A kind of preparation method of fuel activating agent
Technical field
The present invention relates to the preparation method of energy-saving and emission-reduction fuel activating additive, be specifically related to a kind of preparation method of fuel activating agent.
Background technology
Energy-saving and emission-reduction are task of top priority of world today's energy scarcity, and the efficiency of combustion of fuel oil directly affects the effect of energy-saving and emission-reduction, and fuel activating agent can improve oil, promote fuel oil Thorough combustion, improve efficiency of combustion, save fuel oil; Its atomization quality can be improved, make fuel oil Thorough combustion reduce noxious gas emission, reach the object of energy-saving and emission-reduction.
In field of internal combustion engine, in order to improve fuel combustion efficiency, increase output rating, reduction oil consumption, decarbonizing minimizing noxious gas emission, mainly contain two technological approaches at present: one is add or reforming equipment (as various fuel-economizing, reinforcement, cleaner), two is drop into additive to fuel oil.The investment of first approach is large, program is loaded down with trivial details, also increase car and boat deadweight and maintenance difficulty, thus second approach more people accepted.But the fuel oil additive delivered at present exists one of following shortcoming or several mostly: one, save fuel oil, to promote the effect of power undesirable, what have also reduces dynamic performance, and this is current fuel oil additive can not be the generally accepted major cause of users; Two, obviously can not reduce engine noise, what have also add engine noise; Three, easily cause " secondary pollution "---the additive that-dependence chemical reaction works, while performance usefulness, public hazards thing that some have aroused attention or have not yet aroused attention, more difficult natural degradation may be generated, thus become the hidden danger of businessman and the public, such as famous additive MTBE (methyl tertiary butyl ether), after the U.S. passes unimpeded 20 years, be found it can increase oxynitride discharge, especially seriously can permanent polluted source (even deep phreatic water), be thus limited to use; Four, usefulness is unstable: because the component of fuel oil is very complicated, the same label fuel oil technique in process of production that different manufacturers is produced and added ingredients are different, the same label product of even same producer, raw material sources difference due to different batches also can cause the difference of product composition, formally because this uncertainty makes the additive mainly relying on chemical agent to work often can not stablize performance usefulness, and easily produce the adverse consequences such as " secondary pollution " and parts corrosion.
Current existing fuel oil octane promoter unit cost too high and use time addition excessive (being everlasting between 5 ~ 15%), cause octane promoter in high standard fuel price price ratio remain high.When current fuel price rises violently day by day, reduce the cost that one of effective way of fuel price is the additive greatly reduced for promoting gasoline label and diesel cetane-number.
Summary of the invention
Object of the present invention is exactly the defect existed to overcome above-mentioned prior art, and provide a kind of preparation method of fuel activating agent, fuel activating agent of the present invention can improve oil, promotes fuel oil Thorough combustion, improves efficiency of combustion, saves fuel oil; Its atomization quality can be improved, make fuel oil Thorough combustion reduce noxious gas emission, reach the object of energy-saving and emission-reduction.
In order to realize foregoing invention object, technical scheme of the present invention is as follows:
The preparation method of tourmalinite fuel activating of the present invention agent is by rare earth waste dopen Nano TiO
2, then with tourmalinite nano powder, spinel ferrite volume recombination, obtained solid mixture, then adds water, dispersion agent, tensio-active agent, forms solid-liquid mixed pulp; Described rare earth waste, nano-TiO
2, tourmaline mineral powder, ferrospinel mass ratio be 2 ~ 5:1 ~ 3:60 ~ 80:5 ~ 9; The input amount of water is 10 ~ 90% of mixed pulp; The input amount of dispersion agent is 2 ~ 10% of mixed pulp; The input amount of tensio-active agent is 5 ~ 28% of mixed pulp.
Described rare earth waste is the waste residue containing lanthanum, cerium or thorium.
Described ferrospinel is the one in Fe-Mn-Cu and Fe-Mn-Cu-Co ferrospinel.
Described water is pure water, mineral water or other clean waters.
Described dispersion agent is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutylene succinamide, high molecular weight polyisobutylene base succimide, one or more kinds of mixing in boronation high molecular weight polyisobutylene base succimide.
Described tensio-active agent is emulsifying agent or micro-emulsifier, is specially the one in Sodium dodecylbenzene sulfonate, cocinic acid alkylolamide, mono-glycerides, class of department 80.
The preparation method of described fuel activating agent, comprises the following steps:
(1) by TiO
2, tourmaline mineral powder, ferrospinel be polished into nanoscale powder respectively, in proportion tourmaline mineral powder and ferrospinel are mixed, sinter in reducing atmosphere, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, at rare earth mixing with nano TiO
2add solid mixture A in proportion in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) water, dispersion agent, surfactant are mixed in proportion, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
Described sintering temperature is 500 ~ 600 DEG C, and sintering time is 1 ~ 3 hour.
Fuel activating agent of the present invention has strong characteristic nmr, nucleus magnetic resonance makes the molecule containing H atom in fuel be provided with positive and negative electrode feature, molecular arrangement becomes uniform from confusing, the conductivity of fuel is strengthened greatly, and thus the ability of unified ignition, synchronousing combustion is enhanced.Two factors are all impelled fuel synchronously to break out, are carried out simultaneously, and the inevitable outcome of so expecting synchronous outburst is that pinking is eliminated, and pinking eliminates, and the in-fighting problem of engine also just solves.Equal the useful work adding 30%, that is reduce by the fuel consumption of 30%.Visible, tourmalinite composition strengthens the energy-saving effect of additive greatly, and the consumption of fuel declines, the quantity discharged also corresponding minimizing of obnoxious flavour.
Titanium dioxide is that a kind of oxidation capacity is strong, stable chemical nature and nontoxic photocatalyst, be entrained in rare earth element with tourmalinite, spinel compound, there is stronger generation free radical and the ability of negative ion, TiO
2doping can significantly improve the infrared emittance of spinel, meanwhile, through TiO
2spinel after doping can obviously reduce bavin oil surface tension and viscosity.
The interpolation of water is as " microexplosion explosive " for fried loose fuel molecule group, and under the effect of tourmalinite, water can also By Direct Pyrolysis be hydrogen-oxygen, to the oxygen supply of fuel hydrogenation.The effect of water can also with carbon generation water-gas reaction, decarbonizing.In the present invention, water is also as preferred catalyzer, and nucleus magnetic resonance delivery agent, strong nucleus magnetic resonance is there is during H atom in water is subject to, after far-infrared radiation, thus become the outstanding vibration source causing fuel kernel mr, therefore, expand water ratio in the product can strengthen its effect and reduce product cost.And the existence of tensio-active agent, the Homogeneous phase mixing of water and fuel can be promoted, help it to play best katalysis.
Dispersion agent can adsorb the solid particulate matter in fuel oil, is scattered in oil, thus makes there is larger contact area between solid, liquid and fuel oil, makes to be heated more even.
Beneficial effect of the present invention is as follows:
1, with tourmalinite nano powder etc. for main functional component, have developed a kind of energy-saving fuel activator of Be very effective, effectively can improve oil inflame efficiency, reduce noxious gas emission, energy-conserving and environment-protective.
2, by ferrospinel and tourmalinite Material cladding, the shortcoming that after compensate for tourmalinite material poor heat stability, high-temperature heat treatment, low band (3 ~ 5 μm) infrared emittance reduces.
3, theoretical based on nucleus magnetic resonance, use water as nucleus magnetic resonance transmits activator, uniform atomizing before fuel oil is resonated, each component of complicated component resonates, and fuel oil lack of alignment becomes orderly, increases the surface-area that fuel droplet contacts with air, improves efficiency of combustion; The high-temperature vapor that water at high temperature microexplosion produces can also with carbon generation water-gas reaction, generate carbon monoxide and hydrogen, decarbonizing provide fuel and heat further simultaneously.
4, tourmalinite fuel activating agent the present invention prepared is applied in fuel activating device, has important use value and economic benefit.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
1, the preparation method of fuel activating agent of the present invention, comprises the following steps:
(1) by 1kgTiO
2, 60kg tourmaline mineral powder, 5kgFe-Mn-Cu ferrospinel be polished into nanoscale powder respectively, tourmaline mineral powder and ferrospinel are mixed, in reducing atmosphere, carry out sintering 1 hour at 500 DEG C, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, rare earth waste is for containing lanthanum waste residue, and quality is 2kg, at rare earth mixing with nano TiO
2add solid mixture A in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) Sodium dodecylbenzene sulfonate of the water of 7kg, 0.4kg low alkali value synthesized calcium alkyl benzene sulfonate, 1kg high base number linear alkyl benzene calcium alkylbenzenesulfonate, 4kg is mixed, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel activating agent directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 18.0%, reduces CO (carbon monoxide converter) emission 2.5%, reduces hydrocarbon emission amount 7.8%.
Embodiment 2
1, the preparation method of fuel activating agent of the present invention, comprises the following steps:
(1) by 2kgTiO
2, 70kg tourmaline mineral powder, 7kgFe-Mn-Cu-Co ferrospinel be polished into nanoscale powder respectively, tourmaline mineral powder and ferrospinel are mixed, in reducing atmosphere, carry out sintering 1.5 hours at 520 DEG C, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, rare earth waste is for containing cerium waste residue, and quality is 3kg, at rare earth mixing with nano TiO
2add solid mixture A in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) water of 40kg, 1kg high base number synthesis dialkyl benzene sulfonic acids calcium, 1kg long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, 1kg SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, the cocinic acid alkylolamide of 4kg, class of 4kg department 80 are mixed, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel activating agent directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 21.5%, reduces CO (carbon monoxide converter) emission 2.7%, reduces hydrocarbon emission amount 9.1%.
Embodiment 3
1, the preparation method of fuel activating agent of the present invention, comprises the following steps:
(1) by 3kgTiO
2, 80kg tourmaline mineral powder, 9kgFe-Mn-Cu ferrospinel be polished into nanoscale powder respectively, tourmaline mineral powder and ferrospinel are mixed, in reducing atmosphere, carry out sintering 2 hours at 560 DEG C, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, rare earth waste is thoriated waste residue, and quality is 5kg, at rare earth mixing with nano TiO
2add solid mixture A in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) mono-glycerides of the boronation high molecular weight polyisobutylene base succimide of the high molecular weight polyisobutylene base succimide of the boronation polyisobutylene succinamide of the polyisobutylene succinamide of the water of 80kg, 5kg, 5kg, 5kg, 5kg, 25kg is mixed, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel activating agent directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 24.0%, reduces CO (carbon monoxide converter) emission 3.2%, reduces hydrocarbon emission amount 9.6%.
Embodiment 4
1, the preparation method of fuel activating agent of the present invention, comprises the following steps:
(1) by 3kgTiO
2, 70kg tourmaline mineral powder, 8kgFe-Mn-Cu ferrospinel be polished into nanoscale powder respectively, tourmaline mineral powder and ferrospinel are mixed, in reducing atmosphere, carry out sintering 2.5 hours at 580 DEG C, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, rare earth waste is for containing lanthanum waste residue, and quality is 3.5kg, at rare earth mixing with nano TiO
2add solid mixture A in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) the boronation high molecular weight polyisobutylene base succimide of the high molecular weight polyisobutylene base succimide of the water of 76kg, 3kg, 4kg, the Sodium dodecylbenzene sulfonate of 6kg, the cocinic acid alkylolamide of 6kg, the class of department 80 of 5kg are mixed, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel activating agent directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 22.9%, reduces CO (carbon monoxide converter) emission 3.3%, reduces hydrocarbon emission amount 9.3%.
Embodiment 5
1, the preparation method of fuel activating agent of the present invention, comprises the following steps:
(1) by 2kgTiO
2, 65kg tourmaline mineral powder, 6kgFe-Mn-Cu ferrospinel be polished into nanoscale powder respectively, tourmaline mineral powder and ferrospinel are mixed, in reducing atmosphere, carry out sintering 3 hours at 600 DEG C, obtain solid mixture A;
(2) sol-gel method is adopted to prepare rare earth mixing with nano TiO
2colloidal sol, rare earth waste is thoriated waste residue, and quality is 4kg, at rare earth mixing with nano TiO
2add solid mixture A in colloidal sol, stir, leave standstill and obtain gel, then obtain mixture B through super-dry, calcining;
(3) mono-glycerides of the high molecular weight polyisobutylene base succimide of the long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate boronation polyisobutylene succinamide of the high base number linear alkyl benzene calcium alkylbenzenesulfonate of the water of 23kg, 2kg, 2kg, 2kg, 20kg is mixed, stir, obtain mixed solution C;
(4) the mixture B in step (2) is dropped in the mixed solution C in step (3), stir and make it to disperse completely, to obtain final product.
2, by 0.02% of fuel weight ratio above-mentioned obtained tourmalinite fuel activating agent directly added in vehicle fuel activator and use.
3, test shows: car often row 100 kilometers can save gasoline 21.7%, reduces CO (carbon monoxide converter) emission 2.2%, reduces hydrocarbon emission amount 9.1%.