CN105296023A - Fuel additive and preparation method thereof - Google Patents

Fuel additive and preparation method thereof Download PDF

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Publication number
CN105296023A
CN105296023A CN201510643080.7A CN201510643080A CN105296023A CN 105296023 A CN105296023 A CN 105296023A CN 201510643080 A CN201510643080 A CN 201510643080A CN 105296023 A CN105296023 A CN 105296023A
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parts
fuel
fuel oil
water
zinc salt
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CN201510643080.7A
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CN105296023B (en
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丘濠玮
丘寿勇
丘福全
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Qiu Haowei
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Abstract

The invention discloses a fuel additive. The fuel additive is prepared from the following raw materials in parts by weight: 50 to 80 parts of tourmaline nanometer powder, 10 to 20 parts of alcohol, 30 to 50 parts of diisopropyl ether, 10 to 20 parts of biological oil, 5 to 10 parts of antioxidant, 5 to 10 parts of dispersant and 5 to 30 parts of water. The preparation method of the fuel additive comprises the step of uniformly mixing all of the raw materials at normal temperature and pressure. By using the fuel additive, the fuel quality can be improved, fuel is promoted to fully burn, the burning efficiency is improved, and the fuel is saved; the atomization quality of the fuel can be increased, so that the fuel fully burns, the emission of noxious gas is reduced, and the purposes of energy conservation and emission reduction are achieved.

Description

A kind of fuel oil additive and preparation method thereof
Technical field
The present invention relates to the preparation method of energy-saving and emission-reduction fuel activating additive, be specifically related to a kind of fuel oil additive and preparation method thereof.
Background technology
Energy-saving and emission-reduction are task of top priority of world today's energy scarcity, and the efficiency of combustion of fuel oil directly affects the effect of energy-saving and emission-reduction, and fuel oil additive can improve oil, promote fuel oil Thorough combustion, improve efficiency of combustion, save fuel oil; Its atomization quality can be improved, make fuel oil Thorough combustion reduce noxious gas emission, reach the object of energy-saving and emission-reduction.
In field of internal combustion engine, in order to improve fuel combustion efficiency, increase output rating, reduction oil consumption, decarbonizing minimizing noxious gas emission, mainly contain two technological approaches at present: one is add or reforming equipment (as various fuel-economizing, reinforcement, cleaner), two is drop into additive to fuel oil.The investment of first approach is large, program is loaded down with trivial details, also increase car and boat deadweight and maintenance difficulty, thus second approach more people accepted.But the fuel oil additive delivered at present exists one of following shortcoming or several mostly: one, save fuel oil, to promote the effect of power undesirable, what have also reduces dynamic performance, and this is current fuel oil additive can not be the generally accepted major cause of users; Two, obviously can not reduce engine noise, what have also add engine noise; Three, easily cause " secondary pollution "---the additive that-dependence chemical reaction works, while performance usefulness, public hazards thing that some have aroused attention or have not yet aroused attention, more difficult natural degradation may be generated, thus become the hidden danger of businessman and the public, such as famous additive MTBE (methyl tertiary butyl ether), after the U.S. passes unimpeded 20 years, be found it can increase oxynitride discharge, especially seriously can permanent polluted source (even deep phreatic water), be thus limited to use; Four, usefulness is unstable: because the component of fuel oil is very complicated, the same label fuel oil technique in process of production that different manufacturers is produced and added ingredients are different, the same label product of even same producer, raw material sources difference due to different batches also can cause the difference of product composition, formally because this uncertainty makes the additive mainly relying on chemical agent to work often can not stablize performance usefulness, and easily produce the adverse consequences such as " secondary pollution " and parts corrosion.
Current existing fuel oil octane promoter unit cost too high and use time addition excessive (being everlasting between 5 ~ 15%), cause octane promoter in high standard fuel price price ratio remain high.When current fuel price rises violently day by day, reduce the cost that one of effective way of fuel price is the additive greatly reduced for promoting gasoline label and diesel cetane-number.
Summary of the invention
Object of the present invention is exactly the defect existed to overcome above-mentioned prior art, and provide a kind of fuel oil additive and preparation method thereof, fuel oil additive of the present invention can improve oil, promotes fuel oil Thorough combustion, improves efficiency of combustion, saves fuel oil; Its atomization quality can be improved, make fuel oil Thorough combustion reduce noxious gas emission, reach the object of energy-saving and emission-reduction.
In order to realize foregoing invention object, technical scheme of the present invention is as follows:
Fuel oil additive of the present invention, is made up of the raw material comprising following weight part: tourmalinite nano powder 50 ~ 80 parts, ethanol 10 ~ 20 parts, diisopropyl ether 30 ~ 50 parts, bio oil 10 ~ 20 parts, antioxidant 5 ~ 10 parts, dispersion agent 5 ~ 10 parts, 5 ~ 30 parts, water.
Described antioxidant is the mixing of the one or more than one in sulphur phosphorus fourth pungent primary alkyl zinc salt, the two pungent primary alkyl zinc salt of sulphur phosphorus, the two pungent primary alkyl zinc salt of alkali formula sulphur phosphorus, the pungent secondary primary alkyl zinc salt of sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt.
Described dispersion agent is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutylene succinamide, high molecular weight polyisobutylene base succimide, one or more kinds of mixing in boronation high molecular weight polyisobutylene base succimide.
Described water is pure water, mineral water or other clean waters.
The preparation method of described fuel oil additive is:
At normal temperatures and pressures, described tourmalinite nano powder, dehydrated alcohol, diisopropyl ether, bio oil, antioxidant, dispersion agent, water are mixed by weight ratio, stirs, to obtain final product.
Described stirring velocity is 8000 ~ 12000r/min, churning time 10 ~ 90min.
Fuel activating agent of the present invention has strong characteristic nmr, nucleus magnetic resonance makes the molecule containing H atom in fuel be provided with positive and negative electrode feature, molecular arrangement becomes uniform from confusing, the conductivity of fuel is strengthened greatly, and thus the ability of unified ignition, synchronousing combustion is enhanced.Two factors are all impelled fuel synchronously to break out, are carried out simultaneously, and the inevitable outcome of so expecting synchronous outburst is that pinking is eliminated, and pinking eliminates, and the in-fighting problem of engine also just solves.Equal the useful work adding 30%, that is reduce by the fuel consumption of 30%.Visible, tourmalinite composition strengthens the energy-saving effect of additive greatly, and the consumption of fuel declines, the quantity discharged also corresponding minimizing of obnoxious flavour.
The effect of water of the present invention is as " microexplosion explosive " for fried loose fuel molecule group, and under the effect of tourmalinite, water can also By Direct Pyrolysis be hydrogen-oxygen, to the oxygen supply of fuel hydrogenation.The effect of water can also with carbon generation water-gas reaction, decarbonizing.In the present invention, water is also as preferred catalyzer, and nucleus magnetic resonance delivery agent, strong nucleus magnetic resonance is there is during H atom in water is subject to, after far-infrared radiation, thus become the outstanding vibration source causing fuel kernel mr, therefore, expand water ratio in the product can strengthen its effect and reduce product cost.And the existence of tensio-active agent, the Homogeneous phase mixing of water and fuel can be promoted, help it to play best katalysis.
In fuel dope of the present invention, ethanol is as one containing oxygen biofuel, is mixed in fuel oil and burns, and can reduce the discharge of diesel particulation, reduce smoke intensity, namely reduces the discharge of diesel engine noxious pollutant.Antioxidant of the present invention can block, stop oxidation, plays shielding protection effect to fuel oil.Bio oil is enriched in china natural resources, have a extensive future, and the pollutant discharge amount of bio oil is low, has significant environmental benefit, meet the requirement of the strategy of sustainable development.Dispersion agent can adsorb the solid particulate matter in fuel oil, is scattered in oil, thus makes there is larger contact area between solid, liquid and fuel oil, makes to be heated more even.
Beneficial effect of the present invention is as follows:
1, with tourmalinite nano powder etc. for main functional component, have developed a kind of energy-saving fuel additive of Be very effective, effectively can improve oil inflame efficiency, reduce noxious gas emission, energy-conserving and environment-protective.
2, theoretical based on nucleus magnetic resonance, use water as nucleus magnetic resonance transmits additive, uniform atomizing before fuel oil is resonated, each component of complicated component resonates, and fuel oil lack of alignment becomes orderly, increases the surface-area that fuel droplet contacts with air, improves efficiency of combustion; The high-temperature vapor that water at high temperature microexplosion produces can also with carbon generation water-gas reaction, generate carbon monoxide and hydrogen, decarbonizing provide fuel and heat further simultaneously.
3, tourmalinite fuel oil additive the present invention prepared is applied in fuel activating device, has important use value and economic benefit.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
1, the preparation method of fuel oil additive of the present invention, comprises the following steps:
At normal temperatures and pressures, 50kg tourmalinite nano powder, 10kg dehydrated alcohol, 30kg diisopropyl ether, 10kg bio oil, 2kg sulphur phosphorus fourth pungent primary alkyl zinc salt, the two pungent primary alkyl zinc salt of 3kg sulphur phosphorus, 2kg low alkali value synthesized calcium alkyl benzene sulfonate, 3kg high base number linear alkyl benzene calcium alkylbenzenesulfonate, 5kg water are mixed, under 8000r/min, stir 10min, to obtain final product.
2, by 0.1% of fuel weight ratio above-mentioned obtained tourmalinite fuel oil additive directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 18.1%, reduces CO (carbon monoxide converter) emission 2.3%, reduces hydrocarbon emission amount 7.9%.
Embodiment 2
1, the preparation method of fuel oil additive of the present invention, comprises the following steps:
At normal temperatures and pressures, 60kg tourmalinite nano powder, 12kg dehydrated alcohol, 35kg diisopropyl ether, 12kg bio oil, the two pungent primary alkyl zinc salt of 2kg alkali formula sulphur phosphorus, the pungent secondary primary alkyl zinc salt of 2kg sulphur phosphorus third, 3kg sulphur phosphorus brothers alkyl zinc salt, 2kg long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, 3kg high base number synthesis dialkyl benzene sulfonic acids calcium, 3kg long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, 10kg water are mixed, under 9000r/min, stir 20min, to obtain final product.
2, by 0.1% of fuel weight ratio above-mentioned obtained tourmalinite fuel oil additive directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 21.0%, reduces CO (carbon monoxide converter) emission 2.5%, reduces hydrocarbon emission amount 9.0%.
Embodiment 3
1, the preparation method of fuel oil additive of the present invention, comprises the following steps:
At normal temperatures and pressures, 70kg tourmalinite nano powder, 15kg dehydrated alcohol, 40kg diisopropyl ether, 15kg bio oil, the two pungent primary alkyl zinc salt of 4kg alkali formula sulphur phosphorus, the pungent secondary primary alkyl zinc salt of 4kg sulphur phosphorus third, 3kg SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, 3kg polyisobutylene succinamide, 3kg boronation polyisobutylene succinamide, 20kg water are mixed, under 8000r/min, stir 30min, to obtain final product.
2, by 0.1% of fuel weight ratio above-mentioned obtained tourmalinite fuel oil additive directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 22.5%, reduces CO (carbon monoxide converter) emission 3.0%, reduces hydrocarbon emission amount 9.1%.
Embodiment 4
1, the preparation method of fuel oil additive of the present invention, comprises the following steps:
At normal temperatures and pressures, by in 80kg tourmalinite nano powder, 18kg dehydrated alcohol, 45kg diisopropyl ether, 18kg bio oil, the pungent primary alkyl zinc salt of 5kg sulphur phosphorus fourth, 5kg sulphur phosphorus brothers alkyl zinc salt, 2kg long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, 3kg high molecular weight polyisobutylene base succimide, 7kg boronation high molecular weight polyisobutylene base succimide, 25kg water mixes, under 10000r/min, stir 60min, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel oil additive directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 22.9%, reduces CO (carbon monoxide converter) emission 3.3%, reduces hydrocarbon emission amount 9.3%.
Embodiment 5
1, the preparation method of fuel oil additive of the present invention, comprises the following steps:
At normal temperatures and pressures, 65kg tourmalinite nano powder, 20kg dehydrated alcohol, 50kg diisopropyl ether, 20kg bio oil, the pungent primary alkyl zinc salt of 2kg sulphur phosphorus fourth, 8kg low alkali value synthesized calcium alkyl benzene sulfonate, 30kg water are mixed, under 12000r/min, stir 90min, to obtain final product.
2, by 0.1% of fuel weight ratio above-mentioned obtained tourmalinite fuel oil additive directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 20.7%, reduces CO (carbon monoxide converter) emission 2.1%, reduces hydrocarbon emission amount 8.8%.

Claims (6)

1. a fuel oil additive, it is characterized in that, be made up of the raw material comprising following weight part: tourmalinite nano powder 50 ~ 80 parts, dehydrated alcohol 10 ~ 20 parts, diisopropyl ether 30 ~ 50 parts, bio oil 10 ~ 20 parts, antioxidant 5 ~ 10 parts, dispersion agent 5 ~ 10 parts, 5 ~ 30 parts, water.
2. fuel oil additive as claimed in claim 1, is characterized in that: described antioxidant is the mixing of the one or more than one in sulphur phosphorus fourth pungent primary alkyl zinc salt, the two pungent primary alkyl zinc salt of sulphur phosphorus, the two pungent primary alkyl zinc salt of alkali formula sulphur phosphorus, the pungent secondary primary alkyl zinc salt of sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt.
3. fuel oil additive as claimed in claim 1, it is characterized in that: described dispersion agent is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutylene succinamide, high molecular weight polyisobutylene base succimide, one or more kinds of mixing in boronation high molecular weight polyisobutylene base succimide.
4. fuel oil additive as claimed in claim 1, is characterized in that: described water is pure water, mineral water or other clean waters.
5. fuel oil additive as claimed in claim 1, it is characterized in that: its preparation method is at normal temperatures and pressures, described tourmalinite nano powder, dehydrated alcohol, diisopropyl ether, bio oil, antioxidant, dispersion agent, water are mixed by weight ratio, stirs, to obtain final product.
6. fuel oil additive as claimed in claim 5, is characterized in that: described stirring velocity is 8000 ~ 12000r/min, churning time 10 ~ 90min.
CN201510643080.7A 2015-10-08 2015-10-08 A kind of fuel oil additive and preparation method thereof Active CN105296023B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147209A (en) * 2016-06-30 2016-11-23 蔡华君 Method that automobile energy-saving reduces discharging and the object of use and preparation method
CN106281498A (en) * 2016-08-18 2017-01-04 钟磊 A kind of gasoline additive
CN106281489A (en) * 2016-08-17 2017-01-04 丘寿勇 A kind of diesel fuel additives
CN108611135A (en) * 2018-04-17 2018-10-02 吉林市石化成润化工助剂有限公司 A kind of compound antioxygen scale inhibition anti-coagulants
CN109609215A (en) * 2019-01-04 2019-04-12 顺德职业技术学院 A kind of diesel motor exhaust purification additive and manufacturing method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020848A (en) * 2007-03-15 2007-08-22 暨南大学 Composite gasoline additive and its prepn
GB2438262A (en) * 2006-05-13 2007-11-21 John William Carson Reagent for surface calcination of minerals and ashes
CN101560419A (en) * 2008-04-19 2009-10-21 罗琮贵 Energy-saving and emission-reduction tourmaline additive
CN103980964A (en) * 2014-04-21 2014-08-13 丘寿勇 Preparation method of tourmalinite fuel oil activator
CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil
CN104232184A (en) * 2008-04-19 2014-12-24 罗琮贵 Tourmaline additive for saving energy and reducing emission

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2438262A (en) * 2006-05-13 2007-11-21 John William Carson Reagent for surface calcination of minerals and ashes
CN101020848A (en) * 2007-03-15 2007-08-22 暨南大学 Composite gasoline additive and its prepn
CN101560419A (en) * 2008-04-19 2009-10-21 罗琮贵 Energy-saving and emission-reduction tourmaline additive
CN104232184A (en) * 2008-04-19 2014-12-24 罗琮贵 Tourmaline additive for saving energy and reducing emission
CN103980964A (en) * 2014-04-21 2014-08-13 丘寿勇 Preparation method of tourmalinite fuel oil activator
CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147209A (en) * 2016-06-30 2016-11-23 蔡华君 Method that automobile energy-saving reduces discharging and the object of use and preparation method
CN106281489A (en) * 2016-08-17 2017-01-04 丘寿勇 A kind of diesel fuel additives
CN106281498A (en) * 2016-08-18 2017-01-04 钟磊 A kind of gasoline additive
CN108611135A (en) * 2018-04-17 2018-10-02 吉林市石化成润化工助剂有限公司 A kind of compound antioxygen scale inhibition anti-coagulants
CN109609215A (en) * 2019-01-04 2019-04-12 顺德职业技术学院 A kind of diesel motor exhaust purification additive and manufacturing method

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Address before: Lu Chuan County, the Guangxi Zhuang Autonomous Region City, Yulin Office of 537700 Street No. 23

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Application publication date: 20160203

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Denomination of invention: Fuel oil additive and its preparation

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