 parts of hydrogen light tar, food waste edible oil 13 Part, 14 parts of glyceryl triacetate, MTBE12 parts, 8 parts of isobutanol, 8 parts of octanol, 13 parts, 5 portions combustion adjuvants of dimethoxym ethane, 6 parts of stabilizations Agent, 6 parts of anti-knock agents.
The invention also discloses the preparation methods of above-mentioned novel automobile coal alcohol complex biological fuel, and specific technical solution is such as Under.
The preparation method of novel automobile coal alcohol complex biological fuel, includes the following steps:It, will under normal temperature and pressure conditions Bio-ethanol, methanol, octanol, dimethoxym ethane isobutanol are added in configurator and are uniformly mixed, be then added isomery oil, aromatization oil, C9, Add hydrogen light tar, food waste edible oil be uniformly mixed, sequentially add glyceryl triacetate, MTBE, combustion adjuvant, anti-knock agent, Stabilizer is uniformly mixed;Then by above-mentioned mixed raw material by explosion-proof centrifugal pump circulation mix 2-3h, be then allowed to stand 1h to get To the novel automobile coal alcohol complex biological fuel.
Advantageous effect
(1)Novel automobile coal alcohol complex biological fuel of the present invention is using bio-ethanol, methanol plus hydrogen lightweight coal tar As main combustion component, combustion heat value is high, is greatly improved the power of fuel for oil, food waste edible oil;C9 improves component as calorific value, The calorific value of fuel can significantly be improved;Isomery oil can reduce the density of fuel;Aromatization oil is greatly improved the octane number of fuel, from And improve anti-knock index;MTBE is excellent gasoline high-octane rating additive and anti-knock agent, can improve the anti-knock index of fuel, Its susceptibility is reduced, safety is increased;Octanol, dimethoxym ethane are added as cosolvent, each component can be made to dissolve each other;Triacetic acid glycerine Ester with other material combinations in addition to can improve outside the flash-point of fuel, additionally it is possible to form protective film in metallic surface, corruption has been isolated Contact of the substance with metal surface is lost, prevents burning to corrosion of metal so as to play, enhances the corrosion resistance of fuel Energy;The addition of combustion adjuvant can greatly improve the calorific value of fuel;Stabilizer is added and can guarantee the quality of fuel in use Stablize, the main function of anti-knock agent is antiknock, can greatly improve the safety of fuel..
(2)Novel automobile coal alcohol complex biological fuel each component of the present invention cooperates, burn fully thoroughly, Combustion heat value is high, and fuel value is up to 46000kJ/kg.Novel automobile coal alcohol complex biological fuel conduct provided by the invention Efficiently, environmentally friendly alternative fuel has larger development potentiality and important economic benefit, social value.It is of the present invention new The preparation method of the automobile-used coal alcohol complex biological fuel of type, manufacture craft is simple, does not need Pressurized-heated, easily operated, can be big Large-scale production.
Specific implementation mode
Embodiment 1
A kind of novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:
30 parts of bio-ethanol, 30 parts of methanol, 25 parts of isomery oil, 15 parts of aromatization oil, 10 parts of C9 plus 20 parts of hydrogen light tar, kitchen 10 parts of remaining edible oil, 15 parts of glyceryl triacetate, MTBE15 parts, 5 parts of isobutanol, 5 parts of octanol, 10 parts of dimethoxym ethane, 3 parts it is combustion-supporting Agent, 5 parts of stabilizers, 8 parts of anti-knock agents.
The combustion adjuvant is that weight ratio is 1:1.5:3 hexyl ether, dimethyl ether, methyl tertiary butyl ether(MTBE).
The stabilizer is that weight ratio is di-tert-butyl p-cresol.
The anti-knock agent is methyl cyclic diolefine manganese tricarbonyl.
The calorific value of the novel automobile coal alcohol complex biological fuel is 44000kJ/kg.
The preparation method of above-mentioned novel automobile coal alcohol complex biological fuel, includes the following steps:In normal temperature and pressure conditions Under, bio-ethanol, methanol, octanol, dimethoxym ethane isobutanol are added in configurator and are uniformly mixed, isomery oil, aromatization is then added Oil, C9 plus hydrogen light tar, food waste edible oil are uniformly mixed, and are sequentially added glyceryl triacetate, MTBE, combustion adjuvant, are resisted Detonator, stabilizer are uniformly mixed;Then above-mentioned mixed raw material is mixed into 2-3h by explosion-proof centrifugal pump circulation, be then allowed to stand 1h is to get to the novel automobile coal alcohol complex biological fuel.
Embodiment 2
A kind of novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:
40 parts of bio-ethanol, 20 parts of methanol, 15 parts of isomery oil, 25 parts of aromatization oil, 15 parts of C9 plus 15 parts of hydrogen light tar, kitchen 15 parts of remaining edible oil, 10 parts of glyceryl triacetate, MTBE10 parts, 10 parts of isobutanol, 5 parts of octanol, 15 parts of dimethoxym ethane, 8 parts it is combustion-supporting Agent, 8 parts of stabilizers, 5 parts of anti-knock agents.
The combustion adjuvant is that weight ratio is 1:1.5:3 hexyl ether, dimethyl ether, methyl tertiary butyl ether(MTBE).
The stabilizer is that weight ratio is di-tert-butyl p-cresol.
The anti-knock agent is methyl cyclic diolefine manganese tricarbonyl.
The calorific value of the novel automobile coal alcohol complex biological fuel is 46000kJ/kg.
The preparation method of above-mentioned novel automobile coal alcohol complex biological fuel, includes the following steps:In normal temperature and pressure conditions Under, bio-ethanol, methanol, octanol, dimethoxym ethane isobutanol are added in configurator and are uniformly mixed, isomery oil, aromatization is then added Oil, C9 plus hydrogen light tar, food waste edible oil are uniformly mixed, and are sequentially added glyceryl triacetate, MTBE, combustion adjuvant, are resisted Detonator, stabilizer are uniformly mixed;Then above-mentioned mixed raw material is mixed into 2-3h by explosion-proof centrifugal pump circulation, be then allowed to stand 1h is to get to the novel automobile coal alcohol complex biological fuel.
Embodiment 3
A kind of novel automobile coal alcohol complex biological fuel, includes the component of following parts by weight:
35 parts of bio-ethanol, 25 parts of methanol, 20 parts of isomery oil, 22 parts of aromatization oil, 11 parts of C9 plus 18 parts of hydrogen light tar, kitchen 13 parts of remaining edible oil, 14 parts of glyceryl triacetate, MTBE12 parts, 8 parts of isobutanol, 8 parts of octanol, 13 parts of dimethoxym ethane, 5 parts it is combustion-supporting Agent, 6 parts of stabilizers, 6 parts of anti-knock agents.
The combustion adjuvant is that weight ratio is 1:1.5:3 hexyl ether, dimethyl ether, methyl tertiary butyl ether(MTBE).
The stabilizer is that weight ratio is di-tert-butyl p-cresol.
The anti-knock agent is methyl cyclic diolefine manganese tricarbonyl.
The calorific value of the novel automobile coal alcohol complex biological fuel is 43000kJ/kg.
The preparation method of above-mentioned novel automobile coal alcohol complex biological fuel, includes the following steps:In normal temperature and pressure conditions Under, bio-ethanol, methanol, octanol, dimethoxym ethane isobutanol are added in configurator and are uniformly mixed, isomery oil, aromatization is then added Oil, C9 plus hydrogen light tar, food waste edible oil are uniformly mixed, and are sequentially added glyceryl triacetate, MTBE, combustion adjuvant, are resisted Detonator, stabilizer are uniformly mixed;Then above-mentioned mixed raw material is mixed into 2-3h by explosion-proof centrifugal pump circulation, be then allowed to stand 1h is to get to the novel automobile coal alcohol complex biological fuel.

Claims (8)

1. a kind of novel automobile coal alcohol complex biological fuel, which is characterized in that include the component of following parts by weight:Bio-ethanol 30-40 parts, 20-30 parts of methanol, 15-25 parts of isomery oil, 15-25 parts of aromatization oil, 10-15 parts of C9 plus hydrogen light tar 15- 20 parts, 10-15 parts of food waste edible oil, 10-15 parts of glyceryl triacetate, MTBE10-15 parts, 5-10 parts of isobutanol, octanol 5-10 Part, 10-15 parts of dimethoxym ethane.
2. novel automobile coal alcohol complex biological fuel according to claim 1, which is characterized in that further include 3-8 parts and help Agent is fired, the combustion adjuvant is that weight ratio is 1:1.5:3 hexyl ether, dimethyl ether, methyl tertiary butyl ether(MTBE).
3. novel automobile coal alcohol complex biological fuel according to claim 2, which is characterized in that further include 5-8 parts steady Determine agent, the stabilizer is that weight ratio is di-tert-butyl p-cresol.
4. novel automobile coal alcohol complex biological fuel according to claim 3, which is characterized in that further include 5-8 parts anti- Detonator, the anti-knock agent are methyl cyclic diolefine manganese tricarbonyl.
5. novel automobile coal alcohol complex biological fuel according to claim 4, which is characterized in that including following parts by weight Component:30 parts of bio-ethanol, 30 parts of methanol, 25 parts of isomery oil, 15 parts of aromatization oil, 10 parts of C9 plus hydrogen light tar 20 Part, 10 parts of food waste edible oil, 15 parts of glyceryl triacetate, MTBE15 parts, 5 parts of isobutanol, 5 parts of octanol, 10 parts, 3 parts of dimethoxym ethane Combustion adjuvant, 5 parts of stabilizers, 8 parts of anti-knock agents.
6. novel automobile coal alcohol complex biological fuel according to claim 4, which is characterized in that including following parts by weight Component:40 parts of bio-ethanol, 20 parts of methanol, 15 parts of isomery oil, 25 parts of aromatization oil, 15 parts of C9 plus hydrogen light tar 15 Part, 15 parts of food waste edible oil, 10 parts of glyceryl triacetate, MTBE10 parts, 10 parts of isobutanol, 5 parts of octanol, 15 parts, 8 parts of dimethoxym ethane Combustion adjuvant, 8 parts of stabilizers, 5 parts of anti-knock agents.
7. novel automobile coal alcohol complex biological fuel according to claim 4, which is characterized in that including following parts by weight Component:35 parts of bio-ethanol, 25 parts of methanol, 20 parts of isomery oil, 22 parts of aromatization oil, 11 parts of C9 plus hydrogen light tar 18 Part, 13 parts of food waste edible oil, 14 parts of glyceryl triacetate, MTBE12 parts, 8 parts of isobutanol, 8 parts of octanol, 13 parts, 5 parts of dimethoxym ethane Combustion adjuvant, 6 parts of stabilizers, 6 parts of anti-knock agents.
8. according to the preparation method of any novel automobile coal alcohol complex biological fuel of claim 1-7, feature exists In including the following steps:Under normal temperature and pressure conditions, configurator is added in bio-ethanol, methanol, octanol, dimethoxym ethane isobutanol In be uniformly mixed, isomery oil, aromatization oil, C9 is then added, adds hydrogen light tar, food waste edible oil uniformly mixed, then successively Glyceryl triacetate, MTBE, combustion adjuvant, anti-knock agent, stabilizer is added to be uniformly mixed;Then above-mentioned mixed raw material is passed through anti- Quick-fried centrifugation pump circulation mixes 2-3h, is then allowed to stand 1h to get to the novel automobile coal alcohol complex biological fuel.
CN201810136669.1A 2018-02-09 2018-02-09 A kind of novel automobile coal alcohol compound bio fuel and preparation method thereof Pending CN108359501A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113122343A (en) * 2021-04-25 2021-07-16 任新付 Synthetic diesel oil and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948702A (en) * 2010-09-30 2011-01-19 昆明理工大学 Alcohol-based biological fuel oil for boiler and preparation method thereof
CN104357101A (en) * 2014-11-06 2015-02-18 金景达(北京)环保动力科技有限公司 High-efficiency stable composite biodiesel fuel
CN104818056A (en) * 2015-04-28 2015-08-05 中源新能源(福建)有限公司 High-cleanness automotive methanol diesel oil and preparation method thereof
CN106497616A (en) * 2016-11-30 2017-03-15 广西东奇能源技术有限公司 Environment protection biological fuel
CN106635194A (en) * 2016-12-30 2017-05-10 广西东奇能源技术有限公司 Alcohol-based biofuel for vehicles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948702A (en) * 2010-09-30 2011-01-19 昆明理工大学 Alcohol-based biological fuel oil for boiler and preparation method thereof
CN104357101A (en) * 2014-11-06 2015-02-18 金景达(北京)环保动力科技有限公司 High-efficiency stable composite biodiesel fuel
CN104818056A (en) * 2015-04-28 2015-08-05 中源新能源(福建)有限公司 High-cleanness automotive methanol diesel oil and preparation method thereof
CN106497616A (en) * 2016-11-30 2017-03-15 广西东奇能源技术有限公司 Environment protection biological fuel
CN106635194A (en) * 2016-12-30 2017-05-10 广西东奇能源技术有限公司 Alcohol-based biofuel for vehicles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113122343A (en) * 2021-04-25 2021-07-16 任新付 Synthetic diesel oil and preparation method thereof

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